JPS5848303A - Oil-immersed electric device - Google Patents

Oil-immersed electric device

Info

Publication number
JPS5848303A
JPS5848303A JP56147122A JP14712281A JPS5848303A JP S5848303 A JPS5848303 A JP S5848303A JP 56147122 A JP56147122 A JP 56147122A JP 14712281 A JP14712281 A JP 14712281A JP S5848303 A JPS5848303 A JP S5848303A
Authority
JP
Japan
Prior art keywords
oil
insulating
fatty acid
acid ester
silicone oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP56147122A
Other languages
Japanese (ja)
Inventor
進藤 紘二
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
Original Assignee
Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Priority to JP56147122A priority Critical patent/JPS5848303A/en
Publication of JPS5848303A publication Critical patent/JPS5848303A/en
Pending legal-status Critical Current

Links

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明は高温で使用される油入電気機器に関する。[Detailed description of the invention] The present invention relates to oil-filled electrical equipment used at high temperatures.

変圧器、コンデンサーなどの通常の油入電気機器は、使
用時の最高温度が約90〜105°O程度であり、とく
に耐熱性の材料は使用されていない。しかし最近このよ
うな電気機器は小型化、軽量化の傾向にあり、それに伴
なって運転時における温度がより高温となってきている
ため、そのような高温に対応する耐熱性を有する絶縁油
および(または)絶縁紙の開発が必要となってきている
Normal oil-filled electrical equipment such as transformers and capacitors have a maximum temperature of about 90 to 105°O during use, and do not use particularly heat-resistant materials. However, recently, such electrical equipment has become smaller and lighter, and as a result, the operating temperature has become higher. (Or) It has become necessary to develop insulating paper.

たとえば変圧器のばあい、一般的には絶縁油としてシリ
コーン油を使用し、絶縁紙として芳香族ポリアミド紙を
使用しているが、シリコーン油が高価であるため、その
組合せの絶縁材料からなる変圧器は非常に高価である。
For example, in the case of transformers, silicone oil is generally used as the insulating oil and aromatic polyamide paper is used as the insulating paper, but since silicone oil is expensive, transformers made of a combination of these insulating materials The equipment is very expensive.

さらにはシリコーン油は熱膨張係数がやや高いため、高
温で使用する変圧器においては大きなコン豐ベーターを
使用しなければならず、変圧器自体を小を化するには支
障がある。
Furthermore, since silicone oil has a rather high coefficient of thermal expansion, a large converter must be used in transformers used at high temperatures, which poses an obstacle to downsizing the transformer itself.

比較的安価で熱膨張係数の低い絶縁油としては鉱物系変
圧器用絶縁油(以下、鉱物油という)が用いられてきて
いるが、それらは燃焼性、があるため火災の危険があり
、高温で使用する油入電気機器には使用されていない。
Mineral-based transformer insulating oils (hereinafter referred to as mineral oils) have been used as insulating oils that are relatively inexpensive and have a low coefficient of thermal expansion, but they are flammable and pose a fire risk, and cannot be used at high temperatures. It is not used in the oil-filled electrical equipment used.

本発明者らはかかる従来の問題に鑑み鋭意研究を重ねた
結果、ネオペンチルポリオールのm肪酸エステルがシリ
コーン油と比較し・て燃焼性がほぼ同程度と低く、さら
に熱膨張係数が小さくかつ安価な耐熱性絶縁油であり、
電気機器の絶縁油として使用しうろことを見出し、本発
明を完成するにいたった。
The inventors of the present invention have conducted intensive research in view of such conventional problems, and have found that the m-fatty acid ester of neopentyl polyol has low flammability, which is almost the same as that of silicone oil, and also has a small coefficient of thermal expansion. It is an inexpensive heat-resistant insulating oil,
He discovered that scales can be used as an insulating oil for electrical equipment, leading to the completion of the present invention.

すなわち本発明は、絶縁材料としてネオペンチルボリオ
ールの脂肪酸エステルからなる耐熱性絶縁油を用いるこ
とを特徴とし、芳香族ポリアセトを用いてなる油入電気
機器に関する。
That is, the present invention is characterized by using a heat-resistant insulating oil made of a fatty acid ester of neopentylboriol as an insulating material, and relates to an oil-filled electrical device made of aromatic polyacetate.

ネオペンチルポリオールの脂肪酸エステルは公知物質で
あり、すでに潤滑油、作動油、圧延油、グリースなどと
して使用されている。
Fatty acid ester of neopentyl polyol is a known substance and has already been used as lubricating oil, hydraulic oil, rolling oil, grease, etc.

