JPS5851039B2 - How to prevent metalworking oil from rotting - Google Patents

How to prevent metalworking oil from rotting

Info

Publication number
JPS5851039B2
JPS5851039B2 JP2269382A JP2269382A JPS5851039B2 JP S5851039 B2 JPS5851039 B2 JP S5851039B2 JP 2269382 A JP2269382 A JP 2269382A JP 2269382 A JP2269382 A JP 2269382A JP S5851039 B2 JPS5851039 B2 JP S5851039B2
Authority
JP
Japan
Prior art keywords
oil
metal
cobalt
rotting
prevent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP2269382A
Other languages
Japanese (ja)
Other versions
JPS58141297A (en
Inventor
幹夫 佐藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Kosan Co Ltd
Original Assignee
Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Priority to JP2269382A priority Critical patent/JPS5851039B2/en
Publication of JPS58141297A publication Critical patent/JPS58141297A/en
Publication of JPS5851039B2 publication Critical patent/JPS5851039B2/en
Expired legal-status Critical Current

Links

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Lubricants (AREA)

Description

【発明の詳細な説明】 本発明は金属加工油の腐敗防止方法に関する。[Detailed description of the invention] The present invention relates to a method for preventing corrosion of metal working oil.

従来、金属加工油の腐敗を防止する方法として、金属加
工油に殺菌剤、特に有機殺菌剤を添加することが行なわ
れていた。
BACKGROUND ART Conventionally, as a method of preventing metalworking oil from spoiling, a disinfectant, particularly an organic disinfectant, has been added to the metalworking oil.

しかしながら、この有機殺菌剤の腐敗防止効果は特定の
微生物に対して良好であっても、微生物の種類によって
は十分な効果が得られないことがある。
However, even if the anti-corrosion effect of this organic disinfectant is good against specific microorganisms, sufficient effects may not be obtained depending on the type of microorganism.

そのため、該殺菌剤の使用に際しては対象とする微生物
の種類を考慮して適当な殺菌剤を選択する必要があった
Therefore, when using the disinfectant, it was necessary to select an appropriate disinfectant in consideration of the type of target microorganism.

さらに、有機殺菌剤の中には該殺菌剤自身が微生物によ
り分解されるものがあり、このような殺菌剤は必然的に
その腐敗防止効果が短期間しか持続しないため、殺菌剤
を頻繁に添加する必要がある。
Furthermore, some organic disinfectants are themselves degraded by microorganisms, and their anti-septic effects necessarily last only for a short period of time, so disinfectants must be added frequently. There is a need to.

また、金属加工油に金属塩を添加して腐敗を防止する方
法も提案されているが、水に溶けて外部に流出し、環境
を汚染するおそれがある。
Additionally, a method has been proposed to prevent rot by adding metal salts to metalworking oil, but there is a risk that the metal salts will dissolve in water and leak outside, polluting the environment.

本発明は、このような従来法の有する欠点を解消すべく
鋭意研究を重ねた結果、完成されたものである。
The present invention was completed as a result of intensive research to eliminate the drawbacks of the conventional methods.

本発明は、金属加工油を金属コバルトと接触させること
を特徴とする金属加工油の腐敗防止方法である。
The present invention is a method for preventing corrosion of metal working oil, which is characterized by bringing the metal working oil into contact with metallic cobalt.

金属加工油は、第1図に例示した如く、貯蔵タンク1に
貯えられ、その所定量が配管2とポンプ3を経て金属コ
バルト殺菌装置4に送られて金属コバルトと接触させら
れ殺菌されたのち、作業所に送られ、金属材料の切削加
工等に供される。
As illustrated in FIG. 1, the metalworking oil is stored in a storage tank 1, and a predetermined amount of the oil is sent to a metal cobalt sterilizer 4 via piping 2 and a pump 3, where it is brought into contact with metal cobalt and sterilized. , sent to a workshop and used for cutting metal materials, etc.

