JPS58109001A - Base cloth for shoe - Google Patents
Base cloth for shoeInfo
- Publication number
- JPS58109001A JPS58109001A JP56208385A JP20838581A JPS58109001A JP S58109001 A JPS58109001 A JP S58109001A JP 56208385 A JP56208385 A JP 56208385A JP 20838581 A JP20838581 A JP 20838581A JP S58109001 A JPS58109001 A JP S58109001A
- Authority
- JP
- Japan
- Prior art keywords
- dyed
- discoloration
- shoe
- present
- cationic dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明はカチオン染料で染色したカチオン可染ポリエス
テＡ／（以下Ｃ−Ｄ−Ｐという、）を用いることによっ
て加硫変色のない美麗で軽く９強く、堅ロウ度の優れた
靴用基布を提供するものである。Detailed Description of the Invention The present invention uses cationic dyeable polyester A/ (hereinafter referred to as C-D-P) dyed with a cationic dye to create a beautiful, light, strong material with no discoloration upon vulcanization, 9 strong, and low wax fastness. This provides an excellent base fabric for shoes.
従来、靴素材としては木綿が一般的に使用されている。Conventionally, cotton has been commonly used as a material for shoes.
木綿の場合、鮮明性、堅ロウ性、耐薬品性、耐久性、耐
候性、加硫時の変色等の欠点を有している。一方、レギ
ュラーポリエステル、ナイロン等も少量であるが使用さ
れてきている。レギュラーポリエステルの場合は分散染
料が一般的に使用され、その染色挙動は繊維内部への溶
解であり、靴加工における射出成型時の色の泣出しや加
硫時の変色等の問題がある。また、ナイロンは酸性“ｉ
料との造塩結合であるが、加硫時の変色等の関門を有し
ている。Cotton has disadvantages such as clarity, wax fastness, chemical resistance, durability, weather resistance, and discoloration during vulcanization. On the other hand, regular polyester, nylon, etc. have also been used, albeit in small amounts. In the case of regular polyester, disperse dyes are generally used, and their dyeing behavior is dissolution into the interior of the fibers, which causes problems such as color bleeding during injection molding and discoloration during vulcanization during shoe processing. In addition, nylon is acidic
Although it is a salt-forming bond with materials, it has barriers such as discoloration during vulcanization.
本発明はかかる現状に鑑み鋭意研究の結果、カチオン染
料で染色したＣ−Ｄ−Ｐはカチオン染料□と繊維末端基
との造塩結合であり、これを使用すればレギュフーポリ
エステル、ナイロンでの欠点”ＱＪｂる射出成型時の色
泣きや、加硫時硫黄等による変色も起こらず、木綿に比
べて美麗で軽く１強く。The present invention was developed in view of the current situation and as a result of intensive research, it was found that C-D-P dyed with cationic dye is a salt-forming bond between cationic dye Disadvantages: It does not cause discoloration during injection molding or discoloration due to sulfur during vulcanization, and is more beautiful, lighter, and stronger than cotton.
しかも耐薬品性、耐久性、耐候性に優れた靴用基布を提
供できることを見出し本発明に到達した。Furthermore, the present inventors have discovered that it is possible to provide a base fabric for shoes that has excellent chemical resistance, durability, and weather resistance, and has thus arrived at the present invention.
すなわち１本発明はカチオン染料で染色したＣ・Ｄ−Ｐ
長繊維織−物を使用した靴用基布であ・す９本発明外よ
れば色泣きや加硫変色のない軽くて美麗で強力で耐薬品
性、耐久性、耐候性等の利点を有する靴用基布を得るこ
とができる。That is, the present invention is a C-D-P dyed with a cationic dye.
This is a base fabric for shoes using long fiber woven fabric.9 According to the present invention, it is light, beautiful, strong, and has advantages such as chemical resistance, durability, and weather resistance without discoloration or discoloration due to vulcanization. A base fabric for shoes can be obtained.
以下１本発明について詳細に説明する。The present invention will be explained in detail below.
本発明でいうカチオン染料で染色したＣ−Ｄ−Ｐ繊維と
はヌ〃フオイソフタール酸ナトリウムを１〜５ ｍｏ１
％、好ましくは２〜３ ｍｏｌ ４含むポリエチレンテ
レフタレートを意味し、製造のしやすさ。The C-D-P fiber dyed with a cationic dye as used in the present invention refers to the C-D-P fiber dyed with a cationic dye.
