JPS5864413A - Catalytic combustion equipment - Google Patents
Catalytic combustion equipmentInfo
- Publication number
- JPS5864413A JPS5864413A JP16325981A JP16325981A JPS5864413A JP S5864413 A JPS5864413 A JP S5864413A JP 16325981 A JP16325981 A JP 16325981A JP 16325981 A JP16325981 A JP 16325981A JP S5864413 A JPS5864413 A JP S5864413A
- Authority
- JP
- Japan
- Prior art keywords
- temperature
- catalyst
- air
- catalyst body
- combustion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C13/00—Apparatus in which combustion takes place in the presence of catalytic material
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Gas Burners (AREA)
- Spray-Type Burners (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、ガス状の燃料と空気との予混合ガスを酸化触
媒体に供給して接触酸化反応により無炎燃焼を行なわせ
る燃焼&置の、触媒体温度を検知し、これをもとに供給
する空気量を制御し、常に安定した触媒燃焼を行なわせ
るようにした触媒燃焼装置に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention detects the temperature of the catalyst body during combustion and combustion in which a premixed gas of gaseous fuel and air is supplied to the oxidation catalyst body and flameless combustion is performed by a catalytic oxidation reaction. However, the present invention relates to a catalytic combustion device that controls the amount of air to be supplied based on this, and always performs stable catalytic combustion.
一般に、燃料を触媒燃焼させる場合、所定の空気量よシ
多く供給してゆくと、通過速度の上昇に伴ない酸化可能
な量が低下するのと、余分な空気による冷却効果で触媒
体の温度は急速に低下する。Generally, when fuel is catalytically combusted, if a larger amount of air is supplied than a predetermined amount, the amount that can be oxidized decreases as the passing speed increases, and the cooling effect of the extra air causes the temperature of the catalytic body to rise. decreases rapidly.
これにより、ついには反応しきれずに、−酸化炭素や不
完全燃焼成分である炭化水素を放出する、いわゆるスリ
ップ(吹飛び)を生じ乙。逆に空気量を減少してゆくと
上記と逆の効果に、さらに、高温雰囲気中での燃料の分
解酸化量の増加が加わシ、触媒体の、特に予混合ガス流
入側が特に高温となってくる。さらに、予混合ガスの触
媒体への流入速度が火炎伝播速度以下であって、触媒体
表面温度が発火点以上であるとバックを生じ、触媒体よ
り手前で火炎燃焼を始める。このように、スリップを生
じた場合には、−酸化炭素や未燃成分による臭気を発生
し、バックを生じると燃焼筒や触媒体を異常に加熱し、
触媒燃焼装置を損なう場合があった。As a result, the reaction cannot be completed and carbon oxide and hydrocarbons, which are incomplete combustion components, are released, resulting in so-called slip. On the other hand, if the amount of air is decreased, in addition to the opposite effect described above, an increase in the amount of fuel decomposition and oxidation in the high-temperature atmosphere will be added, and the catalyst body, especially the premixed gas inflow side, will become particularly high temperature. come. Furthermore, if the inflow velocity of the premixed gas into the catalyst is lower than the flame propagation velocity and the catalyst surface temperature is higher than the ignition point, backing occurs and flame combustion starts before the catalyst. In this way, when slip occurs, odor is generated due to carbon oxide and unburned components, and when back occurs, the combustion cylinder and catalyst body are heated abnormally,
There were cases where the catalytic combustion device was damaged.
本発明は上記の問題点を解消するもので、触媒体温度を
温度検知素子によってモニタし、常に安定した温度が得
られるように供給する空気量を制御しようとするもので
ある。The present invention aims to solve the above-mentioned problems by monitoring the temperature of the catalyst body using a temperature sensing element and controlling the amount of air supplied so that a stable temperature is always obtained.
以下に本発明を液体燃料を用いた触媒燃焼装置に応用し
だ一実施例を第1図に示しその構成を説明する。An embodiment in which the present invention is applied to a catalytic combustion apparatus using liquid fuel is shown in FIG. 1, and its structure will be explained below.
