JPS58110905A - Combustion device - Google Patents

Combustion device

Info

Publication number
JPS58110905A
JPS58110905A JP56213460A JP21346081A JPS58110905A JP S58110905 A JPS58110905 A JP S58110905A JP 56213460 A JP56213460 A JP 56213460A JP 21346081 A JP21346081 A JP 21346081A JP S58110905 A JPS58110905 A JP S58110905A
Authority
JP
Japan
Prior art keywords
combustion
exhaust gas
catalyst
combustion exhaust
reduction catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP56213460A
Other languages
Japanese (ja)
Inventor
Nobuyuki Kanehara
金原 信行
Yoshifumi Moriya
好文 守屋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP56213460A priority Critical patent/JPS58110905A/en
Publication of JPS58110905A publication Critical patent/JPS58110905A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C13/00Apparatus in which combustion takes place in the presence of catalytic material

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Gas Burners (AREA)

Abstract

PURPOSE:To realize a reduction in NOx (in particular NO2) generation desirable in heating device for domestic use by techniques of performing a complete premixture surfce combustion, preventing an air flow into a burning surface, providing a reductive catalyst in a combustion exhaust gas passage and maintaining the temperature of the catalyst at optimum values. CONSTITUTION:A burner 1 which performs the complete premixture surface combustion is used. A combustion chamber 7 of the burner 1 has a sealed structure which never permits a secondary air to enter the burning surface. At a terminal end of the combustion exhaust gas passage 8 in the downstream of the combustion chamber 7, the reductive catalyst 9 of a transition metal and the like is provided. The reductive catalyst 9 is maintained at optimum temperatures by a method wherein a part of the combustion exhaust gas having passed through the catalyst 9 is led by a duct 10 to the upstream of the catalyst 9 in the combustion exhaust gas passage 8.

Description

【発明の詳細な説明】 、本発明は燃焼装置、特に室内閉放型の暖房器具等にお
ける排ガスの清浄比に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to the cleaning ratio of exhaust gas in combustion devices, particularly indoor closed type heating appliances.

従来の家庭用燃焼器具のバーナはブンゼンバーナが用い
られていたのでNOx値が高いといった欠截を有してい
た。従、りて、暖房器具等の室内で長時間使用する器具
では、低NOx燃焼であるシュバンクバーナ等の予混合
バーナが用いられたものが多かった。
Conventional burners for household combustion appliances used Bunsen burners, which had the drawback of high NOx values. Therefore, in many appliances such as heating appliances that are used indoors for a long time, premix burners such as Schwank burners, which have low NOx combustion, have been used.

