JPS58186427A - Emulsifying agent composition for petroleum product - Google Patents
Emulsifying agent composition for petroleum productInfo
- Publication number
- JPS58186427A JPS58186427A JP57070660A JP7066082A JPS58186427A JP S58186427 A JPS58186427 A JP S58186427A JP 57070660 A JP57070660 A JP 57070660A JP 7066082 A JP7066082 A JP 7066082A JP S58186427 A JPS58186427 A JP S58186427A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- oil
- component
- sulfonic acid
- alkaline earth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003995 emulsifying agent Substances 0.000 title claims abstract description 13
- 239000003209 petroleum derivative Substances 0.000 title claims abstract description 6
- 239000000203 mixture Substances 0.000 title claims description 13
- -1 polyoxyethylene Polymers 0.000 claims abstract description 19
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 10
- 239000000194 fatty acid Substances 0.000 claims abstract description 10
- 229930195729 fatty acid Natural products 0.000 claims abstract description 10
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 6
- 239000003208 petroleum Substances 0.000 claims abstract description 5
- 150000003839 salts Chemical class 0.000 claims abstract description 5
- 239000003513 alkali Substances 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims abstract description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000002253 acid Substances 0.000 claims abstract description 3
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 3
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 10
- 239000003921 oil Substances 0.000 claims description 6
- 239000000295 fuel oil Substances 0.000 claims description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
- 239000005642 Oleic acid Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
- 239000003350 kerosene Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 150000003460 sulfonic acids Chemical class 0.000 claims description 3
- 239000003784 tall oil Substances 0.000 claims description 3
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- 239000001993 wax Substances 0.000 claims 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 229940057995 liquid paraffin Drugs 0.000 claims 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract description 9
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract description 4
- 150000004996 alkyl benzenes Chemical class 0.000 abstract description 3
- 239000000839 emulsion Substances 0.000 abstract description 3
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 abstract description 2
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 abstract description 2
- 229940092714 benzenesulfonic acid Drugs 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000013543 active substance Substances 0.000 abstract 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 159000000003 magnesium salts Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- ZWLYKFAJRHKXDD-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid sulfane Chemical class S.C(CC(O)(C(=O)O)CC(=O)O)(=O)O ZWLYKFAJRHKXDD-UHFFFAOYSA-N 0.000 description 1
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241000158728 Meliaceae Species 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000009841 combustion method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003747 fuel oil additive Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 125000005608 naphthenic acid group Chemical group 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
Description
【発明の詳細な説明】
本発明はW2O型のエマルジョンの製造を目的とする石
油製品の乳化剤組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to emulsifier compositions for petroleum products intended for the production of emulsions of the W2O type.
最近完全燃焼の促進、煤煙並びに燃焼ガス中のNox含
有量の低下などを目的とQで重油に10乃至20係の水
を乳化分散させる方法が実施されている。Recently, a method of emulsifying and dispersing 10 to 20 parts of water in heavy oil with Q has been implemented for the purpose of promoting complete combustion, reducing soot and NOx content in combustion gas, etc.
乳化剤には種々の混合組成物が用いられているが、例え
ば公開特許公報52−37907はアルキルベンゼンス
ルフォン酸カルシウム塩ト非イオノ活性剤の組合はせ又
はアルキルベンゼンスルフオン酸マグネシウム塩を単独
に用いることを提案している。Various mixed compositions are used as emulsifiers, and for example, Japanese Patent Publication No. 52-37907 describes the use of a combination of an alkylbenzenesulfonate calcium salt and a non-ionoactive agent or a single alkylbenzenesulfonate magnesium salt. is suggesting.
本発明者は重油の燃焼方法などの特定の用途に限定され
ることなく燃料油添加剤、助燃剤、コンクリート離型剤
、金属加工油、金属洗浄剤、防水剤、艶出剤など多目的
に応用可能で而も比較的に安価な原料を用い経済的有利
に少量の添加量で強力な機械的攪拌を必要とすることな
く安定なW2O型のエマルジョンを製造出来る重油、軽
油、灯油、流動・9ラフイン、パラフィンワックス等の
石油製品の乳化剤組成物を見出した。The present inventor is not limited to specific uses such as heavy oil combustion methods, but can apply it to various purposes such as fuel oil additives, combustion improvers, concrete mold release agents, metal processing oils, metal cleaning agents, waterproofing agents, and polishing agents. Heavy oil, light oil, kerosene, fluid-9, which can economically produce stable W2O emulsions using relatively inexpensive raw materials and in small amounts without requiring strong mechanical stirring. We have discovered an emulsifier composition for petroleum products such as rough-in and paraffin wax.
本発明の乳化剤組成物は燃焼に際し灰分として残留する
無機化合物の含有量が低く又Noxの発生源となるアミ
ン、アミドなどの窒素化合物を全く含有しない。The emulsifier composition of the present invention has a low content of inorganic compounds that remain as ash upon combustion, and does not contain any nitrogen compounds such as amines and amides that are sources of Nox.
