JPS5847029A - Treatment of decorations for dyeing - Google Patents
Treatment of decorations for dyeingInfo
- Publication number
- JPS5847029A JPS5847029A JP56146694A JP14669481A JPS5847029A JP S5847029 A JPS5847029 A JP S5847029A JP 56146694 A JP56146694 A JP 56146694A JP 14669481 A JP14669481 A JP 14669481A JP S5847029 A JPS5847029 A JP S5847029A
- Authority
- JP
- Japan
- Prior art keywords
- dyeing
- carrier
- water
- processing
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004043 dyeing Methods 0.000 title abstract description 25
- 238000011282 treatment Methods 0.000 title abstract description 13
- 238000005034 decoration Methods 0.000 title description 2
- 238000012545 processing Methods 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 10
- 229920001225 polyester resin Polymers 0.000 claims abstract description 7
- 239000004645 polyester resin Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 17
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 abstract description 4
- 238000005406 washing Methods 0.000 abstract description 3
- 235000010292 orthophenyl phenol Nutrition 0.000 abstract description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 abstract 2
- 235000010290 biphenyl Nutrition 0.000 abstract 1
- 239000004305 biphenyl Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 230000007423 decrease Effects 0.000 description 4
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 241000257303 Hymenoptera Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 hypohenyl Chemical compound 0.000 description 1
- 239000004306 orthophenyl phenol Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Landscapes
- Treatments Of Macromolecular Shaped Articles (AREA)
- Coloring (AREA)
Abstract
Description
【発明の詳細な説明】
本発明はポリエステル樹脂から々る染色用装飾品の処理
方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for treating dyed ornaments made from polyester resin.
ポリエステル樹脂を素材とする装飾品、たとえば釦は、
従来から、まず素材に切削加工またはプレス加工を施し
て所定形状とし、さらＫこれを研磨して未染色の完成品
としていた。以後、この釦の所定数を袋または函に詰め
、染色処理を施す需要先に出荷していた。需要先（染色
工場）では、入手した無着色の釦に着色処理を施して、
これを一般消費者向の完成品としていた。Decorative items made from polyester resin, such as buttons,
Conventionally, a material has been first cut or pressed into a predetermined shape, and then polished to produce an undyed finished product. Thereafter, a predetermined number of these buttons were packed into bags or boxes and shipped to customers who wanted them to be dyed. At the customer site (dyeing factory), the uncolored buttons are colored.
This was a finished product for general consumers.
この着色処理は、一般的な方法としてオーブンの容器（
ステンレス製ボール）に温度約（資）℃の湯を用意し、
これに２〜３ Ｃｒｙ’ｔの比率でキャリヤと前記無着
色の釦を入れ、約５分間攪拌しながら約７０℃〜（資）
１１で徐々に昇温しく前処理工程）、この浴中に所望の
分散染料を淡色の場合は３〜５〜α、濃色の場合は１０
〜１５蜂ｔの割合で混入し、これを約１００℃まで昇温
させながらＩＯ分〜１５分間染色するようにしていた（
染色工程）。次にこれを筒柱ソーダなどによって還元洗
滌したあと、乾燥（後処理工程）し、一般消費者向の完
成品としていた。This coloring process is commonly done in oven containers (
Prepare hot water at a temperature of approximately (100°F) in a stainless steel bowl.
Add the carrier and the uncolored button to this at a ratio of 2 to 3 Cry't, and heat at about 70℃ while stirring for about 5 minutes.
11 (pretreatment step), add the desired disperse dye to this bath at 3-5-α for a light color, and 10 for a dark color.
It was mixed at a rate of ~15 bees and dyed for ~15 minutes while raising the temperature to about 100°C (
dyeing process). This was then reduced and washed with cylindrical soda, etc., and then dried (post-processing process) to create a finished product for general consumers.
ところが前記前処理工程に使用するキャリヤは一般に臭
気、毒性をもち、前記染色処理も含めて作業は常圧のオ
ープンの容器においておこなわれるため、作業環境によ
っては極めて危険な工程であり、また公害問題を発生す
るおそれがあり九。さらに作業者によって製品の染色割
合９強度に不均一性があられれるという欠点があった。However, the carrier used in the pretreatment process generally has an odor and is toxic, and the process, including the dyeing process, is performed in an open container at normal pressure, making it an extremely dangerous process depending on the working environment and causing pollution problems. There is a risk of this occurring. Furthermore, there was a drawback that the dyeing ratio 9 intensity of the product could be non-uniform depending on the operator.