1は有底円筒状のファンケースで、底部には給気導入口
2が設けられており、外方に金具3によってファンケー
ス1底部外方に固定されたモータ4のシャフト5はファ
ンケース1の中心線上を給気導入口2からファンケース
1内゛に挿入されている0モータ4は給気口6を有する
モータケース7によって覆われている。また給気ロ6外
部にはサーボモータ8、これによって駆動されるダンパ
9が設けられている。一方、シャフト5にはファン1o
が、またファンケース1には案内羽根11が固定され、
それぞれ交互に、多段に設けられている。ファンケース
1の他端には中央に空気口12を有する固定板13が嵌
合され、固定板13外方に向けてバッキング14を介し
、燃焼筒15が装着されている。固定板13近傍の燃焼
筒15側壁にはシーズヒータ16が埋設され、その前方
に設けた金鋼あるいはパンチングメタル製の抵抗板17
と固定板13に囲まれる空間を気化予混合室18として
構成している。燃焼筒15内の抵抗板17前方にはスペ
ーサ19、整流作用を有する整流板2o、触媒体保持金
具21が装着され、耐熱無機材料であるアルミナ、コー
ディエライト、ムライト、炭化珪素、アルミナチタネー
ト等をハニカム状に成形して担体となし、白金族金属等
からなる酸化触媒を担持した触媒体22これを固定する
保持金具23を順次装着している。触媒体22装着部分
の燃焼筒15外壁には温度検知素子24を設け、触媒体
22から燃焼筒15に伝わってくる熱を検知し、触媒体
22の温度を二次的にモニタできるようにしである。本
実施例ではシーズ型、に熱電対を用いた。また、燃焼筒
15先端は熱交換器25に接続されている。Reference numeral 1 denotes a cylindrical fan case with a bottom, and an air supply inlet 2 is provided at the bottom. A motor 4 inserted into the fan case 1 from the air supply inlet 2 on the center line is covered by a motor case 7 having an air supply inlet 6. Further, a servo motor 8 and a damper 9 driven by the servo motor 8 are provided outside the air supply chamber 6. On the other hand, the shaft 5 has a fan 1o
However, guide blades 11 are also fixed to the fan case 1,
They are arranged alternately in multiple stages. A fixing plate 13 having an air port 12 in the center is fitted to the other end of the fan case 1, and a combustion cylinder 15 is attached to the fixing plate 13 outwardly via a backing 14. A sheathed heater 16 is embedded in the side wall of the combustion tube 15 near the fixed plate 13, and a resistance plate 17 made of gold steel or punched metal is provided in front of the sheathed heater 16.
The space surrounded by the fixed plate 13 and the fixing plate 13 is configured as a vaporization premixing chamber 18. In front of the resistance plate 17 in the combustion tube 15, a spacer 19, a rectifying plate 2o having a rectifying effect, and a catalyst holding metal fitting 21 are installed, and are made of heat-resistant inorganic materials such as alumina, cordierite, mullite, silicon carbide, alumina titanate, etc. A catalyst body 22 supporting an oxidation catalyst made of platinum group metal or the like is formed into a honeycomb shape to serve as a carrier, and holding fittings 23 for fixing the catalyst body 22 are sequentially attached. A temperature detection element 24 is provided on the outer wall of the combustion tube 15 at the part where the catalyst body 22 is attached, so that the heat transmitted from the catalyst body 22 to the combustion tube 15 can be detected, and the temperature of the catalyst body 22 can be monitored secondarily. be. In this example, a sheath type thermocouple was used. Further, the tip of the combustion tube 15 is connected to a heat exchanger 25.
一方、点火プラグ26は燃焼筒15、触媒体保持金具2
1を貫通して整流板2o近傍に臨んでいる。気化予混合
室1日内に達しているモータシャフト5の先端にはモー
タ4側より、先端に向けて径の大きく−なる円垂台形の
コーン27、回転板28周端に攪拌用小羽根を有する混
合板29を順次固定しである。また給油管30はファン
ケース1を貫通してコーン27上方に開口するよう設定
しである。31は温度検知素子24の熱起電力を基準電
圧と比較してサーボモータ8を駆動し、ダンノく9開度
を調節する制御回路を納めた制御ボックスである。On the other hand, the ignition plug 26 is connected to the combustion tube 15 and the catalyst holding metal fitting 2.
