JPS5824527B2 - Seizouhouhou - Google Patents

Seizouhouhou

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Publication number
JPS5824527B2
JPS5824527B2 JP49082253A JP8225374A JPS5824527B2 JP S5824527 B2 JPS5824527 B2 JP S5824527B2 JP 49082253 A JP49082253 A JP 49082253A JP 8225374 A JP8225374 A JP 8225374A JP S5824527 B2 JPS5824527 B2 JP S5824527B2
Authority
JP
Japan
Prior art keywords
fibers
filament
multifilament
yarn
cut
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP49082253A
Other languages
Japanese (ja)
Other versions
JPS5111929A (en
Inventor
根岸孝雄
富板和夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP49082253A priority Critical patent/JPS5824527B2/en
Publication of JPS5111929A publication Critical patent/JPS5111929A/en
Publication of JPS5824527B2 publication Critical patent/JPS5824527B2/en
Expired legal-status Critical Current

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Description

【発明の詳細な説明】 本発明は、多繊条を牽切して短繊維束と成す方法に関す
るものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method of cutting multifilament fibers into short fiber bundles.

従来、長繊維から成る多繊条を牽切して短繊維束と成す
技術はトウ紡績として良く知られている。
BACKGROUND ART Conventionally, the technique of cutting multifilament consisting of long fibers into short fiber bundles is well known as tow spinning.

しかし、かかる従来技術には”集団切れ“と称し、牽切
された繊維の末端の揃った部分ができる、”跳ね返り”
と称し、牽切前の張力の反動で牽切された繊維の末端が
乱れる、といった不可避な欠陥があった。
However, such conventional technology has a phenomenon known as "collective breakage", in which the ends of the cut fibers are aligned, resulting in "rebound".
However, there was an unavoidable defect that the ends of the cut fibers were disturbed due to the reaction of the tension before the cut.

集団切れ部を少なくしようとして、多繊条の厚みを薄く
し、多繊条を構成する繊維の配列密度を粗にすると跳ね
返りが多発する。
In an attempt to reduce the number of group breaks, if the thickness of the multi-filament strip is made thinner and the arrangement density of the fibers that make up the multi-filament strip is made coarser, bounces will occur frequently.

均斉でかつ充分な強力を持つ繊維を牽切しようというの
であるから牽伸域のどの位置で牽切されるかは、繊維相
互の作用つまり多繊条の集束状態に負うところが犬で、
牽切された繊維の近傍の繊維はその部分で大きな牽伸力
を受け、必然的に集団切れとなる。
Since we are trying to cut fibers that are symmetrical and have sufficient strength, the position in the drawing region at which the fibers are cut depends on the interaction of the fibers, that is, the state of convergence of the multifilaments.
The fibers in the vicinity of the stretched fibers are subjected to a large drafting force at that part, and inevitably break in groups.

従って、マルチフィラメント糸と称され、そのままでも
衣料用として用いられる程度の構成繊維本数の少ない多
繊条を牽切して短繊維束にすることは極めて困難である
Therefore, it is extremely difficult to cut multifilament yarns, which are called multifilament yarns and have a small number of constituent fibers that can be used as is for clothing, into short fiber bundles by cutting.

特にトウ、すなわち構成繊維本数が数千本から数十万本
の多繊条を、牽切して短繊維束にしたものは集団切れ部
や跳ね返り繊維が数多くあり、そのまま精紡機に仕掛け
て紡績糸にするとネップやスラブの多い糸となり、精紡
での糸切れも多発するので、通常のロングステーブル紡
績工程にて、ドラフト、コーミング、ダブリング等の作
用を繰り返して、集団切れ部や跳ね返り繊維を修正して
から紡績糸にするのが常である。
In particular, tows, which are made from multi-filament fibers consisting of several thousand to hundreds of thousands of fibers, are cut into short fiber bundles, and there are many group cuts and rebound fibers, so they are put directly into a spinning machine and spun. When made into yarn, the yarn has many neps and slubs, and yarn breakage occurs frequently during spinning. Therefore, in the normal long stable spinning process, drafting, combing, doubling, etc. are repeated to eliminate group breakage and rebound fibers. It is customary to make corrections before spinning into yarn.

