JPS58161772A - Carburizing and brazing method of steel member - Google Patents

Carburizing and brazing method of steel member

Info

Publication number
JPS58161772A
JPS58161772A JP4386282A JP4386282A JPS58161772A JP S58161772 A JPS58161772 A JP S58161772A JP 4386282 A JP4386282 A JP 4386282A JP 4386282 A JP4386282 A JP 4386282A JP S58161772 A JPS58161772 A JP S58161772A
Authority
JP
Japan
Prior art keywords
carburizing
brazing
composite material
tin
copper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP4386282A
Other languages
Japanese (ja)
Inventor
Takao Tanaka
田中 隆男
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mazda Motor Corp
Original Assignee
Mazda Motor Corp
Toyo Kogyo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mazda Motor Corp, Toyo Kogyo Co Ltd filed Critical Mazda Motor Corp
Priority to JP4386282A priority Critical patent/JPS58161772A/en
Publication of JPS58161772A publication Critical patent/JPS58161772A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0222Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in soldering, brazing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)

Abstract

PURPOSE:To perform brazing and carburizing of steel members simultaneously, by forming a composite material to make the proportion of Cu, Sn within specified range in weight by using the first blank material consisting essentially of Cu and the second blank material consisting essentially of Sn and applying this material to the brazed part of steel members. CONSTITUTION:The first thin wiry material A consisting essentially of Cu and the second thin wiry material consisting essentially of Sn are brought close to each other and bound by a holding device to prevent separation, and a composite material C in which proportion of Cu and Sn is within the range of (85:15)- (65:35) in weight. This composite material C is placed near the upper part of brazed part 4 of steel members 2, 3, and the steel members 2, 3 are put in a carburizing and quenching furnace. After carburizing, the members are taken out from the carburizing and quenching furnace, and quenched. Thus, brazing and carburizing are carried out simultaneously.

Description

【発明の詳細な説明】 本発明は、鋼部材に対して浸炭とろう付を同時に行なう
鋼部拐の浸炭ろう付性に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to carburizing and brazing properties of steel parts in which carburizing and brazing are simultaneously performed on steel members.

たとえば、自動車の変速機に使用される歯車においては
、歯車の製作上の都合で直径の異なる複数の歯車部材を
各々別個に加工した後、これらの各歯車部材を接合して
一体の歯車に形成することが必要な場合がある。
For example, in the case of gears used in automobile transmissions, multiple gear members with different diameters are individually machined for manufacturing reasons, and then these gear members are joined to form an integrated gear. It may be necessary to do so.

この様な鋼部材の接合方法の一つとして、ろう付性があ
るが、さらに、このろう付性として孝炭焼人処理時の熱
を利用し、鋼部材のろう付を浸炭と同時に行なうことも
すてに試みられている(先行技術として、たとえば、実
公昭グロー、20/θ号公報参照)。この方法は、省エ
ネルギーに寄与し、また、工程が簡略であるという点に
おいて優れたものであるが、浸炭処理には最適な温度範
囲があり、該温度範囲においては使用できる従来のろう
材料は数種に限定され、かつ、限定されたろう材料をそ
のまま使用したのではろう付の低廉化と品質の安定化に
対し適用てきないという問題かある。すなわち、通常、
鋼部材の浸炭処理は200℃前後の温度にて定時間保持
されるが、上記温度で使用可能なろう材料としては、黄
銅ろう、銅〜 ・マンガンろう、銀ろうおよび耐銅ろう
などか考えられる。しかし、黄銅ろうは成分としての亜
鉛の蒸気圧が高いために容易に気化して浸炭処理の雰囲
気にとって有害であり、銅−マンガンろうはマンガンが
極めて酸化しやすいためろう付した製品の品質か不安定
となる。また、銀ろうは高価なため肘産化に適さない。
Brazing is one of the joining methods for such steel members, but it is also possible to braze the steel members at the same time as carburizing by using the heat from the charcoal firing process. This method has already been attempted (as a prior art, see, for example, Jikko Sho Glow, Publication No. 20/θ). This method is excellent in that it contributes to energy saving and is a simple process, but there is an optimal temperature range for carburizing, and there are several conventional brazing materials that can be used within that temperature range. There is a problem in that if the brazing material is limited to certain types and is used as it is, it cannot be applied to reduce the cost of brazing and stabilize the quality. That is, usually
The carburizing treatment of steel parts is maintained at a temperature of around 200°C for a certain period of time, and brazing materials that can be used at the above temperature include brass brazing, copper, manganese brazing, silver brazing, and copper-resistant brazing. . However, the high vapor pressure of zinc as a component in brass solder easily vaporizes and is harmful to the carburizing atmosphere, while in copper-manganese solder, manganese is extremely easily oxidized, which may affect the quality of the soldered product. It becomes stable. In addition, silver solder is expensive and is not suitable for producing elbows.