本発明は前記事情に鑑みなされたもので、従来、問題と
なっていた染色作業における前処理工程を省き、そのま
＼染色処理が施せる染色用装飾品の処理方法を提供しよ
うとするものである。The present invention was made in view of the above circumstances, and it is an object of the present invention to provide a method for treating decorative articles for dyeing, which eliminates the pretreatment step in dyeing work that has been a problem in the past, and allows dyeing to be performed as is. .
本発明はポリエステル樹脂からなる装飾品用の素材を、
所定形状に加工した後、これをキャリヤによって処理、
シ、水洗、乾燥したことを特徴とする染色用装飾品の処
理方法である。The present invention uses a material for decorative items made of polyester resin.
After processing into a predetermined shape, it is processed by a carrier,
This is a method for processing dyed ornaments, which is characterized by washing, washing with water, and drying.
以下、本発明の実施例について図面を参照し々がら詳細
に説明する。Embodiments of the present invention will be described in detail below with reference to the drawings.
装飾品の素材はポリエステル樹脂を用いる。The material used for the decorations is polyester resin.
この素材に切削またはプレス加工を施して、例えば、釦
の所定形状とした後、これに研磨を施し、次いで適当な
キャリヤを用い、濃度ｌｏｙ／ｌ〜１Ｆｆ／ｌ、処理温
度頒℃〜１３０℃、好ましくは向℃〜１３０℃、処理時
間加分〜鉛分、好ましくはｂ分〜（資）分、浴比１：１
０による処理を施す。しかるのち、これを水洗し、乾燥
せしめる。This material is cut or pressed to form, for example, a predetermined shape of a button, and then polished, using an appropriate carrier at a concentration of loy/l to 1Ff/l and a processing temperature of ℃ to 130℃. , preferably from 100°C to 130°C, processing time plus lead content, preferably b part to (part) part, bath ratio 1:1
Perform processing using 0. After that, wash it with water and dry it.
以上をもって染色用の製品とし、所定数の袋詰め、また
は微結めとして需要先に出荷すればよい。The above product can be used as a dyeing product, packed in a predetermined number of bags or tied in small knots, and shipped to a customer.
なお、前記濃度をＩＱＦ／ｌ〜１衰々としたのは、濃度
１輸μ以下では染着性（製品の色の濃さ）が劣り、濃度
１”ｆ／を以上では染着性に変化がなく、材料の浪費に
なるからである。また処理温度弐〜１３０℃としたのは
、温度（資）℃以下では染着性が悪く、温度１３０℃以
上では製品の光沢が低下するからである。オた処理時間
加分〜４０分としたのは処理時間加分以下では染着性が
劣り、処理時間切分以上では染着性の向上がみられず、
逆に徐々に低下するからである。こ＼で染着性とは色差
計（日本電色株式会社製、 ＣＦ３Ｈ−１００１ＤＰ屋
）を用い、染色された製品の色の濃さを計測し、これを
数字で表わしたものである。オた、使用するキャリヤは
、オルソフェニルフェノール系、ヒフエニール系、メチ
ルナフタレン系。The reason why the above concentration is set to IQF/l ~ 1 is because if the concentration is less than 1 μm, the dyeing property (the depth of the color of the product) is poor, and if the density is more than 1”f/l, the dyeing property changes. This is because the processing temperature is set at 2 to 130°C because dyeing properties are poor at temperatures below 130°C, and the gloss of the product decreases at temperatures above 130°C. The reason why the treatment time was increased to 40 minutes was because if the treatment time was less than the treatment time, the dyeability would be poor, and if the treatment time was longer than the treatment time, the dyeability would not improve.
On the contrary, it gradually decreases. Here, dyeability refers to the color depth of a dyed product measured using a color difference meter (manufactured by Nippon Denshoku Co., Ltd., CF3H-1001DPya), and expressed as a number. The carriers used are orthophenylphenol, hypohenyl, and methylnaphthalene.
クロルベンゼン系、その他の乳化型キャリヤ。Chlorbenzene-based and other emulsified carriers.
水溶性キャリヤかどの市販のキャリヤを用いる。A commercially available carrier such as a water-soluble carrier is used.
染着性をより向上させるＫｌｆｉ少くとも９０Ｃ以上の
処理温度が必要であり、処理温度約１３０℃以上になる
と製品の染着性にそれほど差がなくなり、逆に光沢が低
下する。A processing temperature of at least 90C or higher is required to further improve the dyeability, and if the processing temperature is about 130C or higher, there will be no significant difference in the dyeability of the product, and on the contrary, the gloss will decrease.
（３）処理時間の影響
前記処理条件のうち、キャリヤ処理濃度１＠／ｌ 、
１５ｊ９／ｌの場合の結果を第３図に示す。(3) Effect of processing time Among the above processing conditions, carrier processing concentration 1@/l,
The results in the case of 15j9/l are shown in FIG.