ネオペンチルポリオールの脂肪酸エステルの具体例とし
てはユニスターH581、ユニスターH3281M(い
ずれも日本油脂■製)などがあげられるが、それらの絶
縁特性は従来の絶縁油に匹敵するもである。
Specific examples of fatty acid esters of neopentyl polyol include Unistar H581 and Unistar H3281M (both manufactured by NOF Corporation), whose insulating properties are comparable to conventional insulating oils.

つぎにネオペンチルポリオールの脂肪1!エステルの物
理的特性の測定結果について述べる。なお、シリコーン
油として商品名KIF?6−50のジメチルシリコーン
油(信越化学工業■製)を、鉱物油としてJより 02
320の試験において1種2号に合格するものをそれぞ
れ比較例として用いた。
Next, neopentyl polyol fat 1! The results of measuring the physical properties of esters will be described. In addition, the product name KIF? is used as silicone oil. 6-50 dimethyl silicone oil (manufactured by Shin-Etsu Chemical Co., Ltd.) from J as mineral oil 02
Those that passed Type 1, No. 2 in the No. 320 test were used as comparative examples.

(イ)引火点および燃焼点 引火点は開放式引火点試験によって測定した。(a) Flash point and combustion point Flash points were determined by open flash point tests.

また燃焼点も同様にして測定した。The combustion point was also measured in the same manner.

(ロ)燃焼速度 燃焼速度はJ工802101・11にしたがって測定し
た。
(b) Burning rate The burning rate was measured in accordance with J Engineering 802101.11.

(ハ)絶縁破壊電圧 絶縁破壊電圧はJより O2101・2oにしたがって
測定した。
(c) Dielectric breakdown voltage The dielectric breakdown voltage was measured according to O2101.2o from J.

に)粘 度 粘度はJIS O2101・8による粘度針を用いて、
25’Oおよび80°0における運動粘性係数(単位二
センチストークス(・at ) )を測定した。
) Viscosity Viscosity is determined using a viscosity needle according to JIS O2101.8.
The kinematic viscosity coefficient (in units of two centistokes (·at)) at 25'O and 80°0 was measured.

(財)熱膨張係数 熱膨張係数は比重の温度詩作より求めた。Coefficient of thermal expansion The coefficient of thermal expansion was determined from the temperature equation of specific gravity.

えられた結果を第1表に示す。The results obtained are shown in Table 1.

第  1  表 第1表かられかるように、ネオペンチルポリオールの脂
肪酸エステルの引火点および燃焼点は鉱物油よりも低く
シリコーン油とほぼ同程度かまたはそれ以上であり、燃
焼速度は鉱物油よりも遅くシリコーン油にほぼ匹敵する
ものであった。またネオペンチルポリオールの脂肪酸エ
ステルの絶縁破壊電圧はシリコーン油および鉱物油とほ
ぼ同等であった。ネオペンチルポリオールの脂肪酸エス
テルの粘度は室温付近ではシリコーン油よりも高いが、
温度勾配が高いため高温度においてはシリコーン油より
も低いものであった。したがって実際の使用時の温度で
は、電気機器内での油の対流性が向上し、機器の冷却効
果がよくなる。またネオペンチルポリオールの脂肪酸エ
ステルは本来潤滑油として使用されているものであり、
冷却用油循環プンプの軸受潤滑のための特別の考慮を必
要としない。さらにネオペンチルポリオールの脂肪酸エ
ステルの熱膨張係数は鉱物油と同程度であり、シリコー
ン油よりも小さいものであった。
Table 1 As can be seen from Table 1, the flash point and combustion point of the fatty acid ester of neopentyl polyol are lower than mineral oil, almost the same as or higher than silicone oil, and the burning rate is higher than that of mineral oil. It was almost comparable to silicone oil. Furthermore, the dielectric breakdown voltage of fatty acid ester of neopentyl polyol was almost the same as that of silicone oil and mineral oil. The viscosity of the fatty acid ester of neopentyl polyol is higher than that of silicone oil at around room temperature;
Because of the high temperature gradient, it was lower than silicone oil at high temperatures. Therefore, at the temperature during actual use, the convection of oil within the electrical equipment is improved and the cooling effect of the equipment is improved. In addition, the fatty acid ester of neopentyl polyol is originally used as a lubricating oil.
Cooling oil circulation pump does not require special consideration for bearing lubrication. Furthermore, the coefficient of thermal expansion of the fatty acid ester of neopentyl polyol was comparable to that of mineral oil and smaller than that of silicone oil.

