JPS5830056A - Pillar-formed electrode of quadruple pole mass analyzer - Google Patents

Pillar-formed electrode of quadruple pole mass analyzer

Info

Publication number
JPS5830056A
JPS5830056A JP56126729A JP12672981A JPS5830056A JP S5830056 A JPS5830056 A JP S5830056A JP 56126729 A JP56126729 A JP 56126729A JP 12672981 A JP12672981 A JP 12672981A JP S5830056 A JPS5830056 A JP S5830056A
Authority
JP
Japan
Prior art keywords
electrode
pillar
aluminum
section
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP56126729A
Other languages
Japanese (ja)
Inventor
Nobuyoshi Shikima
色摩 信義
Kazuo Chitoku
千徳 一夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP56126729A priority Critical patent/JPS5830056A/en
Publication of JPS5830056A publication Critical patent/JPS5830056A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J49/00Particle spectrometers or separator tubes
    • H01J49/26Mass spectrometers or separator tubes
    • H01J49/34Dynamic spectrometers
    • H01J49/42Stability-of-path spectrometers, e.g. monopole, quadrupole, multipole, farvitrons
    • H01J49/4205Device types
    • H01J49/421Mass filters, i.e. deviating unwanted ions without trapping
    • H01J49/4215Quadrupole mass filters
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J49/00Particle spectrometers or separator tubes
    • H01J49/26Mass spectrometers or separator tubes
    • H01J49/34Dynamic spectrometers
    • H01J49/42Stability-of-path spectrometers, e.g. monopole, quadrupole, multipole, farvitrons
    • H01J49/4205Device types
    • H01J49/4255Device types with particular constructional features

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
  • Electron Tubes For Measurement (AREA)

Abstract

PURPOSE:To enhance the surface accuracy of a pillar-formed electrode and manufacture it light in weight and at a low cost by processing four electrode bars into V-shaped profile, made from an electroconductive material, which tolerates subjection for an extrusion or drawout process, and by coating that surface of electrode bars whose cross-section presents a hyperbola, with an anti- corrosive metal material. CONSTITUTION:Pillar-formed telepoles are manufactured in four pieces at one time from a single material specialized for drawing, so that error between telepoles is small. As material is used light-metal such as aluminum to assure lightweight compared with a conventional one made of stainless steel besides, removal of unnecessary parts, which can be easily obtained through designing of the dies in optimum form, can give a still lighter construction. The hyperbola in cross-section can be provided easily with high precision by using an accurately processed dies. Surfaces of these aluminum electrodes are coated with a metal highly resistant against corrosion such as gold because they are likely to corrode owing to ion collision etc. or to be roughed by gases emitted from the inside of the aluminum material under vacuum.

Description

【発明の詳細な説明】 本発明は四重極質量分析計の柱状電極の改良に一関する
ものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to improvements in columnar electrodes for quadrupole mass spectrometers.

第1図は従来の柱状電極の斜視図である。対向する面を
双曲面断面となるごとく形成した4個の電極棒1a、1
b、lcおよび1dは1個の柱状電極1を形成している
。この柱状電極1の中心に破線で示すごとく矢印方向に
イオン2を送り込むと、特定範囲の質量を有するイオン
だけを他端から取り出すことができる。
FIG. 1 is a perspective view of a conventional columnar electrode. Four electrode rods 1a, 1 whose opposing surfaces are formed to have a hyperboloid cross section
b, lc and 1d form one columnar electrode 1. When ions 2 are sent into the center of this columnar electrode 1 in the direction of the arrow as shown by the broken line, only ions having masses within a specific range can be taken out from the other end.

イオン2を送り込む位置と方向は柱状電極1の四重柱の
中心で、電極との距離同じ(r、  としてあり、電極
1a、ICの方向をX、電極1b。
The position and direction of sending the ions 2 is the center of the quadruple column of the columnar electrode 1, and the distance from the electrodes is the same (r, where X is the direction of electrode 1a, IC direction is X, and electrode 1b is the same distance from the electrodes.

1dの方向をyとすると、イオン2はこれらに対して垂
直である2方向に送り込んでいる。また。
When the direction of 1d is y, the ions 2 are sent in two directions perpendicular to these directions. Also.

電極1a、1cとの間にはU−1−VoCopωtとい
う電圧を印加し、電極1b、Ict間には−(U+V、
Cosωt)という電圧を印加している。即ち。
A voltage of U-1-VoCopωt is applied between the electrodes 1a and 1c, and a voltage of -(U+V,
A voltage called Cosωt) is applied. That is.