しかしながら、ンユバンクノ(−す等の従来低NOxバ
ーナといわれていた)く−すでも、近年の住宅の気密性
を考えると十分に低Nox(ヒが達成されているとはい
えず、特に人体へ悪影#金及ぼすことが明らかなNO2
が排気ガスの、NOxに占める割合が大きいといりた欠
点をイ」シていた。その理由は明らかVこなりていない
が、シュノ(ンクノく−す等予混合表面燃焼を行うバー
ナでは、雰囲気酸素濃変低下時にも安定燃焼が得られる
様に燃焼面に2次空気を供給する手段がとられていたの
で、2次空気による空気流によって燃焼ガスが冷却され
、燃焼ガス中のNoがNo2に酸「ヒされる点と、2次
空気が供給されることにより燃焼ガス中の02瞼が増大
して、NO2りSらNO2へと酸[ヒが促進されるへが
考えられている。3 前記欠点を改良する手段としてNOx fz 、771
元しN2と02に分解する手段が考えられているが、ア
ンモニアガス、−酸「ヒ炭素といた有害ガスで還元する
もので、家庭、用燃焼器具に用いるにはその有害ガスの
処理も必要となり実用「上出来ないものでありた。さら
に、No2を蜀に還元する効果を有する触媒も考えられ
ているが、燃焼器具に効果的に適用する手段が確立され
ていないのでNO2からNo−5還元後すぐN02へ酸
[ヒすることもあったΩ一方、工業用燃焼装置では、燃
焼排気ガスそ燃焼室に再循環し、燃焼温度をFげ低NO
x (ヒを図る方法が実用[ヒされているが、家庭用の
室内開放型の暖房器具に適用するには、寸だまだNOx
値が高いものであった。
However, considering the airtightness of homes in recent years, it cannot be said that even the burners used in the past have achieved sufficiently low NOx levels, especially when it comes to the human body. Bad influence #NO2 that clearly affects money
However, the drawback was that the proportion of NOx in the exhaust gas was large. The reason for this is that V is not clearly achieved, but in burners that perform premixed surface combustion, such as those used in burners, secondary air is supplied to the combustion surface so that stable combustion can be obtained even when the oxygen concentration of the atmosphere is low. As measures were taken, the combustion gas was cooled by the airflow caused by the secondary air, and the point at which No. 2 in the combustion gas was oxidized by the No. 02 It is thought that the enlargement of the eyelids promotes acid production from NO2 to NO2.3 NOx fz, 771 as a means to improve the above drawbacks.
A method of decomposing the original into N2 and 02 has been considered, but it is reduced with harmful gases such as ammonia gas, -acid and arsenic, and it is necessary to process the harmful gases in order to use them in household combustion appliances. In addition, a catalyst that has the effect of reducing No2 to Shu has been considered, but a method for effectively applying it to combustion equipment has not been established, so it has been difficult to convert NO2 to No-5. On the other hand, in industrial combustion equipment, the combustion exhaust gas is recirculated to the combustion chamber to lower the combustion temperature and reduce the NO
x (Although methods to reduce NOx emissions have been put into practical use, it is still difficult to apply them to open indoor heating equipment for home use.)
The value was high.

本発明は、前記従来の欠点を改良し、家庭用の暖房器具
に適した、低NOx 、特にN02の低い燃焼装置を提
供せんとすることを目的とする0本発明は、完全予混合
表面燃焼バーナを用いて低NOx (ヒを図ると共に、
燃焼室の燃焼面へ空気の流入を防止した密閉構造とする
ことにより幻からNO2への酸[ヒ率を近減し、かつ、
燃焼室後流の排ガス通路中に遷移金属等の還元触媒を設
け、かつ、燃焼室後流の前記還元触媒上流に燃焼排気ガ
ス又は予熱空気を導ひくことにより、還元触媒の雰囲気
温度を還元及び、還元後の再eel rrIll、’i
防止する上で最も効果的な温明V(設定し、低NOx 
(ヒ、低N02rヒを図ったものである。
The present invention aims to improve the above-mentioned conventional drawbacks and provide a low NOx, especially low N02 combustion device suitable for home heating appliances. In addition to aiming for low NOx using burners,
By adopting a sealed structure that prevents air from flowing into the combustion surface of the combustion chamber, the rate of acid conversion from phantom to NO2 is almost reduced, and
By providing a reduction catalyst such as a transition metal in the exhaust gas passage downstream of the combustion chamber, and by guiding combustion exhaust gas or preheated air upstream of the reduction catalyst downstream of the combustion chamber, the atmospheric temperature of the reduction catalyst can be reduced and , re-eel rrIll after reduction, 'i
The most effective way to prevent NOx
(This is aimed at low N02r.)

以下、本発明の一実@例について、図面に基づき説明す
る。
Hereinafter, an example of the present invention will be explained based on the drawings.

