JPS58196423A - Liquid level control for low temperature liquefied gas - Google Patents

Liquid level control for low temperature liquefied gas

Info

Publication number
JPS58196423A
JPS58196423A JP7975882A JP7975882A JPS58196423A JP S58196423 A JPS58196423 A JP S58196423A JP 7975882 A JP7975882 A JP 7975882A JP 7975882 A JP7975882 A JP 7975882A JP S58196423 A JPS58196423 A JP S58196423A
Authority
JP
Japan
Prior art keywords
float
liquid level
resin
liquefied gas
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7975882A
Other languages
Japanese (ja)
Inventor
Masato Hirata
正人 平田
Toshiaki Kawaguchi
川口 利明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taiyo Sanso Co Ltd
Original Assignee
Taiyo Sanso Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taiyo Sanso Co Ltd filed Critical Taiyo Sanso Co Ltd
Priority to JP7975882A priority Critical patent/JPS58196423A/en
Publication of JPS58196423A publication Critical patent/JPS58196423A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01FMEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
    • G01F23/00Indicating or measuring liquid level or level of fluent solid material, e.g. indicating in terms of volume or indicating by means of an alarm
    • G01F23/30Indicating or measuring liquid level or level of fluent solid material, e.g. indicating in terms of volume or indicating by means of an alarm by floats
    • G01F23/76Indicating or measuring liquid level or level of fluent solid material, e.g. indicating in terms of volume or indicating by means of an alarm by floats characterised by the construction of the float

Landscapes

  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • General Physics & Mathematics (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Level Indicators Using A Float (AREA)

Abstract

PURPOSE:To prevent brittleness and damage by using particular plastic and elastomer materials on the surface layer of a float and float guide rod in a float switch that consists of a float to which a lead switch and magnet are fixed. CONSTITUTION:As particular plastics and elastomers, unsaturated polyester resin, epoxy resin, melamine resin, phenol resin, urethane elastomer (urethane resin), silicone rubber (silicone resin), fluorinated elastomer (fluorinated rubber), long chain polyamide, polyimide, polycarbonate, furan resin, polysulfon, butadiene-acryl nitryl group synthetic rubber and their modified compounds or mixtures obtained by blending them are employed. For manufacturing float guide rods, it is desirable to use those materials in the form of a composite material such as carbon fiber reinforced plastic (CFRP) and fiber reinforced plastic (FRP).

Description

【発明の詳細な説明】 本発明は、低温液化ガス液位の検出制御方法、低温液化
ガス液位検出機器及び低温液化ガス取扱い装置に関する
ものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a low-temperature liquefied gas level detection control method, a low-temperature liquefied gas level detection device, and a low-temperature liquefied gas handling device.

近時液化窒素、液化酸素、液化空気、液化アルゴン或は
、液化天然ガス(LNG)等の低温液化ガスによる冷却
技術が発達し、生物標本、生物細胞、生物組織、ワクチ
ン等の低温保存、低温輸送等が普及しつつある。低温液
化ガスによる冷却保存等は一般に温度条件に敏感な対象
物に対して行われるから、取扱い容器中の温度条件を一
定に保つ為、蒸発により失われる低温液化ガスを補給し
てその液位を一定に保ったり、液位が成る水準になった
場合には賢妹を発する様にして置く等、低温を精密に保
てる様細心の取扱いが要求される場合が多い。
Recently, cooling technology using low-temperature liquefied gases such as liquefied nitrogen, liquefied oxygen, liquefied air, liquefied argon, or liquefied natural gas (LNG) has been developed, and it is now possible to store biological specimens, biological cells, biological tissues, vaccines, etc. at low temperatures. Transportation, etc. are becoming popular. Cooling preservation using low-temperature liquefied gas is generally carried out for objects that are sensitive to temperature conditions, so in order to keep the temperature conditions in the handling container constant, low-temperature liquefied gas lost through evaporation must be replenished to maintain the liquid level. Careful handling is often required to maintain the low temperature precisely, such as by keeping it constant or by placing it in such a way that it emits water when the liquid level reaches a certain level.

従って、低温液化ガスの取扱いに当っては多くの場合そ
の液位の検出や制御が必要となるが、低温液化ガスはそ
の温度が例えば液化窒素の場合沸点−196℃といった
超低温での液位制御を必要とするから、従来からの常・
低温領域に於ける検出・制御技術をそのま′>適用しよ
うとしても信頼性の商い作動を期し得ないのが実情であ
る。低温に於ける液面の検出器として市販されている多
くのものは、液相と気相の温度差を検出し、液面を検知
するものであるが、液化ガスを収容する容器が断熱性能
の高い優秀なものである程、液相と気相の温度差が小さ
いところから、その温度差の検出は難しくなり、検出器
の感度が不充分であったり誤作動を生ずるといったトラ
ブルを招き易い。
Therefore, when handling low-temperature liquefied gas, it is often necessary to detect and control the liquid level, but for low-temperature liquefied gas, the liquid level must be controlled at extremely low temperatures, such as the boiling point of -196°C in the case of liquefied nitrogen. Since it requires
The reality is that even if detection and control technology in the low-temperature region is applied as is, reliable operation cannot be expected. Many commercially available liquid level detectors at low temperatures detect the temperature difference between the liquid phase and gas phase to detect the liquid level, but the container containing the liquefied gas has poor insulation performance. The higher the quality of the detector, the smaller the temperature difference between the liquid and gas phases, making it difficult to detect that temperature difference, which can lead to problems such as insufficient sensitivity of the detector or malfunction. .

液に接触する電気抵抗体の電気抵抗変化を検出するセン
サーでは、超低温での使用の場合、作動が不安定になり
長時間の連続使用は困難になる。熱あるが、この方法で
は、加熱量が、低温液体の蒸発損失を招き容器自体の断
熱性能を損って低温液化ガスによる冷却効果を減殺する
ばかりでなく、加熱と冷却を交互に行うこととなって温
度分布の撹乱を招く様な好ましからざる現象を伴う。
Sensors that detect changes in the electrical resistance of electrical resistors that come into contact with liquid become unstable when used at extremely low temperatures, making it difficult to use them continuously for long periods of time. However, in this method, the amount of heating not only causes evaporation loss of the low-temperature liquid and impairs the insulation performance of the container itself, reducing the cooling effect of the low-temperature liquefied gas, but also requires heating and cooling to be performed alternately. This is accompanied by undesirable phenomena such as disturbance of temperature distribution.

超音波や光電式、静電容量式の液面センサーでは、熱発
生による冷却性能の滅失は免れるが、容器を開閉する場
合に入る空気中の水分が、センサー面に霜を造り誤作動
を招き易く、開放型の容器には不適当である。
Ultrasonic, photoelectric, and capacitive liquid level sensors can avoid loss of cooling performance due to heat generation, but moisture in the air that enters when opening and closing the container can cause frost on the sensor surface and cause malfunction. unsuitable for open containers.

