JPS583859A - Heat insulating panel - Google Patents

Heat insulating panel

Info

Publication number
JPS583859A
JPS583859A JP10270181A JP10270181A JPS583859A JP S583859 A JPS583859 A JP S583859A JP 10270181 A JP10270181 A JP 10270181A JP 10270181 A JP10270181 A JP 10270181A JP S583859 A JPS583859 A JP S583859A
Authority
JP
Japan
Prior art keywords
heat insulating
phenolic resin
fiber reinforcing
insulating panel
foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10270181A
Other languages
Japanese (ja)
Inventor
川嶋 弥須男
吉富 健己
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Altemira Co Ltd
Original Assignee
Showa Aluminum Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Aluminum Corp filed Critical Showa Aluminum Corp
Priority to JP10270181A priority Critical patent/JPS583859A/en
Publication of JPS583859A publication Critical patent/JPS583859A/en
Pending legal-status Critical Current

Links

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 この発明は、断熱パネルに関する。[Detailed description of the invention] The present invention relates to a heat insulating panel.

従来、断熱パネルとしては、互いに対向する金属板同志
の5中間に発泡性ウレタン樹脂原料を注入し、これを発
泡成形することによりっくらnたものが知られている。
BACKGROUND ART Conventionally, heat insulating panels have been known that are made by injecting a foamable urethane resin raw material into the middle of five metal plates facing each other and foam-molding the resulting material.

この従来のウレタンフオームを用いた断熱パネルは主と
して業務用の組立式冷蔵庫および冷凍庫に使用されてい
るが、耐熱性および耐燃性に劣り、しがも発煙性がある
うえに、高温になるとパネルにそりが発生するため、た
とえば冷蔵・−冷凍倉庫の壁材や建築内装材)あるい切
清lマ欠用さ−nる自動車塗装用ブースの壁材等の用途
には不向きであるという問題があった。
Insulating panels using conventional urethane foam are mainly used in commercial refrigerators and freezers, but they have poor heat resistance and flame resistance, are smoke-emitting, and can become damaged when exposed to high temperatures. Because warping occurs, it is unsuitable for applications such as wall materials for refrigerated and frozen warehouses, building interior materials), or wall materials for automobile painting booths that require cutting and cleaning. there were.

剤を介して接合することにより断熱パネルを製造してい
た。しかしながら、これでは断熱パネルの製造が非常に
面倒で手間がか\るし、フェノールフオームは非常に脆
いため曲げ強度が低いという問題があった。また金属板
の対向面にセラコーホ−F等の無機質板を貼り付けた後
、これらにフェノールフオームのスラブを貼り付けるか
、またはこれらの無機質板付き金属板同志の中間にフェ
ノール樹脂原料を注入して発泡成形した断熱パネルが知
られているが、フェノールフォー・ムの表面層は粉状と
なって飼れ易いため接着力が弱く、シたがって断熱パネ
ルは大分大きな強度が得られなかった。、またパネルの
重量が重くなるうえに、無機質板の断熱性能はフェノー
ルフオームに比べて悪いため、パネル厚を大きくしなけ
ればならないという問題があった。さらに、対向状に配
置された金属板同志の中間に発泡性フェノール樹脂原料
を注入して造することも考えられるが、フェノール樹脂
の発泡成形時の反応によって生じる水がフェノール樹脂
と金属板との接合を阻むため、このような方法では一体
化された充分に大きい強度を有する断熱パネルを製造す
ることかで−きながった。
Insulating panels were manufactured by bonding through adhesive. However, this method requires a lot of effort and labor to produce the heat insulating panels, and the phenol foam is very brittle and has a problem of low bending strength. Alternatively, after pasting an inorganic plate such as Ceracoho-F on the facing surface of the metal plate, a slab of phenol foam is pasted on these, or a phenolic resin raw material is injected between the metal plates with the inorganic plate. Foam-molded insulation panels are known, but the surface layer of the phenol foam is powdery and easy to feed, resulting in weak adhesion, and therefore the insulation panels do not have much strength. In addition, there was a problem in that the weight of the panel was increased, and the insulating performance of the inorganic board was poorer than that of phenol foam, so the thickness of the panel had to be increased. Furthermore, it is possible to inject a foamable phenolic resin raw material between the metal plates arranged facing each other, but the water produced by the reaction of the phenol resin during foam molding will cause the phenolic resin and the metal plate to react. To prevent bonding, such methods have been limited to producing integrated insulation panels of sufficient strength.

