JPS5899407A - Emulsion type cosmetic - Google Patents

Abstract

PURPOSE:A creamy or milky lotion cosmetic having improved emulsion stability, moisture retention, etc. during its use free from skin stimulation, containing a water-insoluble water absorbing polymer as an emulsifying agent obtained by polymerizing starch, a water-soluble polymerizable monomer and a crosslinking agent. CONSTITUTION:Starch is polymerized with a polymerizable monomer (e.g., acrylic acid) which is water-soluble or becomes water-soluble by hydrolysis and a crosslinking agent (e.g., 1,6-hexanediol diacrylic acid ester) in a weight ratio of 100:50-1,000:0.001-10 to give a water-insoluble water absorbing polymer. A creamy or milky lotion cosmetic containing this polymer as an emulsifying agent. The cosmetic has improved emulsion stability, viscosity stability, moisture retention during its use, water resistance, feeling, retention of makeup, etc. free from skin stimulation. The water-insoluble water absorbing polymer has particle diameters of about 100mu in dry time, water absorption capacity of at least 60ml/g, and the amount of the polymer used is 0.05-5.0wt% based on the total amount of prescription.

Description

DETAILED DESCRIPTION OF THE INVENTION The present invention enables the production of a starch-water-soluble monobase-crosslinking agent copolymer (water-insoluble ridges) without using an electrically conductive synthetic #P*m glue as an emulsifier. (natural mucilage) as an emulsifier. For use in cream or emulsion cosmetics (emulsification) - For more details: No irritation to the skin, emulsion stability, viscosity stability, moisturizing properties when drinking, water resistance, feel, and chemical properties. This article relates to 4IK excellent round hole cosmetics.

Conventionally, the necessary conditions for emulsified layer cosmetics such as creams and emulsions are (1) safety without shaving the skin M, (2) emulsion stability medium & (tRK) Ij + constant Being sexually active. (5) Supplying, retaining and chewing appropriate moisture to skin JIII etc. (high tlII moisture).

(4) Outflow due to water, sweat, etc. (A emulsification) Lm<, conversion, good make-up durability, and good feel when used on occasion.

However, rounding K satisfies the condition □・, or \.

M-1k composition measurement has been carried out, such as emulsified MO uniform combination, special base material combination, etc., but its purpose is difficult to reach.

For example, Ether Taki's non-ionic surfactants and anionic n-surfactants are highly irritating to the skin, while Maku Ester Seika and Ether Ki's non-ionic surfactants have poor emulsifying power. Emulsified cosmetics made of
By adding a small amount of ethyl alcohol, the emulsion stability and medium viscosity stability are significantly reduced. Unknown・On the other hand, anionic polymer mm quality (Carbo Nakashibi 2 kg 9J
- The cosmetics using carboxymethyl cellulose as an emulsifier give the polymer a sticky and medium feel, and when it comes into contact with water, it causes the attenuation of the polymer in the dark. However, one drawback is that even when applied, the koji paste, which has thickened considerably in one day, will aggregate and the rice will not come out evenly.

In view of the current situation, the inventors of the present invention have conducted nine million years of intensive research.
The emulsifying agent is a starch-water bottle monomer-crosslinking agent copolymer as described above. Emulsified lid cosmetics.

(1) A homogeneous and stable oil-in-water source (0/W oak) forms a gene in the emma, and (2) it remains stable even when a large amount (25x or less) of ethanol is added to the noodles without impairing the emulsifying properties or viscosity. in.

(Age Sonoho-hen is known to have unique properties such as being able to retain an appropriate amount of moisture on the surface of the skin and hair, and being highly water resistant without causing re-emulsification or run-off even when exposed to a large amount of sweat in the water. Headline, book, sent @Kj111.

The primary objective of the present invention is to improve skin stability (emulsion stability,
Viscosity stability, moisture retention during use, water resistance (i!l water-based)
K provides emulsified cosmetics that are excellent in texture, texture, and makeup retention. The second object of the present invention is to provide an emulsified layer cosmetic that softens and smoothes the hair, and provides hair with a thickening effect. 491 is water obtained by polymerizing starch (...) and a polymerizable monomer that is water-soluble or becomes water-soluble by hydrolysis, and a cross-linking agent (as essential components), followed by hydrolysis if necessary. Insoluble water-absorbing polymer as an emulsifier.

