JPS5476576A - Preparation of 1-acyl-2,3-diacyloxyindoline - Google Patents
Preparation of 1-acyl-2,3-diacyloxyindolineInfo
- Publication number
- JPS5476576A JPS5476576A JP13942177A JP13942177A JPS5476576A JP S5476576 A JPS5476576 A JP S5476576A JP 13942177 A JP13942177 A JP 13942177A JP 13942177 A JP13942177 A JP 13942177A JP S5476576 A JPS5476576 A JP S5476576A
- Authority
- JP
- Japan
- Prior art keywords
- acetyl
- electrolytic oxidation
- oxidation
- diacyloxyindoline
- acyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Indole Compounds (AREA)
Abstract
PURPOSE: Title compoud used as an intermediate for indigo dyes is produced from readily available indolines by mild electrolytic oxidation without application of the alkali fusion process requiring the treatment at elevated temperatures.
CONSTITUTION: The electrolytic oxidation of 1-acylindole such as 1-acetyl-indole, 1-acetyl-4-methylindole or 1-acylindoline such as 1-acetylindoline or 1-acetyl-4- methylindoline is conducted using a solvent system mainly containing a lower aliphatic carboxylic acid such as acetic acid in the presence of a base such as triethylamine, pyridine or diazabicycloundecane in the temperature range from 10 to 30°C to produce the objective compound. The electrodes employed in the above oxidation is preferably made of platinum.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13942177A JPS5476576A (en) | 1977-11-22 | 1977-11-22 | Preparation of 1-acyl-2,3-diacyloxyindoline |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13942177A JPS5476576A (en) | 1977-11-22 | 1977-11-22 | Preparation of 1-acyl-2,3-diacyloxyindoline |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5476576A true JPS5476576A (en) | 1979-06-19 |
Family
ID=15244807
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13942177A Pending JPS5476576A (en) | 1977-11-22 | 1977-11-22 | Preparation of 1-acyl-2,3-diacyloxyindoline |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5476576A (en) |
-
1977
- 1977-11-22 JP JP13942177A patent/JPS5476576A/en active Pending
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