この発明は、上記の問題を解決するためになされたもの
で、その構成を、以下図面に示す実施例に基づいて説明
する。
This invention has been made to solve the above problems, and its configuration will be explained below based on embodiments shown in the drawings.

第1図と第2図において、(1)はこの発明にが\る断
熱パネル、(2)はこれの表裏面を構成する一対の金属
板で、これらはアルミニウム板、ステンレス鋼板または
塩化ビニル樹脂被覆鋼板等げ縁部(2a)が設けられて
いる。(3)はこれらの金属板(2)の対向面にそれぞ
れ接着剤(4)により貼り付けられたガラスクロスより
なるマット状の繊維補強材で、これはたとえば100 
f/d〜6o ofedの割合で金属板(2)に貼り付
けられる。
In Figures 1 and 2, (1) is a heat insulating panel according to the present invention, and (2) is a pair of metal plates that constitute the front and back surfaces of this panel, and these are aluminum plates, stainless steel plates, or vinyl chloride resin. A beveled edge (2a) of the coated steel plate is provided. (3) is a mat-like fiber reinforcing material made of glass cloth attached to the opposing surfaces of these metal plates (2) with adhesive (4), for example, 100
It is pasted on the metal plate (2) at a ratio of f/d to 6o ofed.

繊維補強材(3)としては耐燃性を有するものであれば
ガラスクロス以外のものであっても勿論よい。このマッ
ト状繊維補強材(3)はそのま−で貼り付けるか、また
は毛羽型たせたのち接着剤(4)により貼り付ける。接
着剤(4)としてはウレタン系、エポキシ系およびゴム
系等の接着剤を使用し得る。+51 +61は断熱パネ
ル(1)の左右両側縁部に配置された塩化ビニル樹脂よ
りなる一対の枠材で、これらのうち左側の枠材(5)に
は嵌合凹部(7)が設けらn1右側の枠材(6)には嵌
合凸部(8)が設けられている。(9)は金属板(1)
同志の中間に注入発泡成形により充填された発泡フェノ
ール樹脂よりなる断熱材である。
Of course, the fiber reinforcing material (3) may be anything other than glass cloth as long as it has flame resistance. This mat-like fiber reinforcing material (3) may be attached as is, or it may be made into a fluffy shape and then attached using an adhesive (4). As the adhesive (4), urethane-based, epoxy-based, rubber-based adhesives, and the like can be used. +51 +61 is a pair of frame members made of vinyl chloride resin placed on the left and right edges of the heat insulating panel (1), of which the left frame member (5) is provided with a fitting recess (7) n1 A fitting convex portion (8) is provided on the right frame member (6). (9) is a metal plate (1)
This is a heat insulating material made of foamed phenolic resin that is filled between the two layers by injection foam molding.

上記断熱パネル(1)を製造するには、まず第3図に示
すように、表裏一対の金属板(2)の各片面に予め接着
剤(4)によりガラスクロスよりなるマット状の繊維補
強材(3)を貼り付け、これらの繊維補強材付き金属板
(2)を対向状に配置するとともに、左右両側縁部に枠
材151 T6+を配置する。っ−。
In order to manufacture the above-mentioned heat insulating panel (1), first, as shown in Fig. 3, a mat-like fiber reinforcement material made of glass cloth is attached to each side of a pair of front and back metal plates (2) with adhesive (4) in advance. (3), and these metal plates (2) with fiber reinforcing materials are placed facing each other, and frame members 151 T6+ are placed on both left and right edges. -.

