JPS59134507A - Method of surface treating aerial transmission wire - Google Patents
Method of surface treating aerial transmission wireInfo
- Publication number
- JPS59134507A JPS59134507A JP816683A JP816683A JPS59134507A JP S59134507 A JPS59134507 A JP S59134507A JP 816683 A JP816683 A JP 816683A JP 816683 A JP816683 A JP 816683A JP S59134507 A JPS59134507 A JP S59134507A
- Authority
- JP
- Japan
- Prior art keywords
- power transmission
- surface treating
- overhead power
- transmission wire
- watering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 14
- 230000005540 biological transmission Effects 0.000 title claims description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 150000002751 molybdenum Chemical class 0.000 claims description 6
- 238000004381 surface treatment Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000007864 aqueous solution Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- 238000005238 degreasing Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Landscapes
- Non-Insulated Conductors (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】 ［発明の技術分野］ 本発明は架空送電線の表面処理方法に関する。[Detailed description of the invention] [Technical field of invention] The present invention relates to a method for surface treatment of overhead power transmission lines.
［発明の技術的背景とその問題点］
近年、電力需要の増加に伴ない超高圧架空送電線の実用
化の研究がすすめられているが、次のような問題があっ
た。[Technical background of the invention and its problems] In recent years, with the increase in electricity demand, research has been carried out on the practical application of ultra-high voltage overhead power transmission lines, but the following problems have arisen.
（１）伸線工程や撚り合わせ工程でアルミニウム素線表
面に付着した油のために、降雨時に架空送電線の表面に
水滴が生じ、その結果コロナ放電による騒音が発生する
。(1) Due to oil adhering to the surface of aluminum wires during the wire drawing and twisting processes, water droplets form on the surface of overhead power transmission lines during rain, resulting in noise due to corona discharge.
（２）環境保護地域内に布設される架空送電線において
は、表面が金属光沢であるため太陽光線が反射して目立
ち易く、周囲の環境との調和を著しく損なう。(2) Overhead power transmission lines installed in environmentally protected areas have metallic luster on their surfaces, making them highly visible as sunlight reflects off them, which seriously impairs the harmony with the surrounding environment.
これらの問題を解決するために以下に記載するような多
くの方法が提案されている。Many methods have been proposed to solve these problems, as described below.
すなわち（１）の問題については、
（イ）蒸気や純水中での煮沸により撚線表面に親水性の
ベーマイト皮膜を形成する。That is, regarding problem (1), (a) Form a hydrophilic boehmite film on the surface of the stranded wire by boiling it in steam or pure water.
（ロ）撚線表面に界面活性剤を塗布する。(b) Apply a surfactant to the surface of the stranded wire.
（ハ）酸或いはアルカリ溶液により撚線表面を粗面化す
る。(c) Roughening the surface of the stranded wire with an acid or alkaline solution.
（２）の問題については、 （ニ）撚線表面に着色グリースや暗色塗料を塗布する。Regarding problem (2), (d) Apply colored grease or dark paint to the surface of the stranded wires.
（ホ）撚線表面をブラスト加工する。(e) Blast the surface of the stranded wire.
などの方法が提案されている。Other methods have been proposed.
しかしながらいずれの方法を採った場合でも、（１）お
よび（２）の問題の両方を同時に完全に解決することは
できなかった。However, no matter which method is adopted, it has not been possible to completely solve both problems (1) and (2) at the same time.
［発明の目的］
本発明はこれらの両問題を一つの方法で同時に解決する
ためになされたもので、架空送電線の表面に黒色の親水
性の皮膜を形成する方法を提供することを目的とする。[Purpose of the invention] The present invention was made to solve both of these problems simultaneously in one method, and its purpose is to provide a method for forming a black hydrophilic film on the surface of an overhead power transmission line. do.
