JPS5823131B2 - Odeinonetsushiyoriniokel - Google Patents

Odeinonetsushiyoriniokel

Info

Publication number
JPS5823131B2
JPS5823131B2 JP50022327A JP2232775A JPS5823131B2 JP S5823131 B2 JPS5823131 B2 JP S5823131B2 JP 50022327 A JP50022327 A JP 50022327A JP 2232775 A JP2232775 A JP 2232775A JP S5823131 B2 JPS5823131 B2 JP S5823131B2
Authority
JP
Japan
Prior art keywords
sludge
heat treatment
temperature
gas
concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP50022327A
Other languages
Japanese (ja)
Other versions
JPS5196774A (en
Inventor
戸田一郎
上出健一
清水洽
内村輝美
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kubota Corp
Original Assignee
Kubota Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kubota Corp filed Critical Kubota Corp
Priority to JP50022327A priority Critical patent/JPS5823131B2/en
Publication of JPS5196774A publication Critical patent/JPS5196774A/ja
Publication of JPS5823131B2 publication Critical patent/JPS5823131B2/en
Expired legal-status Critical Current

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  • Incineration Of Waste (AREA)
  • Treating Waste Gases (AREA)
  • Treatment Of Sludge (AREA)

Description

【発明の詳細な説明】 本発明は、汚泥の熱処理設備において発生する悪臭を除
去する方法に係るものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for removing bad odors generated in sludge heat treatment equipment.

従来、汚泥の熱処理設備は、反応罐で発生する分解ガス
の悪臭、および熱処理後の汚泥の悪臭等が大きな問題と
なっている。
Conventionally, sludge heat treatment equipment has had major problems such as the bad odor of cracked gas generated in the reaction can and the bad odor of sludge after heat treatment.

これを解消する方法として、先に出願した低温加圧方式
の熱処理法〔特願昭48−64113号(特公昭56−
5600号公報)〕がある。
As a method to solve this problem, we proposed a heat treatment method using low-temperature pressurization method [Patent Application No. 48-64113 (Japanese Patent Publication No.
5600)].

この熱処理法は汚泥熱処理装置罐すなわち反応室内に導
入した汚泥を約150°Cから165°C程度に加熱す
るとともに圧さく空気を供給して反応室内を約9kg/
crri程度に加圧して処理するものである。
This heat treatment method heats the sludge introduced into the sludge heat treatment equipment can, i.e., the reaction chamber, to about 150°C to 165°C, and supplies compressed air to the reaction chamber to produce about 9 kg/kg of sludge.
The process is carried out under pressure of about crri.

この処理方法は公知であり、その他に200°C程度に
加熱して空気の導入を行わずに嫌気状態で処理する方法
が一般的に行われている。
This treatment method is well known, and another commonly used method is to heat it to about 200° C. and treat it in an anaerobic state without introducing air.

このように200°C程度に加熱する方式を一般に高温
処理と称し、150°C程度に加熱して加圧処理する処
理法を一般に低温加圧式と称しており、この低温加圧方
式は前記の200℃程度に加熱する高温方式に比して硫
化水素の発生が少ないのであるが、本発明法は、上記方
法による悪臭除去をさらに改善する目的から開発された
ものである。
The method of heating to about 200°C in this way is generally called high-temperature processing, and the processing method of heating to about 150°C and pressurizing is generally called low-temperature pressing method. Although less hydrogen sulfide is generated than the high temperature method of heating to about 200° C., the method of the present invention was developed for the purpose of further improving the removal of bad odors by the above method.

従来の汚泥熱処理装置から発生する反応罐排ガスは、硫
化水素、メルカプクン類、アミン類を主体とする非常に
複雑な成分であり、刺激性も極めて強く、しかも高濃度
であるため悪臭に耐えられない程である。
The reaction can exhaust gas generated from conventional sludge heat treatment equipment has very complex components, mainly consisting of hydrogen sulfide, mercapcoins, and amines, and is extremely irritating, and the odor is unbearable due to its high concentration. That's about it.

加えて、反応罐からの排ガス発生が間けつ的である関係
もあって、悪臭のモニタおよび悪臭制御が極めて困難な
状態にあった。
In addition, due to the intermittent generation of exhaust gas from the reaction can, it was extremely difficult to monitor and control the odor.

特に前記したように、圧さく空気を吹き込まずに約20
0°C程度に加熱する高温処理方式では硫化水素の発生
が著しい。
In particular, as mentioned above, about 20 minutes without blowing compressed air.
In high-temperature treatment methods that heat to about 0°C, hydrogen sulfide is significantly generated.