一方、リードスイッチとそれを作動させる磁石を3− 固定したフロートとを組合せて成るフロートスイッチが
従来から液面検出・制御用に市販されているが、これら
市販の既製品は一般に低温としては一50℃程度迄の温
度範囲に於ける使用を想定しており、例えば液化窒素や
LNGの如き超低温領域の液化ガスの液位検出や制御に
これら市販の既製品をそのま\使用することを試みたと
ころ、フロートが脆化・損傷を招き易く、フロート案内
枠の、尖端或は肉の薄い場合には案内桿の中程が変形を
起すこともあり、金属製のフロートや案内桿には霜が着
いて、正常な作動を妨げ易く長期に亘る精確で信頼性の
ある検出・制御を期待し得ないことを認めた。そこで本
発明者等は、か\る難点を解決して超低温領域に於ける
液化ガスの液位検出・制御を精密に行う方法につき鋭意
研究を重ねた結果、フロートスイッチ式検出方法に低温
液化ガス検出に好適に用いられる様改良を加えることに
より、本発明の液位制御方法、これを用いる液位制御機
器並びに低温液化ガス取扱い装置の発明を完成するに至
った。
On the other hand, float switches consisting of a combination of a reed switch and a float to which a magnet is fixed to operate the switch have been commercially available for liquid level detection and control, but these commercially available ready-made products generally have low temperatures. It is assumed that it will be used in a temperature range up to about 50 degrees Celsius, and we will try to use these commercially available ready-made products as they are to detect and control the liquid level of liquefied gases in the ultra-low temperature range, such as liquefied nitrogen and LNG. However, floats are susceptible to embrittlement and damage, and if the float guide frame has a pointed tip or thin wall, the middle of the guide rod may become deformed, and metal floats and guide rods are susceptible to frost. It was acknowledged that accurate and reliable detection and control over a long period of time could not be expected as it would easily interfere with normal operation. Therefore, the inventors of the present invention have conducted intensive research into a method for accurately detecting and controlling the liquid level of liquefied gas in an ultra-low temperature region by solving these difficulties. By making improvements for suitable use in detection, we have completed the invention of the liquid level control method of the present invention, a liquid level control device using the same, and a low-temperature liquefied gas handling device.

4一 本発明の方法は、リードスイッチとそれを作動させる磁
石を固定したフロートとを組合せて成るフロートスイッ
チを用いて、容器内に収容した低温液化ガスの液位を検
出・制御するに当り、■ 低温液化ガスの液位の変動に
応じて上下に移動するフロート及びフロート案内枠の少
くとも表層に不飽和ポリエステル樹脂、エポキシ樹脂、
メラミン樹脂、フェノール樹脂、ポリウレタンエラスト
マー(ウレタン樹脂)、シリコーンゴム(シリコーン樹
脂)、弗素化エラストマー(弗素ゴム)長鎖ポリアミド
、ポリイミド、ポリカーボネート、フラン樹脂、ポリサ
ルフオン、ブタジェン−アクリロ三トリル系合成ゴム及
び之等の変性物より成る群から選ばれた1種もしくは2
種以上の混合物を用いると共に、 ■ 上記のフロートを、それを浮べた低温液化ガスの液
位の変動に従って上下に移動させるために、該液化ガ哀
の容器内に設けられた案内稈内部の空間を容器内に収容
された低温液化ガス上の気相空間と等圧力に保つ構造に
した 液位検出部を用いることを特徴とする低温液化ガスの液
位の検出・制御方法にある。
41 The method of the present invention detects and controls the liquid level of low-temperature liquefied gas contained in a container using a float switch consisting of a combination of a reed switch and a float fixed with a magnet for actuating the reed switch. ■ Unsaturated polyester resin, epoxy resin,
Melamine resin, phenolic resin, polyurethane elastomer (urethane resin), silicone rubber (silicone resin), fluorinated elastomer (fluorine rubber), long chain polyamide, polyimide, polycarbonate, furan resin, polysulfone, butadiene-acrylotritrile synthetic rubber, and the like. One or two selected from the group consisting of modified products such as
(1) A space inside a guide culm provided in the container of the liquefied gas in order to move the above-mentioned float up and down according to fluctuations in the liquid level of the low-temperature liquefied gas on which it floats; A method for detecting and controlling the liquid level of a low-temperature liquefied gas, characterized by using a liquid level detection section configured to maintain the pressure equal to the pressure of the gas phase space above the low-temperature liquefied gas contained in a container.

この方法に於て使用されるフロートスイッチは、公知の
如何なる形式のものを用いてもよく、フロートの上下移
動を一定の径路で行う様にさせる案内枠の取付は方法も
任意の方法であってよい。
The float switch used in this method may be of any known type, and the guide frame that allows the float to move up and down along a fixed path may be installed in any manner. good.

フロート、フロート案内枠、リードスイッチの配置の態
様の具体例を第1〜4図に示した。
Specific examples of the arrangement of the float, the float guide frame, and the reed switch are shown in FIGS. 1 to 4.

第1図に示した装置は、リードスイッチ及びこれに接続
するリード線、フロートの案内枠に挿入しリードスイッ
チを作動させる磁石をフロートに内蔵する検出部を設け
た液化ガス試験用装置であるが、この装置に例をとって
本発明の詳細な説明する。
The device shown in Figure 1 is a liquefied gas testing device that is equipped with a reed switch, a lead wire connected to the reed switch, and a detection section built into the float that is inserted into the guide frame of the float and a magnet that activates the reed switch. , the present invention will be explained in detail by taking this device as an example.

デユア−瓶1より成る低温液化ガス容器の断熱蓋2に、
リードスイッチ4及びそれに連結したリード線5を収容
したフロート案内枠3、液化ガス補給管11を取付け、
尖端を閉じた円筒状の案内枠3の外側には、中央にドー
ナッツ状に孔を開けた円板型のフロート6を嵌合させて
あり、フロート6は、この案内枠3に沿って液化ガス8
の液面の上下変位に従って上下に移動し、フロート内に
固定された磁石9がリードスイッチに接近したり離反し
たりすることによって、リードスイッチ接点部の開閉を
行い、リードスイッチとリード線によって繋いだ液位の
検出回路、更には液位の制御回路の点滅作動を起すこと
ができる。
On the insulating lid 2 of the low temperature liquefied gas container consisting of the Dua bottle 1,
Attach the float guide frame 3 housing the reed switch 4 and the lead wire 5 connected thereto, and the liquefied gas supply pipe 11.
A disk-shaped float 6 with a donut-shaped hole in the center is fitted on the outside of the cylindrical guide frame 3 with a closed tip, and the float 6 flows along the guide frame 3 with liquefied gas. 8
The magnet 9 fixed in the float moves up and down according to the vertical displacement of the liquid level, and as the magnet 9 approaches and moves away from the reed switch, the reed switch contact part opens and closes, and the reed switch is connected to the reed switch by a lead wire. It is possible to cause a blinking operation of the saliva level detection circuit and furthermore the liquid level control circuit.

この装置に於て、金属製の案内枠や金属製のフロートを
用いると、使用中表面に着霜してフロートの円滑な移動
が不能になる。フロートに木材質や塩化ビニール樹脂、
塩化ビニリデン樹脂、発泡ポリスチレン、アクリル樹脂
、ナイロン6、天然ゴム、スチレン−ブタジェンゴム、
尿素樹脂等のプラスチフス或はエラストマーを用いると
、霜の耐着は殆どなくなるが、使用中に脆化・損傷を生
じ、到底長期の使用には耐えられなかった。
If a metal guide frame or metal float is used in this device, frost will form on the surface during use, making smooth movement of the float impossible. The float is made of wood or vinyl chloride resin,
Vinylidene chloride resin, expanded polystyrene, acrylic resin, nylon 6, natural rubber, styrene-butadiene rubber,
When plastics or elastomers such as urea resins are used, frost resistance is almost eliminated, but they become brittle and damaged during use, and cannot withstand long-term use.