%, preferably 2 to 3 mol 4 of polyethylene terephthalate, and ease of production.
コスト、染色性から決定すればよい、ｖｌ用に際してこ
の繊維単独で使用してもよいが、レギュラーポリエステ
ルとの交織、交編物でもよい、ただし交織、交編の場合
カチオン染料のみで染色し、レギュラーポリエステルは
白残しすることを定義する。This fiber can be determined based on cost and dyeability.For VL, this fiber may be used alone, but it may also be mixed with regular polyester or mixed with regular polyester.However, in the case of mixed weaving or mixed knitting, it should be dyed with only a cationic dye and regular Polyester is defined as leaving white.
本発明で使用する靴底材質としては途布使用されるもの
でよ＜、Ｍえばポリウレタン系樹脂、ｌり種化ビニル系
樹脂、ｌリアミド系樹脂等がある。The sole material used in the present invention may be any material that is commonly used, such as polyurethane resins, seeded vinyl resins, and lyamide resins.
靴用Ｉ＆布と靴底材質との接着はＣ−Ｄ−Ｐ繊維染上布
を使用してもよいが、接着剤として一般的に使用してい
る薬品を塗布すればより効果的である。塗布方法として
はパッディング、コーティングどちらでもすく、その薬
品としてはポリアクリ＃樹脂ポリウレタン樹脂、メフミ
ン樹ＩＩ旨、エポキｖ ｍ Ｉｌｌ等のｍ剤タイプ、エ
マルジョンタイプ等が挙げられる。Although C-D-P fiber dyed cloth may be used to bond the shoe I&cloth and the sole material, it is more effective to apply a commonly used chemical as an adhesive. The coating method may be either padding or coating, and the chemicals include polyacrylic resin, polyurethane resin, m-agent type such as Mehumine II, epoxy Vm Ill, and emulsion type.
以下ｓＪ！施例によって説明するが９本発明はこれらに
よって何ら制限されるものではない。Below is sJ! Although the present invention will be explained by examples, the present invention is not limited thereto.
ｓｉＩ！鳩例１
ポリエチレンテレフタレートにスＶフオイソフタール酸
ナトリウム２．５ ｍｏｌ ％含むカチオン可染ポリエ
ステ／Ｌ／ＷＩ＆維１５０ｄ１５０ｆを経糸及び緯糸に
使用して製織したタツサーを通常の方法でリラックス精
練、プレセットし、カチオン染料で王妃の条件で染色し
た。siI! Pigeon Example 1 Tatsusa woven using cationic dyeable polyester/L/WI & fiber 150d150f containing 2.5 mol % of sodium V phoisophthalate in polyethylene terephthalate for the warp and weft was relaxed scouring and preset in the usual manner, Dyed with cationic dyes according to the queen's conditions.
染色条件
処方１（紺）
Ｋａｙａｃｒｙｌ Ｎａｖｙ Ａ−ＥＤ ４
＊ｏ、ｗ、ｆＨＣＯＯＲ０，２ｃｔ／ｇ
処方２（赤）
ＫａｙａｃｒｙｌＲｅｄ ＧＲＬ−ＥＤ ２．５
％ｏ、ｗ、ｆ＊ Ｙｅｌｌｏｗ ５ＲＬ−ＥＤ
０．０５＊ ＊傘Ｂｌｕｅ ＧＳＬ−ＥＤ Ｏ，
２％ ケＨＣＯＯＨＯ，２αし′Ｉ
で１２０℃、で４０分間東色した。Dyeing condition prescription 1 (navy blue) Kayacryl Navy A-ED 4
*o, w, fHCOOR0.2ct/g Prescription 2 (red) KayacrylRed GRL-ED 2.5
%o, w, f* Yellow 5RL-ED
0.05* *Umbrella Blue GSL-ED O,
The mixture was dyed with 2% HCOOHO, 2α and I at 120° C. for 40 minutes.
比較用試料としてし゛ギュ、フーボリエステ〜を分散染
料でｆ記の条件で染色したものを用いた。As a comparative sample, a material obtained by dyeing Shigu, Foubolieste~ with a disperse dye under the conditions described in f was used.
