JPS5863787A - Composition for fuel oil - Google Patents

Composition for fuel oil

Info

Publication number
JPS5863787A
JPS5863787A JP16014081A JP16014081A JPS5863787A JP S5863787 A JPS5863787 A JP S5863787A JP 16014081 A JP16014081 A JP 16014081A JP 16014081 A JP16014081 A JP 16014081A JP S5863787 A JPS5863787 A JP S5863787A
Authority
JP
Japan
Prior art keywords
fuel oil
water
oil
composition
perchlorate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP16014081A
Other languages
Japanese (ja)
Other versions
JPS603440B2 (en
Inventor
荘 朝栄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP16014081A priority Critical patent/JPS603440B2/en
Publication of JPS5863787A publication Critical patent/JPS5863787A/en
Publication of JPS603440B2 publication Critical patent/JPS603440B2/en
Expired legal-status Critical Current

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Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明は、燃料油と水を混合していわゆるエマルジ3ン
油とするだめの新規な燃料油用組成物に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a novel fuel oil composition in which fuel oil and water are mixed to form a so-called emulsion oil.

ム重油ないしC3I[油等の液体炭化水素燃料に適量の
水を添加することによシ、燃焼率、空気比等の燃焼条件
を改善し、燃料油の節減を図ると共に、NOxおよびg
o、(So、)の発生を抑制して低公害化することが知
られている。しかしながら、従来燃料油と水とからエマ
ルジlン油を作るKは、例えば特公昭46−37982
号公報や特公昭53−26328号公報等に示される如
くに特別の装置を要し、イニシアルコストが高くつくた
め、中小の工場や施設では容易に採用されず、省エネル
ギー化を推進するのが困難であった。
By adding an appropriate amount of water to liquid hydrocarbon fuel such as heavy oil or C3I oil, it is possible to improve combustion conditions such as combustion rate and air ratio, reduce fuel oil consumption, and reduce NOx and g
It is known that the generation of o, (So,) can be suppressed to reduce pollution. However, K, which conventionally produces emulsion oil from fuel oil and water, is
As shown in Japanese Patent Publication No. 53-26328, etc., it requires special equipment and has a high initial cost, so it is not easily adopted by small and medium-sized factories and facilities, making it difficult to promote energy conservation. Met.

本発明はかかる点に着目してなされたもので、既存の重
油タンクに攪拌機を取付けるだけで水と燃料油を容易に
混合乳化でき、しかも長期間安定な乳化状態を保持し得
る燃料油用組成物を提供することを目的とする。
The present invention has been made with attention to this point, and is a composition for fuel oil that can easily mix and emulsify water and fuel oil by simply attaching an agitator to an existing heavy oil tank, and that can maintain a stable emulsified state for a long period of time. The purpose is to provide something.

即ち、本発明の燃料油用組成物は過塩素酸塩。That is, the fuel oil composition of the present invention is a perchlorate.

過マンガン酸塩および苛性アルカリの三成分を水に溶解
して成るものであり、上記三成分に更に水ガラスおよび
オゾニドル化物の二成分を添加することにより燃料油と
水の乳化或いは相溶性が一層向上する。
It is made by dissolving the three components of permanganate and caustic alkali in water, and by adding two components of water glass and ozonidol to the above three components, the emulsification or compatibility of fuel oil and water is further improved. improves.

本発明によれば、上記組成物を添加して激しく攪拌する
ことKより燃料油と水を所望の配合比で混合、乳化する
ことができ、得られたエマルシロン油は長期間安定であ
り、水と燃料油が分離するようなことがなく、また組成
物は水溶液であるからその調製、保管、取扱いも容易で
安全である。
According to the present invention, fuel oil and water can be mixed and emulsified at a desired blending ratio by adding the above composition and stirring vigorously, and the obtained emulsilon oil is stable for a long period of time, and water There is no separation between the fuel oil and the fuel oil, and since the composition is an aqueous solution, its preparation, storage, and handling are easy and safe.

本発明に使用する過塩素酸塩としては、カリウム、ルビ
ジウム、アンモニウム塩などの難溶性塩を除く易溶性塩
、例えば過塩素酸ナトリウム、過塩素酸マグネシウム等
が好適である。また、過塩素酸塩に代シ飢易溶性の過ヨ
ウ素酸塩を使用することもできる。
As the perchlorate used in the present invention, easily soluble salts excluding hardly soluble salts such as potassium, rubidium, and ammonium salts, such as sodium perchlorate and magnesium perchlorate, are suitable. Furthermore, a readily soluble periodate can be used in place of the perchlorate.

