JPS56115728A - Selective dealkylating method - Google Patents
Selective dealkylating methodInfo
- Publication number
- JPS56115728A JPS56115728A JP1907580A JP1907580A JPS56115728A JP S56115728 A JPS56115728 A JP S56115728A JP 1907580 A JP1907580 A JP 1907580A JP 1907580 A JP1907580 A JP 1907580A JP S56115728 A JPS56115728 A JP S56115728A
- Authority
- JP
- Japan
- Prior art keywords
- dealkylating
- platinum
- hydrogen
- noble metal
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910000510 noble metal Inorganic materials 0.000 abstract 2
- 229910052697 platinum Inorganic materials 0.000 abstract 2
- 239000012808 vapor phase Substances 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 238000007323 disproportionation reaction Methods 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 238000007086 side reaction Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To dealkylate a ≥2C alkyl group linked to an aromatic nucleus in the presence of hydrogen in the vapor phase selectively and in high conversion, by using a specific crystalline aluminosilicate containing a noble metal, e.g. platinum, as a catalyst under specified conditions.
CONSTITUTION: A ≥2C alkyl group linked to the aromatic nucleus of an alkyl substituted aromatic hydrocarbon is dealkylated in the vapor phase in the presence of hydrogen and a crystalline aluminosilicate, having a silica/alumina molar ratio of 20W200, preferably 30W150, and containing a noble metal selected from platinum, palladium, rhodium and iridium as a hydrogenating-dealkylating catalyst at 250W420°C, preferably 320W410°C, and 100psig or below, preferably 0W90psig, selectively in a high conversion with suppressed side reactions., e.g. disproportionation. Thus, an aromatic hydrocarbon, e.g. benzene, toluene or xylene, having a high industrial value can be obtained.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1907580A JPS56115728A (en) | 1980-02-20 | 1980-02-20 | Selective dealkylating method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1907580A JPS56115728A (en) | 1980-02-20 | 1980-02-20 | Selective dealkylating method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56115728A true JPS56115728A (en) | 1981-09-11 |
| JPS5741445B2 JPS5741445B2 (en) | 1982-09-03 |
Family
ID=11989313
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1907580A Granted JPS56115728A (en) | 1980-02-20 | 1980-02-20 | Selective dealkylating method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS56115728A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56158150A (en) * | 1980-04-14 | 1981-12-05 | Mobil Oil Corp | Manufacture of zeolite catalyst containing precious metal, said catalyst and isomerization method of xylene using said catalyst |
| JPS60246330A (en) * | 1984-05-21 | 1985-12-06 | Idemitsu Petrochem Co Ltd | Production of benzene and methyl-substituted benzene |
| JPS61176539A (en) * | 1985-01-30 | 1986-08-08 | Teijin Yuka Kk | Dealkylation process |
| CN106345463A (en) * | 2016-08-26 | 2017-01-25 | 山东恒信科技发展有限公司 | Catalyst for heavy aromatics hydrogenation dealkylation |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5126824A (en) * | 1974-08-26 | 1976-03-05 | Mobil Oil | |
| JPS5278838A (en) * | 1975-12-22 | 1977-07-02 | Mobil Oil | Method of carrying out alternatively catalytic conversion reaction and thermal dealkylation of alkylaromatic hydocarbons in single reactor |
-
1980
- 1980-02-20 JP JP1907580A patent/JPS56115728A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5126824A (en) * | 1974-08-26 | 1976-03-05 | Mobil Oil | |
| JPS5278838A (en) * | 1975-12-22 | 1977-07-02 | Mobil Oil | Method of carrying out alternatively catalytic conversion reaction and thermal dealkylation of alkylaromatic hydocarbons in single reactor |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56158150A (en) * | 1980-04-14 | 1981-12-05 | Mobil Oil Corp | Manufacture of zeolite catalyst containing precious metal, said catalyst and isomerization method of xylene using said catalyst |
| JPS637093B2 (en) * | 1980-04-14 | 1988-02-15 | Mobil Oil | |
| JPS60246330A (en) * | 1984-05-21 | 1985-12-06 | Idemitsu Petrochem Co Ltd | Production of benzene and methyl-substituted benzene |
| JPS61176539A (en) * | 1985-01-30 | 1986-08-08 | Teijin Yuka Kk | Dealkylation process |
| CN106345463A (en) * | 2016-08-26 | 2017-01-25 | 山东恒信科技发展有限公司 | Catalyst for heavy aromatics hydrogenation dealkylation |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5741445B2 (en) | 1982-09-03 |
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