JPS59177547A - Method and device for thermodevelopment and transfer - Google Patents

Method and device for thermodevelopment and transfer

Info

Publication number
JPS59177547A
JPS59177547A JP5473883A JP5473883A JPS59177547A JP S59177547 A JPS59177547 A JP S59177547A JP 5473883 A JP5473883 A JP 5473883A JP 5473883 A JP5473883 A JP 5473883A JP S59177547 A JPS59177547 A JP S59177547A
Authority
JP
Japan
Prior art keywords
layer
image
dye
heat
photosensitive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP5473883A
Other languages
Japanese (ja)
Other versions
JPH0362251B2 (en
Inventor
Isamu Hatanaka
畑中 勇
Yasumitsu Takehara
竹原 庸光
Kazuhiko Yanagihara
柳原 和彦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujifilm Holdings Corp
Original Assignee
Fuji Photo Film Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Photo Film Co Ltd filed Critical Fuji Photo Film Co Ltd
Priority to JP5473883A priority Critical patent/JPS59177547A/en
Publication of JPS59177547A publication Critical patent/JPS59177547A/en
Publication of JPH0362251B2 publication Critical patent/JPH0362251B2/ja
Granted legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C8/00Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
    • G03C8/40Development by heat ; Photo-thermographic processes
    • G03C8/4013Development by heat ; Photo-thermographic processes using photothermographic silver salt systems, e.g. dry silver
    • G03C8/4093Development by heat ; Photo-thermographic processes using photothermographic silver salt systems, e.g. dry silver characterised by the apparatus used

Abstract

PURPOSE:To improve efficiency in thermodevelopment and transfer by obtg. a color image by using a thermodeveloping photosensitive material having a photosensitive layer which releases a mobile hydrophilic dye from an exposed or non-exposed part when heated and a conductive exothermic layer and an image receiving material having a dye fixing layer. CONSTITUTION:Light is irradiated to an original O of a transmission type in an exposing stage 19, and the image of the original is formed on the photosensitive layer of a thermodeveloping photosensitive material. The thermodeveloping photosensitive material is then loaded on a developing stage 20, and a voltage is impressed on rollers 2B and 3B, then a conductive exothermic layer generates heat, by which the photosensitive layer is heated and a mobile hydrophilic dye is released like an image. An image receiving material 21 is inserted into a roller pair 3 and roller pairs 2-4 are driven; at the same time, water is supplied and the thermodeveloping photosensitive material and the image receiving material are superposed while water is uniformly interposed between the same. Both materials are fed to a transfer stage 22. When electricity is conducted to the rollers 3B, 4B, the conductive exothermic layer generates heat, by which the dye fixing layer is heated and the hydrophilic dye released into the dye fixing layer on the image receiving material is moved and is transferred as a color image. The conductive exothermic layer is thus economized.

Description

【発明の詳細な説明】 本発明は熱現像転写方法および装置に係り、特に、加熱
により露光部分あるいは非露光部分から可動性の親水性
色素全放出する感光層および導電発熱層を有する熱現像
感光材料と、色素固定層を有する受像材料を用いてカラ
ー画像−fc得る新しい熱現像転写方法とこの方法を実
施すゐための装置に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a thermal development transfer method and apparatus, and more particularly, to a thermal development photosensitive material having a photosensitive layer and a conductive heating layer that release all of a mobile hydrophilic dye from exposed or non-exposed areas when heated. The present invention relates to a new thermal development transfer method for obtaining a color image-fc using an image-receiving material having a dye-fixing layer, and an apparatus for carrying out this method.

本発明に用いることができる熱現像感光材料としては、
例えは特願昭jt−/3777r号明細書に記載さ几て
いるように、少なくとも感光性ハロゲン化銀、有機銀塩
酸化剤、バインダー、並びに感光性ハロゲン化銀および
/または有機銀塩酸化剤に対して還元性でありかつ感光
性ハロゲン化銀および7才たは有機銀塩酸化剤と加熱に
より反応して可動性の収水性色素を放出する色素供与性
物質を有する感光層を、電極からの通電により発熱して
上記感光層全加熱する導電発熱層とともに有する熱現像
感光材料を挙けることができる。このような熱現像感光
材料は、1而像露光後に熱現像を行なうたけで、露光部
分に銀画像とその銀画像に対応する部分において収水性
色素とを同時に与えろことができる。すなわち、この熱
現像感光材料を画像露光し、こn−全加熱すると露光さ
れた感光性ハロゲン化銀を触媒として有機銀塩酸化剤と
還元性の色素供与性物質の間で酸化ム(光反応が起こり
、露光部に銀画像が生ずる。このステップにおいて色素
供与性物質は、有機銀塩酸化剤により酸化さfL、酸化
体となめ。この酸化体は色素放出助剤の存在下で開裂し
、その結果可動性の収水性色素が放出さ才りゐ。し罠が
って、露光部分においては銀画像と可動性の収水性色素
が得ら庇、との収水性色素を受像材料に転与することに
よりカラー画像が得られるのである。そして、感光層と
してオートポジ乳剤を用いた場合には、未露光部に銀画
像と可動性の親水性色素とが得られることになる。
The heat-developable photosensitive materials that can be used in the present invention include:
For example, as described in Japanese Patent Application No. Shojt-/3777R, at least a photosensitive silver halide, an organic silver salt oxidizing agent, a binder, and a photosensitive silver halide and/or an organic silver salt oxidizing agent. A photosensitive layer containing a dye-donating substance that is reducible to photosensitive silver halide and a dye-donating substance that reacts with a photosensitive silver halide or an organic silver salt oxidizing agent upon heating to release a mobile water-absorbing dye is transferred from an electrode. Examples include heat-developable photosensitive materials having a conductive heat-generating layer that generates heat when energized to completely heat the photosensitive layer. Such a heat-developable photosensitive material can simultaneously provide a silver image in the exposed area and a water-absorbing dye in the area corresponding to the silver image by performing thermal development after one image exposure. That is, when this heat-developable photosensitive material is imagewise exposed and then completely heated, an oxidation film (photoreaction) occurs between an organic silver salt oxidizing agent and a reducing dye-donating substance using the exposed photosensitive silver halide as a catalyst. occurs, producing a silver image in the exposed area. In this step, the dye-donating substance is oxidized by an organic silver salt oxidizing agent fL, and the oxidant is oxidized. This oxidant is cleaved in the presence of a dye-releasing aid. As a result, a mobile water-absorbing dye is released.As a result, a silver image and a mobile water-absorbing dye are obtained in the exposed area, and the water-absorbing dye is transferred to the image-receiving material. By doing this, a color image is obtained.If an autopositive emulsion is used as the photosensitive layer, a silver image and a mobile hydrophilic dye are obtained in the unexposed areas.