1 and faces the vicinity of the current plate 2o. At the tip of the motor shaft 5, which reaches the vaporization premixing chamber within one day, there is a trapezoidal cone 27 whose diameter increases toward the tip from the motor 4 side, and a rotating plate 28 has small stirring blades at the peripheral end. The mixing plates 29 are fixed one after another. Further, the oil supply pipe 30 is set to pass through the fan case 1 and open above the cone 27. A control box 31 houses a control circuit that compares the thermoelectromotive force of the temperature detection element 24 with a reference voltage, drives the servo motor 8, and adjusts the degree of opening.
上記構成において、定常の触媒燃焼状態の動作を次に記
す。In the above configuration, the operation in a steady state of catalytic combustion will be described below.
液体燃料は電磁ポンプ(図示せず)によって給油管30
を通して、回転しているコーン27に送られ、コーン2
7表面を回転板28へと流れ、回転板28の外周端から
円心力により粒子状で飛散され、シーズヒータ16や燃
焼筒15前方からの伝熱によって定温となっている内表
面に接触して気化する。一方、空気はファン1oによっ
て、またダンパ9によって量を制御されて空気口12か
ら予混合室18に送られる。ここで、混合板29によっ
て気化した燃料と充分に攪拌混合されたのち抵抗板17
を通り、整流板2oで整流されて触媒体22に送られる
。触媒体22は高温状態となっており、その表面に担持
された酸化触媒の作用によって予混合ガスは燃焼発熱し
て触媒体温度を一定に保つとともに約700〜1000
℃の燃焼ガスとして熱交換器25へ流入する。定常燃焼
時には従って火炎は存在せず、触媒体22の接触反応あ
るいは、触媒体22のノ・ニウムセル中の高温雰囲気中
で分解酸化を受けて完全燃焼に至るものである0
しかるに、所定の空気量が変動し、許容範囲を越えると
スリップ、あるいはバ・ツク等の異常を引起こす。スリ
ップは空気量が過多となった場合に生じ、触媒体22の
温度低下、酸化触媒の活性度の低下を招き、−酸化炭素
や未反応成分を排出するのである。逆に、バックは空気
量が不足したときに生じ、触媒体22の温度の上昇、高
温雰囲気での分解酸化反応量の増加につれて触媒体22
の予混合ガス流入側で燃料の大部分が反応し、かつ予混
合ガス流入速度が火炎伝播速度以下であるときに、予混
合ガスが触媒体22に達する以前に火炎燃焼してしまう
のである。従って、バックを生じると、燃焼筒16を異
常に加熱したり、触媒体22の寿命を縮めたり、−烏合
によっては触媒体22を溶融する場合もある。Liquid fuel is supplied to the fuel supply pipe 30 by an electromagnetic pump (not shown).
through the rotating cone 27, and the cone 2
7 surface to the rotary plate 28, is scattered in the form of particles from the outer peripheral edge of the rotary plate 28 due to the circular force, and comes into contact with the inner surface, which is kept at a constant temperature by heat transfer from the front of the sheathed heater 16 and the combustion cylinder 15. Vaporize. On the other hand, the amount of air is controlled by the fan 1o and the damper 9, and the air is sent to the premixing chamber 18 from the air port 12. Here, after being sufficiently stirred and mixed with the vaporized fuel by the mixing plate 29, the resistance plate 17
, is rectified by the rectifier plate 2o, and sent to the catalyst body 22. The catalyst body 22 is in a high temperature state, and the premixed gas generates heat by combustion due to the action of the oxidation catalyst supported on its surface, keeping the catalyst body temperature constant and increasing the temperature to approximately 700 to 1,000 yen.