It is a cream-like or emulsion-like emulsified skin cosmetic that is a mixture of oily proboscis and water. The starch used in the production of the water-absorbing polymer with water-absorbing i1# properties in the present invention is t. Raw starch such as sweet potato starch, potato starch, wheat starch, corn starch, rice starch, kubioka starch ν, pregelatinized starch (gelatinized starch, dextrin)
,a#! Bumbun, dialgehyde starch, alkaline etherified starch, arylney? k oxidation f 7 nono, sialic acid starch in o, aa noechi ete k
oxidized starch, cyano, ethyl etherified starch,
Examples include modified starch (modified starch) of the carbo-dimethyldengue group.

- The water-based iris method single grave of trout has at least one iris (S, carboxyl group, carbon-related anhydride 41&, carbon base, sulfonic acid group, sulfone base) , Swimwear, Ether J!, Akido jl11% Aki)
monoethylenically unsaturated monomers having a monoethylenically unsaturated monomer, such as a quaternary amonyl group, a quaternary amonyl group, or a quaternary a/monicomb group, can be used. Examples of the ^-isomer side of such monomers include the following. As a water-soluble monomer having an addition compoundable double bond, (meth)acrylic (means acrylic range or methacrylic *1. The same expression will be used hereinafter)! Carboxyl group-containing monomers such as rain needles, - water! Carbon al such as rain carpet! Kuroki-Turnip containing monomer, sodium (meth)acrylate, alkaline earth metal salt of (meth)acrylic acid, aluminum salt.

Carboxylic base-associated monomers such as ammonium salt, (meth)acrylic triethanolamine, sodium maleate, methylamine salt of maleate, and vinyl nerfone.
, allylsulfonic acid.

Vinyltoluenesulfone #l, styrenesulfone acupuncture, (
meth)acrylic sulfones [sulfoglovir (meth)
Atarylate 1.2- and deUxy-5-(meth)acrylo, xip, tetrapyrsulfonic acid, etc.], 2-methyl-27
Acrylica Sho Dobuta Pansulfone Hitomi, *Sulfone group-containing monomer.

The monomeric alkali metal salt containing the above-mentioned sulfone cell.

An-1 diminutive salt, aden, chloride, sulfonic acid group-containing monomer, (meth)a, acrylic acid, siedel in acrylic acid, (meth)acrylic acid, *human, hydroxyl group in dipropyl group in a Containing monomer 1. (Meta 1) Ethylene acrylate! Repoor Katsume, Chiruenichiruho no Ete & Containing Monomer, ()
,! ) A: Examples include amide group-containing monomers 1 such as kryluad, N-hexynolacrylad, N-binolpyrrolidone, N-methylol, acrylic, and ruad. (Mackerel hydrolysis, decomposition, yosho, monomers that become water-soluble are: red bean paste, #i1. (Meth 1) acrylic methyl, (meth) acrylic ethyl, (meth) acrylic 2
- Ester group-containing monomers such as -ethylhexyl and vinyl acetate, and monomers having nitrile A& such as (meth)acrylic 11 nitrile.

Among these water Sa monomers having addition summerizable 21 bonds, which are monomers that become water soluble by hydrolysis, 9 water-insoluble monoaqueous (water-retainable) J1 combined t-
From the point of view of producing it at Taniichi, it is preferable to use a water-S monomer having 1k addition monomerizable double bond, since electrolyte polymer hydrolysis is required for other purposes of the present invention. , Toru super water absorption (hydration) - is from one point where power is obtained, preferably (meta)
Acrylic #II 1% maleic anhydride gms monomer f having a syl group in Cal I, sodium (meth)acrylate,
(Meta)triethanol is a monomer having a carbonyl group.More preferably, a monomer t-containing a carbonyl group is used. (4) and (to) and (T-m) The method of neutralizing with alkali is a good method because it provides a high total strength of iron water (total water holding power).・This method of neutralizing gold is , conventionally known square iron may be used, and examples of the clay include alkaline earth salts, ammonicum salts, and ammonium salts.

Any crosslinking agent may be used as long as it can produce a BL reaction product of (~ and (casting), including ethylene glycol, trimethylfluorohan, glycerin, 1,6 - Ditang or tree (meth) of polyols based on henanadiol and polyoxyethylene glycol
Acrylic esters%, li, N-methylenebisacrylic esters, tri(meth)acrylates obtained by reacting polyepoxide and (meth)acrylic acid. Diglycidyl ethers of polyols such as If9 cisyl ether, diethylene diglycidyl ether in polyol, glycerin diglycidyl ether, tolylene diinocyanate, polyinonoanate with sameethylene diinocyanate in polyol, etc. (meth)acrylic dihydro-7
Di(meth)acrylic sancarboxylic ester S prepared by reacting with ethyl.