また、別の熱現像感光材料としては、例えば本発明の出
願人が昭和sr年λり/♂日に出願した特願昭、fl−
,2t00♂号「画像形成方法」の明細書に記載さ扛て
いるように、少なくとも感光性ハロゲン化銀、バインダ
ー、並びに還元性であジ加熱により色素を放出し感光性
)・ロケン化銀と刃口熱により反応して親水性色素を放
出しなくなる不動性の色素供与性物質(i:有する感光
層を、電極からの通電により発熱して上記感光層を加熱
する導電発熱層とともに有する熱現像感光材料を挙げる
ことができる。このような熱現像感光材料は、画像露光
後に熱現像を行なうだけで、露光部分に銀画像とその銀
画像に対応する部分以外において可動性の収水性色素と
全同時に与えることができる。
Further, as another heat-developable photosensitive material, for example, a patent application filed by the applicant of the present invention on
, No. 2t00♂, "Image Forming Method", at least photosensitive silver halide, a binder, and silver rokenide which is reducible and releases a dye by di-heating (photosensitive). A thermal developable material having a photosensitive layer having an immobile dye-donating substance (i) that does not react with heat from the edge of the blade and release a hydrophilic dye, together with a conductive heat generating layer that heats the photosensitive layer by generating heat when electricity is applied from an electrode. An example of such a photothermographic material is a heat-developable photosensitive material, which simply undergoes heat development after image exposure to form a silver image in the exposed area and a movable water-absorbing dye in the area other than the area corresponding to the silver image. Can be given at the same time.

すなわち、もともと親水性色素全放出するが、酸化され
ることによって親水性色素の放出を起こさなくなる不動
性の色素供与性物質を用いる場合、この熱現像感光材料
全画像何党し、これを加熱すると露光さT″Lだ感光性
ハロゲン化@全触媒として有機銀塩酸化剤および/また
は感光性ハロゲン化銀と還元性のもともと親水性色素全
放出するが酸化さ几ることによって収水性色素の放出奮
起こさなくなる不動性の色素供与性物質との間で酸化還
元反応が起こり、露光部に銀画像が生じる。このステッ
プにおいて、もともと収水性色素を放出するが酸化さ几
ることによって親水性色素の放出を起こさなくなる不動
性の色素供与性物質は酸化体となり、その結果露光部に
お込て収水性色素が放出されなくなり、未露光部におい
ての不可剛性の親水性色素が得られる。この親水性色素
を受像材料に転写することによりカラー画像が得られる
のである。そして、感光層としてオートポジ乳剤を用い
た場合には、未露光部に@1IiIl像が、露光部に可
動性色素が得らnることになる。
That is, when using an immobile dye-providing substance that originally releases all of the hydrophilic dye, but no longer releases the hydrophilic dye when oxidized, how many images of the entire image of this heat-developable photosensitive material is produced, and when heated? When exposed to light, the photosensitive halogenated @ total catalyst is an organic silver salt as an oxidizing agent and/or a photosensitive silver halide and the reducing originally hydrophilic dye is completely released, but the oxidation process releases the water-absorbing dye. An oxidation-reduction reaction occurs between the immobile dye-donor and the immobile dye-donating substance, producing a silver image in the exposed area.In this step, the water-absorbing dye is originally released, but as it oxidizes, the hydrophilic dye is released. The immobile dye-donating substance that no longer releases becomes an oxidant, and as a result, the water-absorbing dye in the exposed area is no longer released, resulting in a non-rigid hydrophilic dye in the unexposed area. A color image is obtained by transferring the dye to the image-receiving material.When an autopositive emulsion is used as the photosensitive layer, an @1IiIl image is obtained in the unexposed area and a mobile dye is obtained in the exposed area. That will happen.

導電発熱層は、カーホン、チタン、酸化チタン等の導電
性材料の粉末をボールミル等を用いて微粉末にし、こ′
nをゼラチン水溶液やPVA水溶液に混合して熱現像感
光材料の支持体に塗布し乾燥して得られる。この導電発
熱層は感光層を塗布する前に施されていてもよいし、後
から施されてもよい。ま1こ、導電発熱体フィルムを熱
現像感光材料の支持体に貼合わせてもよいし、導電発熱
体フィルムそれ自体を熱現像感光材料の支持体としても
よめ。そして、4電発熱体層は熱現像感光材料の裏面に
施さnるのが好筐しいが、支持体と感光層との間に施さ
れていても工い。さらに、感光層となる乳剤の中に導電
性材料の微粉末を混入するなとして、感光Mjと導電発
熱層とt兼ねるようにしてもよい。また、導電発熱層に
は導電発熱体のみならず写真性や物理性に有用なその他
の物質全含有させておいてもよい。
The conductive heating layer is made by grinding conductive material powder such as carphone, titanium, titanium oxide, etc. into fine powder using a ball mill or the like.
It can be obtained by mixing n with an aqueous gelatin solution or an aqueous PVA solution, applying the mixture to a support of a heat-developable photosensitive material, and drying the mixture. This conductive heating layer may be applied before or after coating the photosensitive layer. Alternatively, the conductive heating element film may be laminated to the support of the photothermographic material, or the conductive heating element film itself may be used as the support of the photothermographic material. It is preferable that the four-electroelectric heating layer be applied to the back side of the photothermographic material, but it may also be applied between the support and the photosensitive layer. Further, by not mixing fine powder of a conductive material into the emulsion forming the photosensitive layer, the emulsion may serve both as the photosensitive layer Mj and the conductive heating layer t. Further, the conductive heating layer may contain not only the conductive heating element but also all other substances useful for photographic properties and physical properties.

本発明に用いることができる受像材料eユ、熱現像感光
材料から加熱現像により放出さ几る色素を受けとめるこ
とのできる受像NIIt:支持体上に形成したものであ
る。この受像層は例えば色票媒染剤なとの色素固定剤を
含み、この色素固定剤は放出さ71.る色素の物性、熱
現像感光材料に含まれるその他の成分、転写条件などに
よシ有用なもの全選択して用いることができる。例えば
特願昭jJ−/!77りざ細密雑書に記載されているも
ののように、高分子量のポリマー媒染剤を用いることが
できる。
The image-receiving material (e) that can be used in the present invention is formed on an image-receiving material (NIIt): a support that can receive the dye released from the heat-developable photosensitive material by heat development. The image-receiving layer contains a dye fixing agent, such as a color patch mordant, which is released 71. All useful dyes can be selected and used depending on the physical properties of the dye, other components contained in the photothermographic material, transfer conditions, etc. For example, Tokugan ShojJ-/! High molecular weight polymeric mordants can be used, such as those described in 77 Riza Specifications.

本発明の目的は、上述しπよう/2:熱′fA像感光感
光材料像材料とを用いて、熱現像転写をよりよく行なう
ための方法とその方法を実施するための装置全提供する
ことである。
The object of the present invention is to provide a method for better performing thermal development transfer using the above-mentioned π/2:thermal 'fA image-sensitive photosensitive material and an entire apparatus for carrying out the method. It is.

