JPS5836942A - Manufacture of polarization retaining optical fiber - Google Patents

Manufacture of polarization retaining optical fiber

Info

Publication number
JPS5836942A
JPS5836942A JP56133740A JP13374081A JPS5836942A JP S5836942 A JPS5836942 A JP S5836942A JP 56133740 A JP56133740 A JP 56133740A JP 13374081 A JP13374081 A JP 13374081A JP S5836942 A JPS5836942 A JP S5836942A
Authority
JP
Japan
Prior art keywords
tube
optical fiber
refractive index
boron oxide
polarization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP56133740A
Other languages
Japanese (ja)
Inventor
Tomoo Yanase
柳瀬 知夫
Kanze Tanigawa
谷川 侃是
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Nippon Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp, Nippon Electric Co Ltd filed Critical NEC Corp
Priority to JP56133740A priority Critical patent/JPS5836942A/en
Publication of JPS5836942A publication Critical patent/JPS5836942A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/014Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
    • C03B37/018Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD] by glass deposition on a glass substrate, e.g. by inside-, modified-, plasma-, or plasma modified- chemical vapour deposition [ICVD, MCVD, PCVD, PMCVD], i.e. by thin layer coating on the inside or outside of a glass tube or on a glass rod
    • C03B37/01853Thermal after-treatment of preforms, e.g. dehydrating, consolidating, sintering
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/014Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
    • C03B37/018Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD] by glass deposition on a glass substrate, e.g. by inside-, modified-, plasma-, or plasma modified- chemical vapour deposition [ICVD, MCVD, PCVD, PMCVD], i.e. by thin layer coating on the inside or outside of a glass tube or on a glass rod
    • C03B37/01861Means for changing or stabilising the diameter or form of tubes or rods
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2201/00Type of glass produced
    • C03B2201/06Doped silica-based glasses
    • C03B2201/08Doped silica-based glasses doped with boron or fluorine or other refractive index decreasing dopant
    • C03B2201/10Doped silica-based glasses doped with boron or fluorine or other refractive index decreasing dopant doped with boron
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2203/00Fibre product details, e.g. structure, shape
    • C03B2203/10Internal structure or shape details
    • C03B2203/22Radial profile of refractive index, composition or softening point
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2203/00Fibre product details, e.g. structure, shape
    • C03B2203/30Polarisation maintaining [PM], i.e. birefringent products, e.g. with elliptical core, by use of stress rods, "PANDA" type fibres

Abstract

PURPOSE:To obtain an optical fiber whose refractive index is not lowered at the central part by forming a quartz glass film contg. boron oxide on the inner wall of a round and hollow glass tube, evacuating the tube, and heating it from the outside to make the tube solid in an elliptical shape. CONSTITUTION:Quartz glass 2 contg. about 5% boron oxide is deposited on the inner wall of a quartz glass tube 1 having a round hollow part by a chemical vapor deposition method. The internal pressure of the tube 1 is made about 10mm.H2O lower than the external pressure, and the tube 1 is heated to about 1,900 deg.C. The boron oxide of high volatility in the innermost layer of the tube 1 is volatilized and scattered to form a thin layer of pure quartz, and by making the tube 1 solid in a flat shape, an elliptical pure quartz part 5 is formed at the central part. Thus, the refractive index distribution is not lowered at the core part 5, and a polarization retaining optical fiber with a small loss is obtd. by drawing.

Description

【発明の詳細な説明】 本発明は光通信、光センサ等で用いられる偏光保存光フ
ァイバの製造方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method of manufacturing a polarization-maintaining optical fiber used in optical communications, optical sensors, and the like.