染色条件
処方＊（１４１）
Ｔｅｒａａｉｌ Ｎａｖｙ Ｂｌｕｅ ８ＧＬ
４．０＊ｏ、ｗ、ｆＳｕａ＋１ｋａｒｏｎ Ｒｕｂｉ
ｎｅ ５ｇ−２ＢＬ Ｏ，２％ ケ処方Ｂ（赤）
Ｄｉａｎｉｘ Ｒｅｌ ＫＢ−８１３，５％ｏ
、ｗ、ｆＦ’ｏｒｏｎ Ｒｕｂｉｎｅ Ｓｇ−ＣＴ
Ｌ Ｏ，５ｑ６ ｅで１５０ｃで４０分間
染色した。Staining condition prescription* (141) Teraail Navy Blue 8GL
4.0*o, w, fSua+1karon Rubi
ne 5g-2BL O, 2% Ke prescription B (red) Dianix Rel KB-813, 5% o
,w,fF'oron Rubine Sg-CT
Stained with L O,5q6e at 150c for 40 minutes.
該織物を靴用基布として使用し、塩化ビニル樹脂を１７
０℃で射出成型した時の塩化ビニルへの色の泣出しを汚
東用グレースケールで判定した０表−１より明らかなご
とく１本発明品は良好な結果を得た。The fabric was used as a base fabric for shoes, and vinyl chloride resin was added to 17
As is clear from Table 1, in which the bleeding of color into vinyl chloride during injection molding at 0° C. was determined using a staining gray scale, the product of the present invention obtained good results.
第１表（色の泣出し）
判定 ５級二色の泣出しなし
１級二色の泣出し大
実施例２
ポリエチレンテレフタレー）にス〜フオイソフタール酸
ナトリウム２ ｍｏ１％含むカチオン可染メリエステル
繊維７５ｄ／２４ｆ／２を経糸及び緯糸に用いて製織し
たフィルを通常の方法でリラックス精練。Table 1 (Color bleeding) Judgment: No bleeding of 5th grade two colors, large bleeding of 1st grade two colors Example 2 Cation dyeable merry ester fiber containing 2 mo1% of sodium phoisophthalate (polyethylene terephthalate) 75d/ The fill woven using 24f/2 for the warp and weft is relaxed and refined in the usual manner.
プレセットし、カチオン染料Ｋａｙａｃｒｙｌ Ｒｅｄ
ＧＲＬ−ＥＤ Ｏ，０２％ｏ、ｗ、ｆで１２０℃で３
０分間染色し、練加工工程の７月硫時の変色を調べた。Preset and cationic dye Kayacryl Red
GRL-ED O, 02% o, w, f at 120℃ 3
The samples were dyed for 0 minutes, and the discoloration during July sulfurization in the kneading process was examined.
なお、比較試料として木綿−ズ応性染料、レギュフーボ
リエステルー分散染料染色物を用いた。Incidentally, as comparative samples, dyed products of cotton-zole reactive dyes and regufubolyester-disperse dyes were used.
１４定は変退色用ブレースブールを用いた。For the 14 constant, a brace bouquet for discoloration and fading was used.
第２表（加硫後の変色） 判定 ５Ｎ＆：変色なし １級：変色大Table 2 (discoloration after vulcanization) Judgment: 5N &: No discoloration Grade 1: Major discoloration
Claims (1)
ル長繊維織編物からなる靴用基布。(1) A shoe base fabric made of a cationically dyeable polyester long fiber woven or knitted fabric dyed with a cationic dye.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56208385A JPS58109001A (en) | 1981-12-22 | 1981-12-22 | Base cloth for shoe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56208385A JPS58109001A (en) | 1981-12-22 | 1981-12-22 | Base cloth for shoe |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS58109001A true JPS58109001A (en) | 1983-06-29 |
Family
ID=16555385
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56208385A Pending JPS58109001A (en) | 1981-12-22 | 1981-12-22 | Base cloth for shoe |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58109001A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6135644A (en) * | 1998-02-24 | 2000-10-24 | Fujitsu Limited | Structures for optical semiconductor module, optical connector, and shape adapting optical connector |
-
1981
- 1981-12-22 JP JP56208385A patent/JPS58109001A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6135644A (en) * | 1998-02-24 | 2000-10-24 | Fujitsu Limited | Structures for optical semiconductor module, optical connector, and shape adapting optical connector |
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