本発明は上記目的金達゛成するためになさ′i′Lだも
ので、その方法は、加熱によりM先部分あるいは非露光
部分から可動性の親水性色票全放出する感光層および導
電発熱層を有す6熱現像感光材料の前記感光層に画像様
の露光?し、前記感光層に画像様の露光がなきれグこ熱
現像感光材料の前記導電発熱層に通電し加熱−f′ゐこ
とによって前記感光層に可動性の親水性色素を画像状に
形成し、しかる後、色索固に層を有する受像材料に前記
熱現像感光材料をそnぞれ前記色素固定層とhiJ記感
光感光層向す合わせて重ね合わせ、前記受像材料と重ね
合わせられた前記熱現像感光材料の導電発熱層に通電し
加艦することによって前記画像状に形成した親水性色素
を前記色素固定層へ移動させ、しかる後、前記受像材料
全前記熱現像感光材料から剥離することによって前記受
像材料にカラー画像を得ること全特徴とする熱現像転写
方法である。そしてその装置は、加熱により露光部分あ
るいは非露光部分から可動性の親水性色素?放出丁ゐ感
光層Pよび導電発熱層奮有する熱現像感光材料の前記感
光層に画像様の露光がなさ7′Lだ前記熱現像感光材料
を支持し前記導電発熱層に通電する第一の電極と、前記
第一の電極での前記導電発熱ノーへの通電により加熱さ
れて前記感光層に可動性の親水性色素全画像状に形成さ
れた熱現像感光材料と色素固定贋金4する受像材料とt
重ね合わせる重ね合わせ手段と、前記重ね合わせ手段に
て重ね合わせら几た前記熱現像感光材料および前記受像
材料を支持し前記導電発熱層に通電する鵠二の電極とか
らなることヶ特徴とする熱現像転写装置である。
The present invention has been made to achieve the above-mentioned object, and the method includes a photosensitive layer that releases all of the movable hydrophilic color particles from the M tip part or the non-exposed part by heating, and conductive heat generation. Imagewise exposure of the photosensitive layer of a heat-developable photosensitive material having 6 layers? If the photosensitive layer is not exposed to light in an imagewise manner, the conductive heat-generating layer of the heat-developable photosensitive material is energized and heated -f' to form a movable hydrophilic dye in the form of an image on the photosensitive layer. Thereafter, the heat-developable photosensitive material is stacked face-to-face with the dye-fixing layer and the photosensitive layer on the image-receiving material having a color fixing layer, and the photothermographic material layered with the image-receiving material is layered. Transferring the hydrophilic dye formed in the image form to the dye fixing layer by applying electricity to the conductive heating layer of the photothermographic material, and then peeling off the entire image-receiving material from the photothermographic material. This is a heat development transfer method characterized in that a color image is obtained on the image-receiving material by the method. Is the device a hydrophilic dye that can be moved from exposed or unexposed areas by heating? A first electrode that supports the heat-developable photosensitive material and conducts electricity to the conductive heat-generating layer, in which the photosensitive layer of the heat-developable photosensitive material comprising an emitting photosensitive layer P and a conductive heat-generating layer is not imagewise exposed. and a heat-developable photosensitive material which is heated by applying electricity to the conductive heat generating node at the first electrode to form an entire image of a movable hydrophilic dye on the photosensitive layer, and an image-receiving material in which the dye is fixed. t
A heating device characterized in that it comprises a superimposing means for superimposing, and an electrode for supporting the photothermographic material and the image receiving material which have been superimposed by the superimposing means and for supplying current to the conductive heat generating layer. It is a development transfer device.

この熱現像転写方法において、色素固定層を有する受像
材料には、現像された熱現像感光材料と重ね合わせるよ
りも前に拡散助剤が付与されていると、よりよく転写が
行なわn;bo溶融性拡散助剤方式の場合は、受像材料
の製造時に予め原票や結晶水やマイクロカプセル等熱に
より水様状になったり水を溶出しfcシ圧力により水や
水溶液ケ滲出させたシする材料全拡散助剤としてイづ与
しであるので、重ね合わせる際の付与は不要である。拡
−助剤として水や塩基性の水溶液を用いる方式の場合は
、重ね合わせ合わせる際に受像材料に拡散助剤を与える
ことになる。拡散助剤として用いる水とは、いわゆる純
水に限らず、一般飲料水、工業用水等が含まれる。また
、こ几らの水に、塩基、界面活性剤等写真的あるいは物
理的な性能を向上させるのに有用な物質全添加した水も
含まnる。
In this heat development transfer method, if a diffusion aid is added to the image receiving material having a dye fixing layer before superimposing it with the developed heat development photosensitive material, the transfer will be performed better. In the case of the diffusion aid method, during the production of the image-receiving material, all materials such as original slips, crystallized water, microcapsules, etc. are made into a water-like state by heat or eluted, and water or aqueous solution is exuded by fc pressure. Since it is applied as a diffusion aid, it is not necessary to add it when stacking. In the case of a method using water or a basic aqueous solution as a spreading aid, the spreading aid is applied to the image-receiving material during superposition. The water used as a diffusion aid is not limited to so-called pure water, but includes general drinking water, industrial water, and the like. It also includes water to which all substances useful for improving photographic or physical performance, such as bases and surfactants, have been added.

そして水の供給皿は、例えば熱現像感光材料の感光層お
よび受像材料の色素固定層の全塗布膜の乾燥基量の70
%以上で、上記全塗布族の最大膨潤時のM量から乾燥重
量?差引いた値以下の量であればよい。
The water supply tray is used, for example, at a rate of 70% of the dry base weight of the total coating film of the photosensitive layer of the heat-developable photosensitive material and the dye fixing layer of the image-receiving material.
% or more, the dry weight from the amount of M at maximum swelling of all the above coating groups? It is sufficient if the amount is less than or equal to the subtracted value.