いてこれらの金属板(2)同志の中間に発泡性フェノー
ル樹脂(レゾール型)の液状原料を注入し、これが繊維
補強材(3)を含んだ状態で発泡成形する。フェノール
樹脂の発泡により、第1図および第2図に示すように繊
維補強材(3)は繊維同志の結合がゆるんで一緒に膨張
し、フェノール樹脂の内部に分散せしめられる。しかし
繊維補強材(3)の金属板(2)との接触部分は接着剤
(4)により接合されたま\である。フェノール樹脂の
硬化後、繊維補強材1)は発泡7エ/−ル樹脂よりなる
断熱材(9)に含まれており、しかも繊維補強材(3)
は金属板(2)の対向面に接合されたま−であるから、
これら王者が一体に結合され、断熱パネル(1)の強度
が増大する。フェノール樹脂の注入発泡成形はバッチ式
または連続方式で実施し得る。なお、フェノール樹脂の
発泡成形時には反応により水が生じるが、上記のように
金属板(2)と1これに接合さnた繊維補強材(3)と
、発泡フエー7−ル樹脂の断熱材(9)とが強固に一体
に結合するので、全く問題はない。また繊維補強材(3
)を金属板(2)に接合する接着剤(4)として湿気硬
化型ウレタン系接着剤を使用した場合には、フェノール
樹脂の反応によって生じた水とウレタン系接着剤とが反
応して、接層剤が硬化するとともに、水が除去されるの
で好都合である。
Then, a liquid raw material of foamable phenolic resin (resol type) is injected into the middle of these metal plates (2), and foam molding is performed in a state where this contains the fiber reinforcing material (3). Due to the foaming of the phenolic resin, as shown in FIGS. 1 and 2, the fiber reinforcing material (3) loosens the bonds between its fibers, expands together, and is dispersed inside the phenolic resin. However, the contact portion of the fiber reinforcement material (3) with the metal plate (2) remains bonded with the adhesive (4). After curing of the phenolic resin, the fiber reinforcement material 1) is included in the insulation material (9) made of foamed 7-El resin, and the fiber reinforcement material (3)
is a ball bonded to the opposite surface of the metal plate (2), so
These kings are combined together to increase the strength of the heat insulating panel (1). Injection foam molding of phenolic resins can be carried out in batch or continuous mode. In addition, water is generated by the reaction during foam molding of phenolic resin, but as mentioned above, the metal plate (2), the fiber reinforcement material (3) bonded thereto, and the foamed fiber resin heat insulating material (7) 9) are firmly combined into one body, so there is no problem at all. In addition, fiber reinforcement material (3
) to the metal plate (2) using a moisture-curing urethane adhesive (4), the water produced by the reaction of the phenol resin reacts with the urethane adhesive, causing the bond to deteriorate. Advantageously, water is removed as the layering agent hardens.

なお、フェノール樹脂よりなる断熱材(9)にはれる場
合がある。ここで、補強材としては、ガラスパウダー、
ガラスファイバーチップ、炭素11JI、シラスバルー
ン1.フェーノールバルーン、i5スt4ルーン等を使
用することができる。ここで、ガラスパウダーはアルカ
リ性であるため、フェノールフオームの酸性を中和して
金属板の腐食を防止し得る。またバルーンは中空である
ため、フェノール樹脂の硬化反応時に生じる水を吸収す
ることができる。このような補強材を含むことにより断
熱材(8)の1強度がさらに増大する。
Note that it may get stuck in the heat insulating material (9) made of phenol resin. Here, as the reinforcing material, glass powder,
Glass fiber chip, Carbon 11JI, Shirasu balloon 1. Phenol balloons, i5 st4 runes, etc. can be used. Here, since the glass powder is alkaline, it can neutralize the acidity of the phenol foam and prevent corrosion of the metal plate. Furthermore, since the balloon is hollow, it can absorb water generated during the curing reaction of the phenol resin. Including such a reinforcing material further increases the strength of the heat insulating material (8).