更に多目的の乳化製品に対し引火性、毒性、臭気、色調
などの条件で満足すべき実用性を提供することが出来る
1゜
本発明の乳化剤組成物は次の三成分を組合わせて配合す
ることを基本とする。Furthermore, the emulsifier composition of the present invention can be formulated by combining the following three components to provide a multi-purpose emulsified product with satisfactory practicality in terms of flammability, toxicity, odor, color tone, etc. Based on.
第一成分は、非イオン活性剤でノニルフェノール又はオ
クチルフェノールに酸化エチレンを1乃至10モル附加
したポリオキシエチレンアルキルフェノールエーテル又
は天然、合成高級アルコールに酸化エチレンを1乃至1
0モル附加したポリオキンエチレンアルキルエーテル又
はそれらの混合物である。The first component is a nonionic activator, and is a polyoxyethylene alkylphenol ether prepared by adding 1 to 10 moles of ethylene oxide to nonylphenol or octylphenol, or a polyoxyethylene alkylphenol ether prepared by adding 1 to 1 mole of ethylene oxide to a natural or synthetic higher alcohol.
0 mol added polyoxine ethylene alkyl ether or a mixture thereof.
第二成分は、オレイン酸又はオレイン酸、リノール酸、
了ビニチン酸を含有するトール油脂肪酸又はナフテン酸
で代表される鎖状不飽和高級脂肪酸並びに環状高級脂肪
酸又はそれらの混合物である。The second component is oleic acid or oleic acid, linoleic acid,
They are tall oil fatty acids containing divinitic acid, chain unsaturated higher fatty acids typified by naphthenic acid, cyclic higher fatty acids, or mixtures thereof.
第三成分は、ドデシルベンゼンスルフォン酸のアルカリ
土類金属塩即ち合成洗剤原料の分岐型又は直鎖型のアル
キルベンゼンスルフォン酸のカル7ウム塩又はマグネシ
ウム塩又はこれらのアルキルベンゼンの製造プロセ、ス
で副生ずるポリアルキルベンゼン(ノアルキルベンゼン
を主成分とLヘビーアルキレート又はアルキレートボト
ムト称せられる)のスルフォン酸のアルカリ又はアルカ
リ土類金属塩(合成石油スルフォネートと称せられる)
、又は流動・母ラフインの製造プロセスで副生する石油
スルフォン酸のアルカリ又はアルカリ土類金属塩(マホ
ガニー石鹸とも称せられる)を用いることが出来る。The third component is an alkaline earth metal salt of dodecylbenzenesulfonic acid, i.e., a calcium salt or magnesium salt of a branched or linear alkylbenzenesulfonic acid as a raw material for synthetic detergent, or a by-product in the production process of these alkylbenzenes. Alkali or alkaline earth metal salts of sulfonic acids (referred to as synthetic petroleum sulfonates) of polyalkylbenzenes (referred to as L-heavy alkylates or alkylate bottoms with noalkylbenzene as the main component)
Alternatively, an alkali or alkaline earth metal salt of petroleum sulfonic acid (also referred to as mahogany soap) which is a by-product in the production process of fluid/matrix rough-in can be used.
更に油溶性金属塩類は上記のスルフ引ン酸塩に限定され
ることなく第二成分即ちオレイン酸、トール油脂肪酸又
はナフテン酸の如きカルボ/酸類のアルカリ土類金属塩
を用いることが出来る。Furthermore, the oil-soluble metal salts are not limited to the above-mentioned sulfur citrates, but alkaline earth metal salts of the second component, ie, carboxylic acids such as oleic acid, tall oil fatty acids, or naphthenic acids, can be used.
従って第二、第三成分の混合物は第二成分の脂肪酸と第
三成分の脂肪酸アルカリ土類金属塩を別々に入手混合す
ることなく又スルフォン酸を用いることなく、第二成分
をアルカリ土類金属、例えば酸化マグネシウム、水酸化
マグネシウム、又は炭酸マグネシウムで部分鹸化するこ
とにより容易に製造することが出来る。Therefore, the mixture of the second and third components can be prepared by separately obtaining the second component fatty acid and the third component fatty acid alkaline earth metal salt without mixing them or using sulfonic acid. , for example, by partial saponification with magnesium oxide, magnesium hydroxide, or magnesium carbonate.
これらの油溶性金属塩類は一般に非常に粘度が高く、室
温で固化又はグル化し連続乳化プロセスにおいて比例注
入することは困難である。市販のアルキルベンゼンスル
フオン酸カルシウムtri 約3(1チメタノールで稀
釈されている。メタノールは引火性の点で満足すべき溶
媒ではない。These oil-soluble metal salts are generally very viscous and solidify or glue at room temperature, making them difficult to proportionately inject in a continuous emulsification process. Commercially available calcium alkylbenzene sulfonate tri approx.
ケロシン、ンルベントナフサの如き石油系溶媒の配合は
乳化力の低下を招き又引火性の点からも好ましくない。The blending of petroleum solvents such as kerosene and rubent naphtha is undesirable from the viewpoint of deterioration of emulsifying power and flammability.