従って、製造工程が長くなり加工費が高くなるばかりか
、もともと断面を構成する繊維本数が完全に均一であっ
た多繊条から、原綿あるいは原毛から得る紡績糸と同程
度の太さ斑を有する紡績糸になってしまうのである。
Therefore, not only does the manufacturing process become longer and processing costs increase, but the multi-filament yarn, which originally had a completely uniform number of fibers in its cross section, has uneven thickness comparable to that of spun yarn obtained from raw cotton or wool. It becomes spun yarn.

更に牽切装置は、衣料用繊維として充分な強力を持つ構
成単繊維を数千本から数十万本収束したものを牽切する
のであるから、頑丈で大型でかつ複雑なものとなってし
まうという欠点があった。
Furthermore, the tension cutting device cuts thousands to hundreds of thousands of condensed single fibers that are strong enough to be used as clothing fibers, so they are sturdy, large, and complex. There was a drawback.

本発明は上記の各欠点の改良を目的とするものであり、
比較的弱い力で牽切でき、かつ牽切工程を経ただけで均
斉な短繊維束となりうる多繊条の製造方法を提供するも
のである。
The present invention aims to improve each of the above-mentioned drawbacks,
The present invention provides a method for producing a multi-filament fiber that can be cut with a relatively weak force and that can be made into a uniform short fiber bundle just by passing through the tension cutting process.

すなわち本発明は、 「構成単繊維の長さ方向に低強力部と高強力部とが交互
に存在する多繊条であって、かつ低強力部が断面方向に
ランダムに存在する多繊条を、牽切して短繊維束とする
に際し、該牽切域供給側において一対のローラとガイド
を用いて、前記多繊条を該一対のローラ間に二回以上通
過させて把持移送することを特徴とする牽切繊維束の製
造方法。
In other words, the present invention provides ``a multifilament in which low-strength regions and high-strength regions alternate in the length direction of the constituent single fibers, and in which the low-strength regions exist randomly in the cross-sectional direction. When cutting into a short fiber bundle by tension cutting, a pair of rollers and a guide are used on the supply side of the tension cutting area, and the multi-filament is passed between the pair of rollers two or more times to be gripped and transferred. A method for producing a characteristic stretch-cut fiber bundle.

」である。”.

更に詳しく説明する。It will be explained in more detail.

単繊維に低強力部と高強力部とを交互に形成せしめるに
は、未延伸繊維を自然延伸比以下の不完全延伸を行ない
、延伸部、未延伸部あるいは半延伸部を作り、太い部分
と細い部分とを交互に作り、該繊維の結晶化温度以上の
温度にて熱処理すると、分子配向度の低い部分(太い部
分)は、分子配向度の高い部分(細い部分)より脆く低
強力となる。
To form alternating low-strength parts and high-strength parts in single fibers, undrawn fibers are incompletely stretched below the natural stretching ratio to create stretched, unstretched, or semi-stretched parts, and thick parts and When thin parts are made alternately and heat treated at a temperature higher than the crystallization temperature of the fiber, the parts with a low degree of molecular orientation (thick parts) become more brittle and have lower strength than the parts with a higher degree of molecular orientation (thin parts). .

低強力部分を多繊条の長さ方向および断面でランダムに
存在せしめるには、多繊条を構成する単繊維各々単独に
上記不完全延伸と熱処理とを施こせば良い。
In order to cause the low-strength portions to exist randomly in the longitudinal direction and cross section of the multifilament, each single fiber constituting the multifilament may be individually subjected to the incomplete stretching and heat treatment described above.

未延伸多繊条に該不完全延伸と熱処理とを施こして、該
低強力部分をランダムに存在せしめるには、該未延伸多
繊条の集束性が弱く、繊維相互の移動が可能であれば良
く、多繊条の撚。
In order to make the low-strength parts exist randomly by subjecting the undrawn multifilament to the incomplete stretching and heat treatment, it is necessary to make the undrawn multifilament have weak cohesiveness and to allow mutual movement of fibers. Good, multi-filament twist.