本発明法は、上記の諸問題を解消するもので、低温加圧
式熱処理法では、添付図面の熱処理反応室2に圧さく空
気(図示省略)を吹き込むため、熱処理反応室2から発
生する分解悪臭ガスG2゜g2の成分および濃度は、空
気による臭気酸化が起るため、従来法に比べて著しく低
くなる利点がある。
The method of the present invention solves the above-mentioned problems. In the low-temperature pressurized heat treatment method, pressurized air (not shown) is blown into the heat treatment reaction chamber 2 shown in the attached drawing, so the decomposition odor generated from the heat treatment reaction chamber 2 is There is an advantage that the components and concentration of gas G2°g2 are significantly lower than in the conventional method because odor oxidation occurs with air.

吉くにH2S濃度の差が大きく、従来法では4500p
pIIlに対し上記低温加圧式ではo、o1ppm以下
になる。
Fortunately, the difference in H2S concentration is large, with the conventional method reaching 4500p.
In the above-mentioned low-temperature pressurization method, the amount of pII is less than 1 ppm.

かくして、低温加圧式の悪臭成分は全炭化水素が主体と
なり他の成分は低いため、全炭化水素計による悪臭モニ
タが可能になるのである。
In this way, the malodor components of the low-temperature pressurized type are mainly composed of total hydrocarbons and other components are low, making it possible to monitor malodors using a total hydrocarbon meter.

以下、悪臭のモニタおよび制御を添付図面のフローシー
トを用いて説明する。
Hereinafter, malodor monitoring and control will be explained using the flow sheet of the attached drawings.

汚泥の熱処理における悪臭発生場所は、主として生汚泥
濃縮貯留室1、熱処理反応室2、熱処理汚泥濃縮室3、
脱水機室4、ホッパ室5である。
The locations where bad odors occur during the heat treatment of sludge are mainly the raw sludge concentration storage chamber 1, the heat treatment reaction chamber 2, the heat treatment sludge concentration chamber 3,
They are a dehydrator room 4 and a hopper room 5.

これら各室の悪臭ガスg1.〜g5をそれぞれ自動的に
炭化水素測定装置6にて各悪臭濃度をチェックする。
Offensive gas g1 in each of these rooms. - g5 are automatically checked for each malodor concentration using the hydrocarbon measuring device 6.

生汚泥濃縮貯留室1、熱処理汚泥濃縮室3、脱水機室4
、ホッパ室5の各室の悪臭ガスG1. G3゜G4.G
5は、比較的低いため、オゾン脱臭塔7にて処理する。
Raw sludge concentration storage chamber 1, heat treated sludge concentration chamber 3, dehydrator chamber 4
, malodorous gas G1 in each chamber of the hopper chamber 5. G3゜G4. G
5 is relatively low, so it is treated in the ozone deodorizing tower 7.

熱処理反応室2の分解排ガスである悪臭ガスG2は極め
て高濃度になるため、脱臭炉8で直接燃焼する。
The malodorous gas G2, which is the decomposed exhaust gas from the heat treatment reaction chamber 2, has an extremely high concentration and is therefore directly combusted in the deodorizing furnace 8.

もし近くに汚泥焼却炉があれば悪臭ガスG2は汚泥燃焼
用空気として用いることにより処理することも可能であ
る。
If there is a sludge incinerator nearby, the foul-smelling gas G2 can be treated by using it as air for sludge combustion.

Dly D3 、D4 、D5は、各室の悪臭ガスG1
゜G3.G4.G5の通気路を開閉するダンパ、81〜
s5は炭化水素測定装置6から発信される信号群で、そ
れぞれダンパD1〜D、を独立に開閉制御する。
Dly D3, D4, D5 are malodorous gases G1 in each room.
゜G3. G4. Damper that opens and closes the air passage of G5, 81~
s5 is a signal group transmitted from the hydrocarbon measuring device 6, which independently controls the opening and closing of the dampers D1 to D, respectively.

なお、信号s2は脱臭炉8の温度をコントロールして悪
臭を除去する。
Note that the signal s2 controls the temperature of the deodorizing furnace 8 to remove bad odors.

これは悪臭ガスG2が極めて強いためである。This is because the malodorous gas G2 is extremely strong.

上記の如くなる本発明法は、たとえば、生汚泥濃縮貯留
室1の悪臭ガスg1、すなわち炭化水素濃度を炭化水素
測定装置6で観測し、該濃度がある設定限界値以上にな
れば、信号s1を発信して、ダンパD1を「開」にして
生汚泥濃縮貯留室1の悪臭ガスG1をオゾン脱臭塔7へ
送る。
In the method of the present invention as described above, for example, the malodorous gas g1, that is, the concentration of hydrocarbons in the raw sludge concentration storage chamber 1 is observed by the hydrocarbon measuring device 6, and if the concentration exceeds a certain set limit value, the signal s1 is is transmitted, the damper D1 is opened, and the malodorous gas G1 in the raw sludge concentration storage chamber 1 is sent to the ozone deodorization tower 7.