本発明者は上記の三成分系の乳化剤組成物の溶媒として
ジエチレングリコール、トリエチレングリコール又はテ
トラエチレングリコールが乳化力の低下を招くことなく
尚引火性と強い臭気をあたえることのない優れた溶媒で
あることを見出した。The present inventor has found that diethylene glycol, triethylene glycol, or tetraethylene glycol is an excellent solvent for the above three-component emulsifier composition, which does not cause a decrease in emulsifying power and does not impart flammability or a strong odor. I discovered that.
テトラエチレングリコールはジエチレングリコール並び
にトリエチレングリコール製造プロセスにおいて副生ず
る蒸溜ボトムを用いることが出来る。Tetraethylene glycol can be obtained from distillation bottoms produced as a by-product in the production process of diethylene glycol and triethylene glycol.
実施例1 第−表に示す。Example 1 Shown in Table 1.
註 ′(1)添加量は油に対する重量%。Note '(1) Addition amount is weight % based on oil.
(2)乳化方法は油に乳化剤を溶解させ油に対し20チ
の水にプロペラで攪拌しつ\(650RPM)添加した
。(2) Emulsification method involved dissolving an emulsifier in oil and adding it to 20 inches of water while stirring with a propeller (650 RPM).
(3)乳化率は15分間静置后、水分離率O%をioo
%乳化率と見做す。(3) Emulsification rate is 0% water separation rate after standing for 15 minutes.
% emulsification rate.
実施例2 第二人に示す。Example 2 Show to a second person.
(1) 実験条件は実施例1に同じ。(1) Experimental conditions were the same as in Example 1.
Claims (2)
フェノールエーテル又はポリオキシエチレンアルキルエ
ーテル、第二成分としてオレイン酸、ナフテン酸、トー
ル油脂肪酸などの鎖状又は環状高級脂肪酸、第三成分と
してアルキルベンゼンスルフォン酸、ホリアルキルベン
ゼンスルフォン酸、石油スルフォン酸などの芳香族炭化
水素スルフォン酸のアルカリ又はアルカリ土類金属塩で
代表される油溶性スルフォン酸塩類又は第二成分のアル
カリ土類金属塩で代表される油溶性カルボン酸塩類の三
成分を組合わせて含有することを特長とする重油、軽油
、灯油、流動・ぐラフイノ、・やラフインワックス等の
石油製品の乳化剤組成物。(1) The first component is polyoxyethylene alkyl phenol ether or polyoxyethylene alkyl ether, the second component is chain or cyclic higher fatty acids such as oleic acid, naphthenic acid, tall oil fatty acid, etc., and the third component is alkylbenzenesulfonic acid, phosphoric acid, etc. Oil-soluble sulfonic acid salts represented by alkali or alkaline earth metal salts of aromatic hydrocarbon sulfonic acids such as alkylbenzene sulfonic acids and petroleum sulfonic acids, or oil-soluble carboxylic acids represented by alkaline earth metal salts of the second component. An emulsifier composition for petroleum products such as heavy oil, light oil, kerosene, liquid/grafino, and rough-in wax, which is characterized by containing a combination of the three components of salts.
ンクリコール、トリエチレングリコール又はテトラエチ
レングリコールを配合することを特長とする重油、軽油
、灯油、流動パラフィン、・ぞラフインワックス等の石
油製品の乳化剤組成物。(2) Petroleum products such as heavy oil, light oil, kerosene, liquid paraffin, and rough wax, which are characterized by blending noethylene glycol, triethylene glycol, or tetraethylene glycol as a solvent with the above emulsifier composition. Emulsifier composition.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57070660A JPS58186427A (en) | 1982-04-26 | 1982-04-26 | Emulsifying agent composition for petroleum product |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57070660A JPS58186427A (en) | 1982-04-26 | 1982-04-26 | Emulsifying agent composition for petroleum product |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS58186427A true JPS58186427A (en) | 1983-10-31 |
Family
ID=13438031
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP57070660A Pending JPS58186427A (en) | 1982-04-26 | 1982-04-26 | Emulsifying agent composition for petroleum product |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS58186427A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0247194A (en) * | 1988-08-08 | 1990-02-16 | Intevep Sa | Viscous hydrocarbon/water emulsion |
CN1329490C (en) * | 2004-09-08 | 2007-08-01 | 阎威凭 | Tail gas dust-laying agent of vehicle |
JP2019048979A (en) * | 2018-10-03 | 2019-03-28 | 有限会社エス・ピー・エイチ | Fatty acid magnesium-containing soap composition and method for producing the same |
-
1982
- 1982-04-26 JP JP57070660A patent/JPS58186427A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0247194A (en) * | 1988-08-08 | 1990-02-16 | Intevep Sa | Viscous hydrocarbon/water emulsion |
JPH0579278B2 (en) * | 1988-08-08 | 1993-11-01 | Intevep Sa | |
CN1329490C (en) * | 2004-09-08 | 2007-08-01 | 阎威凭 | Tail gas dust-laying agent of vehicle |
JP2019048979A (en) * | 2018-10-03 | 2019-03-28 | 有限会社エス・ピー・エイチ | Fatty acid magnesium-containing soap composition and method for producing the same |
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