JPS5476689A - Preparation of peroxy group-containing main chain copolymer - Google Patents
Preparation of peroxy group-containing main chain copolymerInfo
- Publication number
- JPS5476689A JPS5476689A JP14360177A JP14360177A JPS5476689A JP S5476689 A JPS5476689 A JP S5476689A JP 14360177 A JP14360177 A JP 14360177A JP 14360177 A JP14360177 A JP 14360177A JP S5476689 A JPS5476689 A JP S5476689A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- copolymer
- preparation
- main chain
- dialkylperoxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PURPOSE: To prepare the title copolymer having radical reaction sites, and giving a graft copolymer with excellent impact strength, by the radical polymerization of a vinyl-containing dialkylperoxide with a non-conjugated monomer.
CONSTITUTION: A viyl-containing dialkylperoxide of formula II (R1W6 are H, alkyl; R7 is alkyl, etc.; n is 0W4) is prepared by reacting a vinyl epoxide of formula I, e.g. butadiene monoepoxide, with a peroxide of formula R7OOH, e.g. tert- butyl hydroperoxide. The compound II thus obtained is copolymerized with ≥90 mol% of a radically polymerizable non-conjugated monomer such as ethylene, under the conditions not to open the peroxide group. The copolymer is precipitated in a non-solvent, and filtered to obtain the objective polymer.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14360177A JPS6017285B2 (en) | 1977-11-30 | 1977-11-30 | Method for producing peroxy group-containing trunk copolymer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14360177A JPS6017285B2 (en) | 1977-11-30 | 1977-11-30 | Method for producing peroxy group-containing trunk copolymer |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5476689A true JPS5476689A (en) | 1979-06-19 |
JPS6017285B2 JPS6017285B2 (en) | 1985-05-02 |
Family
ID=15342508
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14360177A Expired JPS6017285B2 (en) | 1977-11-30 | 1977-11-30 | Method for producing peroxy group-containing trunk copolymer |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6017285B2 (en) |
-
1977
- 1977-11-30 JP JP14360177A patent/JPS6017285B2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS6017285B2 (en) | 1985-05-02 |
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