比較的低温に耐えるプラスチックスやエラストマーを使
用すると、フロートや案内枠の霜耐着によるトラブルは
免れるが一案内桿をリードスイッチやリード線を収容す
る為管状にし且つ、断熱の為密封して使用すると、薄い
金属管等を強化補強材7− として使用しても変形を免れず、フロートの上下移動の
妨げとなって液位の検出に狂いを生じたり検出不能にし
たりするトラブルを招き易い。
If you use plastics or elastomers that can withstand relatively low temperatures, you can avoid problems caused by frost buildup on the float and guide frame, but the guide rod should be made into a tubular shape to accommodate the reed switch and lead wire, and sealed for insulation. In this case, even if a thin metal tube or the like is used as the reinforcing material 7-, deformation cannot be avoided, which obstructs the vertical movement of the float, which tends to cause problems such as erroneous or impossible detection of the liquid level.

これは案内桿内に入っている空気が低温の使用条件で凝
縮或は凍結を起して容積減少を招き桿内部が減圧となっ
て案内枠の外部空間との間に圧力差を生ずるためである
ことが分った。
This is because the air inside the guide frame condenses or freezes under low-temperature usage conditions, resulting in a volume reduction and a reduced pressure inside the guide frame, creating a pressure difference between the air and the outside space of the guide frame. I found out something.

そこで本発明者等は、これらの難点を克服し、超低温領
域に於ける液位の検出を円滑且つ精密に行うという技術
的課題に解決を与えるべく鋭意研究を進めた結果、 ■ フロート及びフロート案内枠の表層に特定のプラス
チフス、エラストマー材料を使用すると共に■案内稈内
部の空間を低温液化ガス上部の空間と等圧力に保つとい
う2つの条件を組合せて実施することによって始めてこ
うしたトラブルを避は得ることを見出し、本発明を完成
するに至った。
Therefore, the inventors of the present invention have conducted intensive research to overcome these difficulties and solve the technical problem of smoothly and precisely detecting the liquid level in the ultra-low temperature region. These problems can only be avoided by combining the two conditions of using specific plastics and elastomer materials for the surface layer of the frame and maintaining the space inside the guide culm at the same pressure as the space above the low-temperature liquefied gas. The present inventors have discovered that the present invention can be obtained, and have completed the present invention.

上記■の条件を満足する特定のプラスチフス、エラスト
マーとしては、不飽和ポリエステル樹脂、エポキシ樹脂
、メラミン樹脂、フェノールm脂、8− ウレタンエラストマー(ウレタン樹脂)、シリコーンゴ
ム(シリコーン樹脂)、弗素化エラストマー(弗素ゴム
)、長鎖ポリアミド、ポリイミド、ポリカーボネート、
フラン樹脂、ポリサルフォン、ブタジェン−アクリロニ
トリル系合成ゴム及び之等の変性物或は之等をブレンド
した混合物が挙げられる。変性物としては少量のコモノ
マーを共重合又は共縮合せしめた共重合体、共縮合体、
グラフト共重合体等が挙げられる。これ等は単独で或は
2種以上をブレンドして用いてもよく、ブレンドによっ
て、柔軟性、可撓性等物性を適宜調整することができる
Specific plastics and elastomers that satisfy the above condition (■) include unsaturated polyester resins, epoxy resins, melamine resins, phenol resins, 8-urethane elastomers (urethane resins), silicone rubbers (silicone resins), and fluorinated elastomers. (fluororubber), long chain polyamide, polyimide, polycarbonate,
Examples include furan resins, polysulfones, butadiene-acrylonitrile synthetic rubbers, modified products thereof, and mixtures thereof. Modified products include copolymers and cocondensates obtained by copolymerizing or cocondensing small amounts of comonomers,
Examples include graft copolymers. These may be used alone or in a blend of two or more, and physical properties such as softness and flexibility can be adjusted as appropriate by blending.

これ等の材料は容器内1こ収容して、その材料に接触す
る液化ガスの該材料に対する膨潤性、溶解性や、経済性
も考慮して適宜選択して用いればよく、例えば液化窒素
や液化アルゴンの如き不活性な物質に対しては何れの材
料を用いてもよいが、液化天然ガス等の比較的膨潤性・
溶解性に富むものを取扱う場合には、耐溶剤性の大きい
フラン樹脂、弗素化エラストマー(弗素ゴム)、エポキ
シ樹脂、ウレタンエラストマー(ウレタン樹脂)等、溶
媒に対する親和性の乏しい材料が適している。
One of these materials may be stored in a container, and the material may be appropriately selected and used by considering the swelling property, solubility, and economic efficiency of the liquefied gas that comes into contact with the material.For example, liquefied nitrogen or liquefied Any material may be used for an inert substance such as argon, but relatively swellable materials such as liquefied natural gas may be used.
When handling materials with high solubility, materials with poor affinity for solvents such as furan resins with high solvent resistance, fluorinated elastomers (fluorine rubber), epoxy resins, and urethane elastomers (urethane resins) are suitable.

フロートやフロート案内稈の少くとも表層には、これ等
の材料を用いることか、本発明の必須要件の1つである
が、表層のみでなく全体に亘ってこれ等の材料を用い得
ることは勿呻である。
It is one of the essential requirements of the present invention to use these materials for at least the surface layer of the float and the float guide culm, but it is not possible to use these materials not only for the surface layer but also for the entire surface layer. It's a shame.

これ等の材料を用いてフロート案内稈を造る際には、強
度、剛性等の物性を附与する為に、炭素繊維、石英繊維
、硝子繊維、金属繊維や金網、穿孔金属板、セラミック
ス材料等を強化材に使用し、例えば炭素繊維強化プラス
チフス(CFRP)や繊維強化プラスチフス(FRP)
の如き、複合材料の形態で使用することが望ましいが、
適宜充填剤その他の添加剤を加えて成型したり、支持材
料の上に塗覆してもよく、その加工方法は何等限定され
 ない。
When making a float guide culm using these materials, carbon fibers, quartz fibers, glass fibers, metal fibers, wire mesh, perforated metal plates, ceramic materials, etc. are used to provide physical properties such as strength and rigidity. is used as a reinforcing material, such as carbon fiber reinforced plastics (CFRP) or fiber reinforced plastics (FRP).
It is desirable to use it in the form of a composite material, such as
It may be molded with fillers or other additives as appropriate, or may be coated on a support material, and the processing method is not limited in any way.

フロートを造る際にも、フロートとしての機能を果し、
少くともその表層がこれ等の材料より成るものであれば
その加工方法は任意に選んでよい。
When making a float, it also functions as a float,
As long as at least the surface layer is made of these materials, the processing method may be arbitrarily selected.