偏光を保存したまま光を導波する光ファイバは、が高い
、従来開発されてきた偏光保存光ファイバは、通称肉付
は化学蒸着法と呼ばれる方法で、円形の中空部を有する
ガラス管の内壁に、第一に酸化硼素を含む低屈折率のガ
ラス層を形成し、第二に高屈折率のガラス層を形成し、
さらにガ? ’x管の内圧をガラス管の外圧より低くし
かつガラス管を外側から加熱し、前記高屈折率層が楕円
形になるよ、5中実化し、棒状の光フアイバプリフォー
ムな得、さらに線引することにより製造されていた。
Optical fibers that guide light while preserving polarization have a high cost.Polarization preserving optical fibers, which have been developed in the past, are made using a method called chemical vapor deposition, which is a method called chemical vapor deposition, which is made by attaching the inner wall of a glass tube with a circular hollow part. Firstly, a low refractive index glass layer containing boron oxide is formed, secondly a high refractive index glass layer is formed,
More moths? 'The internal pressure of the x-tube is lower than the external pressure of the glass tube and the glass tube is heated from the outside so that the high refractive index layer becomes elliptical. It was manufactured by pulling.

上述の方法により製造された楕円形コアを有する偏光保
存光ファイバの断面図の一例を第1図(mlK示す、こ
の図において、1は外側の石英ガラス層、2は酸化硼素
を含む低屈折率のガラス層、3は高屈折率のコア部であ
る。この第1図(mlの長軸方向の断面における屈折率
分布を示すと、第1図(ロ)のよ5になっている。さて
この方法によって製造された楕円形;アを有する偏光保
存光ファイバは、ガラス管を中実化させる工程時に、ガ
ラス管最内層の高屈折ガラス層の成分中の高屈折率寄与
物質(酸化ゲルマニワム、酸化碑等)が高温のため揮発
し、通称センターディップと呼ばれる屈折率の落ち込み
4が形成されてしまう。上記屈折率分布の中心に屈折率
の落ち込み4を有する楕円コア偏光保存光ファイバは、
コア部3からのエネルギーのしみ出しが楕円コアの短径
方向に特に多くなり、低損失の偏光保存光ファイバを得
にくいという問題があった。したがうて本発明の目的は
、屈折率分布の中心部に屈折率の落ち込みのない、すな
わちコア部からのエネルギーのしみ出しが少ないl低損
失の偏光保存光ファイバの製造方法を提供することKあ
る。本発明の構成は、円形の中空部を有するガラス管の
内壁に、酸化硼素を含む石英ガラス膜を化学蒸着法で形
成し、前記ガラス膜が形成されたガラス管の内圧をガラ
ス管の外圧より低くしかつガラス管を外側から加熱し、
前記ガラス管を楕円形に収縮させて中実化し、中心部に
酸化硼素の揮発したコアを形成するとと゛を特徴とする
偏光保存光ファイバの製造方法である。
An example of a cross-sectional view of a polarization-maintaining optical fiber having an elliptical core manufactured by the method described above is shown in FIG. The glass layer 3, 3, is a core portion with a high refractive index.The refractive index distribution in the cross section in the long axis direction of Figure 1 (ml) is 5 as shown in Figure 1 (b). The polarization-maintaining optical fiber having an elliptical shape produced by this method is produced by adding high refractive index contributing substances (germanium oxide, germanium oxide, Oxide monuments, etc.) are volatilized due to the high temperature, and a dip 4 in the refractive index, commonly called a center dip, is formed.
There was a problem in that the energy seeping out from the core portion 3 was particularly large in the short axis direction of the elliptical core, making it difficult to obtain a polarization-maintaining optical fiber with low loss. Therefore, an object of the present invention is to provide a method for manufacturing a low-loss polarization-maintaining optical fiber in which there is no drop in the refractive index at the center of the refractive index distribution, that is, less energy seeps out from the core. . The structure of the present invention is to form a quartz glass film containing boron oxide on the inner wall of a glass tube having a circular hollow part by chemical vapor deposition, and to control the internal pressure of the glass tube on which the glass film is formed from the external pressure of the glass tube. The temperature is low and the glass tube is heated from the outside.
This method of manufacturing a polarization-maintaining optical fiber is characterized in that the glass tube is shrunk into an elliptical shape to become solid, and a core in which boron oxide is volatilized is formed in the center.