一定の電圧Uとr f (radiofrequenc
y)電圧であるV、 Cosωt の和を印加している
Constant voltage U and r f (radio frequency
y) The sum of voltages V and Cosωt is applied.

このように構成された従来の柱状電極は、対向面の形状
を同一にすることが分解能の向上に役立つので、この電
極面は削り出し加工によって製作していた。したがって
、四重柱間の製作誤差が生じ易く、その分解能は低下す
る。また、電極の材質がモリブデンやステンレススチー
ルで比較的重く、装置が重くなる0更に、電極の断面を
双曲線状に精密加工するのが困難であるという欠点をも
っていた。
In conventional columnar electrodes configured in this manner, the electrode surfaces were manufactured by machining because it helps to improve resolution if the opposing surfaces have the same shape. Therefore, manufacturing errors between the four pillars are likely to occur, and the resolution thereof is reduced. In addition, the material of the electrode is molybdenum or stainless steel, which is relatively heavy, making the device heavy.Furthermore, it is difficult to precisely machine the cross section of the electrode into a hyperbolic shape.

本発明は電極面の双曲面精度を向とし、軽量安価な四重
極質量分析計の柱状電極を提供することを目的とし、そ
の特徴とするところは%4本の電極棒を、押出し又は引
抜き加工を施すことができる導電材を断面がV字状とな
るごとく加工すると共に、電極棒の断面が双曲線状とな
る面を耐食性金属材でコーティングして形成したことに
ある。
The present invention aims to provide a columnar electrode for a quadrupole mass spectrometer that is lightweight and inexpensive, with hyperboloid precision of the electrode surface. The method consists of processing a conductive material that can be processed into a V-shaped cross section, and coating the surface of the electrode rod with a hyperbolic cross section with a corrosion-resistant metal material.

第2図は本発明の一実施例である柱状電柱の斜視図であ
る。この場合の電極はアルミニウム等の導電材を押出し
又は引抜き加工したものを等しい長さに切断して組立て
いる。また、電柱面には金等の腐食しにくい金属材を蒸
着して導電性を増す場合もある。なお、各電柱面の配置
は第1図の場合と同様である。
FIG. 2 is a perspective view of a columnar utility pole that is an embodiment of the present invention. The electrodes in this case are assembled by extruding or drawing a conductive material such as aluminum and cutting it into equal lengths. Additionally, a corrosion-resistant metal material such as gold may be deposited on the surface of the utility pole to increase its conductivity. Note that the arrangement of each utility pole surface is the same as in the case of FIG.

このように構成した柱状電柱は、1本の引抜き材を用い
て4個の電柱を作るので、各電柱間の製作誤差が小さい
。また、アルミニウム等の軽金属を用いるので従来のス
テンレススチール製のものよりも軽量であるし、不要部
分がダイスの形状によって容易に除去できるので更に軽
くなる。なお。
In the pole-shaped utility pole constructed in this way, since four utility poles are made using one drawn material, manufacturing errors between each utility pole are small. Furthermore, since a light metal such as aluminum is used, it is lighter than conventional stainless steel ones, and unnecessary parts can be easily removed due to the shape of the die, making it even lighter. In addition.

双曲線断面はダイスの形状加工を精密に行えば容易に高
精度のものが多数得られるという利点をもっている。
The hyperbolic cross section has the advantage that many high-precision pieces can be easily obtained if the shape of the die is precisely processed.

アルミニウム製電極の表面はイオンの衝突等によって腐
食されたり、アルミニウム材内部から真空時にガスが放
出する際に表面を粗面にすることがあるので、その表面
は金等の腐食されにくい金属でコーティングしである。
The surface of aluminum electrodes may be corroded by ion bombardment, etc., or the surface may become rough when gas is released from inside the aluminum material in vacuum, so the surface may be coated with a corrosion-resistant metal such as gold. It is.

したがって長期間好適に作動させることができる。Therefore, it can be operated suitably for a long period of time.

本実施例の柱状電極は、双曲線断面をもつダイスを用い
て押出し又は引抜き加工可能な導電材を加工して電極を
製作し、その表面を金等でコーティングして組立て構成
しであるので、高精度で軽量、かつ安価なものが得られ
るという効果をもっている。
The columnar electrode of this example is constructed by fabricating the electrode by processing a conductive material that can be extruded or drawn using a die with a hyperbolic cross section, and then coating the surface with gold or the like and assembling it. This has the advantage of being accurate, lightweight, and inexpensive.

