JPS57135007A - Gas separation film - Google Patents

Gas separation film

Info

Publication number
JPS57135007A
JPS57135007A JP2088281A JP2088281A JPS57135007A JP S57135007 A JPS57135007 A JP S57135007A JP 2088281 A JP2088281 A JP 2088281A JP 2088281 A JP2088281 A JP 2088281A JP S57135007 A JPS57135007 A JP S57135007A
Authority
JP
Japan
Prior art keywords
film
dissolved
under vacuum
coefficient
resulting solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2088281A
Other languages
Japanese (ja)
Inventor
Gen Kojima
Hiroshi Wachi
Masaaki Yamabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Priority to JP2088281A priority Critical patent/JPS57135007A/en
Publication of JPS57135007A publication Critical patent/JPS57135007A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE: To form a gas separation film with excellent chemical resistance, heat resistance and oil resistance of which both separation coefficient and a permeation coefficient and a permeation speed of oxygen and nitrogen are high by subjecting an organopolysiloxane and a fluorine containing polymer to graft copolymerization.
CONSTITUTION: 15g fluorine containing polymer segment of which an average polymerization degree is 800 and a molar ratio of C2F2/C3H6/glycidyl vinyl ether is 54/44/2 and 5g amino group containing organopolysiloxane of which a polymerization degree is about 5,000 are dissolved in trifluorotrichloroethane and the resulting solution is stirred for about 2hr. After stirring, the temp. thereof is lowered to 47°C and, while the solvent is volatilized, the reaction is carried out for one hr and said reactants are further heated to 80°C to be reacted for 1.5hr under vacuum. When the obtained polymer is dissolved in ethyl acetate and the resulting solution is coated on a glass plate and dried in air or under vacuum, a film with a thickness of 9.4μ is obtained. The separation coefficient of this film (PO2/PN2) is 3.29.
COPYRIGHT: (C)1982,JPO&Japio
JP2088281A 1981-02-17 1981-02-17 Gas separation film Pending JPS57135007A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2088281A JPS57135007A (en) 1981-02-17 1981-02-17 Gas separation film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2088281A JPS57135007A (en) 1981-02-17 1981-02-17 Gas separation film

Publications (1)

Publication Number Publication Date
JPS57135007A true JPS57135007A (en) 1982-08-20

Family

ID=12039560

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2088281A Pending JPS57135007A (en) 1981-02-17 1981-02-17 Gas separation film

Country Status (1)

Country Link
JP (1) JPS57135007A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3432509A1 (en) * 1983-09-05 1985-03-21 Daicel-Hüls Ltd., Tokio/Tokyo METHOD FOR PRODUCING A POLYAMIDE / POLYSILOXANE BLOCK COPOLYMER
JPS60118217A (en) * 1983-11-29 1985-06-25 Daikin Ind Ltd Gas separation membrane
JPH01278533A (en) * 1988-05-02 1989-11-08 Nippon Unicar Co Ltd Production of polysiloxane-modified olefinic polymer
CN108201792A (en) * 2016-12-16 2018-06-26 大连联和环保技术有限公司 A kind of preparation method of fluorine-containing silicon rubber composite separating film

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3432509A1 (en) * 1983-09-05 1985-03-21 Daicel-Hüls Ltd., Tokio/Tokyo METHOD FOR PRODUCING A POLYAMIDE / POLYSILOXANE BLOCK COPOLYMER
DE3432509C2 (en) * 1983-09-05 1993-04-29 Daicel-Huels Ltd., Tokio/Tokyo, Jp
JPS60118217A (en) * 1983-11-29 1985-06-25 Daikin Ind Ltd Gas separation membrane
JPH0250769B2 (en) * 1983-11-29 1990-11-05 Daikin Ind Ltd
JPH01278533A (en) * 1988-05-02 1989-11-08 Nippon Unicar Co Ltd Production of polysiloxane-modified olefinic polymer
CN108201792A (en) * 2016-12-16 2018-06-26 大连联和环保技术有限公司 A kind of preparation method of fluorine-containing silicon rubber composite separating film

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