例えば、独立気泡を内蔵した発泡成型体や、ヘリウムを
圧入したアルミニウム浮子にプラスチフスを塗覆したり
、密閉されたハニカム構造を内蔵するプラスチフス・エ
ラストマー等種々の形態のものを適宜用いて差支えない
For example, various forms may be used as appropriate, such as a foam molded body with built-in closed cells, an aluminum float in which helium is press-fitted and coated with plastics, or a plastics elastomer with a sealed honeycomb structure. .

ブタジェン−アクリロニトリル系合成ゴムと熱可塑性樹
脂とをブレンドして発泡成型したフロート資材等市販の
材料で利用し易いものを適宜加工して用いて差支えない
。強化用各種繊維を用いた複合材料を使用しても勿論差
支えない。要するにフロートの場合も低温液化ガスに浮
べて使用する際に、冷却によって外形が変り液位の検出
精度が低下する様なことがあってはならないので、変形
の防止は重要であり、必要番こ応じ、フロート内部の空
間には使用温度に於ても液化しないガス例えばヘリウム
を封入することは好ましい。
Commercially available materials, such as a float material made by foaming and molding a blend of butadiene-acrylonitrile synthetic rubber and a thermoplastic resin, may be suitably processed and used. Of course, a composite material using various reinforcing fibers may also be used. In short, when a float is used floating on low-temperature liquefied gas, the external shape must not change due to cooling and the accuracy of liquid level detection must not deteriorate, so prevention of deformation is important, and the required number is Accordingly, it is preferable to fill the space inside the float with a gas that does not liquefy even at the operating temperature, such as helium.

■の条件であるフロート案内稈内部の空間と容器内液化
ガス上の気相空間を等圧力に保つには如何なる手段を用
いてもよいが、一番簡単な方法としては、案内枠の比較
的上部に穿孔し、或はスリットを設は容器内気相空間と
案内稈内部空間のガスが相互に流通し合う様にしておけ
ばよい。この際穿孔部やスリット部に着霜して閉塞を起
さない様、この部分にも霜の耐着し難い材質を使うこと
は望ましいが、着霜する時には既に内部空間も冷却され
ているから実際上内外の圧力差で案内枠が変形する危険
性は少く、工作の都合上案内稈内部に金属材料を使用す
ることを避ける必要はない。
Any means may be used to maintain the space inside the float guide culm and the gas phase space above the liquefied gas in the container at the same pressure, which is the condition (2), but the simplest method is to A hole or a slit may be provided in the upper part so that the gas in the gas phase space inside the container and the space inside the guide culm can mutually circulate. At this time, it is desirable to use a material that is difficult to resist frost to prevent frost from forming on the perforations and slits and causing blockage, but this is because the internal space has already cooled down by the time frost forms. In fact, there is little risk of the guide frame being deformed due to the pressure difference between the inside and outside, and there is no need to avoid using metal materials inside the guide culm for convenience of construction.

この場合、フロート案内稈内部の空間と液化ガス容器内
空間とを等圧に保つ為の穿孔部・内部の金属部を通して
プラスチフス管を通しておけば万全である。
In this case, it is sufficient to pass the plastic tube through the perforation and internal metal part to maintain equal pressure between the space inside the float guide culm and the space inside the liquefied gas container.

本発明の方法は、上記の様に■の特定の材料を用いる条
件と、■のフロート案内稈内部空間と液化ガス容器内部
空間とを等圧に保つ条件の両者を組合せて実施して始め
てフロート式液位検知を可能本発明の方法は従来よい解
決方法が示されていなかった低温液化ガス液位の検出・
制御の方法を大きく前進させるものであり、その実際的
な価値は頗る高く、低温科学・低温工業に与える利便は
著しいものがある。上述の説明ではフロート案内稈及び
これに嵌合するフロートの孔が円筒形のものについて述
さてきたが、案内枠の形状は磁石の向きを固定化するた
め等、必要に応じ適宜角柱形にして差支えない。
As mentioned above, the method of the present invention can only be carried out by combining the conditions (1) using a specific material and (2) maintaining the internal space of the float guide culm and the internal space of the liquefied gas container at equal pressure. The method of the present invention is capable of detecting and detecting low-temperature liquefied gas liquid levels, for which no good solutions have been shown in the past.
This is a major advance in the control method, its practical value is extremely high, and the benefits it brings to low temperature science and industry are significant. In the above explanation, the float guide culm and the float fitting hole are cylindrical, but the shape of the guide frame may be changed to a prismatic shape as necessary, such as to fix the direction of the magnet. No problem.

要するにフロートがフロート案内稈に嵌合し液化ガス液
位の上下変動に追随して液化ガス上に浮いたフロートが
上下移動を円滑且つ鋭敏になし得る構造のものであれば
よい。円筒管或は角筒管状の案内枠の内部lこフロート
を浮かべる方式もあるが、一般には中心の案内枠の外側
にフロートを嵌合させる方が、機能的にも信頼性の上で
も、更に工作のし易さ、保守の点、コストの点、何れの
点でもまさっており、本明細書の図面では案内枠の外側
にフロートが嵌合している場合のみを例示した。
In short, any structure may be used as long as the float fits into the float guide culm and the float floating on the liquefied gas can move up and down smoothly and sharply following the up and down fluctuations of the liquefied gas level. Although there is a method of floating a float inside a cylindrical or rectangular guide frame, it is generally better to fit the float outside the central guide frame, both in terms of functionality and reliability. It is superior in terms of ease of work, maintenance, and cost, and the drawings in this specification only illustrate the case where the float is fitted on the outside of the guide frame.

第2図、第3図、第4図にはリードスイッチ、マグネッ
ト、フロートの配置を種々変えて、本発明の方法の種々
の実施態様を例示したが、本発明がこれ等の例示によっ
て限定されるものではない。
Although FIGS. 2, 3, and 4 illustrate various embodiments of the method of the present invention by changing the arrangement of reed switches, magnets, and floats, the present invention is not limited to these illustrative examples. It's not something you can do.

第2図ではリードスイッチを作動させる磁石を、液化ガ
ス中に浮く浮子部材から離れてかつ支持部材を介して浮
子部材に対して固定し、この磁石を内蔵した磁石部材が
浮子の上下動に応じてフロート案内稈に摺動ヂる場合を
例示した。本発明に於てはこのフロート案内稈に摺動す
る磁石部材、浮子部材、浮子と磁石をつなぐ支持部材の
3者を包含してフロートと称するものとする。第2図の
如き場合もフロート部分に着霜を生ずると液位検出の精
度を落すことになるのでこれらの部材を含めたフロート
部分全体に本発明の方法を実施する必要があることは無
論である。
In Figure 2, the magnet that activates the reed switch is fixed to the float member apart from the float member floating in the liquefied gas and via a support member, and the magnet member containing this magnet responds to the vertical movement of the float. The case where the float slides on the guide culm is illustrated. In the present invention, the term float includes the magnet member that slides on the float guide culm, the float member, and the support member that connects the float and the magnet. In the case as shown in Figure 2, if frost forms on the float part, the accuracy of liquid level detection will be reduced, so it goes without saying that the method of the present invention must be applied to the entire float part including these parts. be.