［発明の概要］
本発明方法は、アルミニウム撚線の少なくとも最外層表
面を微量のモリブデン塩を含む０．１〜１重石％の酸性
フッ化アンモニウム水溶液で加温処理することを特徴と
する。[Summary of the Invention] The method of the present invention is characterized in that at least the surface of the outermost layer of an aluminum stranded wire is heated with an aqueous acidic ammonium fluoride solution containing a trace amount of molybdenum salt and having a concentration of 0.1 to 1% by weight.
本発明に使用するモリブデン塩を含む酸性フッ化アンモ
ニウム水溶液の市販品としては、例えば米国ミツチェル
ープラドフォードケミカル（株）社製のブラックマジッ
クＡＬがあり、これを水で０．１〜１重量％の濃度に希
釈して用いる。As a commercially available acidic ammonium fluoride aqueous solution containing a molybdenum salt used in the present invention, there is, for example, Black Magic AL manufactured by Mitschel-Pradford Chemical Co., Ltd. in the United States. Use after diluting to a concentration of %.
而してモリブデン塩を含む酸性フッ化アンモニウム水溶
液の濃度を０．１〜１重囲％の範囲に限定したのは次の
理由による。The reason why the concentration of the acidic ammonium fluoride aqueous solution containing a molybdenum salt is limited to a range of 0.1 to 1% by weight is as follows.
すなわち濃度が０．１重量％未満では処理の効果がほと
んどみられず、反対に１重量％を越える濃度のものでは
、アルミニウム素線表面の溶解量が大きくなり、いずれ
も好ましくないためである。That is, if the concentration is less than 0.1% by weight, almost no effect of the treatment will be seen, whereas if the concentration exceeds 1% by weight, the amount of dissolution on the surface of the aluminum wire will increase, and both are unfavorable.
本発明においては、このような水溶液で例えば撚り合わ
せ後、巻き取り前の撚線表面を処理するが、撚り合わせ
前に最外層を構成するアルミニウム素線の表面のみを処
理しておくこともできる。In the present invention, for example, the surface of the stranded wires is treated with such an aqueous solution after twisting and before winding, but it is also possible to treat only the surface of the aluminum strands constituting the outermost layer before twisting. .
いずれの場合においても、被処理部には、ブラスト加工
、溶剤脱脂或いはアルカリ洗浄等の脱脂処理を予め施こ
しておくのが望ましい。また処理の方法としては、７０
〜８０’Ｃに加温した前記水溶液中に撚線全体もしくは
最外層のアルミニウム素線を浸漬する方法を採ることも
できる。In either case, it is desirable to previously perform degreasing treatment such as blasting, solvent degreasing, or alkaline cleaning on the treated portion. In addition, as a processing method, 70
It is also possible to adopt a method of immersing the entire twisted wire or the outermost layer of the aluminum wire in the aqueous solution heated to ~80'C.
このようにして得られる架空送電線においては、前記モ
リブデン塩を含む酸性フッ化アンモニウム水溶液とアル
ミニウムとの反応により撚線の被着部に金属モリブデン
を含む黒色の親水性に優れた皮膜が形成されるので、降
雨が撚線表面に水滴状態で付着することがなく、コロナ
放電による騒音が大幅に低減される。また表面が光沢の
ない黒色の皮膜でおおわれているので、周囲の環境にと
けこみ調和を乱すことがほとんどない。In the overhead power transmission line obtained in this way, a black coating with excellent hydrophilic properties containing metallic molybdenum is formed on the adhered portions of the stranded wires by the reaction between the acidic ammonium fluoride aqueous solution containing the molybdenum salt and aluminum. As a result, rain does not adhere to the surface of the stranded wires in the form of water droplets, and noise caused by corona discharge is significantly reduced. In addition, since the surface is covered with a matte black film, it blends into the surrounding environment without disturbing the harmony.
［発明の実施例コ 以下本発明の実施例について記載する。[Embodiments of the invention] Examples of the present invention will be described below.
