JPS55144052A - Production of stable organopolysiloxane emulsion polymeric liquid - Google Patents
Production of stable organopolysiloxane emulsion polymeric liquidInfo
- Publication number
- JPS55144052A JPS55144052A JP5203879A JP5203879A JPS55144052A JP S55144052 A JPS55144052 A JP S55144052A JP 5203879 A JP5203879 A JP 5203879A JP 5203879 A JP5203879 A JP 5203879A JP S55144052 A JPS55144052 A JP S55144052A
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- emulsion
- sulfonic
- monomer
- vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Abstract
PURPOSE: To obtain title stable polymeric liquid which does not contain any emulsifiers and any dispersants, by a method wherein a vinyl monomer is polymerized by emulsion polymn, a cyclic siloxane monomer is subjected to ring-opening emulsion polymn. in the presence of the resulting vinyl polymer, and sulfonic gp. in the resulting polymer are neutralized.
CONSTITUTION: Vinyl monomer of formula I or II (wherein X is a radical of formula III, IV or V; Z is ethylene, butylene, phenylene, Y is H, halogen, methyl) or a mixt. of the vinyl monomer and other monomer, is polymerized by emulsion polymn. to obtain a vinyl polymer contg. at least 2×10-6 moles of sulfonic gp. per gram of the polymer. A cyclic siloxane monomer of formula VI (wherein R is methyl, phenyl; R' is methyl, phenyl, 3W8C alkyl, cycloalkyl; x is 3W6) is subjected to ring-opening emulsion polymn. in the presence of the vinyl polymer to obtain a sulfonic gp.-contg. organopolysiloxane emulsion polymer. The sulfonic gp. in the emulsion polymer are neutralized with an alkaline material to produce a stable organopolysiloxane emulsion polymeric liquid which does not contain any emulsifiers and any dispersants.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5203879A JPS55144052A (en) | 1979-04-28 | 1979-04-28 | Production of stable organopolysiloxane emulsion polymeric liquid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5203879A JPS55144052A (en) | 1979-04-28 | 1979-04-28 | Production of stable organopolysiloxane emulsion polymeric liquid |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS55144052A true JPS55144052A (en) | 1980-11-10 |
Family
ID=12903642
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5203879A Pending JPS55144052A (en) | 1979-04-28 | 1979-04-28 | Production of stable organopolysiloxane emulsion polymeric liquid |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS55144052A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62141029A (en) * | 1985-12-12 | 1987-06-24 | ダウ・コ−ニング・コ−ポレ−シヨン | Production of microemulsion of polydiorganosiloxane |
WO1992002571A1 (en) * | 1990-08-03 | 1992-02-20 | Sri International | Cation conductive solid polymers |
-
1979
- 1979-04-28 JP JP5203879A patent/JPS55144052A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62141029A (en) * | 1985-12-12 | 1987-06-24 | ダウ・コ−ニング・コ−ポレ−シヨン | Production of microemulsion of polydiorganosiloxane |
JPH0471097B2 (en) * | 1985-12-12 | 1992-11-12 | Dow Corning | |
WO1992002571A1 (en) * | 1990-08-03 | 1992-02-20 | Sri International | Cation conductive solid polymers |
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