第3図には、リードスイッチを液化ガス容器本体の外側
に設け、フロート及びフロート案内稈のみをリードスイ
ッチに近接して液化ガス収納部内に配置した例を示した
。また、第4図にはリードスイッチを液化ガス容器の真
空断熱部内に設け、この器壁に近接してフロート及びフ
ロート案内稈を液化ガス収納部内に配置した構成例を示
したが、これ等の例示以外に考えられる種々の態様も本
願特許請求の範囲を逸脱しない限り、すべて本発明の中
に包含される。本発明の低温液化ガス液位検出機器は、
以上詳細に説明してきた液位検索・制御方法を実施する
際に用いる検出部を構成する機器であり、本発明の低温
液化ガス取扱い装置は上記の検出部を具えた貯槽、保管
器、保存容器、輸送装置、反応器、冷却器、実験機器、
分析機器等を意味し、何れも本発明の範囲に包含される
ものである。
FIG. 3 shows an example in which the reed switch is provided outside the liquefied gas container body, and only the float and the float guide culm are arranged in the liquefied gas storage section in close proximity to the reed switch. Furthermore, Fig. 4 shows an example of a configuration in which a reed switch is provided in the vacuum insulation part of the liquefied gas container, and a float and a float guide culm are arranged in the liquefied gas storage part in close proximity to the container wall. Various possible embodiments other than those illustrated are also encompassed within the present invention unless they depart from the scope of the claims of the present application. The low temperature liquefied gas level detection device of the present invention includes:
It is a device that constitutes a detection section used when carrying out the liquid level search and control method described in detail above, and the low-temperature liquefied gas handling device of the present invention is a storage tank, a storage container, a storage container equipped with the above-mentioned detection section. , transportation equipment, reactors, coolers, laboratory equipment,
This term refers to analytical instruments, etc., and all are included within the scope of the present invention.

本発明は、液化窒素、液化酸素、液化空気、液化アルゴ
ン或は液化天然ガス(LNG)等超低温領域に於ける液
化ガスの液位検出・制御に有用なものであるが、この領
域より高い温度に於ける液体の液位検出にも転用できる
点非常に便利である。
The present invention is useful for detecting and controlling the level of liquefied gases such as liquefied nitrogen, liquefied oxygen, liquefied air, liquefied argon, or liquefied natural gas (LNG) in ultra-low temperature ranges, but at temperatures higher than this range. It is very convenient in that it can also be used to detect the level of liquid in water.

LNG等の可燃性液化ガスについては、消防法上取扱機
器に防爆構造が要求されるが、本発明の機器の場合、ス
イッチの端子部は、硝子管内に不活性ガスと共に密封さ
れに構造のものであるから、リード線部及び検出・制御
回路部分にも本質安全防爆形構造を採用することにより
、防爆構造の取扱い機器として好適に使用できる点も本
発明の特長の一つである。本発明は小型で取扱い容易な
検出部を用いて、実施できるので、適用する 低温液化
ガスの取扱い機器が大型のものであっても小型のもので
あっても本発明を容易に実施することができ精度の高い
検出・制御を経済的に実施することを可能ならしめる。
Regarding flammable liquefied gases such as LNG, explosion-proof construction is required for equipment that handles flammable liquefied gases such as LNG, but in the case of the equipment of the present invention, the terminal part of the switch is sealed with an inert gas inside a glass tube. Therefore, one of the features of the present invention is that by adopting an intrinsically safe explosion-proof structure for the lead wire portion and the detection/control circuit portion, it can be suitably used as an explosion-proof structure handling device. Since the present invention can be implemented using a small and easy-to-handle detection section, the present invention can be easily implemented regardless of whether the low-temperature liquefied gas handling equipment to which it is applied is large or small. This makes it possible to perform highly accurate detection and control economically.

以下実施例を挙げて更に説明を加える。Further explanation will be given below with reference to Examples.

実施例1〜10及び対照例1〜10 第1図に示した如き1種のデユア−瓶である液化窒素式
凍結保存容器DR−11(ダイヤ冷機工業株式会社製品
、外径260■、高さ540■、口径63.5m1液化
窒素容量11t)の蓋(図の2、外装アルミニウム製、
断熱部エポキシ樹脂製)に直径18置の孔を開け、ガラ
ス繊維強化エポキシ樹脂製の液化窒素補給管(内径6■
外径9■)とフロートスイッチの案内桿(直径9謹の円
筒管の尖端を閉じた、蓋から下の長さ300■)を入れ
、案内桿には磁石を装着したドーナツ型のフロートを案
内桿に沿って上下方向に移動し得る様に嵌込み、案内桿
の内部にはリード線を連結したリードスイッチを固定し
、蓋に開けた孔を通る液化窒素補給管及び案内桿の部分
には外側に更にパイプを巻いてエポキシ系接着剤で蓋に
対し接着固定した。
Examples 1 to 10 and Control Examples 1 to 10 Liquefied nitrogen cryopreservation container DR-11 (product of Dia Reiki Kogyo Co., Ltd., outer diameter 260 cm, height 540■, diameter 63.5m, liquefied nitrogen capacity 11t) lid (2 in the figure, made of aluminum exterior,
Drill 18 holes in diameter in the insulation part (made of epoxy resin), and insert a liquefied nitrogen supply pipe (inner diameter 6 mm) made of glass fiber reinforced epoxy resin.
Insert a float switch guide rod (a cylindrical tube with a diameter of 9 mm with the tip closed, length 300 mm below the lid), and guide a donut-shaped float equipped with a magnet into the guide rod. It is fitted so that it can move vertically along the rod, and a reed switch with a lead wire connected is fixed inside the guide rod, and a liquefied nitrogen supply pipe that passes through the hole in the lid and the guide rod are A pipe was further wrapped around the outside and fixed to the lid using epoxy adhesive.

案内桿内に尖端部から■57m+、■77w1■152
簡、■175■の位置にリードスイッチを設は液化窒素
が蒸発して減少し、フロートが■のリードスイッチに接
近するとリードスイッチが作動、液位を検出して電磁弁
を作動させ液化窒素を液化窒素補給管から補給し、液化
窒素の液位が上昇してフロートが、■のリードスイッチ
番こ接近するとリードスイッチが作動して液位を検出し
、液化窒素の補給電磁弁を閉止せしめる様にして、液化
窒素の液位を検出し更に制御を行う試験を行った。もし
、液化窒素の補給が円滑に行われず、液位が過度に低下
してフロートが■のリードスイッチに接近すると、リー
ドスイッチの作動によって、液位の低下が検出され、警
報を出す。又液位が過度に上昇してフロートが■のリー
ドスイッチに接近した場合にも警報が出る様にして液位
の検出・制御を行うシステムである。
Inside the guide rod from the tip ■57m+, ■77w1■152
Simply, by setting a reed switch at position ■175■, the liquefied nitrogen evaporates and decreases, and when the float approaches the reed switch at ■, the reed switch is activated, detects the liquid level, and activates the solenoid valve to release liquefied nitrogen. Refill from the liquefied nitrogen supply pipe, and when the liquid level of liquefied nitrogen rises and the float approaches the reed switch number marked with ■, the reed switch operates, detects the liquid level, and closes the liquefied nitrogen replenishment solenoid valve. A test was conducted to detect and further control the liquid nitrogen level. If the replenishment of liquefied nitrogen is not carried out smoothly and the liquid level drops excessively and the float approaches the reed switch (■), the drop in the liquid level will be detected by the operation of the reed switch and an alarm will be issued. The system also detects and controls the liquid level by issuing an alarm even if the liquid level rises excessively and the float approaches the reed switch (①).