なお、悪臭ガスg1すなわち悪臭ガスG1の濃度が、あ
る設定上限値になれば警報を発するようにしておいても
良いことは言うまでもないことである。
It goes without saying that an alarm may be issued when the concentration of the malodorous gas g1, that is, the concentration of the malodorous gas G1, reaches a certain upper limit value.

以上の如くなる本発明法は、低温加用式の汚泥熱処理法
において、悪臭ガスGl t G2.G3 t G4
tG5の発生室から発生する悪臭ガスg12g22g3
゜g4.!!5を炭化水素測定装置6などにて検出し、
該検出信号によって上記悪臭ガスG1〜G5をオゾン脱
臭塔7ならびに脱臭炉8にてそれぞれ除去するようにし
たことを特徴とする汚泥の熱処理における悪臭ガス除去
法であるから、悪臭ガスの除去効率が著しく増大するこ
とになるなど、実用上の効果大なるものがある。
The method of the present invention as described above is a low-temperature application type sludge heat treatment method in which malodorous gas Glt G2. G3 t G4
Malodorous gas g12g22g3 generated from the generation chamber of tG5
°g4. ! ! 5 is detected with a hydrocarbon measuring device 6, etc.
This method of removing malodorous gases in heat treatment of sludge is characterized in that the malodorous gases G1 to G5 are removed in the ozone deodorizing tower 7 and the deodorizing furnace 8 according to the detection signal, so that the malodorous gas removal efficiency is improved. There are significant practical effects, such as a significant increase in the amount of water.

なお、炭化水素測定装置6における炭化水素量の測定値
が設定限界値以下の臭気が低いときは各ダンパD1〜D
5は閉じたままとし、別途に設けた通気路にガスを導い
て公知の活性汚泥処理槽の散気管から活性汚泥中に放出
して処理するかあるいは公知の水洗装置により処理した
のち大気中へ放出する。
Note that when the measured value of the amount of hydrocarbons in the hydrocarbon measuring device 6 is below the set limit value and the odor is low, each damper D1 to D
5 is kept closed, and the gas is introduced into a separately provided ventilation path and discharged into the activated sludge from a diffuser pipe of a known activated sludge treatment tank for treatment, or treated with a known water washing device and then released into the atmosphere. discharge.

【図面の簡単な説明】[Brief explanation of drawings]

図面は本発明法の実施例をしめず流れ図である。 G1. G2. G3. G4. G5・・・・・・悪
臭ガス、6・・・・・・炭化水素測定装置、7・・・・
・・オゾン脱臭塔、8・・・・・・脱臭炉、g12g2
2g32g42g5・・・・・・悪臭ガス。
The drawings are flowcharts illustrating an embodiment of the method of the invention. G1. G2. G3. G4. G5...Odor gas, 6...Hydrocarbon measuring device, 7...
...Ozone deodorizing tower, 8...Deodorizing furnace, g12g2
2g32g42g5...Bad smelling gas.

Claims (1)

【特許請求の範囲】[Claims] 1 汚泥熱処理装置の反応罐を用いて、温度約150°
C程度に加熱するとともに、圧さく空気を吹き込んで加
圧処理する低温加圧式の汚泥処理法において、悪臭ガス
の発生室から発生する悪臭ガスを炭化水素の測定装置等
にて検出し、該測定装置等から発せられる検出信号によ
って上記悪臭ガスをオゾン脱臭塔ならびに脱臭炉にてそ
れぞれ除去するようにしたことを特徴とする汚泥の熱処
理における悪臭ガス除去法。
1 Using the reaction can of the sludge heat treatment equipment, the temperature is approximately 150°.
In a low-temperature pressurized sludge treatment method in which the sludge is heated to a temperature of about A method for removing malodorous gas in heat treatment of sludge, characterized in that the malodorous gas is removed in an ozone deodorizing tower and a deodorizing furnace, respectively, in response to a detection signal emitted from a device or the like.
JP50022327A 1975-02-21 1975-02-21 Odeinonetsushiyoriniokel Expired JPS5823131B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP50022327A JPS5823131B2 (en) 1975-02-21 1975-02-21 Odeinonetsushiyoriniokel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP50022327A JPS5823131B2 (en) 1975-02-21 1975-02-21 Odeinonetsushiyoriniokel

Publications (2)

Publication Number Publication Date
JPS5196774A JPS5196774A (en) 1976-08-25
JPS5823131B2 true JPS5823131B2 (en) 1983-05-13

Family

ID=12079602

Family Applications (1)

Application Number Title Priority Date Filing Date
JP50022327A Expired JPS5823131B2 (en) 1975-02-21 1975-02-21 Odeinonetsushiyoriniokel

Country Status (1)

Country Link
JP (1) JPS5823131B2 (en)

Also Published As

Publication number Publication date
JPS5196774A (en) 1976-08-25

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