本発明において、画像様の露光がなさ汎た感光材料の感
光ノーに可動性の親水性色素全l1fii像状に形成さ
せる現1象の1こめの加熱温度は、約ざo′C〜約、x
zo ’ Cで現像可能であるが、特に約1100C〜
・約/乙O0Cが有用でめろ。加熱時間は熱現像感光材
料の性翼によって異なるが、約O0!秒〜約300秒が
有用である。現像さnた熱現像感光材料と受像材料とを
京ね合わせ画像状の親水性色素を受像利得へ転写するた
めの〃l熱温度は、室温程度から現像温度を越えない程
度の温度でoJ能である。現像温度に近い温度、すなわ
ち現像を進行させ得る温度で転写を行なうときには、転
写時における現像進行をも考慮して現像温度および現像
時間を設定しておかなくてはならない。現像条件と転写
条件との関係は、例えは現像温度/30°Cで20秒、
転写温度20°Cでj秒になるように行なわれる。通常
、この現像温度と転写温度との差は1000以上必賛と
さ几る。
In the present invention, the heating temperature for the first time to form an image of a mobile hydrophilic dye during the exposure of a light-sensitive material without image-wise exposure is about 0'C to about x
It can be developed at zo' C, but especially from about 1100 C.
・About/Otsu O0C is useful. The heating time varies depending on the nature of the photothermographic material, but is approximately O0! Seconds to about 300 seconds are useful. The thermal temperature for transferring the image-shaped hydrophilic dye to the image-receiving material by combining the developed heat-developable photosensitive material and the image-receiving material is from around room temperature to a temperature not exceeding the development temperature. It is. When transferring at a temperature close to the development temperature, that is, at a temperature that allows development to proceed, the development temperature and development time must be set in consideration of the development progress during transfer. The relationship between development conditions and transfer conditions is, for example, development temperature/30°C for 20 seconds,
The transfer is performed for j seconds at a transfer temperature of 20°C. Usually, the difference between the development temperature and the transfer temperature is 1000 or more.

こnら現像のための加熱および転写のための加熱は導電
発熱層への通電により行なわれる。したがって、通電に
より導電発熱層が加熱さn昇温していく立上がりの過程
および加熱さr+−た導電発熱層によシ感光層が加熱さ
れ昇温していく立上がりの過程ケも考慮して通電する電
圧(すなわち電流)と時間を設定する必要がある。導電
発熱層の発熱の程度は単位面積描りの電力量によって異
なる。
Heating for development and heating for transfer are performed by applying electricity to the conductive heating layer. Therefore, when electricity is applied, consideration is given to the rising process in which the conductive heating layer is heated and the temperature rises, and the rising process in which the photosensitive layer is heated and the temperature is rising by the heated conductive heating layer. It is necessary to set the voltage (i.e. current) and time. The degree of heat generated by the conductive heat generating layer varies depending on the amount of power drawn per unit area.

したがって、電極に接触さ才]7る熱塊f8!感光材相
の幅に応じて供給される電流値は具なる。幅が同じ場合
に電@!、間隔に応じて印〃目する電圧値を異ならせ、
同じ値の電流値が得ら几るようにす才りば発熱の8度は
同じになる。
Therefore, the hot mass f8 that comes into contact with the electrode]7! The supplied current value varies depending on the width of the photosensitive material phase. If the widths are the same, call @! , vary the voltage value to be marked depending on the interval,
If the same current value is obtained and reduced, the heat generation will be the same 8 degrees.

現像時の通電に用いる電極の間隔と転写時の通電に用い
る電極の間隔が等しい場合には、転写時の印加電圧を・
坊、保時の印加′電圧よすも低く設定すれは現1#!温
度よりも低め転写温度で処理することができる。
If the spacing between the electrodes used for energization during development is equal to the spacing between the electrodes used for energization during transfer, the voltage applied during transfer should be
Well, the voltage applied during maintenance should also be set low! Processing can be performed at a lower transfer temperature than the transfer temperature.

また通電力λらの昇温しでいく立上り過程の時間を・利
用すすLば、印加電圧丁lわちこの場合の電流値が同じ
であっても転写温槻全現保温夏よりも低くすることがで
きる。例えば、昇温完了までの時間に7〜を抄製するよ
うな場合、現像時の通電を20秒に設定し、転写時の通
電′!i−6〜7秒に設定すれば転写温度が現像温度よ
りも低くなる。
In addition, if we take advantage of the time required for the rising process of the applied power λ to increase the temperature, the applied voltage λ, that is, even if the current value in this case is the same, it is possible to make the transfer temperature lower than in the current thermal insulation summer. can. For example, when making paper from 7 to 7 in the time until the temperature rise is completed, the energization during development is set to 20 seconds, and the energization during transfer is set to 20 seconds. If it is set to i-6 to 7 seconds, the transfer temperature will be lower than the development temperature.

導電発熱層への通電は平行な電極へ熱現像感光材料を接
触させることにより行なわれる。電極は導電発熱層の幅
方向に平行に設けてもよいし、幅方向に直角に設けても
よい。長尺のま\の熱現像感光材料を所定間隔ずつ断続
的に送って処理する場合あるいは連続的に送って処理す
る場合には熱現像感光材料の進行方向に直角に設けられ
た電極が好ましい。電極には熱現像感光材料の支持手段
を兼ねさせてもよいし、また熱現像材料の搬送手段を兼
ねさせてもよい。さらには熱現像感光材料と受像材料と
の重ね合わせ手段を兼ねさせてもよい。搬送手段あるい
は重ね合わせ手段を兼ねさせるには、電極全導電性のロ
ーラで構成子れがよい。
Electricity is supplied to the conductive heating layer by bringing the photothermographic material into contact with parallel electrodes. The electrodes may be provided parallel to the width direction of the conductive heating layer, or may be provided at right angles to the width direction. When a long photothermographic material is fed intermittently at predetermined intervals or continuously for processing, it is preferable to use an electrode provided perpendicular to the traveling direction of the photothermographic material. The electrodes may also serve as means for supporting the photothermographic material, or may serve as means for transporting the photothermographic material. Furthermore, it may also serve as a means for overlapping the photothermographic material and the image-receiving material. In order to serve as a conveyance means or a stacking means, it is preferable to use a roller whose electrodes are entirely conductive.

現像に用いる電極と転写に用いる電極は同一の電極であ
ってもよい。電極に接触させて通電加熱され現像さ′1
1.た熱現像感光材料を受像材料との重ね合わせ部へ移
動させて受像材料と重ね合わせた後、再び同じ電極に接
触頬せて通電加熱し転写するようにしてもよい。この場
合、電極をローラで構成し、搬送手段を兼ねるようにし
、そして電極の一方に重ね合わせ手段を兼ねさせるよう
にするとよい。
The electrode used for development and the electrode used for transfer may be the same electrode. It is brought into contact with an electrode and is heated and developed'1
1. The heat-developable photosensitive material may be moved to the overlapping portion with the image-receiving material and overlaid with the image-receiving material, and then brought into contact with the same electrode again and heated with electricity to perform transfer. In this case, it is preferable that the electrodes be constituted by rollers, so that they also serve as conveyance means, and one of the electrodes is made to serve also as overlapping means.

導電発熱層が感光層と一緒に施されている場合には、熱
現像感光材料よりも幅あるいは長さが短かい受像材料を
重ね合わせるようにし、電極は熱現像感光材料の両縁部
あるいは両端部の表面に接するような構造のものを用い
ることができる。また導電発熱層が支持体と感光層の間
に施さ几てbる場合には、導電発熱層への通電体を熱現
像材料の両縁部の表面あるいは裏面へ施しておいて、電
極はこの通電体に接触し得るようになされた構造のもの
を用いることができる。
When a conductive heat generating layer is applied together with a photosensitive layer, an image receiving material that is shorter in width or length than the photothermographic material is overlaid, and the electrodes are placed on both edges or ends of the photothermographic material. A structure that makes contact with the surface of the part can be used. In addition, when a conductive heat generating layer is applied between the support and the photosensitive layer, the conductive body for the conductive heat generating layer is applied to the front or back side of both edges of the heat-developable material, and the electrodes are connected to this layer. A structure that allows contact with the current carrying body can be used.

