JPS59171457A - Sealed type battery - Google Patents
Sealed type batteryInfo
- Publication number
- JPS59171457A JPS59171457A JP58046207A JP4620783A JPS59171457A JP S59171457 A JPS59171457 A JP S59171457A JP 58046207 A JP58046207 A JP 58046207A JP 4620783 A JP4620783 A JP 4620783A JP S59171457 A JPS59171457 A JP S59171457A
- Authority
- JP
- Japan
- Prior art keywords
- flatness
- sealing lid
- lowermost end
- battery
- sealed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007789 sealing Methods 0.000 claims abstract description 28
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 230000000630 rising effect Effects 0.000 claims description 2
- 239000000565 sealant Substances 0.000 claims description 2
- 239000004020 conductor Substances 0.000 claims 1
- 238000010248 power generation Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 5
- 230000002093 peripheral effect Effects 0.000 abstract description 4
- 230000008602 contraction Effects 0.000 abstract 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 125000000174 L-prolyl group Chemical group [H]N1C([H])([H])C([H])([H])C([H])([H])[C@@]1([H])C(*)=O 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000011255 nonaqueous electrolyte Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/166—Lids or covers characterised by the methods of assembling casings with lids
- H01M50/171—Lids or covers characterised by the methods of assembling casings with lids using adhesives or sealing agents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/166—Lids or covers characterised by the methods of assembling casings with lids
- H01M50/167—Lids or covers characterised by the methods of assembling casings with lids by crimping
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Sealing Battery Cases Or Jackets (AREA)
Abstract
Description
【発明の詳細な説明】 産業上の利用分野 本発明は電解液を内填する密閉式の酸化銀電池。[Detailed description of the invention] Industrial applications The present invention is a sealed silver oxide battery containing an electrolyte.
水銀電池、アルカリマンガン電池、空気亜鉛電池。Mercury batteries, alkaline manganese batteries, zinc air batteries.
リチウム電池、ニッケル・カドミウム電池などに2”” 関するものである。2” for lithium batteries, nickel cadmium batteries, etc. It is related to
従来例の構成とその問題点
従来の密閉式電池の例を第1図及び第2図によシ説明す
る。これらは何れもリチウムを負極とした電池である。Structure of a conventional example and its problems An example of a conventional sealed battery will be explained with reference to FIGS. 1 and 2. All of these batteries use lithium as a negative electrode.
図中1は表面にニッケルを被覆した鋼製電池ケースで、
例えば二酸化マンガン或は弗化炭素等の正極剤2を内填
している。3は特殊な鋼製の封口蓋で、皿状になってお
り、その端縁は第1図においては上方への折返し部4を
有し、 ・第2図においては盃状に外側に開いた端縁
6となっている。この他垂直に下向きに切断することも
ある。6は封口蓋に内接する負極リチウム板、7は非水
系電解液を含浸したセパレータである。8はポリプロピ
レン製ガスケットで、通常このガスケットと封口蓋との
接触面9及びガスケットとケースとの接触面1oにはプ
ロ/アスファルト等の封止剤が塗布されている。1 in the figure is a steel battery case whose surface is coated with nickel.
For example, a cathode material 2 such as manganese dioxide or carbon fluoride is contained therein. 3 is a special steel sealing lid, which is dish-shaped, and its edge has an upwardly folded part 4 in Figure 1, and a cup-shaped opening outward in Figure 2. The edge is 6. Alternatively, the cut may be made vertically downward. 6 is a negative electrode lithium plate inscribed in the sealing lid, and 7 is a separator impregnated with a non-aqueous electrolyte. Reference numeral 8 denotes a polypropylene gasket, and a sealant such as Pro/Asphalt is usually applied to the contact surface 9 between the gasket and the sealing lid and the contact surface 1o between the gasket and the case.
このようにして構成した電池は、第1図からも明らかな
ように、金属ケースの立上り端部の封口曲げ角度や曲げ
の均一性と、部品の寸法精度によ3′”゛
す、液密性即ち電池の耐漏液性が大きく左右される。特
に部品の寸法精度と、形状及び位置の精度(幾何学的精
度)については、それが適正でない場合は、封口をどの
ようにしても耐漏液性をよくすることは困難である。As is clear from Figure 1, the battery constructed in this way is 3''' liquid-tight, depending on the sealing bending angle and uniformity of the bending at the rising end of the metal case, and the dimensional accuracy of the parts. In other words, the leakage resistance of the battery is greatly affected.In particular, if the dimensional accuracy of parts and the accuracy of shape and position (geometric accuracy) are not appropriate, leakage resistance will be affected no matter how the seal is sealed. Improving sexuality is difficult.
発明の目的
本発明は、これら部品の中、封口蓋の外周折返し部最下
端、又は折返し部のない場合は周縁最下ものである。OBJECTS OF THE INVENTION The present invention is directed to, among these parts, the lowermost end of the outer circumference folded part of the sealing lid, or the lowermost part of the circumferential edge if there is no folded part.