繊維相互の交絡、繊維相互の接融着等の程度の弱い未延
伸多繊条で、撚数で表現すれば、トウのように太い多繊
条の場合には無撚が望ましく、マルチフィラメント糸の
ように細い多繊条であれば、20回/m以下が望ましい
It is an undrawn multifilament yarn with a weak degree of intertwining of fibers and bonding of fibers with each other, and when expressed in terms of the number of twists, untwisted is preferable for thick multifilament yarns such as tow. In the case of thin multi-filament strips such as 20 times/m or less, it is desirable.

未延伸多繊条を構成する単繊維が充分単独に挙動すれば
、該不完全延伸を冷延伸で行なえるが、上記限度内で多
少集束していても延伸域を加熱すれば目的を達成できる
If the single fibers constituting the undrawn multifilament behave sufficiently independently, the incomplete drawing can be performed by cold drawing, but even if the fibers are somewhat bunched within the above limits, the purpose can be achieved by heating the drawing region. .

この場合加熱体は非接触式が好ましいが、接触式であっ
ても曲率の小さい加熱体であれば良い。
In this case, the heating body is preferably a non-contact type, but even a contact type heating body may be used as long as it has a small curvature.

曲率の大きなもの例えば熱ピンと称されている程度のも
のは延伸点の位置が固定されてしまい目的を達成できな
い。
If the curvature is large, for example, a so-called hot pin, the position of the stretching point is fixed and the purpose cannot be achieved.

不完全延伸と熱処理とを行なう態様および条件には多く
の方法が考えられるが、次に記載する方法が特に優れて
いる。
Although there are many possible methods and conditions for performing the incomplete stretching and heat treatment, the method described below is particularly excellent.

まず集束性の弱い未延伸多繊条を該繊維の結晶化温度以
上に加熱された帯域にて不完全延伸を行なう。
First, an undrawn multifilament with weak bundling property is incompletely drawn in a zone heated to a temperature higher than the crystallization temperature of the fiber.

このようにして得た多繊条はこのままでも目的を達成し
ているが、更に延伸部を軽減する、低強力部と高強力部
との強力差を助長する、耐熱寸法安定性を良くする、均
染性を良くする等の目的で、上記延伸工程での加熱帯域
の温度以上にて緊張熱処理すると良い。
The multifilament yarn obtained in this way achieves the purpose as it is, but it also has the following properties: to reduce the stretching part, to promote the difference in strength between the low-strength part and the high-strength part, and to improve the heat-resistant dimensional stability. For the purpose of improving the level dyeing property, etc., it is preferable to carry out tension heat treatment at a temperature higher than the temperature of the heating zone in the above-mentioned stretching step.

この二度目の熱処理では多繊条の繊維相互が拘束されて
いた方が好ましく、多繊条が細い場合には仮撚加工が適
している。
In this second heat treatment, it is preferable that the fibers of the multifilament are restrained, and when the multifilament is thin, false twisting is suitable.

このようにして得た低強力部をランダムに有する多繊条
を牽伸すると該低強力部で牽切されるので集団切れの発
生が極めて少ないのである。
When the thus obtained multi-filament fiber having low-strength parts randomly is drawn, the fibers are cut at the low-strength parts, so that the occurrence of group breakage is extremely small.

従って、多繊条を牽切して得る短繊維束をドラフトする
ことなくそのままの太さで集束し、一般衣料向けの糸条
を得るような場合のように、細い多繊条でも一様に牽切
でき均斉な短繊維束を得ることができる。
Therefore, even thin multi-filament fibers can be uniformly collected, such as when short fiber bundles obtained by cutting multi-filament fibers are bundled without drafting to obtain yarn for general clothing. It is possible to obtain uniform short fiber bundles through tension cutting.

本発明は、紡績工程を大巾に短縮する目的で、1次に記
載する工程を採る。
The present invention employs the steps described below in order to greatly shorten the spinning process.

