JPS56141312A - Hetero macrocyclic compound fixed to surface of porous inorganic solid - Google Patents

Hetero macrocyclic compound fixed to surface of porous inorganic solid

Info

Publication number
JPS56141312A
JPS56141312A JP4534580A JP4534580A JPS56141312A JP S56141312 A JPS56141312 A JP S56141312A JP 4534580 A JP4534580 A JP 4534580A JP 4534580 A JP4534580 A JP 4534580A JP S56141312 A JPS56141312 A JP S56141312A
Authority
JP
Japan
Prior art keywords
inorganic solid
porous inorganic
hetero
macrocyclic compound
pref
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4534580A
Other languages
Japanese (ja)
Other versions
JPS6254127B2 (en
Inventor
Takashi Udagawa
Jiro Okamoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Atomic Energy Agency
Original Assignee
Japan Atomic Energy Research Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Atomic Energy Research Institute filed Critical Japan Atomic Energy Research Institute
Priority to JP4534580A priority Critical patent/JPS56141312A/en
Publication of JPS56141312A publication Critical patent/JPS56141312A/en
Publication of JPS6254127B2 publication Critical patent/JPS6254127B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Catalysts (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

PURPOSE:To prepare the titled compound which can be recovered, regenerated, etc. and useful as a packing material, catalyst, etc. for capturing and separation of heavy metals, optical resolution, etc., by adsorbing a solution of a specific hetero macrocyclic compound to the surface of a porous inorganic solid, and irradiating with ionizing radiations. CONSTITUTION:(A) A solution obtained by dissolving a vinyl-containing hetero macrocyclic compound (e.g. 4'-vinylbenzo-15-crown 5) in an organic solvent (e.g. benzene), is adsorbed to the surface of (B) a porous inorganic solid (pref. silica gel), and irradiated with ionizing radiations at a dose of pref. <=3X10<6>R. The amount of the component (A) dissolved in the solvent is pref. 0.5-5wt% of the component (B).
JP4534580A 1980-04-07 1980-04-07 Hetero macrocyclic compound fixed to surface of porous inorganic solid Granted JPS56141312A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4534580A JPS56141312A (en) 1980-04-07 1980-04-07 Hetero macrocyclic compound fixed to surface of porous inorganic solid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4534580A JPS56141312A (en) 1980-04-07 1980-04-07 Hetero macrocyclic compound fixed to surface of porous inorganic solid

Publications (2)

Publication Number Publication Date
JPS56141312A true JPS56141312A (en) 1981-11-05
JPS6254127B2 JPS6254127B2 (en) 1987-11-13

Family

ID=12716690

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4534580A Granted JPS56141312A (en) 1980-04-07 1980-04-07 Hetero macrocyclic compound fixed to surface of porous inorganic solid

Country Status (1)

Country Link
JP (1) JPS56141312A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4523994A (en) * 1982-06-30 1985-06-18 Shimadzu Corporation Bis-crown-ether derivatives and their use

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5170199A (en) * 1974-12-16 1976-06-17 Japan Atomic Energy Res Inst Keisanno gurafutojugohoho

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5170199A (en) * 1974-12-16 1976-06-17 Japan Atomic Energy Res Inst Keisanno gurafutojugohoho

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4523994A (en) * 1982-06-30 1985-06-18 Shimadzu Corporation Bis-crown-ether derivatives and their use
US4554362A (en) * 1982-06-30 1985-11-19 Shimadzu Corporation Bis-crown-ether derivatives and their use

Also Published As

Publication number Publication date
JPS6254127B2 (en) 1987-11-13

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