さらに、既存の青銅ろうは錫の含有量が76重着%以下
のため融点が900℃以上と高(浸炭とろう付を同時に
行なうことができない。融点を下げるために錫の含有量
を76重社%以上にすることも考えられるが合金成分と
して錫含有量を単に増加するだけでは合金中に金属間化
合物が析出して材料が脆くなり加工性が損なわれて線材
に形成できないという問題がある。
Furthermore, because the tin content of existing bronze solders is less than 76% by weight, the melting point is as high as 900°C or higher (carburizing and brazing cannot be performed at the same time.In order to lower the melting point, the tin content is 76% by weight). Although it is possible to increase the tin content to more than 2%, there is a problem that simply increasing the tin content as an alloy component causes intermetallic compounds to precipitate in the alloy, making the material brittle and impairing workability, making it impossible to form it into a wire rod. .

本発明は上記の問題点に鑑みてなされたものであって、
それぞれ別個の銅を主成分とする粉末、細線等の素材(
以下、第1素材という)と、錫を主成分とする同じく粉
末、細線等の素材(以下、第2素材という)とを組合せ
、かつ、その際に銅と錫の全体の成分割合が重量比で!
?6 : /6ないしl、、!;:13;になるように
第7素材と第2素材の配分を調整して複合材を形成し、
次いで、該複合材を鋼部材のろう骨部分に載置し、その
浸炭処理時に複合材を合金化してろう付と浸炭とを同時
に行なえるようにして、従来の問題点を解消することを
目的とするものである。
The present invention has been made in view of the above problems, and includes:
Separate copper-based powders, fine wires, and other materials (
(hereinafter referred to as the first material) and a material such as powder or thin wire that also has tin as its main component (hereinafter referred to as the second material), and at that time, the overall component ratio of copper and tin is in!
? 6: /6 to l,,! Adjusting the distribution of the seventh material and the second material so that ;:13; forms a composite material,
Next, the composite material is placed on the bran bone part of the steel member, and the composite material is alloyed during the carburizing process so that brazing and carburizing can be performed simultaneously, thereby solving the problems of the conventional method. That is.

以下、本発明の構成を実施例について図面に基ついて説
明する。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The configuration of the present invention will be described below with reference to the drawings.

本発明に使用する第1素材Aは粉末または細線に加工し
た純銅もしくは銅を主成分とする銅−錫2元合金で、銅
−錫合金のものは粉末の場合は双方の含有比率を特に問
題にしないが、細線の場合は該細線に加工するために錫
の含有量は76重け%以下にすることが好ましい。第2
素材Bは、粉末または細線に加工した純錫または錫を主
成分とする錫−銅2元合金で通常銅含有量はjθ重社%
以下である。
The first material A used in the present invention is pure copper processed into powder or fine wire, or a copper-tin binary alloy whose main component is copper, and when a copper-tin alloy is in the form of powder, the content ratio of both is particularly important. However, in the case of a thin wire, the tin content is preferably 76% by weight or less in order to process it into the thin wire. Second
Material B is pure tin processed into powder or fine wire, or a tin-copper binary alloy whose main component is tin, and the copper content is usually jθ Jusha%.
It is as follows.

上記第1素材Aと第2素材Bとを組合せて複合材Cを形
成する。複合材Cの形成にあたっては、該複合材形成後
の合金化と取扱い易さとを考慮して、第1素材Aおよび
第2素拐Bがそれぞれ細線の場合はより合せ、粉末どう
しの場合はペースト等の保持手段によって互い力i近接
し、がっ、離反しない状態に拘束された線材に形成する
。しかも、その組合せの際、複合材Cとしての銅と錫の
全体の成分割合か重量比で7?、f : /、3ないし
t、5:3.5の範囲内になるように予じめ第1素材と
第2素材の配分を調整しておく。また、画素材A、Bが
細線の場合には、ト記成分割合の範囲内で所望の比率に
設定するために、第1素材Aおよび第2素材Bに対して
銅めっきもしくは錫めっきを施すことにより適宜比率を
調整することもできる。銅と錫の成分割合をE記範囲に
限定したのは、銅に対して錫が76重量%以下では、浸
炭処理で複合材Cを合金化した際、銅−錫合金の融点が
高くて不適であり、また錫含有量が35重量%以上では
ろう付後の鋼部材のろう骨部分の強度が低く、かつ、錫
の社か多いとろう付に要する費用が高くなるという理由
による。
A composite material C is formed by combining the first material A and the second material B. When forming the composite material C, considering alloying and ease of handling after forming the composite material, if the first material A and the second material B are thin wires, they are twisted together, and if they are powders, they are pasted together. The wire rods are formed into wire rods that are restrained by a holding means such as the like so that they are brought close to each other and do not separate. Moreover, in that combination, is the overall component ratio or weight ratio of copper and tin as composite material C 7? The distribution of the first material and the second material is adjusted in advance so that it falls within the range of , f: /, 3 to t, 5:3.5. In addition, if the image materials A and B are thin lines, copper plating or tin plating is applied to the first material A and the second material B in order to set the desired ratio within the range of component ratios listed above. By doing so, the ratio can be adjusted as appropriate. The reason for limiting the component ratio of copper and tin to the range E is because if tin is less than 76% by weight relative to copper, the melting point of the copper-tin alloy will be unsuitable when alloyed with composite material C by carburizing treatment. This is because if the tin content is 35% by weight or more, the strength of the brazed bone portion of the steel member after brazing will be low, and if the tin content is large, the cost required for brazing will be high.