以下、実施例にて不発#3A’を具体的に説明する。Hereinafter, failure #3A' will be specifically explained in Examples.

第1図は、現像の罠めの電極と転写のための電極とを各
別に設けた実施例装置の要部金示す側面図である。この
実施例装置に用いる熱現像感光材科は表面に感光層を有
し裏面に導電発熱層を有する。この実施例装置は、ロー
ラ対ハ ローラ対コ、ローラ対3、ローラ対≠、ガイド
板j1 ガイド板t5ガイド板7、ガイド板r5光源り
、ミラーボックスlO1コンデンサーレンズ//、原画
キャリヤ/2、結像レンズ/3、色補正フィルタ/4j
・シャッターlj、%L源/1%電源/7、水供給ノズ
ル/♂からなっている。ローラ対lは熱現像感光材料を
露光ステージフタへ送シ込む疋めのもので、ローラ対/
全構成するローラ/A、/Bはゴムローラであゐ。ロー
ラ対2は送9手段と電極とを兼ねろもので、ローラ対コ
を構成するローラ、2Aは耐熱ゴムローラでありローラ
λBは金属ローラである。ローラ対3は送9手段と重ね
合わせ手段と電極とを兼ねるもので、ローラ対3?構成
すゐローラ3Aは耐熱ゴムローラでありローラ3Bは金
属ローラでめる。ローラ対l/lは送り手段とvL極と
ゲ兼ねろもので、ローラ対≠を構成するローラ≠Aは耐
熱ゴムローラでありローラ≠Bは金属ローラである。ロ
ーラ2Bとローラ3Bには電源/乙がリレースイッチ/
xATh介して接続さn第1の電極が構成されている。
FIG. 1 is a side view showing the main parts of an embodiment apparatus in which a developing trap electrode and a transfer electrode are provided separately. The heat-developable photosensitive material used in this example apparatus has a photosensitive layer on the front surface and a conductive heating layer on the back surface. This embodiment device includes: roller pair, roller pair 3, roller pair ≠, guide plate j1, guide plate t5, guide plate 7, guide plate r5, light source, mirror box lO1 condenser lens//, original image carrier/2, Imaging lens/3, color correction filter/4j
- Consists of shutter lj, %L source/1% power source/7, and water supply nozzle/♂. The roller pair l is used to feed the photothermographic material to the exposure stage lid.
The rollers /A and /B that make up the entire structure are rubber rollers. The roller pair 2 serves as a feeding means and an electrode, and the rollers 2A constituting the roller pair 2 are heat-resistant rubber rollers, and the roller λB is a metal roller. The roller pair 3 serves as a feeding means, an overlapping means, and an electrode, and the roller pair 3? Construction: The roller 3A is a heat-resistant rubber roller, and the roller 3B is a metal roller. The roller pair l/l serves as the feeding means and the vL pole, and the roller ≠A constituting the roller pair ≠ is a heat-resistant rubber roller, and the roller ≠B is a metal roller. Roller 2B and roller 3B have a power supply/B is a relay switch/
A first electrode connected via xATh is configured.

ロー23Bとローラ弘Bには電源/7がリレースイッチ
/ 7A2介して接続され第一の電極が構成さnている
。水供給ノズル/fは現像さnた熱現像感光材料の感光
層と受像材料の色素固定層との間へ拡散助剤としての水
を所定量供給するようになされている。各ローラ対11
 λ、3、≠はそれぞn駆動さAるようになされている
A power supply 7 is connected to the row 23B and the roller 23B via a relay switch 7A2 to form a first electrode. The water supply nozzle /f is designed to supply a predetermined amount of water as a diffusion aid between the photosensitive layer of the developed photothermographic material and the dye fixing layer of the image receiving material. Each roller pair 11
λ, 3, ≠ are each driven by n.

m1図のように構成さf′Lだ装置にて不発EAを実施
する様子全説明する。透過型の原稿Oを原稿キャリヤ1
2へ装填し、熱現像感光材料金ローラ対/へ挿入すると
、ローラ対lおよびローラ対コが駆動して熱現像感光材
料は送らnガイド板jの上を通ってローラ対λに先端が
支持されるまで進み露光ステージlりに装填される。ポ
ジめるいはネガの写真フィルム等の透過壓の原稿OKは
、光源りから発せらnミラーボックス/θで均一化さn
コンデンサーレンズで集光さf′Lだ光が照射さnる。
A complete explanation will be given of how the misfiring EA is carried out using the f'L device configured as shown in Fig. m1. Transfer the transparent original O to the original carrier 1.
When the heat-developable photosensitive material is loaded into the roller pair 2 and inserted into the gold roller pair/, the roller pair l and the roller pair k are driven, and the photothermographic material is fed n, passes over the guide plate j, and its tip is supported by the roller pair λ. It advances until it is loaded onto the exposure stage. Transparent originals such as positive or negative photographic film are OK because the light is emitted from the light source and is uniformized using a mirror box/θ.
A condenser lens condenses the light f'L and irradiates it.

