JPS5848062B2 - イオン選択性電極用電極体の製造方法 - Google Patents
イオン選択性電極用電極体の製造方法Info
- Publication number
- JPS5848062B2 JPS5848062B2 JP52046371A JP4637177A JPS5848062B2 JP S5848062 B2 JPS5848062 B2 JP S5848062B2 JP 52046371 A JP52046371 A JP 52046371A JP 4637177 A JP4637177 A JP 4637177A JP S5848062 B2 JPS5848062 B2 JP S5848062B2
- Authority
- JP
- Japan
- Prior art keywords
- electrode body
- silver
- electrode
- precipitate
- ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 12
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000002244 precipitate Substances 0.000 claims description 13
- 229910002692 Ag3SBr Inorganic materials 0.000 claims description 10
- 150000002500 ions Chemical class 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 229910052709 silver Inorganic materials 0.000 claims description 8
- 239000004332 silver Substances 0.000 claims description 8
- -1 silver ions Chemical class 0.000 claims description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 229910052946 acanthite Inorganic materials 0.000 claims description 6
- 229910021612 Silver iodide Inorganic materials 0.000 claims description 5
- 229910052740 iodine Inorganic materials 0.000 claims description 5
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 4
- 229910002691 Ag3SI Inorganic materials 0.000 claims description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 4
- 239000011630 iodine Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000012266 salt solution Substances 0.000 claims description 3
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 claims description 3
- 229940056910 silver sulfide Drugs 0.000 claims description 3
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 claims description 3
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 3
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 claims description 2
- 238000000975 co-precipitation Methods 0.000 claims description 2
- 229940045105 silver iodide Drugs 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 150000004820 halides Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- FSJWWSXPIWGYKC-UHFFFAOYSA-M silver;silver;sulfanide Chemical compound [SH-].[Ag].[Ag+] FSJWWSXPIWGYKC-UHFFFAOYSA-M 0.000 description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- 150000004763 sulfides Chemical class 0.000 description 3
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 229940006460 bromide ion Drugs 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 2
- 229940006461 iodide ion Drugs 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004455 differential thermal analysis Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/333—Ion-selective electrodes or membranes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7604446A NL7604446A (nl) | 1976-04-27 | 1976-04-27 | Ion-selektieve elektrode. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS52132890A JPS52132890A (en) | 1977-11-07 |
| JPS5848062B2 true JPS5848062B2 (ja) | 1983-10-26 |
Family
ID=19826077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52046371A Expired JPS5848062B2 (ja) | 1976-04-27 | 1977-04-23 | イオン選択性電極用電極体の製造方法 |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS5848062B2 (Direct) |
| BE (1) | BE853936A (Direct) |
| CA (1) | CA1081784A (Direct) |
| DE (1) | DE2716646A1 (Direct) |
| FR (1) | FR2349834A1 (Direct) |
| GB (1) | GB1533196A (Direct) |
| NL (1) | NL7604446A (Direct) |
-
1976
- 1976-04-27 NL NL7604446A patent/NL7604446A/xx not_active Application Discontinuation
-
1977
- 1977-04-15 DE DE19772716646 patent/DE2716646A1/de not_active Ceased
- 1977-04-22 GB GB1682077A patent/GB1533196A/en not_active Expired
- 1977-04-23 JP JP52046371A patent/JPS5848062B2/ja not_active Expired
- 1977-04-25 BE BE176999A patent/BE853936A/xx not_active IP Right Cessation
- 1977-04-26 CA CA277,046A patent/CA1081784A/en not_active Expired
- 1977-04-27 FR FR7712720A patent/FR2349834A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| BE853936A (fr) | 1977-10-25 |
| JPS52132890A (en) | 1977-11-07 |
| FR2349834B1 (Direct) | 1980-03-28 |
| NL7604446A (nl) | 1977-10-31 |
| GB1533196A (en) | 1978-11-22 |
| FR2349834A1 (fr) | 1977-11-25 |
| DE2716646A1 (de) | 1977-11-10 |
| CA1081784A (en) | 1980-07-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4172778A (en) | Ion-selective electrode | |
| JPS592856B2 (ja) | 極く低濃度のハロゲン化物イオンの電位差測定用電極及びその製造方法 | |
| Beilby et al. | Comparison of the Pyrolytic Carbon Film Electrode with the Wax-Impregnated Graphite Electrode. | |
| Papeschi et al. | Use of an iridium electrode for direct measurement of pI of proteins after isoelectric focusing in polyacrylamide gel | |
| Zakharova et al. | Bifunctional potentiometric sensor based on MoO3 nanorods | |
| Heijne et al. | The formation and properties of mixed lead sulfide—silver sulfide membranes for lead (II)-selective electrodes | |
| Rechnitz et al. | Sulfate ion-selective membrane electrode | |
| JPS5848062B2 (ja) | イオン選択性電極用電極体の製造方法 | |
| US4083764A (en) | Ion-selective electrode | |
| Mascini et al. | The preparation and analytical evaluation of a new heterogeneous membrane electrode for cadmium (ii) | |
| Ueda et al. | Effective fixed charge density governing membrane phenomena. VI. Activity coefficients and mobilities of small ions in aqueous solutions of poly (styrenesulfonic acid) | |
| Shu et al. | An Ion-Selective Electrode for Dibasic Phosphate Ion | |
| Novak et al. | Tungsten (V) complexes of ethylenediaminetetraacetic acid | |
| Hulanicki et al. | The mechanism of the potential response of bromide-selective electrodes based on mercury salts | |
| Singh et al. | Hydrous zirconium oxide as an anion-exchanger | |
| Watt et al. | THE THERMODYNAMICS OF THE MOLTEN SALT SYSTEM KNO3-AgNO3-K2SO1 FROM ELECTROMOTIVE FORCE MEASUREMENTS | |
| Ghosh et al. | Studies on metal complexes in aqueous solution-III: The biselenate ion and transition metal selenates | |
| Sarkar et al. | Determination of thermodynamic parameters and stability constants of the complexes of⨿-mitsc with transition metal ions | |
| East et al. | Differential electrolytic potentiometry with ion-selective electrodes for end-point detection in compleximetric titrations of mercury (II), copper (II), nickel (II) and bismuth (III) | |
| Kolthoff et al. | The Accuracy of the Potentiometric Iodide—Silver Titration | |
| Swofford et al. | Anodic Depolarization of the Dropping Mercury Electrode in Sodium Nitrate-Potassium Nitrate Eutectic Melts Containing Solutions of Dissolved Alkali Metal Halides. | |
| Shakhashiri et al. | Oxygen-18 exchange reactions between gaseous oxygen and certain oxygen-containing inorganic salts | |
| Tanaka et al. | SPECIFIC ADSORPTION OF ISOTHIOCYANATOCHROMIUM (III) COMPLEX IONS AT THE MERCURY-AQUEOUS SOLUTION INTERFACE | |
| JPS6362445B2 (Direct) | ||
| Pradhananga et al. | Low cost electrochemical sensors for silver, chloride, bromide and iodide ions |