実施例
４１０−のＡＣ３Ｒ３５０■をアセトンに浸漬して脱脂
処理を行なった後、これを次表に示す濃度に希釈して７
０℃に加温したブラックマジックＡＬ中に同表に示す時
間だけ浸漬し表面処理を行なった。処理後の表面の色相
を同表に示す。After degreasing AC3R350■ of Example 410- by immersing it in acetone, it was diluted to the concentration shown in the following table.
Surface treatment was performed by immersing the sample in Black Magic AL heated to 0° C. for the time shown in the same table. The hue of the surface after treatment is shown in the same table.
次にこれらのＡＣ８Ｒに散水パイプにより水通水を１分
間散水し、散水停止後５秒および３０秒経過後の水滴の
付着状態を観察した。観察結果を同表に示す。またこれ
らの散水後のＡＣ８Ｒについてコロナ発生試験を行なっ
た。その結果コロナレベルはいずれも極めて低いもので
あった。Next, water was sprinkled on these AC8Rs for 1 minute from a water sprinkling pipe, and the state of adhesion of water droplets was observed 5 seconds and 30 seconds after the water spraying stopped. The observation results are shown in the same table. A corona generation test was also conducted on AC8R after watering. As a result, the corona levels were all extremely low.
さらに比較のために実施例で用いたものと同じサイズの
ＡＣ８Ｒを０．０５重量％のモリブデン塩を含む酸性フ
ッ化アンモニウムの７０℃水溶液中に浸漬したもの、お
よび全く表面処理を行なわなかったものについて、実施
例と同じ散水試験を行なった。これらの結果を比較例と
して同表に示す。また実施例４、比較例３の散水中およ
び散水後の写真を第１図、第２図に示す。Furthermore, for comparison, AC8R of the same size as that used in the example was immersed in a 70°C aqueous solution of acidic ammonium fluoride containing 0.05% by weight of molybdenum salt, and one without any surface treatment. The same water sprinkling test as in the example was conducted. These results are shown in the same table as a comparative example. Furthermore, photographs of Example 4 and Comparative Example 3 during and after watering are shown in FIGS. 1 and 2.
（以下余白）
［発明の効果］
以上の実施例からも明らかなように、本発明方法によれ
ば架空送電線の表面に黒色の親水性皮膜が形成されるの
で、水滴の表面付着が防止され、従って水滴からのコロ
ナ放電による騒音発生を大幅に低減することができる。(The following is a blank space) [Effects of the Invention] As is clear from the above examples, according to the method of the present invention, a black hydrophilic film is formed on the surface of an overhead power transmission line, which prevents water droplets from adhering to the surface. Therefore, noise generation due to corona discharge from water droplets can be significantly reduced.
また、太陽光の表面反射が少なく周囲の環境に調和した
架空送電線を得ることができる。Further, it is possible to obtain an overhead power transmission line that has less surface reflection of sunlight and is in harmony with the surrounding environment.
第１図（ａ ）、（ｂ）、（０’）はそれぞれ実施例４
の散水中、散水停止後５秒経過、散水停止後３０秒経過
の観察写真、第２図（ａ ）、（ｂ）、（Ｃ）はそれぞ
れ比較例３の散水中、散水停止後５秒経過、散水停止後
３０秒経過の観察写真である。
代理人弁理士 須 山 佐 −
（ばか１名）
図面の浄書（内容に変更なし）
第 １ 因
１８２図
（Ｃ） 膠じ＝ニ冒
手 続 補 正 書 （方式）昭和５８年５月
２６日
特許庁長官 殿
１、事件の表示 特願昭５８−８１６６号２、発明の
名称
架空送電線の表面処理方法
３、補正をする者
事件との関係 ・ 特許出願人
神奈川県用崎市用崎区小田栄２丁目 １番１号（２２５
）昭和電線電纜株式会社
４、 代 理 人 〒 １０１東京都千代
田区神田多町２丁目１番地
昭和５８年４月２６日（発送日）
６、補正の対象
（１）明細書の「発明の詳細な説明」、「図面の７、補
正の内容
（１）明細書第６頁１行目「写真」を「水滴の付着状態
」と訂正する。
（２）同第９頁７〜１２行目を以下の通り訂正する。
「第１図＜ａ ＞、（ｂ）、（ｃ ）はそれぞれ実施例
４の散水中、散水停止後５秒経過、散水停止後３０秒経
過の水滴の付着状態を示す正面図、第２図（ａ）、（ｂ
）、（Ｃ）はそれぞれ比較例３の散水中、散水停止後５
秒経過、散水停止後３０秒経過の水滴の付着状態を示す
正面図である。」（３）第１図および第２図を別紙の通
り訂正する。
以 上FIG. 1 (a), (b), and (0') are respectively Example 4.