即ち、前記方法によって得た低強力部をランダムに有す
る多繊条を牽切して短繊維束と成し、一旦収納すること
なく直ちに該短繊維束を集束して糸条を形成するのであ
る。
That is, the multi-filament yarn having random low-strength portions obtained by the above method is cut into short fiber bundles, and the short fiber bundles are immediately bundled to form yarn without being stored once. .

集束する手段は、撚あるいは繊維相互の交絡。The means of focusing is twisting or entangling the fibers.

接融着、その他いかなる方法でも良い。Adhesion bonding or any other method may be used.

上記工程を採ることによって紡績工程を大巾に短縮する
ことができるが、従来の紡績工程の精紡工程、特にリン
グ精紡機、オープンエンド精紡機の如く、錘間をコンパ
クトにしなければ無意味なものとなってしまう。
By adopting the above process, the spinning process can be greatly shortened, but it is meaningless unless the distance between the spindles is made compact, as in the spinning process of conventional spinning processes, especially ring spinning machines and open-end spinning machines. It becomes a thing.

その為には牽切装置を簡便なものにしなければならない
For this purpose, the tension cutting device must be made simple.

そのために本発明は前記工程において、牽切の為の牽伸
域供給側を該多繊条を把持移送する一対のローラと、該
ローラに該多繊条を二回以上把持させる為の該多繊条を
折り返すガイドとで構成させるものである。
To this end, in the above process, the present invention provides a drafting zone supply side for tension cutting with a pair of rollers that grip and transfer the multi-filament strip, and a pair of rollers that grip and transfer the multi-filament strip two or more times. It is made up of a guide that folds back the fibers.

本発明を更に詳しく説明する。The present invention will be explained in more detail.

第1図は、従来の牽切装置に利用されていた、多繊条の
把持方法を示す概略図である。
FIG. 1 is a schematic diagram showing a multi-filament gripping method used in a conventional tension cutting device.

多繊条を把持する力を大きくする為に把持点の数を多く
し、ローラと多繊条との接触を長くするのである。
In order to increase the force with which the multi-filament is gripped, the number of gripping points is increased and the contact between the roller and the multi-filament is extended.

従来は、三本のローラを組み合わせたものが多く、aの
セルフロック型、bの二点把持型、Cの三段締型等が代
表的なものである。
Conventionally, there have been many combinations of three rollers, and typical examples include the self-locking type (a), the two-point gripping type (b), and the three-stage clamping type (C).

この従来方式は、機構的に複雑でかつ大きな力で締め付
ける為に頑丈で大型なものを必要とした。
This conventional method is mechanically complex and requires a large and sturdy device to tighten with a large force.

本発明は、錘間をコンパクトにすることを目的の一つに
しているので、かかる従来方式を採用し難いのである。
Since one of the purposes of the present invention is to make the space between the spindles compact, it is difficult to adopt such a conventional method.

本発明は、細い多繊条を供給するものであるから、第2
図に示す如く、多繊条Yを折り返しガイド3によって折
り返し、一対のローラ1および2に必要な回数だけ把持
させることができるのである。
Since the present invention supplies thin multifilament strips, the second
As shown in the figure, the multifilament yarn Y can be folded back by the folding guide 3 and gripped by the pair of rollers 1 and 2 as many times as necessary.

折り返しガイド3には、例えば第3図dの回転式のセパ
レートローラ3.Leの溝付きの固定式セパレートガイ
ド3.2.fのスネールワイヤ3.3等が使用できる。
The folding guide 3 includes, for example, a rotary separate roller 3 as shown in FIG. 3d. Le grooved fixed separate guide 3.2. Snail wire 3.3 or the like can be used.

次に実施例について説明する。Next, an example will be described.

第4図は、牽伸域への多繊条Yの供給方式を本発明の方
式とし、一対のローラ10および11にて把持牽伸する
FIG. 4 shows a method of supplying the multifilament yarn Y to the drafting area according to the method of the present invention, in which the multifilament yarn Y is gripped and drafted by a pair of rollers 10 and 11.

多繊条Yは前記方法にて加工しであるので、集団切れの
発生は極めて少なく、一様に牽切され、均斉な短繊維束
となる。
Since the multi-filament yarn Y is processed by the above-mentioned method, the occurrence of group breaks is extremely low, and the fibers are cut uniformly to form uniform short fiber bundles.