It flows into the heat exchanger 25 as combustion gas at .degree. Therefore, during steady combustion, there is no flame, and the catalyst body 22 undergoes a catalytic reaction or undergoes decomposition and oxidation in the high temperature atmosphere in the nitrogen cell of the catalyst body 22, leading to complete combustion. If it fluctuates and exceeds the allowable range, it will cause abnormalities such as slipping or buckling. Slip occurs when the amount of air is excessive, leading to a decrease in the temperature of the catalyst body 22 and a decrease in the activity of the oxidation catalyst, and causes carbon oxide and unreacted components to be discharged. Conversely, backing occurs when the amount of air is insufficient, and as the temperature of the catalyst body 22 increases and the amount of decomposition and oxidation reaction increases in a high temperature atmosphere,
When most of the fuel reacts on the premixed gas inflow side and the premixed gas inflow speed is less than the flame propagation speed, the premixed gas burns with flame before it reaches the catalyst body 22. Therefore, if backing occurs, the combustion tube 16 may be heated abnormally, the life of the catalyst body 22 may be shortened, and the catalyst body 22 may be melted depending on the caking.
このように触媒燃焼は、供給する空気量をコントロール
することによって正常状態を保ち得る。In this way, catalytic combustion can be maintained in a normal state by controlling the amount of air supplied.
即ち、供給空気量が適量であれば、触媒体温度も適度に
保たれ、安定した触媒燃焼が得られるのである。本発明
は、この供給空気量と触媒体温度の関連を考慮し、触媒
燃焼を制御しようとするものである。That is, if the amount of air supplied is appropriate, the temperature of the catalyst body can be maintained at an appropriate level, and stable catalytic combustion can be obtained. The present invention attempts to control catalytic combustion by considering the relationship between the amount of supplied air and the temperature of the catalyst body.
第2図に燃料供給量を一定としたときの空気量変化(空
気過剰率の変化)に対する触媒体内で示率の変化に伴な
い触媒体最高温度も変化し、かつ温度検知素子も触媒体
の温度変化につれて変動しておシ、触媒体の温度をモニ
タすることは充分に可能である。即ち、第2図の状態で
は、温度検知素子の温度が300〜380℃の範囲に納
まるようにダンパを調節してやればよいのである。具体
的には温度検知素子にに熱電対を使用し、その起電力を
基準電圧(K熱電対の3oO〜380℃に和尚する電圧
)と比較し、高い場合にはダンパを開け、低い場合には
ダンパを閉じる方向に駆動させることにより可能となる
。実施例では温度検知素子を燃焼筒の側壁に設けたが、
触媒体の後方に臨ませて触媒体からの輻射を検知する方
法でも触媒体の温度をモニタすることは可能である。ま
た、空気量制御方法にはダンパを用いたが、モータ回転
数を制御して供給空気量を制御する方法でも効果は変ら
ない。Figure 2 shows that when the fuel supply amount is constant, the maximum temperature of the catalyst changes as the reading rate changes within the catalyst in response to changes in air amount (changes in excess air ratio). It is fully possible to monitor the temperature of the catalyst body as it fluctuates as the temperature changes. That is, in the state shown in FIG. 2, the damper may be adjusted so that the temperature of the temperature sensing element falls within the range of 300 to 380°C. Specifically, a thermocouple is used as a temperature sensing element, and its electromotive force is compared with a reference voltage (voltage that ranges from 3oO to 380℃ for a K thermocouple).If it is high, the damper is opened, and if it is low, it is This is possible by driving the damper in the closing direction. In the example, the temperature sensing element was installed on the side wall of the combustion tube, but
It is also possible to monitor the temperature of the catalyst by detecting radiation from the catalyst by facing the rear of the catalyst. Further, although a damper is used to control the amount of air, a method of controlling the amount of supplied air by controlling the motor rotation speed will have the same effect.