第1回灯、本発明全ガスストーブ4c4用した場合の一
実施例である。図中1は完全予混舎人面燃焼を行うバー
ナであり、ガスノズル2は前記バーナ1の混合管人口3
と対向して設けられており、ガスノズル2から噴出した
ガスは、ガス流のエジェクター効果で燃焼に必要な空気
と共に混合気として混合管人口3から混合気室4へ導か
れ、均圧となりて金網炎口部で表面燃焼を行う。バーナ
1の外筒6は耐熱ガラスで構成されており、赤熱した金
網炎口部5の輻射熱を透過放熱する。7は燃焼室であり
、燃焼面に2次空気が流入しない様に密閉構造となりて
いる。8は燃焼室7の下流の燃焼排気ガス通路であり、
その終端に遷移金属等からなる還元触媒9が設けられて
おり、#J記還元触媒9を通過後の燃焼排気ガスの一部
を導管1oで、前記燃焼排気ガス通$8の還元触媒9の
上、席に導ぐ様になっている。尚、燃焼排気ガス通路8
け燃焼排気ガスのドラフト力によりて負圧になっている
ので吸引力があり、還元触媒9を通過後の燃焼排気ガス
の1部を吸引することが可能であり、還元触媒温度を効
果的な温度に設定できる。
The first light is an example of the case where the all-gas stove 4c4 of the present invention is used. In the figure, 1 is a burner that performs completely premixed combustion, and the gas nozzle 2 is the mixing tube 3 of the burner 1.
The gas ejected from the gas nozzle 2 is guided as a mixture from the mixing tube 3 to the mixture chamber 4 along with the air necessary for combustion due to the ejector effect of the gas flow, and the pressure is equalized and the wire mesh Surface combustion is performed at the flame mouth. The outer cylinder 6 of the burner 1 is made of heat-resistant glass, and transmits and radiates the radiant heat of the red-hot wire mesh flame port 5. 7 is a combustion chamber, which has a sealed structure to prevent secondary air from flowing into the combustion surface. 8 is a combustion exhaust gas passage downstream of the combustion chamber 7;
A reduction catalyst 9 made of a transition metal or the like is provided at its terminal end, and part of the combustion exhaust gas after passing through the reduction catalyst 9 marked #J is passed through a conduit 1o to the reduction catalyst 9 of $8. The top is designed to lead you to your seat. In addition, the combustion exhaust gas passage 8
Since the pressure is negative due to the draft force of the combustion exhaust gas, there is a suction force, and it is possible to suck a part of the combustion exhaust gas after passing through the reduction catalyst 9, thereby effectively controlling the temperature of the reduction catalyst. You can set the temperature.

前記本実施列によれば、均一な予混合表面燃焼を行って
いるので局部的な高温域の発生を防止できるので低NO
x (ヒが達成されると共に、燃焼室内に2次空気の流
入を防止したのでNoからNo2への酸[ヒを減少させ
るこ七ができる。
According to this embodiment, since uniform premixed surface combustion is performed, it is possible to prevent the occurrence of localized high temperature areas, resulting in low NO
x (2) was achieved, and since the inflow of secondary air into the combustion chamber was prevented, it was possible to reduce the amount of acid from No. 2 to No. 2.

さらに、ステンレス鋼、鉄クロム鋼、モリブデン鋼とい
った遷移金属系の材Rueoo℃〜”s o o℃の高
温帯でNO2を幻に還元を促進する効果があるものであ
るっ燃焼排気ガスは、燃焼帯中ではほとんどNoであり
、その後@度低下と共に、NO2へと酸rとが進む。
In addition, transition metal materials such as stainless steel, iron chromium steel, and molybdenum steel have the effect of promoting the reduction of NO2 in the high-temperature range from 200°C to 200°C. In the zone, it is mostly No, and then as the temperature decreases, the acid r progresses to NO2.

