JPS58132137A - Highly transparent fabric - Google Patents
Highly transparent fabricInfo
- Publication number
- JPS58132137A JPS58132137A JP57011868A JP1186882A JPS58132137A JP S58132137 A JPS58132137 A JP S58132137A JP 57011868 A JP57011868 A JP 57011868A JP 1186882 A JP1186882 A JP 1186882A JP S58132137 A JPS58132137 A JP S58132137A
- Authority
- JP
- Japan
- Prior art keywords
- fabric
- fibers
- polyamide
- highly transparent
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Knitting Of Fabric (AREA)
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】 不発明は、m透明性布帛tこ関するものである。[Detailed description of the invention] The invention relates to transparent fabrics.
さらに詳しくは、酷透明性と高東♂鮮明性を有する布帛
に関するものである。More specifically, the present invention relates to a fabric having excellent transparency and high clarity.
最近布帛、特に女注衣料用布吊tこおいては、片体の隠
幣、体表等の一義的な目的だけでは満足されず、高ファ
ッション化への兆しが着しい。Recently, fabrics, especially cloth hangers for women's clothing, are no longer satisfied with the primary purpose of concealment, body surface, etc., and there are signs that they are becoming more fashionable.
中でも肌を美しく見せる様な部位、待tこファンデーV
ヨン、ランジェリ−、ストッキング等の分野においては
より透明性が望まれる傾向がある。従来これらを満足す
る方策として、例えば使用する繊維のトータル繊度を減
少させる方法あるいはトータル繊度を同じtこして単糸
数を減らす方法等が試みられて来た。しかるに前者1こ
おいては布帛の強度の点から問題があり、また後者eこ
おいては単糸数を減らすeこつれ布帛の柔軟性が損われ
るといった欠点が生じ、それらを犠牲にしなければ透明
性の良い布帛が得られなかった。Particularly, the parts that make your skin look beautiful, Waittoko Foundation V
There is a tendency for greater transparency to be desired in fields such as yongs, lingerie, and stockings. Conventionally, attempts have been made to satisfy these requirements by, for example, reducing the total fineness of the fibers used, or reducing the number of single yarns while maintaining the same total fineness. However, in the former case, there is a problem in terms of the strength of the fabric, and in the latter case, there are disadvantages such as reducing the number of single threads and damaging the flexibility of the tangled fabric. A fabric with good properties could not be obtained.
本発明者らはこのような従来技侑の欠点を解消するため
鋭意慣討した結果、本発明tこ至ったものである。した
がって、本発明の目的は一度及び未軟性を損なうことな
く透明性tこすぐれ、かっ采已爵明性Eこも丁ぐれた布
帛゛を提供することtこあり。The inventors of the present invention have made extensive studies to overcome the drawbacks of the conventional techniques, and have thus arrived at the present invention. Therefore, it is an object of the present invention to provide a fabric which has excellent transparency and excellent clarity without impairing its softness.
即ち本iv明り布帛1工下記一般式(1)または(2)
でボさイLるジアミド化合物を0005〜2.O7[j
llTo舌有するポリアミド繊維を有することを要旨と
するものであQo
〔た7こし、R1’ 、 R4は汰素原子数10〜20
のアルキル裁、nは1〜10の歴数を示ス〕以下、本発
明を更に具体的に説明する。That is, the following general formula (1) or (2)
The bulky diamide compound is 0005-2. O7[j
The gist is that the polyamide fiber has a polyamide fiber having a tongue.
where n is a number of 1 to 10] The present invention will be described in more detail below.
本究明C・こ3いて用いられるジアミド化合物は上記一
般式(1)または(2)に示される構造式を有する化B
’411Jであり、こわらはシカフレポン酸とアルキル
モノアミンとの反応により、あるいはアルキレンジアミ
ンと七ツカlレポン酸との反応により調製することがで
きる。代表的なジアミンとしてはメチレンジアミン、エ
チレンジアミン、グロビレンジアミン、ブチレンジアミ
ンがあり、炭X数1〜10までのアルキレンジアミンが
含まれる。また、代表的なジカルボン酸としてはコハク
酸、アジピン酸、セパシン酸であす、炭素数2〜12ま
でのジカルボン酸が含まれる。The diamide compound used in this study C.3 has the structural formula shown in the above general formula (1) or (2).
'411J, and the stiffness can be prepared by the reaction of cicafreponic acid with an alkyl monoamine, or by the reaction of an alkylene diamine with 7kaleponic acid. Typical diamines include methylene diamine, ethylene diamine, globylene diamine, and butylene diamine, including alkylene diamines having 1 to 10 carbon atoms. Typical dicarboxylic acids include succinic acid, adipic acid, sepacic acid, and dicarboxylic acids having 2 to 12 carbon atoms.
アルキルモノアミンとしてはオクタデシルアミン、メチ
ルオクタデンルアミン、エチルオクタデンルアミン等の
ように、炭素数10〜20のアルキル基を有する1敏ア
ミン及びそれらが更tこメチル基、エチル基で置換され
た2敢プミンが含まれる。Examples of alkyl monoamines include monoamines having an alkyl group having 10 to 20 carbon atoms, such as octadecylamine, methyloctadenylamine, ethyloctadenylamine, etc., and monoamines having alkyl groups of 10 to 20 carbon atoms, and 2-monoamines substituted with methyl or ethyl groups. Contains Ganpumin.