また、一対の金属板(2)の対向面にクラフト紙等より
なる吸水性シートを貼り付け、この吸水性シートにガラ
スクロス等の繊維補強材(3)を接層剤(4)により接
合するようにしてもよい。したがってこの場合には、繊
維補強材(3)は吸水性シートを介して金属板(2)に
貼り付けらnることになる。このようにすると、フェノ
ール樹脂の発泡成形の反応により生じた水が吸水性シー
トに吸い取られて除かれるため、フェノール樹脂が硬化
することにより、吸水性シー)とフェノール樹脂より)
jる断熱材(9)とが接合することができるとともに、
上記のように断熱材(9)は繊維補強材(3)を含んで
いるので、断熱パネル(1)の強度明する。
Additionally, a water-absorbent sheet made of kraft paper or the like is pasted on the opposing surfaces of the pair of metal plates (2), and a fiber reinforcing material (3) such as glass cloth is bonded to this water-absorbent sheet using a bonding agent (4). You can do it like this. Therefore, in this case, the fiber reinforcing material (3) is attached to the metal plate (2) via the water absorbent sheet. In this way, the water generated by the reaction of the foam molding of the phenolic resin is absorbed by the water-absorbing sheet and removed, so that the phenol resin hardens, causing the water-absorbing sheet () and the phenolic resin () to harden.
In addition to being able to join with the heat insulating material (9),
As mentioned above, since the heat insulating material (9) includes the fiber reinforcement material (3), the strength of the heat insulating panel (1) is improved.

:つぎの3種の断熱パネルに)〜C)を製造した。: The following three types of insulation panels) to C) were manufactured.

(1)一対のアルミニウム板(2)の対向面にそれぞれ
ガラスクロス(3)をゴム系接着剤(4)により接着し
、これらの金属板(2)同志の中間に発泡性フェノール
樹脂原料を注入し、発泡成形して、 断熱パネル(5)
を製造した。
(1) Glass cloth (3) is adhered to the opposing surfaces of a pair of aluminum plates (2) using rubber adhesive (4), and foamable phenolic resin raw material is injected between these metal plates (2). Then, foam-mold the insulation panel (5)
was manufactured.

(II)  一対のアルミニウム板(2)の対向面にそ
れぞれガラスクロス(3)をゴム系接着剤(4)により
接着したのち、このガラスクロ刈3)を毛羽室たせ、つ
いで金属板(2)同志の中間に発泡性?工。
(II) Glass cloth (3) is adhered to the opposing surfaces of a pair of aluminum plates (2) using a rubber adhesive (4), and then the glass cloth (3) is placed in a fluff chamber, and then the metal plate (2) is attached to the metal plate (2). Effervescent in the middle? Engineering.

ノール樹脂原料を注入し、発泡成形して断熱パネル(B
)を製造した。
Inject the Knoll resin raw material and foam mold it to create a heat insulating panel (B
) was manufactured.

<1)  参考例として、一対のアルミニウム板(2)
の対向面にそれぞれクラフト紙を貼り付け、これらの金
属板(2)同志の中間に発泡性フェノール樹脂原料を注
入し、発泡成形してフェノール樹脂の反応によって生じ
る水を紙に吸収させて、両アルミニウム板(2)とクラ
フト紙と断熱材(9)とが一体に結合した断熱パネル(
C)を製造した。
<1) As a reference example, a pair of aluminum plates (2)
A piece of kraft paper is pasted on the opposing surfaces of each metal plate (2), a foamable phenolic resin raw material is injected into the middle of these two metal plates (2), and the water generated by the reaction of the phenolic resin is absorbed by the paper through foam molding. A heat insulating panel (in which an aluminum plate (2), kraft paper, and a heat insulating material (9) are combined together)
C) was produced.

これらの断熱パネル(5)(B) (C)について曲げ
強度を測定し、得られた結果を下表にまとめた。
The bending strength of these heat insulating panels (5), (B), and (C) was measured, and the results are summarized in the table below.

この表から明らかなように、この発明による断熱パネル
(A)■)は、参考例(C)に比べてすぐnだ曲げ強度
を有しているものである。
As is clear from this table, the heat insulating panel (A) (2) according to the present invention has a bending strength just above that of the reference example (C).