次に1本発明の一実施例にやいて説明する。さて円形の
中空部を有する石英管の゛内壁に一酸化硼素な會む石英
ガラス層を堆積する工程は、通常一般に実施されている
肉付は化学蒸着法で行なわれる。典形的には、外径14
−1肉厚l−の石英管の内壁に、酸化硼素を5パーセン
ト含む石英ガラスが゛堆積された0次に、石英管の内部
圧力をガラス管の外圧に対しl0IEI水柱圧程度低く
しかつ、1900t:’になるまで石英管を加熱する。
Next, one embodiment of the present invention will be explained. The step of depositing a quartz glass layer containing boron monoxide on the inner wall of a quartz tube having a circular hollow portion is usually carried out by a chemical vapor deposition method. Typically an outer diameter of 14
A quartz glass containing 5% boron oxide is deposited on the inner wall of a quartz tube with a wall thickness of -1 l. Next, the internal pressure of the quartz tube is lowered by about l0 IEI water column pressure than the external pressure of the glass tube, and The quartz tube is heated until it reaches 1900t:'.

すると石英管最内層中の揮発性の高い酸化硼素は揮発飛
散し、純粋石英の薄い層が形成され、さらに減圧されて
いるため、偏平に中実化し、中心部に楕円形の純粋石英
部が形成される。酸化硼素が揮発していない部分は、中
心の純粋の石英の部分に比して屈折率がo、oos程度
低く、偏光保存光ファイバのクツノド部となり、さらに
中心部の楕円形をした純粋石英部は;ア部となる0次い
で上記工程で得′られた約8−の棒状プリフォームを線
引し偏光保存光ファイバを得る。このような方法で製造
された偏光保存光ファイバのコア部は純粋石英で形成さ
れているため、屈折率の中心部における落ち込みがない
。この偏光保存光7アイパの断面図を第2図(−に示す
。この図において、lは外側の石英ガラス層、2は酸化
硼素を含む低屈折率のガラス層、5は酸化硼素が揮発す
ることkより生成された純粋石英よりなるコア部である
。第2図(b)K112図((転)の長軸方向にあける
断面の屈折率分布を示す。この図に示すよ5に、コア部
5には屈折率分布の落ち込みがなく、そのためエネルギ
ーの;ア部5からのしみ出しが少なく、低損失の偏光保
存光ファイバが得られる。
Then, the highly volatile boron oxide in the innermost layer of the quartz tube volatilizes and scatters, forming a thin layer of pure quartz.As the pressure is further reduced, the solid becomes flat, with an elliptical pure quartz part in the center. It is formed. The part where boron oxide has not volatilized has a refractive index that is about o, oos lower than the pure quartz part in the center, and becomes the nose part of the polarization-maintaining optical fiber. Then, the approximately 8-mm rod-shaped preform obtained in the above step is drawn to obtain a polarization-maintaining optical fiber. Since the core of the polarization-maintaining optical fiber manufactured by this method is made of pure quartz, there is no drop in the refractive index at the center. A cross-sectional view of this polarization preserving light 7-eyeper is shown in Figure 2 (-. In this figure, l is the outer quartz glass layer, 2 is the low refractive index glass layer containing boron oxide, and 5 is the glass layer where the boron oxide volatilizes. The core part is made of pure quartz produced from Kotok. Figure 2(b) shows the refractive index distribution of a cross section taken in the long axis direction of K112 ((Rotation). There is no dip in the refractive index distribution in the portion 5, so that less energy leaks out from the portion 5, and a polarization-maintaining optical fiber with low loss can be obtained.

上記実施例では、石英管の中実化を行ない、棒状になり
たプリフォームを線引して偏光保存光ファイバを得た力
\偏平に中実化する工程と線引する工程を同時に行なっ
てもよい。
In the above example, the quartz tube is solidified, and the rod-shaped preform is drawn to obtain a polarization preserving optical fiber. Good too.