その後、濾過等の処理を経て配管5より貯蔵タンク1に
戻される。
Thereafter, it is returned to the storage tank 1 through the pipe 5 after undergoing treatments such as filtration.

本発明において、金属加工油を金属コバルトと接触させ
る方法には特に制限はないが、第2図に示す如く、ガラ
ス製などの筒状の殺菌装置(殺菌筒)を用いて行なうこ
とが好ましい。
In the present invention, there is no particular restriction on the method of bringing metal working oil into contact with metal cobalt, but as shown in FIG. 2, it is preferable to use a cylindrical sterilizer (sterilizer cylinder) made of glass or the like.

第2図aはコバルト粒子あるいはコバルトを表面に担持
させたコバルトメッキの粒子を充填させた殺菌筒を、第
2図すは穴あきのコバルトメッキ板を列設させた殺菌筒
を、第2図Cはコバルトメッキされた網を内在させた殺
菌筒をそれぞれ示す斜視図である。
Figure 2a shows a sterilization cylinder filled with cobalt particles or cobalt plating particles with cobalt supported on the surface, Figure 2A shows a sterilization cylinder filled with perforated cobalt plated plates, and Figure 2C 2A and 2B are perspective views showing sterilization cylinders each having a cobalt-plated mesh therein.

このような殺菌筒を用いる場合、その大きさなどは金属
加工油の使用量などを考慮して適宜選定すればよい。
When using such a sterilizing cylinder, its size etc. may be appropriately selected in consideration of the amount of metal working oil to be used.

本発明ではこのように殺菌筒などの殺菌装置に金属加工
油を通すことにより、金属加工油を金属コバルトと接触
させて金属加工油の腐敗を防止するものである。
In the present invention, by passing the metal working oil through a sterilizing device such as a sterilizing cylinder, the metal working oil is brought into contact with metal cobalt, and the metal working oil is prevented from decomposing.

金属加工油としては、たとえば切削油、圧延油、熱処理
油等があげられる。
Examples of metalworking oils include cutting oils, rolling oils, heat treatment oils, and the like.

切削油には主として鉱油、界面活性剤、防錆剤および水
よりなるエマルジョン型と、主として多量の界面活性剤
、少量の鉱油、防錆剤および水よりなるソリュプル型の
ものがあり、圧延油にはエマルジョン型のものがある。
There are two types of cutting oil: emulsion type, which mainly consists of mineral oil, surfactant, rust inhibitor, and water, and soluple type, which mainly consists of large amount of surfactant, small amount of mineral oil, rust inhibitor, and water. There is an emulsion type.

また、熱処理油としては、たとえばポリエチレングリコ
ールと水よりなるものなどがある。
Furthermore, examples of the heat-treated oil include those made of polyethylene glycol and water.

本発明の方法によれば、金属塩を添加して金属加工油の
殺菌を行なう従来の方法のように水に溶けて流出し、環
境を汚染するおそれがない。
According to the method of the present invention, unlike the conventional method of sterilizing metal working oil by adding a metal salt, there is no risk of the oil dissolving in water and flowing out and polluting the environment.

しかも、本発明の方法は微生物の種類に関係なく、はと
んどの微生物に対し腐敗防止効果を示すとともに、長期
間にわたり腐敗防止効果が持続するという利点を有して
いる。
Furthermore, the method of the present invention has the advantage that it exhibits a spoilage-preventing effect against most microorganisms, regardless of the type of microorganism, and that the spoilage-preventing effect lasts for a long period of time.

したがって、本発明の方法は自動車産業、機械工業等の
金属加工分野においてきわめて有用なものである。
Therefore, the method of the present invention is extremely useful in metal processing fields such as the automobile industry and the machinery industry.

次に、本発明を実施例により詳しく説明する。Next, the present invention will be explained in detail with reference to examples.