上記断熱パネルは、強度が非常に大きくまた発煙性が非
常に小さいので、冷蔵・冷凍倉庫の壁材、建築内装材、
雨戸、扉、間仕切等として使用することができるととも
に、耐熱性、耐燃性にすぐnでいて、高温でもそりが発
生せず、寸法精度がすぐれているので、たとえば自動車
(クリーンルーム)等に使用することができるものであ
る。
The above insulation panels have very high strength and very low smoke generation, so they can be used as wall materials for refrigerated and frozen warehouses, building interior materials, etc.
It can be used as shutters, doors, partitions, etc., and it is also heat resistant and flame resistant, does not warp even at high temperatures, and has excellent dimensional accuracy, so it can be used for example in automobiles (clean rooms), etc. It is something that can be done.

この発明による断熱パネルは、上述のように、相互に所
定間隔をあけて対向状に配置された一対の金属板(2)
の各対向面に繊維補強材(3)が貼り付けられ為これら
の繊維補強材(3)付き金属板(2)同志の中間部に発
泡性フェノール樹脂原料が注入されて1これが繊維補強
材(3)を含んだ状態で発泡成形され、硬化後の発泡フ
ェノール樹脂よりなる断熱材(9)と、これに含まれた
繊維補強材イ手 (3)と、両会翼板(2)とが−保に結合せられている
ものであるから、断熱パネル(1)は非常に大きな強度
を有しており、しかも耐熱性および耐燃性にすぐれてい
て、高温においてもそりを生じることがないうえに、発
煙性が小さいので、冷蔵・冷凍倉庫や建築内装材並びに
自動車塗装用ブース等の各種の用途に有効に使用するこ
とができる。そしてフェノール樹脂を注入発泡成形する
ことにより断熱パネル(1)をつくることができるから
、その製造作業が非常に簡単であるという効果を奏する
As described above, the heat insulating panel according to the present invention includes a pair of metal plates (2) arranged facing each other at a predetermined distance from each other.
A fiber reinforcing material (3) is pasted on each opposing surface of the metal plate (2) with the fiber reinforcing material (3), and a foamable phenolic resin raw material is injected into the middle part of the metal plate (2) with the fiber reinforcing material (3). A heat insulating material (9) made of a foamed phenolic resin that is foam-molded in a state containing 3) and cured, a fiber reinforcing material (3) contained therein, and a double wing plate (2). - Because the insulation panel (1) is bonded to the insulation panel, it has extremely high strength, has excellent heat resistance and flame resistance, and does not warp even at high temperatures. In addition, since it has low smoke generation, it can be effectively used in various applications such as refrigerated and frozen warehouses, architectural interior materials, and automobile painting booths. Since the heat insulating panel (1) can be made by injection foam molding the phenolic resin, the manufacturing operation is very simple.

【図面の簡単な説明】[Brief explanation of drawings]

図面はこの発明の実施例を示すもので、第1図は部分切
欠き斜視図、第2図は部分拡大断面図、第3図は同部分
拡大断面図で、フェノール樹脂の発泡成形前の状態を示
している。 (1)・・・断熱パネル、(2)・・・金属板、(3)
・・・ガラスクロス(繊維補強材) 、+41・・・接
着剤、(5)(6)・・・枠材、(9)・・・発泡フェ
ノール樹脂製断熱材。 特許出願人  昭和アルミニウム株式会社第2図 1 第8図
The drawings show an embodiment of the present invention, in which Fig. 1 is a partially cutaway perspective view, Fig. 2 is a partially enlarged sectional view, and Fig. 3 is an enlarged sectional view of the same part, showing the state before foam molding of phenolic resin. It shows. (1)...insulation panel, (2)...metal plate, (3)
... Glass cloth (fiber reinforcement material), +41 ... Adhesive, (5) (6) ... Frame material, (9) ... Foamed phenolic resin insulation material. Patent applicant Showa Aluminum Co., Ltd. Figure 2 1 Figure 8