過マンガン酸塩としては、例えば過マンガン酸カリウム
、過マンガン酸ナトリウムが好適であり、また苛性アル
カリとしては水酸化ナトリウム、水酸化カリウム等が挙
けられる。
Suitable examples of the permanganate include potassium permanganate and sodium permanganate, and examples of the caustic alkali include sodium hydroxide and potassium hydroxide.

上記三成分の配合割合は、特に制限されないが過塩素酸
塩100重量部に対し、過マンガン酸塩。
The blending ratio of the above three components is not particularly limited, but permanganate to 100 parts by weight of perchlorate.

苛性アルカリ共に50〜150重量部、特にT。50 to 150 parts by weight of both caustic alkali, especially T.

〜110重量部とするのが好ましい。It is preferable to set it as 110 parts by weight.

また、上記三成分の他に添加する水ガラスとしては市販
品或いはメタケイ酸ナトリウムを水に溶かして用いるこ
とができ、オゾニドル化物としてはカリウムオシニドが
挙けられる。水ガラスは上記過塩素酸塩100mff1
部に対して70〜200重を部、特El 10〜160
重量部が好ましく、またオゾニドル化物は50〜150
重量部、特に70〜110重量部が適当である。
Further, as water glass to be added in addition to the above three components, a commercially available product or sodium metasilicate dissolved in water can be used, and an example of the ozonidol compound includes potassium oscinide. Water glass is 100mff1 of the above perchlorate
70 to 200 parts per part, special El 10 to 160 parts
Parts by weight are preferred, and the ozonidol compound is preferably 50 to 150 parts by weight.
Parts by weight are suitable, especially 70 to 110 parts by weight.

本発明の燃料油用組成物を調製するには、例えば過塩素
酸塩、過マンガン酸塩、苛性アルカリ等の各々の水溶液
を混合するか、苛性アルカリの水溶液に順次過塩素酸塩
、過マンガン酸塩等を添加し溶解する等通常の方法によ
り作ることができる。
To prepare the fuel oil composition of the present invention, for example, aqueous solutions of perchlorate, permanganate, caustic alkali, etc. are mixed, or perchlorate and permanganate are added to an aqueous solution of caustic alkali in order. It can be made by a conventional method such as adding and dissolving an acid salt.

組成物の濃度は特に制限されないが、過マンガン酸塩の
溶解度以下、例えば過マンガン酸カリウムノ場合? 6
.5 F/100 F(20℃)以下となるように他の
成分を溶解する。
The concentration of the composition is not particularly limited, but if it is below the solubility of permanganate, for example potassium permanganate? 6
.. Dissolve the other ingredients to a temperature of 5 F/100 F (20° C.) or less.

このよう処して得られ九燃料油用組成物を用いて、水と
燃料油からエマルジョン油を作るKは、配合すべき水に
該組成物を予め溶解したのち、通常の攪拌操作で激しく
混合、攪拌すればよく、従来の如く特別な装置を要しな
い。
To prepare an emulsion oil from water and fuel oil using the nine fuel oil composition obtained in this way, after dissolving the composition in the water to be blended in advance, mix vigorously with a normal stirring operation. It only needs to be stirred, and no special equipment is required as in the past.

次に実施例について説明スル。Next, examples will be explained.

実施例1 過塩酸ナトリウム502.苛性ソーダ40fおよび過マ
ンガン酸カリウム40fを常温で水1tに溶解し、三成
分の混合水溶液とした燃料油用組成物を調製した。
Example 1 Sodium perchlorate 502. A fuel oil composition was prepared by dissolving 40 f of caustic soda and 40 f of potassium permanganate in 1 t of water at room temperature to prepare a mixed aqueous solution of the three components.

一方、燃料油としてC重油を用い、このC重油と水の配
合比が95:5,90:10.80:20・・・・・・
so: soおよび10: 90で全容積が50〇−と
彦るように、C重油と水を別りの容器に採9、缶水に上
記燃料油用組成物を5−添加した後、対応するC重油と
水を混合して激しく攪拌した。
On the other hand, C heavy oil is used as fuel oil, and the blending ratio of C heavy oil and water is 95:5, 90:10.80:20...
so: So and 10: After adding 50% of the above fuel oil composition to the canned water, put C heavy oil and water in separate containers so that the total volume is 500% with 90%. C heavy oil and water were mixed and vigorously stirred.