発明の構成
本発明は、上記目的を達成するため、封口蓋の周縁最下
端の平面度を、封口蓋の全円周にわたって0.03++
lIl+以下としたことを特徴とするものである。平面
度は■工5B0621の「形状及び位置の精度の定義」
によれば、「平面度とは、平面部分の幾何学的平面から
の狂いの大きさをいう」と定義されている。Structure of the Invention In order to achieve the above object, the present invention has the flatness of the lowermost edge of the sealing lid set to 0.03++ over the entire circumference of the sealing lid.
It is characterized in that it is less than lIl+. Flatness is determined by ■Technical 5B0621 “Definition of shape and position accuracy”
According to ``Flatness is defined as the amount of deviation of a flat part from a geometric plane.''
本発明において、封口蓋折返し部最下端又は折返し部を
有しない場合の周縁最下端の平面度とは、円周スリーブ
部分を互いに平行な二つの幾何学的平面ではさんだとき
、それら両半部の間隔が最小となる場合の両半部の間隔
の大きさをいい、これを0.03mm以内としだもので
ある。In the present invention, the flatness of the lowest end of the folded part of the sealing lid or the lowest end of the peripheral edge when there is no folded part means that when the circumferential sleeve part is sandwiched between two geometric planes parallel to each other, the flatness of both halves It refers to the size of the gap between the two halves when the gap is the minimum, and this should be within 0.03 mm.
実施例の説明
第3図は折返し部を有する封口蓋3の最下端の平面度が
わるい例を、また第4図は折返し部4を持たない封口蓋
3のスリーブ最下端の平面度のわるい例をそれぞれ示す
。DESCRIPTION OF EMBODIMENTS FIG. 3 shows an example in which the lowermost end of the sealing lid 3 having a folded part has poor flatness, and FIG. 4 shows an example in which the lowermost end of the sleeve of the sealing lid 3 without a folded part 4 has poor flatness. are shown respectively.
このように、封口蓋3の最下端の平面度が劣る場合、金
属ケース1の端縁を曲げても封口蓋最下端にかかる圧力
は均一化されず、圧力の小さいところから電解液が漏出
する。In this way, if the flatness of the bottom end of the sealing lid 3 is poor, even if the edge of the metal case 1 is bent, the pressure applied to the bottom end of the sealing lid will not be equalized, and the electrolyte will leak from the area where the pressure is low. .
近年、機械的加工部品は、単なる寸法精度のみでなく、
形状及び位置の精度(幾何学的精度)について論議され
ることが多いが、本発明はその中の封口蓋の周縁折返し
部最下端、又は折返し部を持たない場合はスリーブ最下
端の平面度についてこれを0.03mm以内にしだもの
である。このよう5ペヘジ
にすることにより、封口蓋最下端にかかる圧力を均一に
することができ、電池の耐漏液性が向上する。In recent years, mechanically processed parts require not only dimensional accuracy but also
Although the accuracy of shape and position (geometric accuracy) is often discussed, the present invention concerns the flatness of the lowermost end of the circumferential folded part of the sealing lid, or the lowermost end of the sleeve if it does not have a folded part. This is to be within 0.03 mm. By setting the pressure to 5 degrees as described above, the pressure applied to the lowermost end of the sealing lid can be made uniform, and the leakage resistance of the battery is improved.
平面度の良好な封口蓋は、抜き及び絞りのプロセスを選
ぶことと、金型精度を保つことによって得られる。折返
し部を有する場合は特に絞りの過程において折返し部上
端を金型で叩くことにより、その最下端の平面度が向上
する。A sealing lid with good flatness can be obtained by selecting the punching and drawing processes and by maintaining mold precision. When a folded part is provided, the flatness of the lowermost end can be improved by hitting the upper end of the folded part with a mold especially during the drawing process.
平面度を0.03mm以内とした理由は、平面度は小さ
ければ小さい程よいことはいうまでもないが、電池漏液
テストの結果、これが0.03mm以内であれば、電池
として実用上支障がないことが判明したためである。今
、電池の外径23闘、高さ2.0団の弗化炭素リチウム
系電池をもってテストした。The reason for setting the flatness within 0.03 mm is that it goes without saying that the smaller the flatness, the better, but as a result of the battery leakage test, as long as it is within 0.03 mm, there is no problem in practical use as a battery. This is because it has become clear that A fluorocarbon lithium battery with an outer diameter of 23mm and a height of 2.0mm was tested.
テストの方法は電池を60″Cに1時間保管し、直ちに
一10″Cに1時間保管することを連続して30日間繰
返した後、10倍の顕微鏡で漏液の有無を観察した。The test method was to store the battery at 60''C for 1 hour, then immediately store it at -10''C for 1 hour, which was repeated for 30 consecutive days, and then observe the presence or absence of leakage under a 10x microscope.
(1)折返しを有する場合
6”’
平面度区分 テスト数 漏液数
0.02w以下 20 0
0.021〜0.030胴 20 00.
031〜0.040ran 20 5
0.041問以上 20 11(2)折返し部
のない場合
平面度区分 テスト数 漏液数 媚 考0.02
胴以下 20 00.021〜0.030
朋 20 2 極めて微少0.031〜0.
