JPS57142927A - Preparation of chloromethane - Google Patents
Preparation of chloromethaneInfo
- Publication number
- JPS57142927A JPS57142927A JP2691881A JP2691881A JPS57142927A JP S57142927 A JPS57142927 A JP S57142927A JP 2691881 A JP2691881 A JP 2691881A JP 2691881 A JP2691881 A JP 2691881A JP S57142927 A JPS57142927 A JP S57142927A
- Authority
- JP
- Japan
- Prior art keywords
- reactor
- chloromethane
- liquid phase
- chlorine
- methane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain a chloromethane with a high reaction rate of chlorine and increased selectivity for the chloromethane, by carrying out the partial chlorination of methane or the photochlorination of chlorine in the vapor phase in the presence of the liquid phase.
CONSTITUTION: Methane or partially chlorinated methane is reacted with chlorine in a photochlorinating ractor to give a chloromethane. In the process, the reaction is carried out in the presence of the liquid phase. The condensate of a reaction mixture from the photochlorinating reactor is partially circulated for use advantageously as the coexisting liquid phase. More preferably, the uncondensed gas containing HCl formed as a by-product as a principal component from the reactor is circulated through the reactor for use, and the gas-liquid contact efficiency in the reactor is increased to remove the heat of reaction more efficiently. The amount of the liquid phase present in the reactor is preferably in the range of 0.02W0.20mol based on 1mol total amount of the gaseous and liquid phases.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2691881A JPS57142927A (en) | 1981-02-27 | 1981-02-27 | Preparation of chloromethane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2691881A JPS57142927A (en) | 1981-02-27 | 1981-02-27 | Preparation of chloromethane |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57142927A true JPS57142927A (en) | 1982-09-03 |
JPH0238572B2 JPH0238572B2 (en) | 1990-08-31 |
Family
ID=12206569
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2691881A Granted JPS57142927A (en) | 1981-02-27 | 1981-02-27 | Preparation of chloromethane |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57142927A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4614572A (en) * | 1985-07-08 | 1986-09-30 | The Dow Chemical Company | Liquid phase chlorination of chlorinated methanes |
US5023387A (en) * | 1989-04-24 | 1991-06-11 | The Dow Chemical Company | Liquid feed injection in a chloromethanes process |
JP2003055279A (en) * | 2001-08-10 | 2003-02-26 | Tokuyama Corp | Method for producing high-purity carbon tetrachloride |
JP2007308478A (en) * | 2006-04-18 | 2007-11-29 | Tokuyama Corp | Process for producing highly chlorinated methanes |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55154924A (en) * | 1979-05-22 | 1980-12-02 | Asahi Glass Co Ltd | Preparation of 1,1,1-trichloroethane |
-
1981
- 1981-02-27 JP JP2691881A patent/JPS57142927A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55154924A (en) * | 1979-05-22 | 1980-12-02 | Asahi Glass Co Ltd | Preparation of 1,1,1-trichloroethane |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4614572A (en) * | 1985-07-08 | 1986-09-30 | The Dow Chemical Company | Liquid phase chlorination of chlorinated methanes |
US5023387A (en) * | 1989-04-24 | 1991-06-11 | The Dow Chemical Company | Liquid feed injection in a chloromethanes process |
JP2003055279A (en) * | 2001-08-10 | 2003-02-26 | Tokuyama Corp | Method for producing high-purity carbon tetrachloride |
JP2007308478A (en) * | 2006-04-18 | 2007-11-29 | Tokuyama Corp | Process for producing highly chlorinated methanes |
Also Published As
Publication number | Publication date |
---|---|
JPH0238572B2 (en) | 1990-08-31 |
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