跳ね返り繊維が問題となる場合には、第5図に示す如く
、多繊条Yを湿潤状態にて牽切すると良い。
If rebound fibers are a problem, it is preferable to cut the multifilament Y in a wet state as shown in FIG.

即ち、多繊条Yに液付与ローラ12にて液浴13の液を
付与し過剰の液を液絞装置14にて除去してから牽切す
る。
That is, the liquid in the liquid bath 13 is applied to the multifilament yarn Y by the liquid applying roller 12, and the excess liquid is removed by the liquid squeezing device 14, and then the tension is cut.

また、牽伸域をエプロンで軽く把持しても良く、第6図
は中抜式、第7図は中実式にて実施した態様を示す概略
図である。
Alternatively, the drafting area may be lightly gripped with an apron, and FIG. 6 is a schematic diagram showing an embodiment in which a hollow type is used, and FIG. 7 is a schematic diagram showing an embodiment in which a solid type is used.

次に実施例について説明する。Next, an example will be described.

実施例 1 第4図に示す如き本発明の態様と、第4図のバンクロー
ラを従来方式に置き換えた態様とを比較した。
Example 1 An embodiment of the present invention as shown in FIG. 4 was compared with an embodiment in which the bank roller in FIG. 4 was replaced with a conventional method.

8態様について次に記す5項目の評価を行なった。The following 5 items were evaluated for the 8 aspects.

簡便性:装置の製作費 操作性:糸切れ時の糸掛は時間 把持性:(V2−V )/(v、、−v、 )Vl:バ
ックローラ速度 v2:フロントローラ速度 ■:バツクローラにおける多繊条速度 V=V2・D2/D1で求める。
Simplicity: Manufacturing cost of the device Operability: Thread hooking time when thread breaks: (V2-V)/(v,, -v,) The filament speed is determined by V=V2・D2/D1.

Dl:牽切前の多繊条の太さくデニール)D2:牽切後
の多繊条の太さくデニール)稼動性:糸切れ数 耐久性:バックローラのうちゴムローラの交換日数 評価結果を統一表現するために次の様に変換した。
Dl: Thickness denier of multi-filament yarn before tension cutting) D2: Thickness denier of multi-filament thread after tension cutting) Workability: Number of yarn breaks Durability: Unified expression of evaluation results of number of days to replace rubber rollers among back rollers To do this, I converted it as follows.

各項目内において、評価結果に表われる数の小さい方が
好ましいもの、つまり簡便性、操作性。
Within each item, the smaller the number that appears in the evaluation results, the more preferable it is, that is, simplicity and operability.

稼動性については、(最小評価/各態様の評価)X10
0で変換する。
Regarding operability, (minimum evaluation/evaluation of each aspect)
Convert with 0.

これに対し、評価結果に表われる数の大きい方が好まし
いもの、つまり把持性、耐久性については、(各態様の
評価/最大評価)X100で変換する。
On the other hand, for items with higher numbers appearing in the evaluation results, that is, gripability and durability, the conversion is performed by (evaluation of each aspect/maximum evaluation) x100.

変換後は数の大きい方が好ましく、この結果を次の表に
まとめた。
After conversion, a larger number is preferable, and the results are summarized in the table below.

表中「単−把持」とは一対のローラで単に1回だけ把持
することを意味する。
In the table, "single gripping" means gripping only once with a pair of rollers.

バックローラは、直径40mm、把持中(ローラ巾)4
0mmに統一した。
The back roller has a diameter of 40 mm and is gripped (roller width) 4
Standardized to 0mm.

フロントローラは、直径40mm、把持巾12mm把持
力4kgとした。
The front roller had a diameter of 40 mm, a grip width of 12 mm, and a grip force of 4 kg.

把持性については、マルチフィラメント糸を把持させ手
で引き抜いたところすべることなく切断したことにて確
認した。
Gripability was confirmed by the fact that when the multifilament thread was held and pulled out by hand, it was cut without slipping.

