JPS59179614A - Metal atom-containing resoles - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

DETAILED DESCRIPTION OF THE INVENTION BACKGROUND OF THE INVENTION The present invention relates to resols containing 7 or more metal atoms in the polymer chain.

pre-impregnated resin (relmpregnatlon resi)
n) is a carbon/carbon combination (Carbon/C
arbon Composite) is a thermosetting aggregate that is introduced as a liquid. The resin is then cured and heat treated, thus increasing the overall density of the composite.

The selected polymer will impart specific desired properties to the composite depending on the end use. To make re-impregnation a viable option, the fat must be kept at an unduly low viscosity during the impregnation process, and also has a relatively high char yield.
You have to demonstrate.

Robert C., U.S. Patent No. 11.7
g! , No. 0'lJ discloses thermoplastic and thermoset polymers that bind gold nugget atoms of W and/or Mo. The gold nugget atoms are R into a polymer by reacting a monomer or polymer containing at least 7 free carboxyl radicals with the reaction product of tungsten or molybdenum carbonyl and pyroliso/ to form a compound.
-To match. It is disclosed that Okiitai is used as a ladle-containing cleansing resin.

Known as resols, the thermosetting phenolic side fats that react with base metals are UJ1, which is a metal atom that is more selective than the group consisting of tungsten and/or zirconium. It has now been discovered that it can be improved by bonding one or more phenolic resins to one or more of them.Such heat-like, high-quality phenolic resins can be combined with resole total zirconyl acetate, 4!L # or It is produced by reacting with tungsten carbonyl/pyrrolisif anti-Lt5 cow drink.The metal is attached to the main button of one unit, and scientifically one unit is 7'L.

This combination shows improved heat-reducing properties, and the carbide (char) of fL has an improved thermal agility that makes them similar to carbon/charcoal mixtures. Extract.

The thermosetting modified resol resin of the present invention is a viscous solid at room temperature, but becomes extremely low in viscosity as the temperature rises. The basic structural unit of one of these compounds is produced by the reaction of hydroxybenzenes and formaldehyde in the presence of a base. The gold column precursor can be used as both a linking agent and a crosslinking agent without significantly changing the basic properties of the phenolic resin.

The resols used in the practice of this invention are well known. It is obtained by reacting phenol with an aldehyde such as formaldehyde using an alkali catalyst. Resoles are also known as A-stage #LI fats. Regarding the controversy regarding resols, Gol(i
lng, D., Van NostrandCompa.
ny Inc,, POIVmer'5 And Re
5lns 13g, pages 211.5-2119 (7957), the description of which is incorporated herein by reference. Resoles can be produced with di- or di-hydroxybenzene and formaldehyde.

Zirconyl acetate added to the first resin - 1. The city of Shio Rie is θ ~ / The leopard that makes the zirconium of Otsu9 (1 purpose): It can be changed by such means.

Ushio, the capital of boric acid that is added to the initial resin; I platform 0-7
In the 96 boron-11 arsenic compound, /f=! You can become rich by borrowing all your resources. Glycerol of up to /5 light (l) is added to this resin to completely improve casting properties.
Add f.

The tungsten carbonyl/pyrrolidine reaction product, which has an initial fA of 8% and an addition of 0.zeta., can be modified in such a way that it can contain, for example, from -0 to 20% tungsten. The reaction between tungsten carbinyl, pyrrolidine, and
Group VI Meta
l CarbonylsWlth Pyrroll
lne, Plperazine and Morph
It can be carried out by one of the several methods described and described in "Reaction of Group II Kinki Carbonyl with Pyrrolidine, Bibenzine, and Serforin". The beef sumata is ground into fine powder for the subsequent reaction.The reaction product of vilorisone-tungsten carbonyl is tange
It is believed that there is at least 2 moles of pyrrolison per mole of pyrolison.

♀Genitive 1. The metallurgy in the IL/non-ruol range can be varied by increasing or decreasing the strength of the resol used in the reaction with zirconyl acetate, boric acid or tungsten carbonyl/pyrrolidine reaction product. The zirconyl acetate, arll, or tungsten carbonyl/pyrrolidine reaction product is prepared by mixing the resol and one material, and the reaction mixture preferably contains about 100 to 2
The reaction is carried out by heating for about 2 to 2 hours at 00''C.
The ratio of body to resol varies widely depending on the amount of metal desired in the final product.

and 71 et al.'s Kama Genus 1/Zol class, any B
It can be combined with other things in the desired ratio, and
It is possible to bond the BE molded polymer to the metal in a wide range of ratios. The only limiting factor is the maximum metal size in the primary cormorant fishing fat.

Main trunk, Jinjima of Ming Dynasty, including runur h,: Fl ((14(
7) Junkan, 簀ｲｲｲｲyori charcoal＠', / tm, 1 to 1 to 1 to 1 for re-impregnation of elementary nucleus union - seems to be a local person by ax! σ
), press the button and press the button with a yield of 7 shots. These people (
Shirazuki 1・rj1 Sumai or Kurotoge Jiban, and @O8 shooting (
7 and shows the dramatic behavior that makes oneself Jσ fif, -t・ru.