Figures 2 (a), (b), and (C) are observation photographs taken 5 seconds after stopping watering and 30 seconds after stopping watering during watering in Comparative Example 3, respectively. This is an observation photograph taken 30 seconds after watering stopped. Representative Patent Attorney Suyama Sa - (1 idiot) Engraving of drawings (no changes to the content) 1st cause Figure 182 (C) Proceedings for blasphemy amendment (Method) May 26, 1982 Commissioner of the Japan Patent Office 1. Indication of the case: Japanese Patent Application No. 58-8166 2. Name of the invention: Surface treatment method for overhead power transmission lines 3. Relationship with the amended person case - Patent applicant: Yozaki Ward, Yozaki City, Kanagawa Prefecture Oda Sakae 2-chome 1-1 (225
) Showa Cable and Wire Co., Ltd. 4, Agent Address: 2-1 Kanda Tamachi, Chiyoda-ku, Tokyo 101 April 26, 1982 (Date of shipment) 6. Subject of amendment (1) ``Details of the invention'' in the description ``Drawing 7, Contents of the amendment (1) ``Photograph'' in the first line of page 6 of the specification is corrected to ``state of adhesion of water droplets.'' (2) Lines 7 to 12 on page 9 are corrected as follows. Figure 1 <a>, (b), and (c) are front views showing the state of adhesion of water droplets during watering in Example 4, 5 seconds after stopping watering, and 30 seconds after stopping watering, respectively; (a), (b
) and (C) are respectively during watering in Comparative Example 3 and 5 after stopping watering.
FIG. 3 is a front view showing the state of adhesion of water droplets after 30 seconds have elapsed after the water sprinkling stopped. (3) Figures 1 and 2 are corrected as shown in the attached sheet. that's all
Claims (1)
のモリブデン塩を含む０．１〜１重量％の酸性フッ化ア
ンモニウム水溶液で加温処理することを特徴とする架空
送電線の表面処理方法。(1) A method for surface treatment of overhead power transmission lines, which comprises heating at least the outermost layer surface of an aluminum stranded wire with a 0.1 to 1% by weight aqueous acidic ammonium fluoride solution containing a trace amount of molybdenum salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP816683A JPS59134507A (en) | 1983-01-21 | 1983-01-21 | Method of surface treating aerial transmission wire |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP816683A JPS59134507A (en) | 1983-01-21 | 1983-01-21 | Method of surface treating aerial transmission wire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS59134507A true JPS59134507A (en) | 1984-08-02 |
Family
ID=11685745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP816683A Pending JPS59134507A (en) | 1983-01-21 | 1983-01-21 | Method of surface treating aerial transmission wire |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59134507A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4354465A1 (en) * | 2022-10-14 | 2024-04-17 | Nexans | Method for producing a hydrophilic electrical conductor and electrical conductor |
-
1983
- 1983-01-21 JP JP816683A patent/JPS59134507A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4354465A1 (en) * | 2022-10-14 | 2024-04-17 | Nexans | Method for producing a hydrophilic electrical conductor and electrical conductor |
| FR3140982A1 (en) * | 2022-10-14 | 2024-04-19 | Nexans | METHOD FOR MANUFACTURING A HYDROPHILIC ELECTRICAL CONDUCTOR AND CORRESPONDING ELECTRICAL CONDUCTOR |
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