その結果、何れもC重油と水が均一に混合、乳化され、
外観上全くC重油と変らないエマルジョン油が得られた
。このもの#i1ケ月経過してもなお、油と水が分離せ
ず、極めて安定であった。
As a result, C heavy oil and water are uniformly mixed and emulsified,
An emulsion oil was obtained that had no difference in appearance from C heavy oil. This product #i remained extremely stable with no separation of oil and water even after one month had passed.

実施例2 過塩素酸ナトリウム40f、水酸化カリウム35t、過
マンガン酸カリウム35f、水ガラス55tおよびカリ
ウムオシニド35Fを常温で水1tK溶解し、三成分の
混合水溶液とした燃料油用組成物を調製した。
Example 2 40 f of sodium perchlorate, 35 t of potassium hydroxide, 35 f of potassium permanganate, 55 t of water glass, and 35 F of potassium ocinide were dissolved in 1 tK of water at room temperature to prepare a three-component mixed aqueous solution for fuel oil. did.

この燃料油用組成物を各々5−採り、実施例1と同様の
配合比とした水に添加し、C重油と共に激しく攪拌した
ところ外観上C重油と変らない安定ナエマルジョン油が
得られた。
Five portions of each of these fuel oil compositions were taken, added to water with the same blending ratio as in Example 1, and stirred vigorously with C heavy oil to obtain a stable emulsion oil that was visually similar to C heavy oil.

本発明によれば、燃料油用組成物を水に添加し、これを
燃料油と攪拌混合するだけで、所望の配合比を有する極
めて安定なエマルジョン油が得られるので、従来の如く
特殊な装置を要せず中小の工場や力投でも容易に実施で
さ、燃料油の省エネルギー化を強力に推進することがで
きる。また、従来、重油タンクやタンカーの底部に貯っ
た水は定期的に抜出し掃除する必要があったが、本発明
の組成物を水に投入し、これに新たな重油を供給して攪
拌すれば、そのまま水を添加したエマルジョン油が得ら
れるので、煩しい掃除を省くことができる。
According to the present invention, an extremely stable emulsion oil having a desired blending ratio can be obtained by simply adding a fuel oil composition to water and stirring and mixing it with fuel oil. It can be easily implemented even in small and medium-sized factories and power plants without the need for additional equipment, and can strongly promote energy conservation of fuel oil. In addition, conventionally, water accumulated at the bottom of heavy oil tanks and tankers had to be periodically drained and cleaned, but instead of adding the composition of the present invention to water, supplying new heavy oil to it, and stirring it. For example, since an emulsion oil with water added thereto can be obtained as it is, troublesome cleaning can be omitted.

Claims (1)

【特許請求の範囲】 1)過塩素酸塩、過マンガン酸塩および苛性アルカリの
三成分を水に溶解して成る燃料油用組成物。 2)過塩素酸塩、過マンガン酸塩および苛性ジルカリの
三成分と共に水ガラスおよびオゾニドル化物を水圧溶解
して成る燃料油用組成物。
[Scope of Claims] 1) A fuel oil composition comprising three components, perchlorate, permanganate, and caustic alkali, dissolved in water. 2) A fuel oil composition prepared by hydraulically dissolving water glass and ozonidolate together with the three components of perchlorate, permanganate and caustic zirkaline.
JP16014081A 1981-10-09 1981-10-09 Emulsion stabilizer composition for fuel oil Expired JPS603440B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16014081A JPS603440B2 (en) 1981-10-09 1981-10-09 Emulsion stabilizer composition for fuel oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16014081A JPS603440B2 (en) 1981-10-09 1981-10-09 Emulsion stabilizer composition for fuel oil

Publications (2)

Publication Number Publication Date
JPS5863787A true JPS5863787A (en) 1983-04-15
JPS603440B2 JPS603440B2 (en) 1985-01-28

Family

ID=15708732

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16014081A Expired JPS603440B2 (en) 1981-10-09 1981-10-09 Emulsion stabilizer composition for fuel oil

Country Status (1)

Country Link
JP (1) JPS603440B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6269131A (en) * 1985-09-24 1987-03-30 Fujikura Ltd Optical fiber temperature sensor

Also Published As

Publication number Publication date
JPS603440B2 (en) 1985-01-28

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