以上に述べたように、本発明によれば、中心部のコア部
に屈折率分布の落ち込みがなく、そのためエネルギーの
;ア部からのしみ出しが少なく、低損失の偏光保存光フ
ァイバが得られる効果がある。
As described above, according to the present invention, there is no dip in the refractive index distribution in the central core portion, and therefore less energy leaks out from the core portion, making it possible to obtain a polarization-maintaining optical fiber with low loss. effective.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図(ロ)は従来の方法によって製造された偏光保存
光ファイバの一例の断面図、第1図(ロ)は第1図(ロ
)の長軸方向における断面の屈折率分布を示す図、第2
図(2)は本発明の方法によって製造された偏光保存光
ファイバの実施例の断面図、第2図(ロ)は第2図(補
の長袖方向における断面の屈折率分布を示す図である。 なお図面に使用した符号はそれぞれ以下のものを示す。 1−−・外側の石英ガラス層、2−一低屈折率のガラス
層、3−一屈折車の落ち込みがあるコア部。 4−一屈折率の落ち込み、5・−一屈折率の落ち込みが
ないコア部・ 篤 / ロ / 篤 Z 口
Figure 1 (B) is a cross-sectional view of an example of a polarization-maintaining optical fiber manufactured by a conventional method, and Figure 1 (B) is a diagram showing the refractive index distribution of the cross section in the long axis direction of Figure 1 (B). , second
Figure (2) is a cross-sectional view of an example of a polarization-maintaining optical fiber manufactured by the method of the present invention, and Figure 2 (b) is a diagram showing the refractive index distribution of the cross section in the long sleeve direction of Figure 2 (supplementary figure 2). The symbols used in the drawings indicate the following: 1--Outer quartz glass layer, 2--Low refractive index glass layer, 3--Core portion with depression of the refraction wheel. 4-1. Core part with no drop in refractive index, 5.-1 drop in refractive index / Atsushi / B / Atsushi Z mouth

Claims (1)

【特許請求の範囲】[Claims] 偏光を保存したまま光を導波する光ファイバの製造方法
において、円形の中空部を有するガラス管の内壁に、酸
化硼素を含む石英ガラ−ス膜を化学蒸着法で形成し、前
記石英ガラス膜が形成されたガラス管の内圧をガラス管
の外圧より低くしかつガラス管を外側から加熱し、前記
ガラス管を楕円形に収縮させて中実化し、中心部に酸化
硼素の揮発したコアを形成することを特徴とする偏光保
存光ファイバの製造方法。
In a method for manufacturing an optical fiber that guides light while preserving polarization, a quartz glass film containing boron oxide is formed on the inner wall of a glass tube having a circular hollow part by chemical vapor deposition, and the quartz glass film is The internal pressure of the glass tube in which is formed is lower than the external pressure of the glass tube, and the glass tube is heated from the outside to shrink the glass tube into an oval shape and solidify it, forming a core in which boron oxide has volatilized in the center. A method of manufacturing a polarization preserving optical fiber, characterized in that:
JP56133740A 1981-08-26 1981-08-26 Manufacture of polarization retaining optical fiber Pending JPS5836942A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56133740A JPS5836942A (en) 1981-08-26 1981-08-26 Manufacture of polarization retaining optical fiber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56133740A JPS5836942A (en) 1981-08-26 1981-08-26 Manufacture of polarization retaining optical fiber

Publications (1)

Publication Number Publication Date
JPS5836942A true JPS5836942A (en) 1983-03-04

Family

ID=15111806

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56133740A Pending JPS5836942A (en) 1981-08-26 1981-08-26 Manufacture of polarization retaining optical fiber

Country Status (1)

Country Link
JP (1) JPS5836942A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102249533A (en) * 2011-04-28 2011-11-23 长飞光纤光缆有限公司 Method for manufacturing large-size low-water-peak prefabricated rod

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102249533A (en) * 2011-04-28 2011-11-23 长飞光纤光缆有限公司 Method for manufacturing large-size low-water-peak prefabricated rod
CN102249533B (en) * 2011-04-28 2013-09-11 长飞光纤光缆有限公司 Method for manufacturing large-size low-water-peak prefabricated rod

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