Because of the invention σ + 屡hs, the body is 16 years old, and the corrosion resistance is high! The edible product is defined by the industry name (C1 round 1 sho 1σ
) The number of bodies in the river was 4. Glaze with 1 rice, 1 sacrificial W4 ko, 9/, '7A/: Sin 62. OtsuΩri, Otsurig; 3rd, 2nd Otsuko, 7 Otsu/Issuing Garano Hitsumugi as shown in W, Ushisumata'fc commercial silica h/adhesive T4 material or C1''i Cotton, rayon, 1rjl, Yogin I, and other conditions, such as λb 1 rice bag 1 d sheep 3,29 ri, g9 υ;, 1 as shown. θ-decomposes and crosses, and mosquito heat-sensitivity is ten thousand (-yu) σ) (7 Imperial colors '杢槓(11!, + name-soaked n, zo) (/+ b h'-r p , 24.7~
3037. The clear part mζt'L is the minor fourth of g''C (goθ~tataθOF').

The 6th generation was created under the direction of Tami η and Ding Wangyo.

It possesses bean paste and lya', and has all the characteristics of improved melting properties, heat retention, and corrosion resistance, which can be seen as pyrolytic urine.

The impregnable fiber material can be used to form entire molded parts, such as rocket conical nozzles and arrester conical heads. The presence of wire mesh atoms in resin produces a dense material that enables the material to absorb the energy of the energy and generally produces improved eating properties.

The pine-containing composites of the present invention can also be used to form films, coatings or cast articles 11. They can also be used in combination with conventional additives such as film-forming luborimers, fillers, etc. which are compatible with -f':n, etc. The gold-containing polymer d-(:D,I) was then treated at a graphitization temperature, and the resulting H material was crushed to improve the energy-absorbing properties of the metal-goldstone 1 coalescence. The 4'ili fat provides particles that can be used as a filler in elastomers.

Is the next 7I'+1+11 the invention? It represents the best mode for implementation.

Example g096 vinegar'gθ heavy part of data 60 jjiaibe's zirconyl acetate and lIOru\'old i3σ):
r Ta / - / I / containing Ij1 ゛ force 0 brewing liquid, Otsu, 0 voice is % /3 /, 0 blade r % > HB phenol 1 / Sole base / containing In the end; I jl;, resin reaction kettle (final addition - resol is /, smol C) forno\aldehyde,! It is produced from Ni /, 0 mo, L σ no phenol, and this m combination ■lid, light minute W, 伜 stirred 7
Heat to 77°C for 3θ minutes [V13 or higher. Add l'l resin to this foam-resistant amber product: mJ 1-r
2.1f 0 tons 1S zomethylformamide 1 '1' 2 again. It is possible to heat a raw plate i-, J, /otsu 1-rudo at θ℃ within λ hours.

Oka i 1yIfs/evening, 0-fold t5'section's wisdom (・(Implemented 11/1Δ・
Beta, OM-1% and 1 g7.0 knowledge 8 of the total addition of phenol resol, this σ) mixture sound (k matter 1-
Heat to 0°C for 2 iρ・ra/hour or more. Like this V
(If you were born, you would be able to see the bright and clean face of the cow.彪4ψsum.The living thing is
It can be thermally cured at 200″C within 11Jj at λθ.

Example 3 1 mole of tungsten hexacarvinyl was reacted with excess pyrrolidine to produce a ψ group pyrrolidine complex,
At the end of the reaction, the product is washed and ground to a fine powder. This complex is the same as mentioned in ON Okibe and implementation 9'll/.
Phenol resol 73.3 parts v with θ% solids
The compound is heated to 0℃ in a completely open resin reaction pot for 1 yen per hour! Add the above p-f. The raw, clear brown resin is Ir1. Solvate with methylformamide from 6 to 6 methylformamide. This product can be heat cured at 200° C. within 20 hours.

The following example shows the copolymerization of three all-containing resins made in Example 1.

EXAMPLE The open willow fat and the reaction pot were prepared as described in Example 1-[
Zirconium phenolic resin coated with 0. ON deaf section, carried out as described in Example 2.
0.0 part by weight is mixed and the solution is constantly stirred for at least 20 minutes at a temperature of t/O<0>C. Continue stirring throughout;
A total of 601 da parts of dimethylformamide is added for further solvation. The solution is heated for / θ minutes or more / 2
The resin can be heat cured at 760°C within 77 hours.

Claims (1)

[Scope of Claims] (11) A thermoplastic material containing 7 or more (2') chemically bonded metal group atoms selected from the group consisting of (11) boron atoms, tungsten atoms and/or zirconium atoms. Curable resol. (Claim No. 21 Containing chemically bonded boron atoms (thermosetting resol described in Clause 11). (3) Claim No. 1 containing chemically bonded tungsten atoms ( Thermosetting resol according to claim 11. (4) Thermosetting resol according to claim 11 containing chemically bonded zirconium atoms. (5) Thermosetting resol containing chemically bonded zirconium atoms. (6) The thermosetting resol according to claim 11. (6) The resol contains zirconyl acetate, 4M acid, and tungsten carbonyl/pyrrole. Taken by reacting with a reaction product / (II!+
A method for producing a thermosetting resol containing one or more chemically bonded boron, tungsten and/or zirconium atoms. (7; Claim No. 61, in which the resol is reacted with zirconyl acetate. (8) Claim No. 61, in which the resol is reacted with the rim. (9) Resol. The method described in Paragraph 61 of Hayabusa 1 for the purpose of reacting a tungsten carbonyl/pyrrolisine reaction product with a tungsten carbonyl/pyrrolisine reaction product.
A chemical composition consisting of reacting together a chemical resol, a thermosetting resol containing chemically bonded tungsten atoms, and a thermosetting resol containing chemically bonded zirconium atoms. Formation method of thermosetting resol containing 7 bonded boron atoms, tungsten atoms, and zirconium atoms.