Examples include allylated dengue/etc., and in some cases, methylolated (meth)acrylate.

Under certain reaction conditions, such as gliopolymer, 1% adipine, ethylene chloride, etc., the reaction product of (AI) and (alcohol) can be cross-linked with bifunctional metal compounds or calcium oxides. Polyvalent metal salts such as diacetate, JIL brass, etc. can also be used. Among these cross-agents, the di(
Meth)acrylic acid esters, glycidyl ethers of polyols, and bisacrylic acid esters are well suited for use.
・In the production of the insoluble water-absorbing polymer of the present invention,
- Metal compounds (monomers) other than those mentioned above, such as styrene, ethylene, and
, butene, etc. can also be used.

The method of polymerizing the polymerization of 2), (Xi) and (X) may be any conventionally known method, such as a method of irradiating with radiation, electron beam, ultraviolet rays, etc. Benzoyl persulfide, azobisinobuti nitri #, azobisinopalesonic acid, persulfuric acid 4
Examples include polymerization methods using radical heavy metals such as crystallization.Among these, radiation polymerization involves irradiation with electron beams, algae, etc. The method of polymerization using a hydrogen peroxide catalyst or a hydrogen peroxide catalyst improves the ratio between the starch in #4 and the polymerizable monomer in the cast, and results in a high %A water absorption ( It has the ability to hold water.

This insoluble water-absorbing polymer is preferable because it is easy to obtain. The weight of − gold is 4410 @ (for so ~1ooo, (
(I Tsuji (LO・1-10 is preferable, most preferably Hiro (
鴫dlGo-500,1CI (LOl-5&h
If necessary, add water, methanol, ethanol-dimethylformade, and these hot metals as needed.
The temperature when using & is used in the CC building is 10 to 150℃.
℃, preferably 20 to 143 QC, and the hydrolysis of the above-obtained Jusha Rat reaction product may be carried out by any method known in the art.
Normally water-soluble Nakatomarusha water and Allure in a warm medium of 1
For example, it is carried out at 11 degrees Celsius at 1G to 150 degrees Celsius using a layer of sodium hydroxide, hydroxide, etc.. If sulfone groups, etc. are present, neutralize them using an unknown method,
JI+ (alkali metal salts, ammoecum salts, adenyal salts) can be converted into salts. Wash to remove unreacted crosslinking agent in the monomer, dry and grind.

In this way, C' is obtained, and the water absorption Ik of Kuhonfumei's water resistance is
The polymer has a high %A water absorption (hydration) performance, i.e. at least 60 fin (40ws#/F) of its own weight.
1jloO-8ol) times (100m breath/f~5OO)
s + A / A), does not lose water retention even under pressure, and can be used for long-term water-retaining (water-retaining) dal-like dishes.
K is retained and ζO is water-resistant! The water-absorbing polymer of ik is water-independent, but it retains a large amount of water, and @jll
1g of EK Glue-like Krogel is used to uniformly and stably emulsify and disperse an oil-based substance from 1k into an emulsifying base.

Rich feel when applying emulsion layering, and a firm feel after application!
As a reference, in addition to giving a smooth and sandy feel, it also provides the right amount of moisture to the skin, has a long-lasting effect, and has remarkable properties. Regarding the skin III irritation of water-insoluble water-absorbent 1, the CC10 result, animal skin irritation score, and human skin irritation score are all substantially Ω, according to the method of Biographical Drais. It is acknowledged that both are non-irritating.
soo1a11ox> of Wood and
Drugoffioials or Ski@Unit
@d atats-ppra-1sml of
th@1laf@ty of Oh@m1otl
- Mun Foods.

Drugs and Comm@tiom, 44
(1959) eT@xas, a%a%* Da)ar
tmsnt of Wealth,Austim,
The water-insoluble monomer OIa content (value noodle) in the three-shot mIC is a 5 to 10 weight percent, preferably a2 to 502 to 40 weight% WaS, relative to the amount of gold. Emulsification is very high when the weight % is 51% by weight, and the fluidity decreases when it exceeds 51% by weight.The particle size of the water-insoluble water-absorbing polymer when dried is:

One of the preferred oily substances that can be used in the present invention is one with a diameter of 100 microns or less, which is a well-known oily substance for skin cosmetics, and is the best known oily substance for use in skin cosmetics. l! Chin, prayer oil-
Types, vegetable oils and fats, and related products.