本発明の実施例1〜10に於ては、液位の検出・制御が
円滑に行われ何等問題がなかったのに対し、対照例1〜
10では、フロートや案内桿に欠損や変形を起したり着
霜を生じたりして正確な作動を保つことができなかった
In Examples 1 to 10 of the present invention, the detection and control of the liquid level was performed smoothly and there were no problems, whereas in Comparative Examples 1 to 10,
In No. 10, accurate operation could not be maintained because the float and guide rod were damaged, deformed, or frosted.

第1表 19− 20一 実施例11〜17 外形寸法高さ939調、幅876籠、奥行952■の角
形ステンレス鋼製外−の中に、内形寸法深さ648m、
内径787mで円筒形のガラス繊維強化エポキシ樹脂の
内側壁と鋼製外側壁より構成されたデユア−瓶を入れ、
外装がステンレス鋼製で内側に発泡ウレタン樹脂製断熱
カバー(表面ポリアミド被覆)を設けた自在開閉蓋を外
内に取付けた構造の液化窒素式超低温保管器(米国、ユ
ニ既設の液位検出制御装置を取外し、当該保管器の本体
の内壁面に沿って下降し、デユア−瓶の底面近くに開口
するステンレス鋼製液化窒素補給管に支持クリップでフ
ロートスイッチの案内桿を取付けた。
Table 1 19-20 - Examples 11 to 17 External dimensions Height: 939 m, Width: 876 cm, Depth: 952 cm Inside a square stainless steel outer cage, Inner dimensions: Depth: 648 m,
A cylindrical Dua bottle with an inner diameter of 787 m and consisting of an inner wall made of glass fiber reinforced epoxy resin and an outer wall made of steel was placed.
A liquefied nitrogen type ultra-low temperature storage container with a stainless steel exterior and a freely opening/closing lid with a foamed urethane resin insulation cover (surface polyamide coating) installed on the outside and inside. The guide rod of the float switch was attached with a support clip to a stainless steel liquefied nitrogen supply pipe that descended along the inner wall surface of the main body of the storage container and opened near the bottom of the Dua bottle.

当該案内稈は表2に示した如き仕様の尖端を閉じた直径
9■、長さ600mの円筒管で、この内部にはデユア−
瓶内底から57[■−・77■■、152冒■、175
■■の位置にリードスイッチを固定し、リードスイッチ
に繋いだリード線は、案内稈上部から引出して液化窒素
補給管に沿って容器の外に設けた検出制御用の電子回路
に連結した。案内桿のリード線引出し口は細く絞ってエ
ポキシ樹脂で封じ、桿の下端から250簡の位置には案
内稈内の空間に通ずる径1■の円形の小孔を開けた。案
内桿にはマグネットを取付けたドーナッツ型のフロート
を嵌込み、液面の上下に従ってフロートが動く構成にし
た。こうしてできた構成この超低温保管器内に液化窒素
を入れて、この液化窒素の自然蒸発と補給によって液面
を降下、上昇させ、液位が降下してフロートがリードス
イッチ■に接近すると液化窒素補給装置が働く様にスイ
ッチが作動し、フロートがリードスイッチ■に接近する
と液化窒素補給装置が停止する様にスイッチが作動し、
又液位が過度に低下してフロートがリードスイッチ■に
接近、或は液位が過度番こ上昇してフロートがリードス
イッチ■に接近すると、警報が鳴るシステムとして電子
回路を設けた。フロートとその案内桿は第2表に示す仕
様とした。
The guide culm is a cylindrical tube with a closed tip as shown in Table 2, with a diameter of 9 mm and a length of 600 m.
57 from the bottom of the bottle [■-・77■■, 152 defacement, 175
The reed switch was fixed at the position of ■■, and the lead wire connected to the reed switch was pulled out from the upper part of the guide culm and connected to an electronic circuit for detection control provided outside the container along the liquefied nitrogen supply pipe. The lead wire outlet of the guide rod was narrowed and sealed with epoxy resin, and a small circular hole with a diameter of 1 square inch was opened at a position 250 mm from the bottom end of the guide rod, which communicated with the space inside the guide culm. A donut-shaped float with a magnet attached was fitted into the guide rod, and the float was configured to move according to the rise and fall of the liquid level. This is the structure created by placing liquefied nitrogen in this ultra-low-temperature storage container, causing the liquid level to drop and rise by natural evaporation and replenishment of the liquefied nitrogen, and when the liquid level drops and the float approaches the reed switch ■, liquefied nitrogen is replenished. The switch operates so that the device works, and when the float approaches the reed switch ■, the switch operates so that the liquefied nitrogen supply device stops.
In addition, an electronic circuit was installed as a system that would sound an alarm if the liquid level dropped excessively and the float approached the reed switch (2), or if the liquid level rose too much and the float approached the reed switch (2). The float and its guide rod had the specifications shown in Table 2.

容器内に液化窒素を入れ、蓋をした後、上記の液位検出
制御用の電子回路の作動を開始させた。液化窒素の補給
が行われるとその日時と補給量を自動記録計に記録させ
ると共に、2日に1回蓋を開けて内部を観察した。
After filling the container with liquefied nitrogen and closing the container, the electronic circuit for liquid level detection control was started. When replenishment of liquefied nitrogen was performed, the date and time and amount of replenishment were recorded on an automatic recorder, and the lid was opened once every two days to observe the inside.

第2表に示した実施例の何れの場合も数日毎に自然気化
による液化窒素の減少を検出してこれを補うため制御機
構が働いて液化窒素を補給した。容器内上方には蓋の開
閉時に大気中に含まれる湿気が入って凝縮し、次第に霜
の耐着量を増したが、液位の検出・液量の制御装置は正
常に働いて、液化窒素の蒸発、補給の動作を繰返し3力
月の試験中警報も鳴らず、何等の支障も生じなかった。
In all of the examples shown in Table 2, a control mechanism operated to detect a decrease in liquefied nitrogen due to natural vaporization every few days and to compensate for this, replenishing liquefied nitrogen. Moisture contained in the atmosphere entered the upper part of the container when the lid was opened and closed and condensed, gradually increasing the amount of frost that could build up.However, the liquid level detection and liquid volume control devices were working normally and the liquid nitrogen The evaporation and replenishment operations were repeated, and no alarms were sounded during the Mikizuki test, and no problems occurred.