触媒体の温度を直接測定するには、1400〜1500
℃以上の高温に耐える温度検知素子を選択しなくてはな
らないが、本発明の如く、触媒体の温度を二次的に、間
接的にモニタすることで、容易に触媒燃焼を制御するこ
とが可能となった。また空気量を自動調節し、触媒体温
度を常に一定に保つようにすることでス゛リップやバッ
ク等の異常を未然に防止し、異常に伴なって生じる。−
酸化炭素、臭気の発生、あるいは燃焼筒の異常加熱、触
媒の劣化促進等の現象をも防止することができるもので
ある。To directly measure the temperature of the catalyst, 1400-1500
Although it is necessary to select a temperature sensing element that can withstand high temperatures of ℃ or higher, catalytic combustion can be easily controlled by secondarily and indirectly monitoring the temperature of the catalyst as in the present invention. It has become possible. In addition, by automatically adjusting the amount of air and keeping the temperature of the catalyst body constant, abnormalities such as slip and back-up can be prevented, and abnormalities that may occur as a result of abnormalities can be prevented. −
It is also possible to prevent phenomena such as the generation of carbon oxides and odors, abnormal heating of the combustion cylinder, and accelerated deterioration of the catalyst.
実施例では液体燃料用の装置を示しだが、ガス燃料を用
いた場合でも本発明の効果は何ら変らない0In the example, an apparatus for liquid fuel is shown, but the effects of the present invention do not change in any way even when gas fuel is used.
第1図は本発明の一実施例を示す液体燃料用の触媒燃焼
装置の縦断面図、第2図は燃料供給量を一定として供給
空気量を変動させ、触媒体の最高温度、および、第1図
示しだ如く設置した温度検知素子の指示温度をプロット
した図である09・・・・・・ダンパ、16・・・・・
・燃焼筒、22・・・・・・触媒体、24・・・・・・
温度検知素子。FIG. 1 is a vertical cross-sectional view of a catalytic combustion device for liquid fuel showing an embodiment of the present invention, and FIG. 2 shows the maximum temperature of the catalyst body and the 1 is a diagram plotting the indicated temperature of the temperature sensing element installed as shown in Figure 09...Damper, 16...
・Combustion tube, 22...Catalyst body, 24...
Temperature sensing element.
Claims (1)
担持させた触媒体を有し、前記予混合ガスを前記触媒体
で酸化燃焼させ、る触媒燃焼装置であって、触媒体の温
度をモニタする温度検知素子と、温度検知素子の検知し
た温度によって制御される空気量調節機構を備えた触媒
燃焼装置。A catalytic combustion device comprising means for supplying a premixed gas of fuel and air, and a catalyst body supporting an oxidation catalyst, the premixed gas being oxidized and burned by the catalyst body, wherein the temperature of the catalyst body is A catalytic combustion device equipped with a temperature sensing element that monitors temperature, and an air amount adjustment mechanism that is controlled based on the temperature detected by the temperature sensing element.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16325981A JPS5864413A (en) | 1981-10-13 | 1981-10-13 | Catalytic combustion equipment |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16325981A JPS5864413A (en) | 1981-10-13 | 1981-10-13 | Catalytic combustion equipment |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5864413A true JPS5864413A (en) | 1983-04-16 |
Family
ID=15770394
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP16325981A Pending JPS5864413A (en) | 1981-10-13 | 1981-10-13 | Catalytic combustion equipment |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5864413A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59195023A (en) * | 1983-04-20 | 1984-11-06 | Matsushita Electric Ind Co Ltd | Catalyst combustion burner |
EP1058055A1 (en) * | 1998-12-18 | 2000-12-06 | Matsushita Electric Industrial Co., Ltd. | Catalyst combustion device |
-
1981
- 1981-10-13 JP JP16325981A patent/JPS5864413A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59195023A (en) * | 1983-04-20 | 1984-11-06 | Matsushita Electric Ind Co Ltd | Catalyst combustion burner |
JPS6238602B2 (en) * | 1983-04-20 | 1987-08-19 | Matsushita Electric Ind Co Ltd | |
EP1058055A1 (en) * | 1998-12-18 | 2000-12-06 | Matsushita Electric Industrial Co., Ltd. | Catalyst combustion device |
EP1058055A4 (en) * | 1998-12-18 | 2005-05-18 | Matsushita Electric Ind Co Ltd | Catalyst combustion device |
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