光照射さf′した原稿Oの画像は結像レンズ/3にて露
光ステージ/りの熱現像感光材料の感光層上に結像さ几
るようになされていて、B(青)、G(緑)、■(赤)
あるいはC(シアン)、M(マゼンタ)、Y(イエロー
)等の色補正フィルりl≠およびシャッターirq介し
て露光制御さn、て熱現像感光材料へ露光δnる。熱現
像感光材料への画像様露光が終了f心と、ローラ対ハロ
ーラ対2、およびローラ対3が駆動して熱現像感光材料
は送られガイド板2の上全通ってローラ対3に先端が支
持さ几るまで進み現像ステージ、20に装填さ几る。こ
の状態で設定さ扛罠電圧の電源/&がリレースイッチ/
7Aによりz/の電極となるローラ2Bとローラ3Bへ
設定さf′1.1ζ時間だけ印加さ九、熱現像感光材料
の裏面の導電発熱層が発熱し、表面の感光層が加熱さn
可動性の親水性9累が画像様に放出される。現像が終了
するとガイド板7上に待機させておいた受像材料21が
ローラ対3へ挿入され10−ラ対コ、ロー2対3、およ
びローラ対弘が駆動されるとともに水供給ノズル/lか
ら所定量の水が供給される。水供給ノズルから供給さn
た水は毛細効果により熱現像感光材料と受像材料との重
ね合わせ線に沿って広がシビード?形成する。熱現像感
光材料と受像材料は水奮均−に介在させながらローラ対
3によって重ね合わさnて送らnガイド板rの上全辿っ
てローラ対≠に先端が支持される才で進み転写ステージ
、2.2に装填される。この状態で設定さft’7(電
圧の電源/7がリレースイッチ/7Aによシ第λの電極
となるロー23BとローラpBへ設定さ−i″L、た時
間だけ印加さ几、熱現像感光材料の裏面の導電発熱層が
発熱し、表面の感光層およびこの感光層に接する受像材
料の色素固定層が加熱され、感光層に放出さnた親水性
色素が拡散助剤である水倉介して色素固定層へ移動して
受像材料へカラー画像として転写さnる。しかる後、′
ローラ対3およびローラ対弘が駆動し、M、ね合わさn
たままの状態で熱現像感光材料と受像材料が排出さn;
bo熱現像感光材料から受像材料を剥がせば受像材料に
カラー写真が得ら几−る。
The image of the original O, which has been irradiated with light f', is formed on the photosensitive layer of the heat-developable photosensitive material on the exposure stage/1 by the imaging lens/3, and the images are B (blue), G ( green), ■(red)
Alternatively, the exposure is controlled via a color correction film l≠ such as C (cyan), M (magenta), or Y (yellow) and a shutter irq, and the photothermographic material is exposed to light δn. Imagewise exposure of the heat-developable photosensitive material is completed. The center, roller pair 2, and roller pair 3 are driven, and the heat-developable photosensitive material is fed, passes completely over the guide plate 2, and the tip is placed on the roller pair 3. It advances until it is supported and loaded onto the developing stage 20. In this state, the power supply/& is the relay switch/
7A is applied to rollers 2B and 3B, which serve as electrodes of z/, for a time of f'1.1ζ.9, the conductive heating layer on the back side of the heat-developable photosensitive material generates heat, and the photosensitive layer on the front side is heated n.
The mobile hydrophilic ninefolds are released in an imagewise manner. When the development is completed, the image-receiving material 21, which has been kept on standby on the guide plate 7, is inserted into the roller pair 3, and the roller pairs 10-1, 2-3, and 2-3 are driven, and at the same time, the image-receiving material 21, which has been kept on standby on the guide plate 7, is driven. A predetermined amount of water is supplied. Supplied from the water supply nozzle
The water spreads along the overlapping line of the heat-developable photosensitive material and image-receiving material due to the capillary effect. Form. The heat-developable photosensitive material and the image-receiving material are superimposed by a pair of rollers 3 with water evenly interposed between them, and are fed to a transfer stage 2, which traces the entire top of the guide plate r and advances with its tip supported by the pair of rollers ≠. .2 is loaded. In this state, set ft'7 (voltage power supply /7 is applied to the row 23B and roller pB, which becomes the λth electrode by the relay switch /7A -i''L, is applied for a period of time, then thermal development is performed. The conductive heating layer on the back side of the photosensitive material generates heat, and the photosensitive layer on the front side and the dye fixing layer of the image-receiving material in contact with this photosensitive layer are heated, and the hydrophilic dye released into the photosensitive layer is released into the Mizukura-mediated diffusion aid. The color image is transferred to the dye fixing layer and transferred to the image receiving material as a color image.
Roller pair 3 and roller pair Hiro are driven, M, and n
The photothermographic material and the image-receiving material are discharged as they are;
When the image-receiving material is peeled off from the heat-developable photosensitive material, a color photograph can be obtained on the image-receiving material.

第2図は、現像のための′rJL極と転写のための電極
とを同一の電極が兼ねるようにした実施例装置の要部を
示す側面図である。この実施例装置に用いる熱現像感光
材料は第1図に示した実施例で用いんものと同じである
。しかし、受像材料は加熱により溶融して水桶状となる
もの、あるいは加熱にニジ水分全放出するものを拡散助
剤として予め含んでいるもの音用いることができる。こ
び)実施例装置はローラ対30、ローラ対3/、 ガイ
ド板3、!、ガイド板33、ガイド板7、電源jlI−
からなっている。ローラ対30は送り手段と電極とを兼
ねるもので、ローラ対30全構成するローラ30Aは耐
熱ゴムローラでありローラ30BIrl金属ローラであ
る。ローラ対3/に送り手段と車ね合わせ手段と電極と
才兼ねゐもσ〕で、ローラ対3/全構成するローラJ/
Aは耐熱ゴムローラでありローラ3/f3は金属ローラ
である。ローラ30’f3とローラj/Bには異なる電
圧全供給し得々電源3≠が切替え可能なリレースイッチ
33f介して接続さ几、第1(7)電極と第2の電極と
を兼ねるように構成さnている。
FIG. 2 is a side view showing the main parts of an embodiment apparatus in which the same electrode serves as the 'rJL pole for development and the electrode for transfer. The photothermographic material used in this embodiment apparatus is the same as that used in the embodiment shown in FIG. However, the image-receiving material may be one that melts into a pail-like shape when heated, or one that previously contains a diffusion aid as a diffusion aid that releases all of the water when heated. Difficulty) The embodiment device has a roller pair 30, a roller pair 3/, a guide plate 3,! , guide plate 33, guide plate 7, power supply jlI-
It consists of The roller pair 30 serves both as a feeding means and an electrode, and the roller 30A that makes up the entire roller pair 30 is a heat-resistant rubber roller, and the roller 30BIrl is a metal roller. The roller pair 3/ has a feeding means, a wheel alignment means, an electrode, and a function σ], and the roller pair 3/all the rollers J/
A is a heat-resistant rubber roller, and roller 3/f3 is a metal roller. The roller 30'f3 and the roller j/B are supplied with different voltages, and the power source 3≠ is connected via a switchable relay switch 33f, so that the roller 30'f3 and the roller j/B are configured to serve as the first (7) electrode and the second electrode. I'm here.

第2図のように構成さnた装置にて本発明を実施する様
子を説明する。コンピュータデータやビデオ信号を光変
更して走査し画像様の露光がなさrしている熱現像感光
材料金ローラ対3θへ挿入すると、ローラ対3θおよび
ローラ対31が駆動して熱現像感光材料は送られガイド
板32の上ゲ通ってローラ対3/に先端が支持さ扛るま
で進む。
The manner in which the present invention is implemented using an apparatus configured as shown in FIG. 2 will be described. When computer data or a video signal is scanned by changing the light and inserted into a pair of gold rollers 3θ of a heat-developable photosensitive material for image-wise exposure, the pair of rollers 3θ and the pair of rollers 31 are driven and the photothermographic material is It passes through the upper part of the guide plate 32 and advances until the tip is supported by the roller pair 3/.