Grade alcohol, 114#11) I; fI fat-ester oil 1 silicone oil, etc.;
For example, liquid Bakufin, Squalano, and Vaseline.

Dragon resin, vegetable oils and fats such as olive oil, k,
! &m% Cacao oil, nominate oil, physical oils and fats include mesu liver oil, beef tallow, butter, etc.

In a pinch, if you have leftovers, you can use kanrou, carnauba pt, etc., and for high-quality tuna ribs, for example, Laughlin Maro.

Electric listin, Palshonan acupuncture, stearin carpet.

Olein carpet, behemoth iron, lanolin tuna fat, etc.

One example of high court alcohol is 12>ci millirua tomi.
Stearate, stearyl alcohol, seven del artzol, oleyl alcohol, tatami, ester oil, beech, stearate, heki VJ & Tsukreji, oil dodecyl myristenite, diinoprobil adipate, shiitsubu μ
Examples include linear esters and branched chain esters of pilsepacute;

These tIs substances are used alone or in combination, and the amount of O used (total amount of IBD) is usually 5 to 40% by weight
``There is.

The amount of water used is SO~9s weight X.

The cream-like or emulsion-like emulsified cosmetics of this invention can be made by blending ethyl alcohol.

Moreover, when the weight is less than 20X, the emulsion stability improves with the increase in the blending amount. Found in emulsified cosmetics emulsified with active agents
It is unique. The amount of ethyl alcohol used (blended amount) is at most 2s weight x, preferably 2 to 20% by weight. With iK$P, pigments (for example, Merck, Kaolin, Uneka Chiin Tatami) are blended into the makeup base, etc., and the amount thereof is 5%, preferably (L
i-=triple 1[.

The ingredients of the ring are 0 fragrances, colorants, etc.
*Required* Kj6 also contains a tL-toning agent, a skin mJm1m inflammation agent, an antiseptic agent, an external line collection agent, a softening agent, and a propagation agent.

Book! ii Akira cream or milky emulsion layer makeup 1%
&i, emulsion stability 1 jolle (inkstone FIL) has good stability, rope retention during use, water resistance, * water resistance, feel (sleep and movement, sariba movement, ff cool feeling), makeup retention, etc. 11
p (f4JL is Suchuinterim, skin book.

make-a, base, t-screen, etc.), Kabushina for 屹M (
It is extremely useful as a hair treatment tatami (ehiro hair cream, hair treatment tatami).Hereinafter, the actual 1 hour of one day's work will be examined. to sing the part. In addition, feel, stability, and viscosity are low!
sex.

For emulsion-stable wax, water resistance, water resistance, etc., please use method O described below.

(11 Sensation Panel - 20 people conducted a practical test on the first sea -
Evaluation (5-point system) was performed, and the results are shown as average values. A high TK score indicates that F is Arashiyoshi & M1 bales feel (famous, steady) feeling) (2) Moisturizing property 1, Bjj company's slogan I/P〆sme 7- (fill-
, 554 birth) and added one more constant is 20℃ f
fi+l1jiK oi? , constant Jli ((L 2
A sample of f/4-) was applied to the upper arm of an adult male.

As a matter of fact, the conductance (in units of mike peaks)' was constant.It was very hot in the air, but the electric stove in Illllll was small.

*It is said that the humidity is good.

(5) Viscosity stability (change in viscosity by 1 degree per - day) A sample was placed in a constant temperature bath at 45° C., and a change of 8 degrees was observed. In addition&
! i degree is % Bffi-1 Viscosity was measured at SOC using a needle.90(4) Emulsion stability Sample T45C was placed in a constant temperature bath, and the appearance of the emulsified tumor was observed after being released for 3 months, and no abnormalities were observed. If not (emulsified g
If the process is uniform and homogeneous, then Fi
It is considered to be in good condition, but if any abnormality is observed (if oil separates, 1)
- (gradient water resistance test myristic octyldodecyl (MOD) (oil-based 411)
+1 Negative) 1-, Spring 2-Apply a certain amount evenly to a certain area of the back and chest of 10 people.
Lru・After that, do water body (water bath) for 11 hours, Maruki, Shima o@
From the yam part, I wiped off the key mark, 14#lK wipe, 1111L coffee, and a sample for electricity storage after water mixing. Seal the soaked sample into cm-thin pieces and seal the large 1h) / a
a 7 orum (extraction agent) 5 omit) Soak it in KN and stir for 10 minutes to extract it, then repeat this operation with a new couloform. Insoluble
(if any), fill up a certain amount with a film, and calculate the value from calibration by gas chromatography under the following conditions.
Quantify ODI.