実施例1および比較例1.2 エマルジョン型金属加工油(希釈倍率30倍)10−を
試験管に採取し、これに摺動面油0.5vo1%、鋳物
切粉0.5%(W/V)、腐敗サンプル0.5%(V/
V)を添加した。
Example 1 and Comparative Example 1.2 Emulsion-type metalworking oil (dilution ratio: 30 times) 10- was collected in a test tube, and this was mixed with 0.5vol% of sliding surface oil and 0.5% of casting chips (W/ V), decayed sample 0.5% (V/
V) was added.

次いで、これに*;コバルト粉末を添加したもの(実施
例1)、市販有機殺菌剤を添加したもの(比較例1)お
よび殺菌剤を添加しなかったもの(比較例2)を10日
間、30℃で静置培養し、細菌数を測定した。
Next, *: one to which cobalt powder was added (Example 1), one to which a commercially available organic fungicide was added (Comparative Example 1), and one to which no fungicide was added (Comparative Example 2) were tested for 30 days for 10 days. The cells were statically cultured at ℃, and the number of bacteria was measured.

測定結果を第1表に示す。The measurement results are shown in Table 1.

なお、摺動面油は金属加工中に切削油などの金属加工油
中に混入するもので、微生物による腐敗作用を促進する
性質がある。
Note that sliding surface oil is mixed into metal processing oil such as cutting oil during metal processing, and has the property of promoting the decomposition effect by microorganisms.

また、鋳物切粉は金属加工に際して削られて生ずる鋳物
粉末であり、金属加工油中に混入するものである。
Further, casting chips are foundry powder produced by cutting during metal processing, and are mixed into metal processing oil.

好気性細菌数は寒天平板法により、嫌気性細菌数および
硫酸環元菌数はロールチューブ法によりそれぞれ測定し
た。
The number of aerobic bacteria was measured by the agar plate method, and the number of anaerobic bacteria and sulfate ring-forming bacteria was measured by the roll tube method.

実施例2および比較例3 ガラス製の2.Ol容器に金属加工油(希釈倍率30倍
)1.51を採取し、これに摺動面油0.5%(V/V
)を添加した。
Example 2 and Comparative Example 3 Glass 2. Collect 1.51 of metal working oil (dilution ratio: 30 times) in an oil container, and add 0.5% (V/V) of sliding surface oil to this.
) was added.

該容器内の金属加工油をガラス管を通してポンプにより
抜き出し、金属コバルト粒子(直径4〜10mπ)20
1を充填したガラス容器を通し、次いで75グの鋳物切
粉を入れた漏斗に注いだ。
The metal working oil in the container is extracted by a pump through a glass tube, and 20 metal cobalt particles (diameter 4 to 10 mπ) are extracted.
1 and then poured into a funnel containing 75 grams of foundry chips.

油剤の流量は油剤全量を10※※分間に1回の割合で循
環せしめるものであった。
The flow rate of the oil was such that the entire amount of oil was circulated once every 10 minutes.

所定日数毎に悪臭発生の有無および細菌数を測定した。The presence or absence of bad odor and the number of bacteria were measured every predetermined number of days.

測定結果を第2表に示す。また、比較のために金属コバ
ルト粒子を充填したガラス容器を通さずに循環させた場
合(比較例3)の結果を併せて第2表に示す。
The measurement results are shown in Table 2. For comparison, Table 2 also shows the results when the metal cobalt particles were circulated without passing through a glass container (Comparative Example 3).