このようにして複合材Cを形成した後は、該複合側を所
要長さに切断し、次いで、鋼部材2,3のろう骨部分4
の上部近傍に配置し、この鋼部材−2,3をガス浸炭焼
入炉(図示省略)中に入れて浸炭処理を行なう。この浸
炭処理において、鋼部材2,6は200℃AiT後の温
度に所定時間保持されるので、その際に、まず複合側C
のうちの第2素材Bが溶融して第/素材Aの表面を覆い
、錫か第/素材A中に拡散して合金化が促進されるとと
もに、第/素材Aの融点か低下し第1素材Aも溶融して
第1素材Aと第2素材Bが混り合い、ぬれ特性により鋼
部材2,3のろう骨部分4全而に行きわたる。引き続い
て鋼部材2,3をガス浸炭焼入炉から取出して焼入する
ことによりろう付と浸炭が同時に完了した製品1が得ら
れる。
After forming the composite material C in this way, the composite side is cut to a required length, and then the wax bone portions 4 of the steel members 2 and 3 are
The steel members 2 and 3 are placed in a gas carburizing and quenching furnace (not shown) and carburized. In this carburizing process, the steel members 2 and 6 are held at a temperature of 200°C after AiT for a predetermined time, so first, the composite side C
The second material B melts and covers the surface of the first material A, and tin diffuses into the first material A to promote alloying, and the melting point of the first material A decreases. The material A is also melted, and the first material A and the second material B are mixed, and due to their wetting properties, they are spread throughout the wax bone portions 4 of the steel members 2 and 3. Subsequently, the steel members 2 and 3 are taken out of the gas carburizing and quenching furnace and quenched, thereby obtaining a product 1 in which brazing and carburizing have been completed simultaneously.

さらに上記実施例に基づく実験例を次に示す。Furthermore, an experimental example based on the above embodiment will be shown below.

〈複合材C〉 第1図参照。<Composite material C> See Figure 1.

9fJ/素材A;0/IIIII+直径の錫めっきした
純銅線。
9fJ/Material A; 0/III+ diameter tin-plated pure copper wire.

第2素材” ; 0 / trm直径の純錫線。Second material: Pure tin wire with a diameter of 0/trm.

第1素材Aを2本と第2素材を2本とを互いにより合せ
て形成した。より合せ後の銅と錫の成分割合は、?0 
: 20 (重量比)である。
Two pieces of the first material A and two pieces of the second material were twisted together and formed. What is the composition ratio of copper and tin after twisting? 0
: 20 (weight ratio).

く鋼部材2,3〉 転動画車部材2;鋼種JIS規格SCR,2,2クラッ
チ歯車部材3;鋼種JIS規格SCR,)、2この両歯
屯部材2,6の嵌合部をろう骨部分4とし、該ろう骨部
分の上部に所要長さに切断した上記複合材Cをリング状
に配置して浸炭焼入炉中に入れ、浸炭ろう付処理を行な
った。
Steel members 2, 3> Rolling wheel member 2; Steel type JIS standard SCR, 2, 2 Clutch gear member 3; Steel type JIS standard SCR, 4, the above-mentioned composite material C cut into a required length was arranged in a ring shape on the upper part of the wax bone portion, placed in a carburizing and quenching furnace, and carburizing and brazing treatment was performed.

く浸炭およびろう材処理条件〉 ガス浸炭焼入炉中雰囲気;温度230℃、露点−6℃、
吸熱ガス中。
Carburizing and brazing metal treatment conditions> Atmosphere in gas carburizing and quenching furnace; temperature 230°C, dew point -6°C,
In endothermic gas.