Kammu: (jV-1, stainless steel column: 1 steel.

Temperature [=270℃, IJ-Jiji 2 4500℃.

Gang, JII! ! The amount of MOD obtained by wiping it off immediately after the cloth is 100, and the amount of MOD obtained by wiping it from another part after swimming for 1 hour ff1K is expressed as the MOD f1m tube remaining, and 10
Indicates the average value of the name.

(6) Slightly aqueous soap panel - 20 people's hands, spread a sample of emulsified cosmetics with a constant lid - Km, rub with both hands under running water for 1 minute 4t1
However, the slight aqueous t Shirape 9 that the skin dregs of the large fingers had was evaluated using a 5-point system, and the average value of 7 M vermilion was used. A high score of 1 indicates that the water quality is stormy.

Example 1 (Cream) 40 g of pregelatinized starch (Hodogaya Chemical), 160 parts of water and 800 parts of methyl alcohol were added to a reaction mixture,
``iI! Spiritual flow down 511111.14 Sekihiko stirred and dissolved.
Cool this pregelatinized densate to 1mmk3Ω℃, and add 6
0 parts of acrylic area %a 2 parts of 1,6-nanodiol di-l-acrylic ester and 11 rim of persulfur of (L2-) as a polymerization catalyst were added and polymerized at 40°C for 5 hours with stirring. White-IIi! filter-shaped Physioglycera sinensis was used for the purpose, and the polymerization rate was 98%, or 69%, based on the total amount of large monomers.

Prayers were prayed for by walking down this white ms slope. Pregelatinized starch - acrylic acid #fi - 1,4- to nanedioldiathalyl sapon ester 27) Electrolyte ゛t 30% and thoroughly washed with methyl alcohol-crystal compound (5:1)' and dried under reduced pressure for 5 hours to obtain pregelatinized starch-acrylic-sodium-1.
, 6-Nakanandiol diacrylic Jllll ester glat polymerization IIK to Mokanaka (, The blending amount of water-insoluble polymer is (115 ~ 1%, 66caz ~ &
ON is good.

Example 112 (Riso-mu) 1!9436) IF Moguri Kosidenopun was dispersed in 400 parts of water and 1001 g of methane, heated to 7S°C under a stream of air, and heated and stirred for 1 hour. Special basket M'
: 1 $ / starch water S * in the 9-this tofu basket - rich starch 7 water solution 1 I Q' @ akshi kIII AS club 7
Zobisparerlic acid was added and polymerized for 2 hours at 50°C.90 Then the heavy metal product was added with 25% sodium hydroxide V
rim water - methanol to maple gold 1i111 (water to methanol 1
z) Heated in o and reacted for 2 hours under methanol flow.
) and dried under reduced pressure.The yield of the large gold body obtained was 97X, the water absorption was 180%, and the polymer was insoluble in water. A cream was prepared in the same manner as in Example 1, except that the particle size of this polymer was shown in the second column, and it was carbonized to a large extent. As is clear from the results of Recommendation 21I shown in Tate!
I21I Example S (cream) 20m Wil method starch y f 400 NO water KSO
The highly soluble dengue water sm obtained by stirring and dissolving at ℃ was then cooled to 60 ℃, and to this was added 80 parts of acrylic acid, 5 g of ethylene glycol dimethyl chloride, and αS@ as a polymerization catalyst. Added ammonium and heated to 60℃
, 5 o'clock I41a Stir and polymerize 9. At this point, the whole becomes gel-like. 60 E・The gel-like state is finely ground, S! The mixture was dispersed in 600 parts of ethyl alcohol with sodium hydroxide and left overnight to neutralize.

ah, filtered through a thick gel, and diluted with water in ethyl alcohol.
4/1 Kaede's match with the enemy, the light was washed.

At 120℃＾g! Dry it and then crush it with a jet mill to make the elephant powder wood the size of a tower.

At the end of the above-mentioned Harayo, wash it with water and remove the Wednesday-minute amount by 10 minutes.
Vacuum tgIk at 120°C.

Obtain l1tiIPL, a water-insoluble powder, at the factory.

Water-resistant #wood is 110% starch, 12% acrylic acid.
0%, sodium acrylate 7α6X.

