JPS5656231A - Stabilization of recovered oxidation catalyst - Google Patents
Stabilization of recovered oxidation catalystInfo
- Publication number
- JPS5656231A JPS5656231A JP13156079A JP13156079A JPS5656231A JP S5656231 A JPS5656231 A JP S5656231A JP 13156079 A JP13156079 A JP 13156079A JP 13156079 A JP13156079 A JP 13156079A JP S5656231 A JPS5656231 A JP S5656231A
- Authority
- JP
- Japan
- Prior art keywords
- carbonate
- catalyst
- cobalt
- acetic acid
- manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Abstract
PURPOSE: To enhance the preservation stability of a catalyst by recovering a cobalt and manganese catalyst used in preparing terephthalic acid as a carbonate and adding a small amount of acetic acid to this carbonate.
CONSTITUTION: Terephthalic acid is prepared in the pesence of a cobalt and manganese catalyst by using paraxylene as a raw material and acetic acid as a solvent. In this case, after terephthalic acid and acetic acid are removed from a reaction mixture, the recovered catalyst is backed and dissolved in sulfuric acid, thereafter the precipitate crystallized out by neutralization is separated and carbonate ion is added. To a cobalt and manganese catalyst recovered as a carbonate, acetic acid is added in an amount of 0.001pt.wt. or more against one pt.wt. of the carbonate. Thereby, deterioration phenomena of a carbonate of cobalt and manganese are prevented and a catalyst stable for a long period is obtained.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13156079A JPS5656231A (en) | 1979-10-11 | 1979-10-11 | Stabilization of recovered oxidation catalyst |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13156079A JPS5656231A (en) | 1979-10-11 | 1979-10-11 | Stabilization of recovered oxidation catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5656231A true JPS5656231A (en) | 1981-05-18 |
JPS636269B2 JPS636269B2 (en) | 1988-02-09 |
Family
ID=15060913
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13156079A Granted JPS5656231A (en) | 1979-10-11 | 1979-10-11 | Stabilization of recovered oxidation catalyst |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5656231A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100377651B1 (en) * | 2000-09-21 | 2003-03-26 | 박영효 | A collection method a cobalt oxide in waste cobalt sludge |
CN102369572A (en) * | 2009-03-30 | 2012-03-07 | 芝浦机械电子装置股份有限公司 | Apparatus for forming thin film and method for forming thin film |
JP2013039561A (en) * | 2011-08-17 | 2013-02-28 | Korea Inst Of Geoscience & Mineral Resources (Kigam) | Method for producing cma liquid catalyst from spent cmb catalyst |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5653750A (en) * | 1979-10-08 | 1981-05-13 | Kuraray Yuka Kk | Stabilizing method for recovered oxidation catalyst |
-
1979
- 1979-10-11 JP JP13156079A patent/JPS5656231A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5653750A (en) * | 1979-10-08 | 1981-05-13 | Kuraray Yuka Kk | Stabilizing method for recovered oxidation catalyst |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100377651B1 (en) * | 2000-09-21 | 2003-03-26 | 박영효 | A collection method a cobalt oxide in waste cobalt sludge |
CN102369572A (en) * | 2009-03-30 | 2012-03-07 | 芝浦机械电子装置股份有限公司 | Apparatus for forming thin film and method for forming thin film |
JPWO2010116654A1 (en) * | 2009-03-30 | 2012-10-18 | 芝浦メカトロニクス株式会社 | Thin film forming apparatus and thin film forming method |
JP2013039561A (en) * | 2011-08-17 | 2013-02-28 | Korea Inst Of Geoscience & Mineral Resources (Kigam) | Method for producing cma liquid catalyst from spent cmb catalyst |
Also Published As
Publication number | Publication date |
---|---|
JPS636269B2 (en) | 1988-02-09 |
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