モノカルボン酸としてはツウリン酸、パルミチン酸、ス
テアリン酸等、炭素数11〜21のアルキルモノアミン
酸が含まれる。Monocarboxylic acids include alkyl monoamic acids having 11 to 21 carbon atoms, such as turic acid, palmitic acid, and stearic acid.
本発明でいうポリアミド繊維とは分子鎖中にアミド結合
を有する線状制分子、たとえはポリ力グフミド、ポリへ
キサメチレンアジパミドを紡出したwR維である。The polyamide fibers used in the present invention are wR fibers spun from linear molecules having amide bonds in their molecular chains, such as polyglypamide and polyhexamethylene adipamide.
本托明のジアミド化合物をポリアミドtこ添加底台する
方法としては、ポリアミドの血合時に、厘合糸内tこ添
加する方法、ポリアミド繊維グに添加する方法等がある
が、いずわにしても、これらを浴融紡出したとき、ジア
ミド化合物がポリアミド中tこ均−tこ分散されている
ことが重要である。Methods for adding the diamide compound of the present invention to polyamide fibers include adding it to the folded fibers when the polyamide is combined, and adding it to the polyamide fibers. Also, when these are bath-melt spun, it is important that the diamide compound is uniformly dispersed in the polyamide.
ジアミド化合物の添加量はポリアミドに対して、u、o
、os〜2.0皿量%の範囲(こする必要があり、00
05厘t%未満では透明性効果が小さく、また、2.O
JM量%を越えるとジアミド化合物とポリアミドとの相
溶性が悪くなり、かえって透明性を損なう結果となる。The amount of diamide compound added is u, o relative to polyamide.
, os ~ 2.0 dish volume% range (needs to be rubbed, 00
If it is less than 0.05 t%, the transparency effect will be small, and 2. O
If the amount exceeds the JM amount %, the compatibility between the diamide compound and the polyamide will deteriorate, resulting in a loss of transparency.
勿舖、IIJ記一般式(1) 、(2)以外のアミド化
合物、たとえはステアリン酸アミド、テレフタル酸アミ
ド等では本托明の目的を連成することができない。Of course, the object of the present invention cannot be achieved with amide compounds other than the general formulas (1) and (2) of IIJ, such as stearic acid amide and terephthalic acid amide.
不弁明のジアミド化合物をポリアミドに添加し、これを
紡出して繊維にすることにより、得られた繊維はη・な
りの透明性を有するが、更1ここの繊維を布帛1こした
場合、その効果が極めて顕著tこなる。By adding an unexplained diamide compound to polyamide and spinning it into fibers, the resulting fibers have a transparency of η. The effect is extremely noticeable.
ここでいう布帛とは繊物、編物あるいはこれらを組合せ
たものであり、布帛を構成する繊維としては本発明のジ
アミド化合物?添加したポリアミド繊維が少なくとも便
用され℃いる必要がある。したがって、布帛を構成する
繊維のすべてが本発明のポリアミド繊維であってもよい
し、また、他の天然繊維、合成繊維と本究明のポリアミ
ド繊維とで布帛を構成していてもよい。The fabric here refers to fibers, knitted fabrics, or a combination thereof, and the fibers that make up the fabric include the diamide compound of the present invention. It is necessary that the added polyamide fibers be kept at least 10°C. Therefore, all of the fibers constituting the fabric may be the polyamide fibers of the present invention, or the fabric may be composed of other natural fibers, synthetic fibers, and the polyamide fibers of the present invention.
以下、実施例を挙げて本発明の詳細な説明する。Hereinafter, the present invention will be explained in detail by giving Examples.
実施例1
硫酸相対粘度2.85のナイロン6チツグに0.3厘1
1%のエチレンビスステアリン酸アミド(ライオンアク
ゾ社製ロアーモワックスEES”)粉末を痕加し、よ(
混合したのち混合刃を285℃で溶趨俊、[L5誠の孔
径を6個有する口金から押し出し、800 m7分の速
度で捲き取り、次いでA 51fitこ延伸して単糸数
6の60デニールのマルチフィラメントを得た。同様の
方法でステアリンはアミド、テレフタル酸アミドおよび
ブランクのマルチフィラメントを得た。Example 1 0.3 liter of sulfuric acid relative viscosity 2.85 nylon 6
Add 1% ethylene bisstearic acid amide (Lion Akzo Roarmo Wax EES) powder, and
After mixing, the mixed blade was melted at 285°C, extruded through a nozzle with 6 L5 hole diameters, rolled up at a speed of 800 m7, and then drawn with A51 fit to form a 60 denier mulch with a single thread count of 6. I got the filament. Stearin amide, terephthalic acid amide and blank multifilaments were obtained in a similar manner.
