JPS57135007A - Gas separation film - Google Patents
Gas separation filmInfo
- Publication number
- JPS57135007A JPS57135007A JP2088281A JP2088281A JPS57135007A JP S57135007 A JPS57135007 A JP S57135007A JP 2088281 A JP2088281 A JP 2088281A JP 2088281 A JP2088281 A JP 2088281A JP S57135007 A JPS57135007 A JP S57135007A
- Authority
- JP
- Japan
- Prior art keywords
- film
- dissolved
- under vacuum
- coefficient
- resulting solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
PURPOSE: To form a gas separation film with excellent chemical resistance, heat resistance and oil resistance of which both separation coefficient and a permeation coefficient and a permeation speed of oxygen and nitrogen are high by subjecting an organopolysiloxane and a fluorine containing polymer to graft copolymerization.
CONSTITUTION: 15g fluorine containing polymer segment of which an average polymerization degree is 800 and a molar ratio of C2F2/C3H6/glycidyl vinyl ether is 54/44/2 and 5g amino group containing organopolysiloxane of which a polymerization degree is about 5,000 are dissolved in trifluorotrichloroethane and the resulting solution is stirred for about 2hr. After stirring, the temp. thereof is lowered to 47°C and, while the solvent is volatilized, the reaction is carried out for one hr and said reactants are further heated to 80°C to be reacted for 1.5hr under vacuum. When the obtained polymer is dissolved in ethyl acetate and the resulting solution is coated on a glass plate and dried in air or under vacuum, a film with a thickness of 9.4μ is obtained. The separation coefficient of this film (PO2/PN2) is 3.29.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2088281A JPS57135007A (en) | 1981-02-17 | 1981-02-17 | Gas separation film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2088281A JPS57135007A (en) | 1981-02-17 | 1981-02-17 | Gas separation film |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS57135007A true JPS57135007A (en) | 1982-08-20 |
Family
ID=12039560
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2088281A Pending JPS57135007A (en) | 1981-02-17 | 1981-02-17 | Gas separation film |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57135007A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3432509A1 (en) * | 1983-09-05 | 1985-03-21 | Daicel-Hüls Ltd., Tokio/Tokyo | METHOD FOR PRODUCING A POLYAMIDE / POLYSILOXANE BLOCK COPOLYMER |
JPS60118217A (en) * | 1983-11-29 | 1985-06-25 | Daikin Ind Ltd | Gas separation membrane |
JPH01278533A (en) * | 1988-05-02 | 1989-11-08 | Nippon Unicar Co Ltd | Production of polysiloxane-modified olefinic polymer |
CN108201792A (en) * | 2016-12-16 | 2018-06-26 | 大连联和环保技术有限公司 | A kind of preparation method of fluorine-containing silicon rubber composite separating film |
-
1981
- 1981-02-17 JP JP2088281A patent/JPS57135007A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3432509A1 (en) * | 1983-09-05 | 1985-03-21 | Daicel-Hüls Ltd., Tokio/Tokyo | METHOD FOR PRODUCING A POLYAMIDE / POLYSILOXANE BLOCK COPOLYMER |
DE3432509C2 (en) * | 1983-09-05 | 1993-04-29 | Daicel-Huels Ltd., Tokio/Tokyo, Jp | |
JPS60118217A (en) * | 1983-11-29 | 1985-06-25 | Daikin Ind Ltd | Gas separation membrane |
JPH0250769B2 (en) * | 1983-11-29 | 1990-11-05 | Daikin Ind Ltd | |
JPH01278533A (en) * | 1988-05-02 | 1989-11-08 | Nippon Unicar Co Ltd | Production of polysiloxane-modified olefinic polymer |
CN108201792A (en) * | 2016-12-16 | 2018-06-26 | 大连联和环保技术有限公司 | A kind of preparation method of fluorine-containing silicon rubber composite separating film |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0080617B1 (en) | Use of permselective membranes for the separation of gas mixtures | |
US4324901A (en) | Soluble polysilastyrene and method for preparation | |
ES445869A1 (en) | Curable poly(alkylene) ether polyol-based grafted resins having improved properties | |
JPS57209607A (en) | Preparation of polyimide separation film | |
JPS5535910A (en) | Permselectivity composite membrane and preparation thereof | |
EP0509260A1 (en) | Composite or asymmetric fluorine-containing polyimide membrane, a process for manufacturing the same and a method for the separation and concentration of gas using the same | |
Tezuka et al. | Surface studies on poly (vinyl alcohol)—poly (dimethylsiloxane) graft copolymers | |
US4759776A (en) | Polytrialkylgermylpropyne polymers and membranes | |
EP0070730B1 (en) | Selective gas-permeable films | |
JPS57156004A (en) | Gas separating membrane | |
EP0146020B1 (en) | Gas separating membrane | |
JPS57135007A (en) | Gas separation film | |
US4567245A (en) | Substituted polyacetylene copolymer | |
JPH04122714A (en) | Production of high molecular weight epoxy resin | |
US4033731A (en) | Partially crosslinked silalactone polymers, their preparation and their use | |
JPS57200210A (en) | Fibrous silicon nitride and its production | |
JPS5584331A (en) | Preparation of weather resistant improved vinyl chloride resin molded article | |
JPH0371170B2 (en) | ||
JP2643644B2 (en) | High thermal conductive epoxy film | |
JPS5543174A (en) | Preparation of phosphazene polymer | |
JPS54122399A (en) | Crosslinked polyimine and its preparation | |
JPH02241529A (en) | Gas separation membrane | |
JPS5569610A (en) | Copolymeric prepolymer and its preparation | |
JPH05228350A (en) | Polycarbonate gas separation membrane | |
JPS63141626A (en) | Permselective membrane for gas |