040間 2o 110.041mm以上
2o 20発明の効果
以上のとおり、封口蓋折返し部最下端、あるいは折返し
部のない封口蓋にあっては、その周縁最下端の平面度を
0.03m以内に保つことは、電池の耐漏液性において
極めてすぐれた効果を有する。(1) If there is a fold, 6"' Flatness classification Number of tests Leakage number 0.02w or less 20 0 0.021-0.030 Cylinder 20 00.
031~0.040ran 20 5
0.041 questions or more 20 11 (2) Flatness classification when there is no folded part Number of tests Number of leaks Loveness 0.02
Below the torso 20 00.021~0.030
Tomo 20 2 Extremely minute 0.031~0.
Between 040 2o 110.041mm or more
2o 20 Effects of the Invention As described above, maintaining the flatness of the bottom end of the folded part of the sealing lid, or the bottom end of the periphery of the sealing lid without a folded part, within 0.03 m is important for the leakage resistance of the battery. It has extremely excellent effects.
なお、第1図及び第2図においては、ガスケット下面が
直接電池ケースの内面周縁に接する例を示したが、正オ
)合剤に接するような構成においても同様な効果が認め
られた。Although FIGS. 1 and 2 show an example in which the lower surface of the gasket is in direct contact with the inner peripheral edge of the battery case, the same effect was also observed in a configuration in which the lower surface of the gasket is in contact with the mixture.
第1図は封口蓋周縁に折返し部を有する電池の半断面図
、第2図は周縁に折返し部のない封口蓋を用いた電池の
半断面図、第3図及び第4図は平面度のわるい封口蓋を
示す側面図である。
1・・・・・電池ケース、2・・・・・正極剤、3・・
・−・封口蓋、4・・・・・・折返し部、5・・・・一
端縁、6・・・負極、7・・・・・セパレータ、8・・
・・絶縁性ガスケット。
代理人の氏名 弁理士 中 尾 敏 男 ほか1名手続
補正書(方式)
1事件の表示
昭和58年特許願第46207 号
2発明の名称
密閉式電池
3補正をする者
事件との関係 特 許 出 願 大
佐 所 大阪府門真市大字門真1006番地名 称
(582)松下電器産業株式会社代表者 山
下 俊 彦
4代理人 〒571
住 所 大阪府門真市大字門真1006番地松下電器
産業株式会社内
図面全図を別紙の逃JWA止しぽ丁0
第1図
第2図
第3図
第4図Figure 1 is a half-sectional view of a battery that has a folded part on the periphery of the sealing lid, Figure 2 is a half-sectional view of a battery that uses a sealed lid without a folded part on the periphery, and Figures 3 and 4 show flatness. It is a side view which shows a bad sealing lid. 1... Battery case, 2... Positive electrode material, 3...
・- Sealing lid, 4... Folded portion, 5... One edge, 6... Negative electrode, 7... Separator, 8...
...Insulating gasket. Name of agent Patent attorney Toshio Nakao and one other person Procedural amendment (method) 1 Description of the case Patent application No. 46207 filed in 1982 2 Name of the invention Sealed battery 3 Person making the amendment Relationship to the case Patent issue Colonel Wan Address 1006 Kadoma, Kadoma City, Osaka Prefecture Name
(582) Matsushita Electric Industrial Co., Ltd. Representative Yama
Toshihiko Shimo 4 Agent 571 Address Matsushita Electric Industrial Co., Ltd. 1006 Oaza Kadoma, Kadoma City, Osaka Prefecture All drawings are attached to JWA Toshipoto 0 Figure 1 Figure 2 Figure 3 Figure 4
Claims (3)
スケットと、これらの間を液密に充填する封止剤とによ
シ発電要素を密閉した電池であって、封口蓋の周、導最
下端の平面度が全円周にわたって0.03 mm以内で
るる密閉式電池。(1) A battery in which a power generation element is sealed by a metal battery case, a metal sealing lid, an insulating gasket, and a sealant liquid-tightly filled between these, and the area around the sealing lid is sealed. A sealed battery whose flatness at the lowest end of the conductor is within 0.03 mm over the entire circumference.
部を有する特許請求の範囲第1項記載の密閉式電池。(2) The sealed battery according to claim 1, wherein the sealing lid has an upwardly folded rising portion on its periphery.
端で切断されている特許請求の範囲第1項記載の密閉式
電池。(3) The sealed battery according to claim 1, wherein the sealing lid has no folded portion on the periphery and is cut off at the lowermost end.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58046207A JPS59171457A (en) | 1983-03-18 | 1983-03-18 | Sealed type battery |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58046207A JPS59171457A (en) | 1983-03-18 | 1983-03-18 | Sealed type battery |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS59171457A true JPS59171457A (en) | 1984-09-27 |
Family
ID=12740633
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58046207A Pending JPS59171457A (en) | 1983-03-18 | 1983-03-18 | Sealed type battery |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59171457A (en) |
-
1983
- 1983-03-18 JP JP58046207A patent/JPS59171457A/en active Pending
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