上表にて本発明の優れていることがわかる。The above table shows that the present invention is superior.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、従来の牽切方法に利用されていた、多繊条の
把持方式を示す概略図である。 第2図は、本発明の牽切方法における多繊条の把持方式
を示す概略図である。 第3図は、本発明の牽切方法における折り返しガイドの
使用例を示す概略図である。 第4図、第5図、第6図および第7図は、本発明の実施
態様例を示す概略図である。 1:バックボトムローラ、2:バックトップローラ、3
、3.1 、3.2 、3.3 :折り返しガイド、
3.1:セパレートローラ、3.2:セパレートガイド
、3.3ニスネールワイヤー、4:ボトムエプロンロー
ラ、5:中抜トップエプロンローラ、5′:中実トップ
エプロンローラ、6:ボトムエプロン、7:トップエプ
ロン、8:ボトムエプロンローラ、9:トップエプロン
テンサ、10:フロントボトムローラ、11:フロント
トップローラ、12:液付与ローラ、13:液浴、14
:液絞装置、Y:多繊条。
FIG. 1 is a schematic diagram showing a multifilament gripping method used in a conventional tension cutting method. FIG. 2 is a schematic diagram showing a multi-filament gripping method in the tension cutting method of the present invention. FIG. 3 is a schematic diagram showing an example of the use of a folded guide in the tension cutting method of the present invention. FIG. 4, FIG. 5, FIG. 6, and FIG. 7 are schematic diagrams showing embodiments of the present invention. 1: Back bottom roller, 2: Back top roller, 3
, 3.1 , 3.2 , 3.3: Folding guide;
3.1: Separate roller, 3.2: Separate guide, 3.3 Varnish nail wire, 4: Bottom apron roller, 5: Hollowed top apron roller, 5': Solid top apron roller, 6: Bottom apron, 7 : Top apron, 8: Bottom apron roller, 9: Top apron tensor, 10: Front bottom roller, 11: Front top roller, 12: Liquid applying roller, 13: Liquid bath, 14
: Liquid squeezing device, Y: Multifilament.

Claims (1)

【特許請求の範囲】[Claims] 1 構成単繊維の長さ方向に低強力部と高強力部とが交
互に存在する多繊条であって、かつ低強力部が断面方向
にランダムに存在する多繊条を、牽切して短繊維束とす
るに際し、該牽切域供給側において一対のローラとガイ
ドを用いて、前記多繊条を該一対のローラ間に二回以上
通過させて把持移送することを特徴とする牽切繊維束の
製造方法。
1 A multi-filament fiber in which low-strength parts and high-strength parts exist alternately in the length direction of the constituent single fibers, and in which low-strength parts exist randomly in the cross-sectional direction, is cut in tension. Stretch cutting characterized in that when forming short fiber bundles, a pair of rollers and a guide are used on the supply side of the tension cutting area, and the multi-filament fibers are passed between the pair of rollers two or more times to be gripped and transferred. Method for producing fiber bundles.
JP49082253A 1974-07-19 1974-07-19 Seizouhouhou Expired JPS5824527B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP49082253A JPS5824527B2 (en) 1974-07-19 1974-07-19 Seizouhouhou

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP49082253A JPS5824527B2 (en) 1974-07-19 1974-07-19 Seizouhouhou

Publications (2)

Publication Number Publication Date
JPS5111929A JPS5111929A (en) 1976-01-30
JPS5824527B2 true JPS5824527B2 (en) 1983-05-21

Family

ID=13769263

Family Applications (1)

Application Number Title Priority Date Filing Date
JP49082253A Expired JPS5824527B2 (en) 1974-07-19 1974-07-19 Seizouhouhou

Country Status (1)

Country Link
JP (1) JPS5824527B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5231130A (en) * 1975-09-03 1977-03-09 Teijin Ltd Production of sliver

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS551368A (en) * 1978-06-21 1980-01-08 Nippon Synthetic Chem Ind Fiber sizing agent composition

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS551368A (en) * 1978-06-21 1980-01-08 Nippon Synthetic Chem Ind Fiber sizing agent composition

Also Published As

Publication number Publication date
JPS5111929A (en) 1976-01-30

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