23− 第2表 24一 実施例18〜23 外形全高813■、外径445m、内径356冒、液化
窒素容量46.61の外装アルミニウム製円筒ケースの
中にガラス繊維強化エポキシ樹脂製デユア−瓶を入れた
構造の液化窒素式超低温保管器(米国、ユニオンカーバ
イド社製、型番LR−40)の蓋(外装アルミニウム製
内装発泡ポリウレタン断熱材をポリアミド系樹脂で被覆
したもの)に直径18■の円孔を開け、液化窒素の補給
管(ステンレス鋼5US316製)を取付け、当該補給
管と孔の僅かな隙間からリード線を通して残りの隙間は
エポキシ樹脂を用いて完全に封じた。
23- Table 2 24 - Examples 18 to 23 A glass fiber-reinforced epoxy resin dual-bottle was placed inside an aluminum cylindrical case with a total external height of 813 mm, an outer diameter of 445 m, an inner diameter of 356 mm, and a liquefied nitrogen capacity of 46.61 cm. A circular hole with a diameter of 18 cm was inserted into the lid of the liquefied nitrogen cryogenic storage container (manufactured by Union Carbide, USA, model number LR-40) (made of aluminum exterior and foamed polyurethane insulation material covered with polyamide resin). was opened, a liquefied nitrogen supply pipe (made of stainless steel 5US316) was attached, and a lead wire was passed through a small gap between the supply pipe and the hole, and the remaining gap was completely sealed with epoxy resin.

この液化窒素の補給管に支持クリップを用いて直径9謹
、長さ300−の円筒管状で尖端を閉じたフロート案内
枠を取付けた。このフロート案内枠の内部にはデユア−
瓶の内底から57W■、77■■、152調■、175
■■の位置にリードスイッチを固定し、上述の液化窒素
補給管に沿ってリード線を連結し、リード線の他の端は
容器の外に設けた検出・制御用の電子回路に連結した。
A cylindrical float guide frame having a diameter of 9 mm and a length of 300 mm and having a closed tip was attached to the liquefied nitrogen supply pipe using a support clip. Inside this float guide frame, there is a dual
57W ■, 77 ■■, 152 tone ■, 175 from the inner bottom of the bottle
A reed switch was fixed at the position of ■■, and a lead wire was connected along the above-mentioned liquefied nitrogen supply pipe, and the other end of the lead wire was connected to an electronic circuit for detection and control provided outside the container.

案内桿にはリードスイッチを作動させるためのマグネッ
トを取付けたドーナッツ型のフロートを嵌め込み、液面
の上下に従ってフロートが動く構成にした。
A donut-shaped float with a magnet attached to activate the reed switch was fitted into the guide rod, and the float moved according to the rise and fall of the liquid level.

フロート及びフロート案内枠の仕様は第3表に示す通り
である。
The specifications of the float and float guide frame are as shown in Table 3.

リードスイッチからのリード線の電子回路への接続は、
フロートがリードスイッチ■に接近すると液化窒素の補
給開始、フロートがリードスイッチ■に接近すると液化
窒素の補給停止、フロートがリードスイッチ■又は■に
接近すると警報というシステムを作る様にした。
To connect the lead wire from the reed switch to the electronic circuit,
We created a system that starts replenishing liquefied nitrogen when the float approaches reed switch ■, stops replenishing liquefied nitrogen when the float approaches reed switch ■, and warns when the float approaches reed switch ■ or ■.

容器内に液化窒素を入れ、蓋をした後、上記の液位検出
制御用の電子回路の作動を開始させた。液化窒素の補給
日時と補給量を自動記録させると共に、5日に1回蓋を
開けて内部を観察した。
After filling the container with liquefied nitrogen and closing the container, the electronic circuit for liquid level detection control was started. The date and time of liquefied nitrogen replenishment and the amount of replenishment were automatically recorded, and the lid was opened once every five days to observe the inside.

第3表に示した実施例の何れの場合も、数日毎に自然気
化による液化窒素の減少を検出してこれを補うための制
御機構が働いて液化窒素を補給した。
In all of the examples shown in Table 3, a control mechanism was operated to detect a decrease in liquefied nitrogen due to natural vaporization every few days and to compensate for this, thereby replenishing liquefied nitrogen.

容器内上方には、蓋の開閉時に大気中の湿気が取込まれ
て凝縮し霜が着いたが、フロートや案内桿には霜も着か
ず、変形や破損もなく、液位の検出・液量の制御装置は
正常な動作を繰返し6力月の試験期間中、警報が鳴るこ
ともなく何等の支障も生じなかった。実施例18の装置
を高真空排気系のコールドトラップ用の液化窒素収容容
器に応用し、実用テストを行ったが、6力月の試験期間
中全く支障を来さなかった。
When the lid was opened and closed, moisture from the atmosphere was taken in and condensed, forming frost on the upper part of the container, but there was no frost on the float or guide rod, and there was no deformation or damage. The quantity control device repeatedly operated normally, and no alarms sounded and no problems occurred during the June test period. The device of Example 18 was applied to a liquefied nitrogen storage container for a cold trap in a high vacuum evacuation system, and a practical test was conducted, but no problems were caused during the six month test period.

第3表Table 3

【図面の簡単な説明】[Brief explanation of the drawing]

第1図〜第4図は本発明を説明するための見取図である
。 1、デユア−瓶 2、断熱蓋 3、 フロート案内枠 4、 リードスイッチ 5、 リード線 6、 フロート 7、等圧力を得る為の小孔 8、液化ガス 9、磁石 io、  支持部材 11、液化ガス補給管 、特許出願人 大陽酸素株式会社 手続補正書(自発 [I訓関年5月U日 1、事件の表示 157年 特許願第79′?沼号 2、発明の名称 低温液化ガスの液位検出制御方法 3、補正をする者 絽との■   特許出願人 4、補正の対象 明細書の「特許請求の範囲」の欄 5、補正の内容 H1iiEO通り 別紙 特許請求の範囲 (1)  リードスイッチとそれを作動させる磁石を固
定したフロートとを組合せて成るフロートスイッチを用
いて、容器内に収容した低温液化ガスの液位を検出制御
するに当り、 ■ 低温液化ガスの液位の変動に応じて上下に移動する
フロート及びフロートの案内稈の少くとも表層部に不飽
和ポリエステル樹脂、エポキシ樹脂メラミン樹脂、フエ
/゛−ル樹脂、ポリウレタンエラストマー(ウレタン樹
脂)、シリコーンゴム(シリコーン樹脂)、弗素系エラ
ストマー(弗素ゴム)、長鎖ポリアミド、ポリイミド、
ポリカーボネート、フラン樹脂、ポリサルフォン、ブタ
ジェン−アクリロニトリル系合成ゴム及び之等の変性物
より成る群から選ばれた1種もしくは2種以上の混合物
を用いると共に、 ■ 上記のフロート牽、それを浮べた低温液化ガスの液
位の変動に従って上下に移動させるために該液化ガスの
容器内に設けた案内稈内部の空間を容器内液化ガス上の
気相空間と等圧力に保つ構造にした液位検出部を用いる
ことを特徴とする低温液化ガス液位の検出制御方法 ■ 上記のフロートを、それを浮べた低温液化ガにした
液位検出部を有する低温液化ガス液位検出機器。 エン−アクリロニトリル系合成ゴム及び之等の変性物よ
り成る群から選ばれた1種もしくは2種以、ミ」ユな液
位検出部を用いて低温液化ガスの液位を検出し或は更に
制御する機構を有する低温液化ガス取扱い装置。 127−
1 to 4 are sketches for explaining the present invention. 1. Dual bottle 2, insulation lid 3, float guide frame 4, reed switch 5, lead wire 6, float 7, small hole 8 for obtaining equal pressure, liquefied gas 9, magnet IO, support member 11, liquefied gas Supply pipe, patent applicant: Taiyo Sanso Co., Ltd. Procedural Amendment (Voluntary application [I, May 1, 2006] Case indication: 157 Patent application No. 79'?Numa No. 2, Title of invention: Low-temperature liquefied gas liquid Position detection control method 3, name of the person making the amendment■ Patent applicant 4, "Claims" column 5 of the specification to be amended, content of the amendment H1ii As per the EO, appendix Claims (1) Reed switch When detecting and controlling the liquid level of low-temperature liquefied gas contained in a container using a float switch consisting of a float switch and a float to which a magnet is fixed to operate the switch, At least the surface layer of the float that moves up and down and the guide culm of the float contains unsaturated polyester resin, epoxy resin, melamine resin, fluorine resin, polyurethane elastomer (urethane resin), silicone rubber (silicone resin), and fluorine-based resin. Elastomer (fluororubber), long chain polyamide, polyimide,
In addition to using one or a mixture of two or more selected from the group consisting of polycarbonate, furan resin, polysulfone, butadiene-acrylonitrile synthetic rubber, and modified products such as; A liquid level detection unit is provided with a structure in which a space inside a guide culm provided in a container for the liquefied gas is kept at the same pressure as a gas phase space above the liquefied gas in the container in order to move the gas up and down according to fluctuations in the liquid level. Low-temperature liquefied gas liquid level detection control method characterized by using ■ A low-temperature liquefied gas level detection device having a liquid level detection section using the above-mentioned float as a floating low-temperature liquefied gas. Detecting or further controlling the liquid level of low-temperature liquefied gas using one or more types selected from the group consisting of en-acrylonitrile-based synthetic rubber and modified products thereof. Low-temperature liquefied gas handling equipment with a mechanism to 127-