また本実施列では燃−焼室7内へ空気の流入を防d−シ
ているので、燃焼排ガス温度は比較的高いので、燃焼排
ガス通路8ではNOの比率が高い。燃焼排ガス通路8′
ff:出て室内空気と混ざる時にNO2へと酸(Bが進
むので、最も効果的に還元触媒9を用いるには、還7し
効果の期待出来る最も低い温度に触媒位置を設定するこ
とによって、触媒通過後の酸化を含めて最も低No2r
ヒが達成出来ることになる。すなわち、燃焼排気ガス通
路8にNo2からNoへの還元全促進する還元触媒9を
設け、かつ、還元触媒雰囲気温度を還元効果があり、か
つ、還元触媒9を通過にNoからNO2への再re−(
BKなる様に燃焼排気ガスを専びくことによりて、効果
的に低N02rヒが図れるものである。
Furthermore, in this embodiment, since air is prevented from flowing into the combustion chamber 7, the temperature of the combustion exhaust gas is relatively high, so the ratio of NO in the combustion exhaust gas passage 8 is high. Combustion exhaust gas passage 8'
ff: When the acid (B) comes out and mixes with the indoor air, it progresses to NO2, so in order to use the reduction catalyst 9 most effectively, set the catalyst position at the lowest temperature where the reduction 7 effect can be expected. Lowest No2r including oxidation after passing through the catalyst
This means that H can be achieved. That is, the combustion exhaust gas passage 8 is provided with a reduction catalyst 9 that completely promotes the reduction of No. 2 to No. At the same time, the reduction catalyst atmosphere temperature is reduced to have a reducing effect, and the re-reduction of No. to NO. −(
By exclusively using the combustion exhaust gas as BK, it is possible to effectively reduce N02r.

第2図に本発明を開放型温風暖房器に実施した場合と示
す。
FIG. 2 shows the case where the present invention is implemented in an open type hot air heater.

図中、第1図と同一番号がついているのは同じ構成要素
を示す。
In the figure, the same numbers as in FIG. 1 indicate the same components.

図において6′は板金からなるバーナ1の外筒であり、
1o′は空気を燃焼排気ガス通路8の還元触媒9の上流
に導く導管であり、その先端開口部に対向して変向板1
1が前記還元触媒9上流で均一に空気と燃焼排気ガス(
!−を混合するために設けられている。12は送風機で
、還元触媒9.燃焼室77こ風が吹き込んで還元効果や
燃焼特注をそこなわない様に送風ガイド13が設けられ
ている。14は温風通路、15は温風吹出口、16は温
風暖房器本体ケーシングである。
In the figure, 6' is the outer cylinder of the burner 1 made of sheet metal,
1o' is a conduit that guides air upstream of the reduction catalyst 9 in the combustion exhaust gas passage 8, and a deflection plate 1 is placed opposite the opening at the tip of the conduit.
1 is uniformly distributed between air and combustion exhaust gas (
! - is provided for mixing. 12 is a blower, and reduction catalyst 9. A blower guide 13 is provided to prevent the blowing of air into the combustion chamber 77 from damaging the reduction effect and custom combustion. 14 is a hot air passage, 15 is a hot air outlet, and 16 is a main body casing of the hot air heater.

本実施例で、バーナ1の外筒6′と板金で構成したのは
外筒6′外周を@風通路14としたので、輻射熱を取る
必要がないためと、輻射熱を少なくしたため低負荷燃焼
でも安定した燃焼が可能となり一層の低NoI(fE、
を可能にするためである。
In this embodiment, the burner 1 is constructed of the outer cylinder 6' and sheet metal because the outer periphery of the outer cylinder 6' is @ the air passage 14, so there is no need to collect radiant heat, and because the radiant heat is reduced, low-load combustion is possible. Stable combustion is possible, resulting in even lower NoI (fE,
This is to make it possible.

導管10′が燃焼室7を貫通して空気を導び〈様にした
のけ、空気を燃焼室7で予熱し、還元触媒9上流で空気
と燃焼排気ガスが混合する時、空気が冷たい為、Noか
らNO2への酸fEが促進されるのと防ぐ目的である。
The conduit 10' passes through the combustion chamber 7 and guides the air, so that the air is preheated in the combustion chamber 7, and when the air and combustion exhaust gas are mixed upstream of the reduction catalyst 9, the air is cold. , the purpose is to promote and prevent acid fE from No to NO2.

尚、本実施列では、空気を還元触媒9の上流に導いてい
るが、遅元触媒9通過鏝の燃焼排気ガスを導いても一層
よいことはもちろんである。
In this embodiment, air is guided upstream of the reduction catalyst 9, but it is of course better to introduce the combustion exhaust gas from the trowel that passes through the retarding catalyst 9.