ZfV:/f9 Starch-acrylic acid-sodium acrylate 99-mu ethylene dalyl dimethacrylic acid ester graft 1 consisting of cold dimethacrylate ester a4X
In the body, e, ta * sexual magnification 0 μ), carboxymethyl cell ■-su (o MO) * carboxyvinyl polymer (
Add 10 parts of each of Kerr and Polyvinyl Altool (PTA), and use 8 & 9 parts of water, and mix 1 and 1 to prepare a cream. The results are shown in the stripes S. As is clear from Table 5, the water-insoluble water-absorbent 1 combination had good release and elongation at m1, and good stiffness after m1, and inductance value. Kadaisho <(a a lot of water)
It has excellent moisture resistance, emulsion stability, viscosity stability, water resistance, and hydrophobicity.

In contrast, carboxyvinylpolyw-1PVA, O
MG has a long lasting stiffness and stiffness after m1, and the conductance value is low and the moisturizing properties, water resistance, and water repellency are also poor. 5IR Example 4 (Cream) Example 1 It can be used for hexachloride, acrylic acid and 1.
6-Nakasu/Diol Diacrylic Textile Technology Chill (Crosslinking Agent)
By changing the preparation composition.

In the same manner as the base 1mM5, starch with the composition shown in Table 4 was added (water absorption Q1 combination of water fM characteristics).
I got it. The yield was 97% or more in all cases, and 1 ton of the above polymer was obtained as a water absorption 1 polymer of Suigun II property.
A cream was prepared by using 100 g of water and 8 to 9 g of water by combining it with Example 1 and I'l. Seventy Seeds 4th
I showed you ^ Example 5 (Cream) Break down the monomers of Wheat Gide/G/ and Shinsui.

Blat polymerization was carried out in the same manner as in the example site of *Placement and Use-Seitatisha, and potassium potassium persulfate α was used as a polymerization catalyst.
3ii1. Large size for sodium sulfur a1StS.

In addition, as a polymer number of Mu1 of the 5th fiber, it is a kohan body.

Acrylic region and 2-hydroxyethyl methacrylic acid ester, cyacrylic J to tetraethylene/1 co as a similar agent
/1111 Threatening co-optation using esthetician K! Coalescence Example 1 and the large polymer produced by neutralizing the acrylic region of the polymer component with hydrated sodium are methanolyl-methyl ester. and M, M
-Methylenebisacrylamide was used to give x-# and was hydrolyzed in the same manner as in Practical Example 2.

A simple polymer contains 2-methyl-2-a/l as a monomer.
Luaden dope pansulfone, propylene 11-carbon dimethane as m-agent, each daft polymer (water-insoluble water-absorbing polymer) was thoroughly washed with 70X ethyl alcohol, purified, dried and gelatinized. Crush it with a tl.

50~60μK11il! IL9. The reason for using 1 m of these as a water-absorbing polymer and 9 parts of 11 a of water is to mix it with practical fit and psjroku and make ai cream.
*The performance of Jllil and Hakama cream is shown in Table 6 and circled.

Stripes 6 Fitting Example 6 (Cream) Example 10 Water-insoluble water-absorbing 1 combination (Grain @ SO ~ 60
μ) Mix tOW, disodium edetate, and ethyl alpur as in Iris 7wR, add water to the necessary amount to bring the total amount of prescribed ingredients to 100%, and mix in the same manner as in Example 1. The performance of different creams containing ethyl alcohol is shown in Table 7.90 As is clear from these results, even if a relatively large amount (25x or less) of ethyl alcohol is added, A smooth emulsion with emulsion stability and excellent cooling sensation is obtained, and water resistance 6. *It has excellent aqueous properties, and when the ethyl alcohol content is below 20X, the stability of the emulsion system increases as the ethyl alcohol content increases. death#
s71& Example 7 (Make F, Base) Add 1sII of ethyl alcohol, add 81iK of pigment (titanium oxide), and adjust the amount of water until the total amount of prescription ingredients is 100 parts. The mixture was mixed in the same manner as Example 1, except that the amount (/(2 ounce amount)) was used.
Emulsify and make make-up base tll to obtain a large amount of make-up and make-up base properties as shown in Table 8. Department.

A local skin cream containing J/11Fj/10g, water s & 6@, Z detox xf tosoum (II drug) czll, and fragrance Na1ll-6 was prepared in accordance with Example 1. 4.Rare skin cream has good texture, gloss, homogeneity, and stability.
) a, pJgloOPB (45°C, moldy for 3 months, #o
oops), etekue, the above-mentioned Kanemoto nature is high (at 5),
Panera uses K11l to give you a cool feeling on the skin, a good feeling on the lines, and also makes your makeup last longer.
(18 out of 20 people) IIIg from K Example 9 (Skinki Luk) Water-absorbing polymer ah@ of the water-insoluble method of implementation f4t.