Claims (1)

【特許請求の範囲】 (1)  リードスイッチとそれを作動させる磁石を固
定したフロートとを組合せて成るフロートスイッチを用
いて、容器内に収容した低温液化ガスの液位を検出制御
するに当り、 ■ 低温液化ガスの液位の変動に応じて上下に移動する
フロート及びフロートの案内稈の少くとも表層部に不飽
和ポリエステル樹脂、エポキシ樹脂、メラミン樹脂、フ
ェノール樹脂、ポリウレタンエラストマー(ウレタン樹
脂)、シリコーンゴム(シリコーン樹脂)、弗素系エラ
ストマー(弗素ゴム)、長鎖ポリアミド、ポリイミド、
ポリカーボネート、フラン樹脂、ポリサルフォン、ブタ
ジェン−アクリロニトリル系合成ゴム及び之等の変性物
より成る群から選ばれた1種もしくは2種以上の混合物
を用いると共に、 ■ 上記のフロートを、それを浮べた低温液化ガスの液
位の変動に従って上下に移動させるために該液化ガスの
容器内に設けた案内稈内部の空間を容器内液化ガス上の
気相空間と等圧力に保つ構造にした 液位検出部を用。害とを特徴とする低温液化ガス液位の
検出制御方法 (2、特許請求の範囲(1)記載の液位検出部を構成す
る低温液化ガス液位検出機器。 (3)特許請求の範囲(1)記載の液位検出部を用いて
低温液化ガスの液位を検出し或は更に制御する機構を有
する低温液化ガス取扱い装置。
[Claims] (1) In detecting and controlling the liquid level of low-temperature liquefied gas contained in a container using a float switch consisting of a combination of a reed switch and a float fixed with a magnet for actuating the reed switch, ■ Unsaturated polyester resin, epoxy resin, melamine resin, phenol resin, polyurethane elastomer (urethane resin), silicone is used at least in the surface layer of the float and the guide culm of the float, which move up and down in response to fluctuations in the liquid level of low-temperature liquefied gas. Rubber (silicone resin), fluorine-based elastomer (fluorine rubber), long-chain polyamide, polyimide,
Using one or a mixture of two or more selected from the group consisting of polycarbonate, furan resin, polysulfone, butadiene-acrylonitrile synthetic rubber, and modified products thereof, and A liquid level detection unit is provided with a structure in which a space inside a guide culm provided in a container for the liquefied gas is kept at the same pressure as a gas phase space above the liquefied gas in the container in order to move the gas up and down according to fluctuations in the liquid level. for. (2) A low-temperature liquefied gas level detection device constituting the liquid level detection section according to claim (1). (3) Claims ( 1) A low-temperature liquefied gas handling device having a mechanism for detecting or further controlling the liquid level of low-temperature liquefied gas using the liquid level detection section described above.
JP7975882A 1982-05-11 1982-05-11 Liquid level control for low temperature liquefied gas Pending JPS58196423A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7975882A JPS58196423A (en) 1982-05-11 1982-05-11 Liquid level control for low temperature liquefied gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7975882A JPS58196423A (en) 1982-05-11 1982-05-11 Liquid level control for low temperature liquefied gas

Publications (1)

Publication Number Publication Date
JPS58196423A true JPS58196423A (en) 1983-11-15

Family

ID=13699118

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7975882A Pending JPS58196423A (en) 1982-05-11 1982-05-11 Liquid level control for low temperature liquefied gas

Country Status (1)

Country Link
JP (1) JPS58196423A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0334876A1 (en) * 1986-11-20 1989-10-04 Nde Technology, Inc. Volumetric leak detection system for underground storage tanks and the like
JPH03114700U (en) * 1990-03-07 1991-11-26
JPH0672031U (en) * 1993-03-24 1994-10-07 株式会社木村製作所 float
CN103289413A (en) * 2013-06-24 2013-09-11 苏州新区佳合塑胶有限公司 Shock resistant and stretch proof plastic containing dimethyl silicone rubber
JP2013220059A (en) * 2012-04-17 2013-10-28 Taiyo Nippon Sanso Corp Preliminary freezer for biological sample
JP2014032175A (en) * 2012-07-13 2014-02-20 Kawasaki Heavy Ind Ltd Float, liquid level sensor, and absorption type refrigerator
JP2020051449A (en) * 2018-09-25 2020-04-02 大陽日酸株式会社 Liquid nitrogen filling adapter, and liquid nitrogen filling device

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0334876A1 (en) * 1986-11-20 1989-10-04 Nde Technology, Inc. Volumetric leak detection system for underground storage tanks and the like
JPH03114700U (en) * 1990-03-07 1991-11-26
JPH0672031U (en) * 1993-03-24 1994-10-07 株式会社木村製作所 float
JP2013220059A (en) * 2012-04-17 2013-10-28 Taiyo Nippon Sanso Corp Preliminary freezer for biological sample
JP2014032175A (en) * 2012-07-13 2014-02-20 Kawasaki Heavy Ind Ltd Float, liquid level sensor, and absorption type refrigerator
CN103289413A (en) * 2013-06-24 2013-09-11 苏州新区佳合塑胶有限公司 Shock resistant and stretch proof plastic containing dimethyl silicone rubber
JP2020051449A (en) * 2018-09-25 2020-04-02 大陽日酸株式会社 Liquid nitrogen filling adapter, and liquid nitrogen filling device

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