なお、添加生菌数は第1表の場合と同様であった。The number of viable bacteria added was the same as in Table 1.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の方法の1実施例のフローシートであり
、第2図a、b、cは本発明の方法において筒状の殺菌
装置(殺菌筒)を用いた場合の殺菌筒の各態様を示す斜
視図である。 1・・・・・・貯蔵タンク、2,5・・・・・・配管、
ンプ、4・・・・・・金属コバルト殺菌装置。 3・・・・・・ポ
Fig. 1 is a flow sheet of one embodiment of the method of the present invention, and Fig. 2 a, b, and c are each of the sterilization tubes when a cylindrical sterilization device (sterilization tube) is used in the method of the present invention. It is a perspective view showing an aspect. 1... Storage tank, 2, 5... Piping,
4...Metal cobalt sterilizer. 3...Po

Claims (1)

【特許請求の範囲】[Claims] 1 金属加工油を金属コバルトと接触させることを特徴
とする金属加工油の腐敗防止方法。
1. A method for preventing corrosion of metal working oil, which comprises bringing metal working oil into contact with metal cobalt.
JP2269382A 1982-02-17 1982-02-17 How to prevent metalworking oil from rotting Expired JPS5851039B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2269382A JPS5851039B2 (en) 1982-02-17 1982-02-17 How to prevent metalworking oil from rotting

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2269382A JPS5851039B2 (en) 1982-02-17 1982-02-17 How to prevent metalworking oil from rotting

Publications (2)

Publication Number Publication Date
JPS58141297A JPS58141297A (en) 1983-08-22
JPS5851039B2 true JPS5851039B2 (en) 1983-11-14

Family

ID=12089948

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2269382A Expired JPS5851039B2 (en) 1982-02-17 1982-02-17 How to prevent metalworking oil from rotting

Country Status (1)

Country Link
JP (1) JPS5851039B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60167132U (en) * 1984-04-13 1985-11-06 ダイハツ工業株式会社 Resin parts inside the engine room

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60167132U (en) * 1984-04-13 1985-11-06 ダイハツ工業株式会社 Resin parts inside the engine room

Also Published As

Publication number Publication date
JPS58141297A (en) 1983-08-22

Similar Documents

Publication Publication Date Title
JPH09228080A (en) Method for preventing pitting corrosion in copper
US3509254A (en) Deodorizing and bactericidal compositions
Tsai et al. The impacts of the AOC concentration on biofilm formation under higher shear force condition
JP2015129065A (en) Method for producing bark compost
EP0025863A1 (en) Use of 1,2,4-triazole derivatives as corrosion inhibitors for non ferrous metals
JPS5827318B2 (en) How to prevent metalworking oil from rotting
JPS5851039B2 (en) How to prevent metalworking oil from rotting
EP0677485A1 (en) Means for preventing deposit formation in industrial process waters
US7854888B2 (en) Methods for determining effectiveness of waste water tank deodorizers and synthetic waste compositions for use in said methods
Doğruöz Güngör et al. Effect of mixed-species biofilm on copper surfaces in cooling water system
JP3446867B2 (en) Slime adhesion prevention method for seawater cooling water system
Pivnick et al. Methods for testing the germicidal value of chemical compounds for disinfecting soluble oil emulsions
EP0698580B1 (en) Composition for preventing deposit formation and oxygen corrosion in industrial process waters
DE68927180T2 (en) CLEANING OF INDUSTRIAL LUBRICANTS
JPS606990B2 (en) metal working oil
Zhang et al. Abatement of sulfide generation in sewage by glutaraldehyde supplementation and the impact on the activated sludge accordingly
JPH0730348B2 (en) Antibacterial water-soluble cutting fluid
RU1807077C (en) Cleansing and disinfecting agent for cleaning surface against impurities
JPS60150899A (en) Dissolving agent of adhered material
JPH0238638B2 (en) KINZOKUKAKOYUNOFUHAIBOSHIHOHO
Deans et al. Gamma irradiation of piggery slurry
Abosaty et al. Assessment and Control of Microbial Induced Corrosion in Sae Water in Nuclear Power Plant Materials
Roslan et al. Characterisation of wastewater quality from a local ruminant abattoir in Banting, Selangor, Malaysia.
SU1723049A1 (en) Method of decontamination of dispersed-colloidal systems
JP2000080484A (en) Water base anticorrosive and corrosion preventing method