JPS55142012A - Preparation of acetylene high polymer film or fiber having improved drawability - Google Patents

Preparation of acetylene high polymer film or fiber having improved drawability

Info

Publication number
JPS55142012A
JPS55142012A JP4788679A JP4788679A JPS55142012A JP S55142012 A JPS55142012 A JP S55142012A JP 4788679 A JP4788679 A JP 4788679A JP 4788679 A JP4788679 A JP 4788679A JP S55142012 A JPS55142012 A JP S55142012A
Authority
JP
Japan
Prior art keywords
catalyst
acetylene
high polymer
polymer
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4788679A
Other languages
Japanese (ja)
Other versions
JPS6160844B2 (en
Inventor
Masao Kobayashi
Hideki Shirakawa
Sakuji Ikeda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Holdings Corp
Original Assignee
Showa Denko KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Denko KK filed Critical Showa Denko KK
Priority to JP4788679A priority Critical patent/JPS55142012A/en
Publication of JPS55142012A publication Critical patent/JPS55142012A/en
Publication of JPS6160844B2 publication Critical patent/JPS6160844B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)

Abstract

PURPOSE: To prepare an acetylene high polymer having anisotropic electrical conductivity and high strength and, useful for electronic elements, etc., by contacting acetylene with a catalyst prepared by dissolving a transition metal compound and an organometallic compound in an aromatic ether at specific concentrations and applying the solution to a solid surface.
CONSTITUTION: (A) A catalyst consisting mainly of (a) a transition metal compound (e.g. tetrabutoxytitanium) and (b) an organometallic compound (e.g. triethylaluminum), is dissolved in (B) an aromatic ether compound (e.g. anisole). The amount of the catalyst is 0.001 mole on the basis of 1l of the solvent. Acetylene is contacted with the standing catalyst solution or with a solid surface coated with the catalyst solution, and polymerized at 0W-100°C to give a high polymer. The polymer is drawn at 100W250°C at a draw ratio of ≥250% under mechanical tension to give a polymer having anisotropic electrical conductivity.
COPYRIGHT: (C)1980,JPO&Japio
JP4788679A 1979-04-20 1979-04-20 Preparation of acetylene high polymer film or fiber having improved drawability Granted JPS55142012A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4788679A JPS55142012A (en) 1979-04-20 1979-04-20 Preparation of acetylene high polymer film or fiber having improved drawability

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4788679A JPS55142012A (en) 1979-04-20 1979-04-20 Preparation of acetylene high polymer film or fiber having improved drawability

Publications (2)

Publication Number Publication Date
JPS55142012A true JPS55142012A (en) 1980-11-06
JPS6160844B2 JPS6160844B2 (en) 1986-12-23

Family

ID=12787871

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4788679A Granted JPS55142012A (en) 1979-04-20 1979-04-20 Preparation of acetylene high polymer film or fiber having improved drawability

Country Status (1)

Country Link
JP (1) JPS55142012A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57154904A (en) * 1981-03-20 1982-09-24 Asahi Glass Co Ltd Antenna glass of car
JPS5896402A (en) * 1981-12-03 1983-06-08 Asahi Glass Co Ltd Antenna glass for automobile
US4600756A (en) * 1982-08-03 1986-07-15 Enichimica S.P.A. High-orientability polyacetylene films and process for their production
US4675137A (en) * 1983-08-31 1987-06-23 Hoxan Corporation Method for producing polyacetylene film
WO1994005710A1 (en) * 1992-08-29 1994-03-17 Basf Aktiengesellschaft Polyacetylenes

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57154904A (en) * 1981-03-20 1982-09-24 Asahi Glass Co Ltd Antenna glass of car
JPH0147921B2 (en) * 1981-03-20 1989-10-17 Asahi Glass Co Ltd
JPS5896402A (en) * 1981-12-03 1983-06-08 Asahi Glass Co Ltd Antenna glass for automobile
JPH0156562B2 (en) * 1981-12-03 1989-11-30 Asahi Glass Co Ltd
US4600756A (en) * 1982-08-03 1986-07-15 Enichimica S.P.A. High-orientability polyacetylene films and process for their production
US4675137A (en) * 1983-08-31 1987-06-23 Hoxan Corporation Method for producing polyacetylene film
WO1994005710A1 (en) * 1992-08-29 1994-03-17 Basf Aktiengesellschaft Polyacetylenes

Also Published As

Publication number Publication date
JPS6160844B2 (en) 1986-12-23

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