この状態で電源3弘の現像用に設定さnた電圧の電源端
子317A側へリレースイッチ3!が設定時間だけ作動
することによシローラ30f3とローラ3/Bへ現像用
の電圧が印加さnl、熱現像感光材料の矢面の導電発熱
層が発熱し表面の感光層が加熱され可動性の親水性色素
が画像様に放出さnる。
In this state, switch the relay switch 3! to the power supply terminal 317A side of the voltage set for the development of the power supply 3! By operating for a set time, a developing voltage is applied to the roller 30f3 and the roller 3/B, and the conductive heating layer, which is the main part of the heat-developable photosensitive material, generates heat, and the photosensitive layer on the surface is heated, and the movable hydrophilic layer is heated. The color pigment is released in an imagewise manner.

現像が終了すると再びロー2対30$−よびローラ対3
/が駆動芒几現像された熱現1オ感光材料はガイド板3
3上へ送らn波端がロージ対3ノに挾ま几でいる状態で
停止する。しか6後、ガイド板7上に待伏させておいた
受像材料3乙がローラ対3/へ挿入さn5 ローラ対3
/、ローラ対3θは逆転駆動さi″L熱現像感光材料と
受憬材Hにローラ対3/によって重ね合わされて送らn
ガイド板3コの上を通ってローラ対30に先端が支持さ
f′L、ゐ1で進む。この状態で電源J4’の転写用に
設定さnた電圧の電源端子34Lf3側へリレースイッ
チ3jが設定時間たけ作動することによりローラ30B
とローラ3/Bへ転写用の電圧か印加さ扛、熱現像感光
材料の裏面の導這発熱左iが発熱し、表51Jり)感光
層およびこの感光層に接する受像材料の色票固定舶が加
熱でれ色素固定局に予め@4几ている溶融性物質が水分
を出し、感光層に放出ざ1.た親水性色素が水分を介し
て色素レジI定層へ移動して受像月利へカラー画像とし
て転力さf’lる。しかる後、ロー2対30およびロー
ラ対3/が躯勤し、重ね合わされた甘まの状態で熱現像
感光材料と受像材料が排出さ才1.る。熱現像感光材料
から党1象材刺を剥がせば受像材料にカラーノー−トコ
ビーが傅ら庇る。
When the development is completed, the roller pair 30 and the roller pair 3 are applied again.
/ is driven by the heat development method 1. The developed photosensitive material is placed on the guide plate 3.
3 and stops when the n-wave end is sandwiched between the logi and the 3. After 6, the image-receiving material 3 which had been left in ambush on the guide plate 7 is inserted into the roller pair 3/n5.
/, the roller pair 3θ is reversely driven, and the photothermographic material H and the receiving material H are overlapped and fed by the roller pair 3/.
The tip passes over three guide plates and is supported by a pair of rollers 30, and advances at f'L,i1. In this state, the relay switch 3j is operated for a set time to the power supply terminal 34Lf3 side of the voltage set for transfer of the power supply J4', thereby transferring the roller 30B.
When a voltage for transfer is applied to the roller 3/B, the heat-generating portion on the back side of the heat-developable photosensitive material generates heat. When heated, the meltable substance previously placed in the dye fixing station releases moisture and releases onto the photosensitive layer. The hydrophilic dye moves through the water to the dye register I constant layer and is transferred to the image receiver as a color image. After that, the rollers 2 and 30 and the rollers 3 and 3 work hard, and the heat-developable photosensitive material and the image-receiving material are discharged in a superimposed state. Ru. By peeling off the color notes from the heat-developable photosensitive material, color notebooks will cover the image-receiving material.

上記第1図2よび第2図の実施例に用いた熱現像感光材
料は電極間の長さgj鴎電極に接す小幅to町であム導
電発熱虐の長き方向び〕抵抗値はtooΩである。現像
においては電極に約/2!■の電圧を印加しl弘O′C
に加熱した。転写においては約/10vの電圧全印加し
/l o ’ Ct1c加熱した。したがって現像にお
ける電流は0.2/A、転写におけろ電流はθ、/ざA
であった。
The heat-developable photosensitive material used in the examples shown in FIGS. 1 and 2 above has a length between the electrodes of gj, a narrow width in contact with the electrode, and a resistance value of too Ω in the long direction of conductive heat generation. be. Approximately 2 times the electrode during development! Apply the voltage of ■ and
heated to. During the transfer, a total voltage of about /10 V was applied and heating was performed at /lo'Ct1c. Therefore, the current in development is 0.2/A, and the current in transfer is θ, /A
Met.

本発明は上記したごとく、新規な熱現像転写方法お工ひ
装置であり、−導電発熱層に通電することにより現像2
よび転写の双方の加熱kT;bという簡易なやり方で転
写カラー画欲が得らn、特にカラー写真やハードコピー
として画数が得ら几る受像材料には導電発熱層が不要で
あゐことの実用的効果は太きい。
As mentioned above, the present invention is an apparatus for implementing a novel thermal development transfer method, and includes:
The transfer color image can be obtained by the simple method of heating kT and b for both the image transfer and transfer, and in particular, the conductive heating layer is not necessary for image-receiving materials that can obtain a high number of images such as color photographs and hard copies. The practical effects are significant.

【図面の簡単な説明】[Brief explanation of the drawing]

第7図は本発明を実施するための熱現像転写装置全例示
する要部の側面図、第2図は同装置の別の実施例r示す
要部の側面図である。 /、ノ、3、tl 30.3/・・・・・・ローラ対、
! B、’3 B、  グB、 30B、 3/f3・
・・・・・金属のローラ /l、、/7.3弘・・・・・・′亀源手続補正書 特許庁長官殿 1、事件の表示    昭和!に年特願第 5≠731
号2、発明の名称  熱現像転写方法および装置3、補
正をする者 事件との関係       特許出願人4、補正の対象
  明細書の「発明の詳細な説明」の欄 5、補正の内容 /)明細書比7頁第r行の 「導電発熱体層」 を 「導電発熱層」 に補正する。 、2)明細書第20頁第、20行〜第1♂頁第1行の 「水供給ノズル」 會 「水供給ノズル/ど」 に補正丁ゐ。 3)明細書第20頁第3行の 「光変更」 ? 「光変換」 に補正する。
FIG. 7 is a side view of the main parts showing an example of a thermal development transfer apparatus for carrying out the present invention, and FIG. 2 is a side view of the main parts showing another embodiment of the same apparatus. /,ノ,3,tl 30.3/...roller pair,
! B, '3 B, Gu B, 30B, 3/f3・
...Metal roller /l,, /7.3 Hiroshi...' Kamegen procedural amendment letter Mr. Commissioner of the Patent Office 1, case display Showa! Patent Application No. 5≠731
No. 2, Title of the invention Thermal development transfer method and apparatus 3, Relationship with the case of the person making the amendment Patent applicant 4, Subject of the amendment Column 5, "Detailed explanation of the invention" of the specification, Contents of the amendment/) Specification Correct “conductive heating layer” in line r of page 7 to “conductive heating layer”. , 2) "Water supply nozzle" and "Water supply nozzle/do" on page 20, line 20 to page 1♂, line 1 of the specification have been corrected. 3) “Light change” on page 20, line 3 of the specification? Correct to “light conversion”.