この結果から、処理時間約加分から約（資）発着では染
着性が向上し、以後処理時間約鉛分までは殆ど変化なく
、４０分以降は徐々に低下する。From this result, the dyeing property improves when the processing time is from about 100 minutes to about 100 minutes (lead), after that there is almost no change until the processing time is about 40 minutes, and it gradually decreases after 40 minutes.
以上、本発明によれば、従来、染色処理の場合におこ々
っていた有害、危険な前処理を省き、染色工場では染色
工程のみを実施すればよく、危険対策は不要と々す、公
害問題は解決される。As described above, according to the present invention, the harmful and dangerous pre-treatments that conventionally occurred in the dyeing process can be omitted, and the dyeing factory only has to carry out the dyeing process, and there is no need for any dangerous measures. The problem will be resolved.
オだ、染色工場では前処理を省いたことにより、作業者
による製品の染色１強度に現われる不均一性が防止でき
、品質が向上する。By omitting pre-treatment in dyeing factories, it is possible to prevent unevenness that appears in the intensity of dyeing of products by workers, improving quality.
さらに本発明による処理を施すことにより、従来法によ
る製品に比較して濃色に染色され、かつ艶のある染色製
品が得られる。Furthermore, by applying the treatment according to the present invention, a dyed product can be obtained which is dyed in a deeper color and has a glossier color than a product produced by a conventional method.
また、従来法による前処理工程を除く、染色工程のみの
処理時間と本発明による染色用装飾品を用いた染色工程
の処理時間を同一対象品について比較した場合、前者で
＃ｉＩＯ分〜１５分であるのに対し、後者でＦｉ５分〜
１ｏ分で着色が完了し処理時間を短縮させることができ
る。In addition, when comparing the processing time of the dyeing process alone, excluding the pretreatment process by the conventional method, and the processing time of the dyeing process using the dyeing ornament according to the present invention for the same target product, the former takes #iIO minutes to 15 minutes. On the other hand, the latter takes Fi 5 minutes ~
Coloring can be completed in 1 minute, reducing processing time.
第１図は染着性に対する本発明に係る処−理方法におけ
る処理濃度の影響を示すグラフ、第２図は同処理温度の
影響を示すグラフ、第３”図は、同処理時間の影響を示
すグラフである。Figure 1 is a graph showing the influence of treatment concentration in the treatment method according to the present invention on dyeing properties, Figure 2 is a graph showing the influence of treatment temperature, and Figure 3 is a graph showing the influence of treatment time. This is a graph showing.
Claims (1)
に加工した後、これをキャリヤによって処理し、水洗、
乾燥したことを特徴とする染色用装飾品の処理方法。After processing the decorative material made of polyester resin into a predetermined shape, it is treated with a carrier, washed with water,
A method for processing dyed ornaments characterized by drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56146694A JPS5847029A (en) | 1981-09-17 | 1981-09-17 | Treatment of decorations for dyeing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56146694A JPS5847029A (en) | 1981-09-17 | 1981-09-17 | Treatment of decorations for dyeing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5847029A true JPS5847029A (en) | 1983-03-18 |
Family
ID=15413446
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56146694A Pending JPS5847029A (en) | 1981-09-17 | 1981-09-17 | Treatment of decorations for dyeing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5847029A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0189110A2 (en) * | 1985-01-24 | 1986-07-30 | D. Swarovski & Co. | Dyed decorated material and process for dyeing a decorated material |
| JP2001140172A (en) * | 1999-11-04 | 2001-05-22 | Kawaguchiko Seimitsu Co Ltd | Colored parts and coloring process therefor |
| GB2393961A (en) * | 2002-10-12 | 2004-04-14 | Colormatrix Europe Ltd | Moulded thermoplastic article with surface-bound additive |
-
1981
- 1981-09-17 JP JP56146694A patent/JPS5847029A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0189110A2 (en) * | 1985-01-24 | 1986-07-30 | D. Swarovski & Co. | Dyed decorated material and process for dyeing a decorated material |
| JP2001140172A (en) * | 1999-11-04 | 2001-05-22 | Kawaguchiko Seimitsu Co Ltd | Colored parts and coloring process therefor |
| GB2393961A (en) * | 2002-10-12 | 2004-04-14 | Colormatrix Europe Ltd | Moulded thermoplastic article with surface-bound additive |
| GB2393961B (en) * | 2002-10-12 | 2007-03-14 | Colormatrix Europe Ltd | Moulded thermoplastic articles and process |
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