Claims (1)

【特許請求の範囲】[Claims] 相互に所定間隔をあけて対向状に配置さnた一対の金属
板(2)の各対向面に繊維補強材(3)が貼り付けられ
、これらの繊維補強材(3)付き金属板(2)同志の中
間部に発泡性フェノール樹脂原料が注入さnて、こnが
繊維補強材(3)を含んだ状態で発泡成形され、硬化後
の発泡フェノール樹脂よりなる断熱材(9)と、これに
含まれた繊維補強材(3)と、両全翼板(2)とが一体
に結合せらnている断熱パネル。
Fiber reinforcing materials (3) are pasted on each opposing surface of a pair of metal plates (2) that are arranged facing each other at a predetermined interval, and these metal plates (2) with fiber reinforcing materials (3) are attached. ) A foamable phenolic resin raw material is injected into the middle part of the material, and this material is foam-molded in a state containing the fiber reinforcing material (3), and after curing, a heat insulating material (9) made of the foamed phenolic resin is formed. A heat insulating panel in which the fiber reinforcing material (3) contained therein and both flying wing plates (2) are integrally combined.
JP10270181A 1981-06-30 1981-06-30 Heat insulating panel Pending JPS583859A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10270181A JPS583859A (en) 1981-06-30 1981-06-30 Heat insulating panel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10270181A JPS583859A (en) 1981-06-30 1981-06-30 Heat insulating panel

Publications (1)

Publication Number Publication Date
JPS583859A true JPS583859A (en) 1983-01-10

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JP10270181A Pending JPS583859A (en) 1981-06-30 1981-06-30 Heat insulating panel

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60206635A (en) * 1984-03-30 1985-10-18 旭ファイバーグラス株式会社 Sound-insulating heat-insulating plate
JPS6158735A (en) * 1984-08-30 1986-03-26 株式会社ブリヂストン Refractory composite board
JPS6177236U (en) * 1984-10-25 1986-05-23
JPS6177235U (en) * 1984-10-25 1986-05-23
JPS61172728A (en) * 1985-01-28 1986-08-04 群栄化学工業株式会社 Manufacture of metallic siding board
JPH04135323U (en) * 1991-06-12 1992-12-16 昭和アルミニウム株式会社 insulation panels
WO2007141393A1 (en) * 2006-06-08 2007-12-13 Walki Group Oy Insulation board
GB2571396A (en) * 2018-02-26 2019-08-28 Fairview Architectural Pty Ltd A cladding for application to a structure and an assembly of the cladding with the structure
JP2019167764A (en) * 2018-03-26 2019-10-03 パナソニックIpマネジメント株式会社 Interior panel and interior panel manufacturing method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5620811B2 (en) * 1977-05-25 1981-05-15

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5620811B2 (en) * 1977-05-25 1981-05-15

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60206635A (en) * 1984-03-30 1985-10-18 旭ファイバーグラス株式会社 Sound-insulating heat-insulating plate
JPH042098B2 (en) * 1984-03-30 1992-01-16
JPS6158735A (en) * 1984-08-30 1986-03-26 株式会社ブリヂストン Refractory composite board
JPS6177236U (en) * 1984-10-25 1986-05-23
JPS6177235U (en) * 1984-10-25 1986-05-23
JPS61172728A (en) * 1985-01-28 1986-08-04 群栄化学工業株式会社 Manufacture of metallic siding board
JPH0473379B2 (en) * 1985-01-28 1992-11-20 Gunei Kagaku Kogyo Kk
JPH04135323U (en) * 1991-06-12 1992-12-16 昭和アルミニウム株式会社 insulation panels
WO2007141393A1 (en) * 2006-06-08 2007-12-13 Walki Group Oy Insulation board
GB2571396A (en) * 2018-02-26 2019-08-28 Fairview Architectural Pty Ltd A cladding for application to a structure and an assembly of the cladding with the structure
JP2019167764A (en) * 2018-03-26 2019-10-03 パナソニックIpマネジメント株式会社 Interior panel and interior panel manufacturing method

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