Etel Albou K 15 parts.

N◆, 50 parts of olive oil, 9 parts of MODtO, 7°C water,
Disodium edetate (L1 part, the schuin written in the fragrance asi1 belongs to the verb N-6 in the ordinary law. At the industrial margin, Kinuta IIL (30℃) is
110018 (45℃, loooopa after 3 months)i
``6 pieces, .-tlll Che alcohol Kusoki's water resistance (MOD survival rate) after 10 minutes -l'' 92, 4. 89% after 50 minutes, 1 hour value is OX <, m The water resistance rating is 4, which is good, and when used, it gives an IKK cool feeling, a good TK feel like a P1 type, and it is confirmed by the spring 2- that it is different from the Garrison JLIA. -Example tg (^Arcream) - Water-insoluble water-based polymer LO part of Example 1, white wax seven parts A part, tsutsuro tag, 15 parts of chaotic paraffin, 7 parts of water
Tun 4i11. Make the edetate dinato sotsumu atg, fragrance as part into a w-method verb.

This hair cream is @-, glossy Arashi Ikatsu homogeneous, stable 10/W wear emulsion, manufactured by Kinuta Arashihiro wIi after /U ρρρ 01B, 45℃, Sumika A after // 3ρρ
It was OPB. Its water repellency rating was 5, and the emulsion stability after 45°C and S Yugetsu was also good, 629.

Chiku, when used, it comes off easily and grows easily.

! ij Example 11 (8-anti-slip cream) \ water-insoluble textbook 1 coalescence α8 part of treatment 1.

Olive draw 10m! , Motto department, m-dynamic paraffin 1
ρ0 part, 40 copies of the sophistication teaching agent, water 6 & 8 pieces, Edet #!
Engineering 1. A sunscreen cream consisting of 1 part of thorium α and 5 parts of fragrance is made according to the conventional method, and the 8-threshold sunscreen cream is homogeneous, stable and OA-certified emulsion, and is kept at 45℃, S? Emulsification stability after 0 milk after J4 Stability was also good. Also, &l Haruka's water quality rating is 5
．． MOD's water resistance rating is 97 in 10 minutes of swimming.
%, 90% after 30 minutes, and 859 after 1 hour of bales.

夷jmMt2 (Sun-Sunscreen Cream) 1iit without adding MOD and using water 44cm was carried out in the same manner as in Example 11 to prepare Sunscreen Cream II4. After 9 days, the cream is homogeneously stable and has good emulsion stability and viscosity stability after 5 months at 45℃. A total of -45, and the make-up in Jl sub is also good.

The panelists (females = 19 out of 20) reported that the anti-inflammatory cream of Example 11 was as good as the anti-inflammatory cream.

Example 18 (Cream hair treatment) Water 8
・Isopropyl iris in the part) Sil.

Flavoring (Add Ll noodles, stir well, and add a small amount of water-insoluble iron aqueous polymer as a two-part emulsifier)! Stir for 10 minutes and prepare a creamy hair treatment containing lead (hereinafter referred to as Treatmentm for convenience). ・This treatment A is stable even after 4 SC and 4 Yugetsu #, and there is no abnormality in the emulsified haze. And hard jmb (
The card meter showed no hardness and K4 keying.

For comparison, hair treatment (treatment men) B) was expanded in the same manner as in the present invention, except that carboxyvinylbo 1Jff- (iiill14, car 4pol) was used for the decomposition of the slightly aqueous polymer. For the past 90 years, V Young- Spread the above treatments (M and B) evenly on 4 km of well-washed hair, massage the hair, rinse with warm water, dry, and apply the hair treated in this manner for 4 km. WIfwa) and t
Evaluate the length of the hair using the Enikusaka Judgment and show the results in section 91iK.

Table 9, IL-11) Treatment A) Treatment B (invention) (Comparison) Taimanatsu 0.154 0.202 Wages -
Stress (jF) 4,565. Rating (points) 5 out of 11 Notes: (11 dynamic manatu 4Ik numbers were determined by radar method massatu grip.