保持時間;3時間 上記条件のもとで両歯車2,3を浸炭ろう付し、一体成
形した歯車1のろう骨部分4のせん断強度を測定した。
Holding time: 3 hours Both gears 2 and 3 were carburized and brazed under the above conditions, and the shear strength of the wax bone portion 4 of the integrally molded gear 1 was measured.

その結果、せん断強度は/♂6Ky/rdか得られた。As a result, a shear strength of /♂6Ky/rd was obtained.

これは所要のせん断強度を充分に満足している。This sufficiently satisfies the required shear strength.

以上のように、本発明によれば銅を主成分とする第1索
材と、錫を主成分とする第2素材とを銅と錫の成分割合
が重3量比で?、5:/jないしA、5:36になるよ
うに保持手段で拘束して複合材を形成し、該複合材を鋼
部材のろう骨部分に適用して鋼部材の浸炭処理時に複合
材を合金化し、ろう付と浸炭とを同時に行なえるように
したので、従来のろう材料を使用して行なう浸炭ろう寸
法に比べてろう付に要する費用か人1]に低減され、ま
た、複合材は浸炭処理時の温度で確実に溶融し、かつ、
ろう付後のろう骨部分の接合強度も確保され、これによ
って製作された部品の品質が安定化する等、従来の方法
では達成できなかったろう付の低廉化と品質の安定化が
同時に可能となるという優れた効果がある。
As described above, according to the present invention, the first rope material containing copper as a main component and the second material containing tin as a main component have a composition ratio of copper to tin in a weight ratio of 3 to 3. , 5:/j to A, 5:36 to form a composite material by restraining it with a holding means, and applying the composite material to the wax bone portion of the steel member to apply the composite material during the carburizing process of the steel member. Since the alloy is alloyed and brazing and carburizing can be performed simultaneously, the cost required for brazing is reduced to 1] compared to carburizing using conventional brazing materials. Reliably melts at the carburizing temperature, and
The joint strength of the wax bone part after brazing is also ensured, which stabilizes the quality of the manufactured parts, making it possible to reduce the cost of brazing and stabilize quality at the same time, which was not possible with conventional methods. This has an excellent effect.

【図面の簡単な説明】[Brief explanation of drawings]

図面は本発明の実施例を示し、第7図はより合せて形成
した複合材の斜視図、第2図は鋼部材に複合材を適用し
た状態を示す縦断面図、第3図は浸炭ろう付処理後の一
体化された製品の縦断面図である。
The drawings show embodiments of the present invention, FIG. 7 is a perspective view of a composite material formed by twisting, FIG. 2 is a vertical cross-sectional view showing a state in which the composite material is applied to a steel member, and FIG. 3 is a carburized solder. FIG. 3 is a vertical cross-sectional view of the integrated product after the application process.

Claims (1)

【特許請求の範囲】[Claims] (1)銅を主成分とする粉末、細線等の第/素材と、錫
を主成分とする粉末、細線等の第2素材とか互いに近接
し、かつ、離散しない状態に保持する保持手段で拘束さ
れ、かつ、全体の銅と錫の成分側合が重量比でj’6 
: /6ないし乙j:3.sの範囲内にある複合材を形
成し、該複合材を鋼部材のろう付部分に載置し、浸炭炉
に入れて加熱して鋼部材のろう付と浸炭とを同時に行な
うことを特徴とする鋼部材の浸炭ろう付性。
(1) A primary material such as a powder or thin wire containing copper as a main component and a second material such as a powder or thin wire containing tin as a main component are held close to each other and restrained by a holding means that holds them in a non-discrete state. and the overall copper and tin component ratio is j'6 in terms of weight ratio.
: /6 to Otsuj: 3. The method is characterized by forming a composite material within the range of s, placing the composite material on the brazing part of the steel member, putting it in a carburizing furnace and heating it, and brazing and carburizing the steel member at the same time. carburizing brazing properties of steel parts.
JP4386282A 1982-03-18 1982-03-18 Carburizing and brazing method of steel member Pending JPS58161772A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4386282A JPS58161772A (en) 1982-03-18 1982-03-18 Carburizing and brazing method of steel member

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4386282A JPS58161772A (en) 1982-03-18 1982-03-18 Carburizing and brazing method of steel member

Publications (1)

Publication Number Publication Date
JPS58161772A true JPS58161772A (en) 1983-09-26

Family

ID=12675503

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4386282A Pending JPS58161772A (en) 1982-03-18 1982-03-18 Carburizing and brazing method of steel member

Country Status (1)

Country Link
JP (1) JPS58161772A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110894585A (en) * 2018-09-12 2020-03-20 台州鑫宇铜业股份有限公司 Copper bar heat treatment process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110894585A (en) * 2018-09-12 2020-03-20 台州鑫宇铜业股份有限公司 Copper bar heat treatment process

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