侍らねたマルチフィラメントをシリンダー径51/2イ
ンチ、針数520本の九mmを使用し、送り糸長50イ
ンチ/周で筒編を編成した。梢練後の透明性評価結果を
第1表に示す。A tube knit was knitted using a 9 mm cylinder with a cylinder diameter of 5 1/2 inches and 520 needles, and a feed yarn length of 50 inches/circumference. Table 1 shows the transparency evaluation results after kneading.
第 1 表
圧1a:逍明性評価は水準4(プランクンを基準とした
一対比軟1六で実施
第1表で示したように本発明の布帛(水準1)は従来の
布帛(水準4ンと比較して透明性が非常tこ優れている
。またこの布帛は従来品に比べて物理的性貿の点で何ら
父る所がな(、しかも従来品より布帛の柔軟性という点
て浸れていた。1st surface pressure 1a: Clarity evaluation was carried out at level 4 (16 vs. The transparency is extremely superior compared to conventional products.Also, compared to conventional products, this fabric has no disadvantages in terms of physical intercourse (in addition, the fabric is more flexible than conventional products). was.
実施例2
実施例1で得られた、本発明の布帛(水準1)と従来布
帛(水準4)を常法に便って染色し、分光色差計で明度
彩度を測定した。染料一度を変更し2水準共に彩度が最
高値となる栗色条件で染色した布帛tこついての測定結
果を第2表eこ示す。Example 2 The fabric of the present invention (Level 1) and the conventional fabric (Level 4) obtained in Example 1 were dyed using a conventional method, and the brightness and saturation were measured using a spectrophotometer. Table 2 shows the measurement results for a fabric that was dyed under maroon conditions where the dye was changed once and the saturation reached the highest value for both levels.
第2表
を関知した。緩町よkiunter色度凶(こ芯けるり
、a%bllt1である。I was aware of Table 2. Yurumachi yo kiunter chromaticity evil (this is a%bllt1).
仝透明り布帛(水準1)は第2表で示したよう(こ、従
来布帛(水準4)と比すして、明度カー同じであるが色
相彩度力;品(、染色鮮明性eこ優lLでいる。As shown in Table 2, the transparent fabric (Level 1) has the same brightness, color saturation, quality, and dye clarity as compared to the conventional fabric (Level 4). I'm LL.
Claims (1)
物を0005〜2.0厘量%含有するポリアミド繊維を
有することを特徴とする高透明性布帛。 〔ただし、R,、R4は炭T:IJ3を子畝10〜20
のアルキル基、R2、R3は水素原子、メチIし基また
はエチル基、n 121.1〜I QのyWkを示す〕[Scope of Claims] A highly transparent fabric characterized by having polyamide fibers containing 0005 to 2.0 weight percent of a diamide compound represented by the following general formula (1) or (2). [However, R,, R4 is charcoal T: IJ3 with 10 to 20 ridges
an alkyl group, R2 and R3 are a hydrogen atom, a methyl group or an ethyl group, and n121.1 to yWk of IQ]
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57011868A JPS58132137A (en) | 1982-01-29 | 1982-01-29 | Highly transparent fabric |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57011868A JPS58132137A (en) | 1982-01-29 | 1982-01-29 | Highly transparent fabric |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS58132137A true JPS58132137A (en) | 1983-08-06 |
Family
ID=11789695
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP57011868A Pending JPS58132137A (en) | 1982-01-29 | 1982-01-29 | Highly transparent fabric |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS58132137A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6241315A (en) * | 1985-08-12 | 1987-02-23 | Toray Monofilament Co Ltd | Polyamide monofilament |
JPS62170515A (en) * | 1986-01-23 | 1987-07-27 | Toray Monofilament Co Ltd | Polyamide monofilament |
JPH0418117A (en) * | 1990-05-02 | 1992-01-22 | Toray Ind Inc | Highly clear color-developable polyamide fiber and production thereof |
JPH0418118A (en) * | 1990-05-07 | 1992-01-22 | Toray Ind Inc | Polyamide fiber having excellent transparency and clear dyeability and production thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53137253A (en) * | 1977-04-21 | 1978-11-30 | Mitsubishi Chem Ind Ltd | Polyamide composition |
-
1982
- 1982-01-29 JP JP57011868A patent/JPS58132137A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53137253A (en) * | 1977-04-21 | 1978-11-30 | Mitsubishi Chem Ind Ltd | Polyamide composition |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6241315A (en) * | 1985-08-12 | 1987-02-23 | Toray Monofilament Co Ltd | Polyamide monofilament |
JPS62170515A (en) * | 1986-01-23 | 1987-07-27 | Toray Monofilament Co Ltd | Polyamide monofilament |
JPH0418117A (en) * | 1990-05-02 | 1992-01-22 | Toray Ind Inc | Highly clear color-developable polyamide fiber and production thereof |
JPH0418118A (en) * | 1990-05-07 | 1992-01-22 | Toray Ind Inc | Polyamide fiber having excellent transparency and clear dyeability and production thereof |
JPH076089B2 (en) * | 1990-05-07 | 1995-01-25 | 東レ株式会社 | Polyamide fiber excellent in transparency and dye vivid color development and method for producing the same |
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