本実施例でも第1図の夷流圀と前述の多少の相異r、χ
はあるが基本的な効果については同じであるっ以上上記
二つの実施例で説明したように、本発明によれば次の如
き効果どバイ4Iられるっ■ 完全予nJs合表面燃・
焼含行い、かつ、燃焼面への空気流入を防+):、した
のて低NOx、低NO2が達成される。
In this example, there are some differences r,
However, the basic effects are the same.As explained in the above two embodiments, according to the present invention, the following effects can be achieved.
Burning and impregnation and prevention of air inflow to the combustion surface (+): As a result, low NOx and low NO2 are achieved.

■ 燃焼排気ガス通路に還元触媒を設け、かつ、還元触
媒雰囲気温度を還元効果、還元鏝町酸1ヒを防止する最
適温度V′cなる様に、燃焼排気ガス又は、予熱空気を
還元触媒上流の燃焼排気ガスに均一に混ぜるので一層の
低No2(ヒが達成される0
■ A reduction catalyst is installed in the combustion exhaust gas passage, and the combustion exhaust gas or preheated air is passed upstream of the reduction catalyst so that the atmospheric temperature of the reduction catalyst becomes the optimum temperature V'c for reducing effects and preventing reduction oxidation. Because it is evenly mixed with the combustion exhaust gas of the combustion engine, an even lower No.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の一実施例である燃焼装置の基本構成を
示す正面断面図、第2図は同燃焼装置と実施した温風暖
房器のfll!1面断面図である。 1・・・・・・バーナ、7・・・・・・燃焼室、8・・
・・・・燃焼排気ガス通路、9・・・・・・還元触媒、
10・・・・・・導管。 代理人の氏名 弁理士 中 尾 敵 男 ほか1名第1
図 第2図 2
FIG. 1 is a front cross-sectional view showing the basic configuration of a combustion device that is an embodiment of the present invention, and FIG. 2 is a full view of a hot air heater implemented with the same combustion device. It is a 1-plane sectional view. 1... Burner, 7... Combustion chamber, 8...
... Combustion exhaust gas passage, 9 ... Reduction catalyst,
10... Conduit. Name of agent: Patent attorney Nakao (man) and 1 other person (1st)
Figure 2Figure 2

Claims (1)

【特許請求の範囲】[Claims] 完全予混合表面燃焼を行うバーナと、前記バーナの燃焼
面への空気の流入を防止する密閉構造とした燃焼室と、
前記燃焼室の下流の燃焼排気ガス通路に設けられた還元
触媒とを備え、前記還元触媒の上流で、かつ燃焼室の下
流に前期還元触媒通過後の燃焼排気ガス、又は予熱空気
を供給する手段を設ける構成とした燃焼装置。
a burner that performs fully premixed surface combustion; a combustion chamber that has a sealed structure that prevents air from entering the combustion surface of the burner;
and a reduction catalyst provided in a combustion exhaust gas passage downstream of the combustion chamber, and means for supplying combustion exhaust gas or preheated air after passing through the first reduction catalyst to an area upstream of the reduction catalyst and downstream of the combustion chamber. A combustion device configured to provide a.
JP56213460A 1981-12-25 1981-12-25 Combustion device Pending JPS58110905A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56213460A JPS58110905A (en) 1981-12-25 1981-12-25 Combustion device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56213460A JPS58110905A (en) 1981-12-25 1981-12-25 Combustion device

Publications (1)

Publication Number Publication Date
JPS58110905A true JPS58110905A (en) 1983-07-01

Family

ID=16639573

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56213460A Pending JPS58110905A (en) 1981-12-25 1981-12-25 Combustion device

Country Status (1)

Country Link
JP (1) JPS58110905A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4717414U (en) * 1971-03-27 1972-10-28
JPS5455829A (en) * 1977-10-13 1979-05-04 Takeuchi Shiyouhei Solid fuel combustor

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4717414U (en) * 1971-03-27 1972-10-28
JPS5455829A (en) * 1977-10-13 1979-05-04 Takeuchi Shiyouhei Solid fuel combustor

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