Claims (1)

【特許請求の範囲】 /)加熱により露光部分あるいは非露光部分から可動性
の親水性色素を放出する感光層および導電発熱層を有す
る熱現像感光材料の前記感光層に画像様の露光ケし、前
記感光層に画像様の露光がなさf′L、た熱現像感光材
料の前記導電発熱層に通電し加熱することによって前記
感光層に可動性の親水性色素を画像状に形成し、しかる
後、色素固定Nを有する受像材料に前記熱現像感光材料
をそれぞれ前記色素固定層と前記感光層と全向い合わせ
て重ね合わせ、前記受像材料と重ね合わせら′nた前記
熱現像感光月相の導電発熱層に通電し加熱することによ
って前記画像状に形成した親水性色素を前記色素同定層
へ移動させ、しかる後、前記受像材料を前記熱現像感光
材料から剥離することに2)前記感光層に可動性の親水
性色素を画像状に形成する際に前記導電発熱層へ通電す
る電流値よりも、前記画像状の色素を色素固定層へ移動
させる際に前記4電発熱層へ通電する電流値を小さくす
ることを特徴とする特許請求の範囲第1項記載の熱現像
転写方法。 3)前記感光層に可動性の親水性色素を画像状に形成す
る際に前記導電発熱層へ通電する通電時間よりも、前記
画像状の色素全色素固定層へ移動させる際に前記導電発
熱層へ通電する通電時間を短かくすることを特徴とする
特許請求の範囲81項記載の熱現像転写方法。 り加熱により露光部分あるいは非露光部分から可動性の
親水性色素全放出する感光層および導電発熱層を有する
熱現像感光材料の前記感光層に画像様の露光がなさn7
こ前記熱現像感光材料を支持し前記4(転)発熱へに進
%丁/)第一の′電極と、前記第一の電極での前記導電
発熱層への前篭にょシ加熱さ九て前記感光層に可動性の
親水性色素を画像状に形成さfした熱現像感光I科と色
素同定層を有する受像材料とを重ね合わせる1ね合わせ
手段と、前記重ね合わせ手段にて重ね合わせらnた前記
熱現像感光材料および前記受像材料を支持し前記導電発
熱層に通電する第二の電極とを有することを特徴とする
熱現像転写装置。 り前記第一の電極と前記第二の電極と全同一電極が兼ね
るようになしたことを特徴とする特許請求の範囲第3項
記載の熱現像転写装置。
[Scope of Claims] /) imagewise exposing the photosensitive layer of a heat-developable photosensitive material having a photosensitive layer and a conductive heating layer that release a mobile hydrophilic dye from exposed or non-exposed areas when heated; When the photosensitive layer is not imagewise exposed f'L, a movable hydrophilic dye is formed on the photosensitive layer in the form of an image by applying electricity to and heating the conductive heating layer of the heat-developable photosensitive material, and then , the heat-developable photosensitive material is superimposed on an image-receiving material having a dye-fixed N, with the dye-fixed layer and the photosensitive layer facing each other, and the conductivity of the heat-developable photosensitive material that is superimposed on the image-receiving material is 2) Transferring the hydrophilic dye formed in the image form to the dye identification layer by applying electricity to the heat generating layer and heating it, and then peeling off the image receiving material from the photothermographic material. The current value applied to the four-electroelectric heating layer when moving the image-formed dye to the dye fixing layer is higher than the value of the current applied to the conductive heating layer when forming the mobile hydrophilic dye in the form of an image. 2. The thermal development transfer method according to claim 1, wherein: 3) When forming a movable hydrophilic dye in the form of an image on the photosensitive layer, the conductive heat generating layer is longer than the current application time to the conductive heat generating layer when the image form of the dye is transferred to the fixed dye layer. 82. The heat development and transfer method according to claim 81, wherein the time period during which the current is applied to is shortened. There is no imagewise exposure of the photosensitive layer of a photothermographic material having a photosensitive layer and a conductive heating layer that release all of a mobile hydrophilic dye from exposed or non-exposed areas when heated.
The heat-developable photosensitive material is supported, and the process proceeds to the above-mentioned (4) heat generation process. a superimposing means for superimposing a heat-developable photosensitive material having a movable hydrophilic dye formed in the form of an image on the photosensitive layer and an image receiving material having a dye identification layer; A heat development transfer device comprising: a second electrode that supports the heat-developable photosensitive material and the image-receiving material and supplies electricity to the conductive heating layer. 4. The thermal development transfer device according to claim 3, wherein all the same electrodes serve as the first electrode and the second electrode.
JP5473883A 1983-03-29 1983-03-29 Method and device for thermodevelopment and transfer Granted JPS59177547A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5473883A JPS59177547A (en) 1983-03-29 1983-03-29 Method and device for thermodevelopment and transfer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5473883A JPS59177547A (en) 1983-03-29 1983-03-29 Method and device for thermodevelopment and transfer

Publications (2)

Publication Number Publication Date
JPS59177547A true JPS59177547A (en) 1984-10-08
JPH0362251B2 JPH0362251B2 (en) 1991-09-25

Family

ID=12979122

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5473883A Granted JPS59177547A (en) 1983-03-29 1983-03-29 Method and device for thermodevelopment and transfer

Country Status (1)

Country Link
JP (1) JPS59177547A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61245158A (en) * 1985-04-22 1986-10-31 Fuji Photo Film Co Ltd Adjustment control method for transfer position
JPS623255A (en) * 1985-06-28 1987-01-09 Konishiroku Photo Ind Co Ltd Image recording device
EP0394943A2 (en) 1989-04-25 1990-10-31 Fuji Photo Film Co., Ltd. Silver halide color photographic material
EP0772088A1 (en) 1991-03-05 1997-05-07 Fuji Photo Film Co., Ltd. Heat-developable diffusion transfer color photographic material

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61245158A (en) * 1985-04-22 1986-10-31 Fuji Photo Film Co Ltd Adjustment control method for transfer position
JPH059014B2 (en) * 1985-04-22 1993-02-03 Fuji Photo Film Co Ltd
JPS623255A (en) * 1985-06-28 1987-01-09 Konishiroku Photo Ind Co Ltd Image recording device
EP0394943A2 (en) 1989-04-25 1990-10-31 Fuji Photo Film Co., Ltd. Silver halide color photographic material
EP0772088A1 (en) 1991-03-05 1997-05-07 Fuji Photo Film Co., Ltd. Heat-developable diffusion transfer color photographic material

Also Published As

Publication number Publication date
JPH0362251B2 (en) 1991-09-25

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