(The stress at work is determined by adding a certain amount of II & salt 4 to 40 and the stress at 9 o'clock.) 5 and the lowest is 1). As is clear from this result, the 1 m pine mooring is small for the 1 m pine mooring, so it is smooth and smooth. It is good that the stress at the time of elongation is small, so it is good to use the system, and according to the evaluation of the vice-ministerial letter, it is good that the stress is good during the process. In the 4 hairs that were well treated with Treatment B, there was a tendency for the hair to become weaker and weaker, and the hair Il to be medium. *
VSO Example 19 (skin cream) Water-absorbent water-absorbent filter body of Example 1 as an emulsifier (Ll)
ml, olive oil 1 (LOiil, Mt) DLO part, a
mba 27 (/1911% water 41-6 @, z detoxifying sodium α 1 part, fragrance 1lL 5 parts) and use the usual method to prepare skin cream. The water resistance of λ gene is 97% after 1υ minutes and 90% after 60 minutes.
, 63% at 1 o'clock threshold lie ^ (, it is 5 and it is large.
Comparison Example 1 As an emulsifying steel, polyoxyethylene ceter ether # (MO-
5,544) aS 1611 and vxt7 phosphorus ethylene norpitane (0 = 20 mol) αSS
0/
W! ! Prepare IT's skin cream.The water resistance test of this skin cream shows that MOD's retention rate was 48% after 10 minutes.

It was 21% after 50 minutes and 8x after 1 hour, which is extremely low. In addition, as a result of the above-mentioned water rupture trial conducted by panelists, the evaluation score was 0, indicating that there was no binding property and that the skin cream applied to the hands and fingers turned white in water and dispersed. Applicant: M-Hyaku Stock Co., Ltd. Procedural Amendment (Voluntary) April 5, 1980 Patent Office Officer Shima 1) 11 Indication of 1 item Patent No. 197196 of 1982 2, Title of the invention Emulsified Cosmetics 5 Relationship with the person who makes the correction Patent applicant Address: 1-3-80 Tomobuchi-cho, Bejima-ku, Osaka-shi, 5-17-4 Aeda, Sumida-ku, Tokyo 554-\, 5. Column 6 “Detailed Description of the Invention” of the specification subject to amendment 6 Contents of the amendment (1) r described in the specification @5j+j lines 5 to 7 Aeon Li Fan activation l!
ll#i Poor emulsifying power. Delete j.

(2) r (oil-based substance) described in the specification, page 20, line 11, j of 10 panelists, ``(oil-based substance) as a marker, test t + panel-1
Corrected to 0 people.

(5) M from the r calibration curve described in the specification, page 21, line 6
Correct the OD in the sample from the standard curve.

Claims (1)

[Scope of Claims] (1) Starch (starch), a polymerizable monomer C@ which is water-soluble or becomes water-soluble by hydrolysis, and a crosslinking agent (starch) as an essential component, must be 11 The water-insoluble 0.1* property obtained by adding moisture to the liquid is a milky emulsion. Stratified IIIL% (2) - A water-absorbing polymer with non-water distribution properties is distributed in an amount of aO- to each Dg amount % to the bulk component-!L lid.Claims S (1) - The emulsified cosmetics described above have a water absorption performance of at least 60 ws#/lf. 11th paragraph (1) 1it -
44) Water-absorbing heavy metals with hydrophilicity are composed of #-arranged (axis and (q) and (q and t heavy metals. 411 Permissible range! (Emulsified layer cosmetics according to item 13) (The water-insoluble water-absorbing polymer is
1: (Shou no Ryōkai (J [Rokuhi) sings from 00:50 to 000
: Polymerize with ccoo1 to 10 circles to produce nine things,
Machining needle #1 - It can be obtained by polymerizing the former polymerizable monomer and □Emulsification-reduced cosmetics. (7) The water-insoluble water-absorbent 1 combination is -(4)
and. (to) A polymerizable monomer having a 1M tube and (2) are polymerized, and the acid groups of the produced heavy metal body are substantially neutralized with an alkali metal hydroxide. Emulsion layering of rattan (1) in claim I11@
・(…The water-absorbing polymer is water-resistant and has a grain movement of 1 when dry planing.
4alOQt/Ron's. Dinner - Request Ohan - Stripe (
1) Emulsified layer cosmetics described by Kaede (9) The alcohol content is at most 25% by weight with respect to the stannous component. 411 Enchanted Mouse (1) Maki Nori's emulsified cosmetics. (In fact, the pigment content is at most 5.01% of the total amount of prescription ingredients.)
Amount X is mixed. Claim 11 WA jII
Emulsification as described in (1) - Cosmetics