以上の結果から、本発明に用いる絶縁油は従来のシリコ
ーン油または鉱物油からなる絶縁油のそれぞれの欠点を
除来したものとなりうろことがわかる。
From the above results, it can be seen that the insulating oil used in the present invention will eliminate the drawbacks of conventional insulating oils made of silicone oil or mineral oil.

本発明に用いる芳香族ポリアミド紙は、H種連続使用可
能な耐熱絶縁紙として知られ、従来の油入電気機器に用
いられているものが使用しうる。
The aromatic polyamide paper used in the present invention is known as an H type heat-resistant insulating paper that can be continuously used, and may be one that is used in conventional oil-filled electrical equipment.

その具体例としては、N0VIC! (米国デュポン社
製)・Aペーパー、ムボード(いずれも三菱−製紙■製
)などがあげられ、鹸述のネオペンチルボリオールの脂
肪酸エステルと組み合せて使用することにより、両者の
耐熱性を発揮させることができる。
A specific example is N0VIC! (manufactured by DuPont in the United States), A Paper, and Mubodo (both manufactured by Mitsubishi Paper Industries), etc., and when used in combination with the fatty acid ester of neopentylboriol mentioned above, the heat resistance of both can be demonstrated. be able to.

本発明の油入電気機器はシリコーン油入電気機器と同等
の耐熱性を有するとともに、熱膨張が小さく、より安価
であるという長所を有する。
The oil-filled electrical equipment of the present invention has the same heat resistance as silicone oil-filled electrical equipment, has small thermal expansion, and has the advantage of being cheaper.

代理人 葛舒信−(ほか1名) 手続補正書(自発) 特許庁長官殿 1、事件の表示    特願昭 64−147122 
 量2、発明の名称 油入電気機器 3、補正をする者 事件との関係   特許出願人 住 所     東京都千代田区丸の内二丁目2番3号
名 称(601)   三菱電機株式会社代表者片由仁
八部 4、代理人 5、補正の対象 (1)明細書の「発明の詳細な説明」の欄6、補正の内
容 (1)明細書1頁19行の「一般的には絶縁油」を「絶
縁油」と補正する。
Agent: Ge Shuxin (and 1 other person) Procedural amendment (spontaneous) Commissioner of the Japan Patent Office 1, case description Patent application No. 64-147122
Quantity 2, Name of the invention Oil-filled electrical equipment 3, Relationship to the case of the person making the amendment Patent applicant address 2-2-3 Marunouchi, Chiyoda-ku, Tokyo Name (601) Mitsubishi Electric Corporation Representative Hitoshi Katayuki Section 4, Agent 5, Subject of amendment (1) Column 6 of “Detailed Description of the Invention” of the specification, Contents of amendment (1) Change “generally insulating oil” in line 19 of page 1 of the specification to “ "Insulating oil".

(2)同2頁1行の「使用しているが」を「使用したも
のがあるが」と補正する。
(2) In the first line of page 2, ``I use it'' is corrected to ``I use something.''

以  上that's all

Claims (1)

【特許請求の範囲】[Claims] (1)絶縁材料として、ネオペンチルポリオールの脂肪
酸エステルからなる耐熱性絶縁油を用いることを特徴と
し、芳香族ポリアミド紙を用いてなる油入電気機器。
(1) An oil-filled electrical appliance made of aromatic polyamide paper, characterized in that a heat-resistant insulating oil made of fatty acid ester of neopentyl polyol is used as an insulating material.
JP56147122A 1981-09-17 1981-09-17 Oil-immersed electric device Pending JPS5848303A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56147122A JPS5848303A (en) 1981-09-17 1981-09-17 Oil-immersed electric device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56147122A JPS5848303A (en) 1981-09-17 1981-09-17 Oil-immersed electric device

Publications (1)

Publication Number Publication Date
JPS5848303A true JPS5848303A (en) 1983-03-22

Family

ID=15423031

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56147122A Pending JPS5848303A (en) 1981-09-17 1981-09-17 Oil-immersed electric device

Country Status (1)

Country Link
JP (1) JPS5848303A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5317066A (en) * 1992-02-19 1994-05-31 Daicel Chemical Industries, Ltd. Polyester-grafted polyamide, process for preparing the same, and thermoplastic resin composition containing the same
US5997454A (en) * 1995-10-11 1999-12-07 Selco S.R.L. Panel cutting machine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5317066A (en) * 1992-02-19 1994-05-31 Daicel Chemical Industries, Ltd. Polyester-grafted polyamide, process for preparing the same, and thermoplastic resin composition containing the same
US5997454A (en) * 1995-10-11 1999-12-07 Selco S.R.L. Panel cutting machine

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