上記実施例においては各電柱の長さを等しくすると説明
したが、電極保持の都合上その長さを異にすることは差
支えない。また、電極の一部を第1図に示すような異種
の金属ブロックで置き換えてもほぼ同等の効果が得られ
る。
In the above embodiment, it has been explained that the lengths of the utility poles are equal, but the lengths may be different for convenience of holding the electrodes. Furthermore, substantially the same effect can be obtained by replacing part of the electrode with a different type of metal block as shown in FIG.

本発明の四重極質量分析計の柱状電極は1面精度を向上
すると共に、軽量安価に製作できるという効果が得られ
る。
The columnar electrode of the quadrupole mass spectrometer of the present invention has the effect of improving one-plane accuracy and being lightweight and inexpensive to manufacture.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は従来の柱状電極の斜視図、第2図は本発明の一
実施例である柱状電極の斜視図である。 皐 10 寮 2図
FIG. 1 is a perspective view of a conventional columnar electrode, and FIG. 2 is a perspective view of a columnar electrode according to an embodiment of the present invention. Satsuki 10 Dormitory 2 Diagram

Claims (1)

【特許請求の範囲】[Claims] 1、対向する面の断面を双曲線状に形成した2対の電極
棒よりなる四重極質量分析計の柱状電極において、上詰
゛電極棒を、押出し又は引抜き加工を施すことができる
導電材を断面がV字状となるごとく加工すると共に、上
記電極棒の断面が双曲線状となる面を耐食性金属材でコ
ーティングして形成したことを特徴とする四重極質量分
析計の柱状電極。
1. In a quadrupole mass spectrometer columnar electrode consisting of two pairs of electrode rods with hyperbolic cross sections on opposing surfaces, the upper electrode rod is made of a conductive material that can be extruded or drawn. A columnar electrode for a quadrupole mass spectrometer, characterized in that the electrode rod is processed to have a V-shaped cross section, and the surface of the electrode rod having a hyperbolic cross section is coated with a corrosion-resistant metal material.
JP56126729A 1981-08-14 1981-08-14 Pillar-formed electrode of quadruple pole mass analyzer Pending JPS5830056A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56126729A JPS5830056A (en) 1981-08-14 1981-08-14 Pillar-formed electrode of quadruple pole mass analyzer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56126729A JPS5830056A (en) 1981-08-14 1981-08-14 Pillar-formed electrode of quadruple pole mass analyzer

Publications (1)

Publication Number Publication Date
JPS5830056A true JPS5830056A (en) 1983-02-22

Family

ID=14942424

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56126729A Pending JPS5830056A (en) 1981-08-14 1981-08-14 Pillar-formed electrode of quadruple pole mass analyzer

Country Status (1)

Country Link
JP (1) JPS5830056A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6164260A (en) * 1984-09-06 1986-04-02 小川 源之郎 Warmer of dripping liquid and transfusion liquid
JPS62295667A (en) * 1986-06-16 1987-12-23 小川 源之郎 Infusion liquid heater
JPH0574411A (en) * 1991-09-11 1993-03-26 Japan Atom Energy Res Inst Quadrupole electrode
US5384461A (en) * 1991-05-10 1995-01-24 Fisons Plc Process for the manufacture of a multipolar elongate-electrode lens or mass filter
EP0772224A1 (en) * 1995-11-03 1997-05-07 Varian Associates, Inc. Analysis of samples

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6164260A (en) * 1984-09-06 1986-04-02 小川 源之郎 Warmer of dripping liquid and transfusion liquid
JPH0361459B2 (en) * 1984-09-06 1991-09-19 Genshiro Ogawa
JPS62295667A (en) * 1986-06-16 1987-12-23 小川 源之郎 Infusion liquid heater
US5384461A (en) * 1991-05-10 1995-01-24 Fisons Plc Process for the manufacture of a multipolar elongate-electrode lens or mass filter
JPH0574411A (en) * 1991-09-11 1993-03-26 Japan Atom Energy Res Inst Quadrupole electrode
EP0772224A1 (en) * 1995-11-03 1997-05-07 Varian Associates, Inc. Analysis of samples

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