JPS5463053A - Preparation of 3, 4, 5, 6-tetrahydrophthalic anhydride - Google Patents
Preparation of 3, 4, 5, 6-tetrahydrophthalic anhydrideInfo
- Publication number
- JPS5463053A JPS5463053A JP13009077A JP13009077A JPS5463053A JP S5463053 A JPS5463053 A JP S5463053A JP 13009077 A JP13009077 A JP 13009077A JP 13009077 A JP13009077 A JP 13009077A JP S5463053 A JPS5463053 A JP S5463053A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- tetrahydrophthalic anhydride
- palladium catalyst
- preparation
- palladium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Furan Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To obtain the title compound usable as a raw material for pesticides and polyesters, a hardener for epoxy resins, etc., by isomerizing 1, 2, 3, 6-tetrahydrophthalic anhydride in the presence of a palladium catalyst and a basic compound.
CONSTITUTION: 1, 2, 3, 6- Tetrahydrophthalic anhydride is isomerized in the presence of (a) a palladium catalyst consisting of 0.1W10%, preferably 1W5% of palladium on a carrier, e.g. alumina, carbon, silica abhestos etc. and (b) a small amount of a compound selected from a hydroxide of an alkali (earth) metal, ammonia compound, a salt of a weak acid with a strong base, an organic amine, etc. in an atmosphere of nitrogen at 130W230°C, preferably 150W200°C for 3W12 hr to give the desired compound with little by-product formation.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP52130090A JPS5854144B2 (en) | 1977-10-29 | 1977-10-29 | Method for producing 3,4,5,6-tetrahydrophthalic anhydride |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP52130090A JPS5854144B2 (en) | 1977-10-29 | 1977-10-29 | Method for producing 3,4,5,6-tetrahydrophthalic anhydride |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5463053A true JPS5463053A (en) | 1979-05-21 |
JPS5854144B2 JPS5854144B2 (en) | 1983-12-02 |
Family
ID=15025722
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP52130090A Expired JPS5854144B2 (en) | 1977-10-29 | 1977-10-29 | Method for producing 3,4,5,6-tetrahydrophthalic anhydride |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5854144B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2948414A1 (en) * | 1979-12-01 | 1981-06-04 | New Japan Chemical Co. Ltd., Kyoto | 3,4,5,6-Tetra:hydro-phthalic anhydride prepn. - by isomerism of 1,2,3,6-isomer with palladium catalyst and inorganic salt |
JPH03188073A (en) * | 1989-12-15 | 1991-08-16 | New Japan Chem Co Ltd | Purification of 3,4,5,6-tetrahydrophthalic anhydride |
-
1977
- 1977-10-29 JP JP52130090A patent/JPS5854144B2/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2948414A1 (en) * | 1979-12-01 | 1981-06-04 | New Japan Chemical Co. Ltd., Kyoto | 3,4,5,6-Tetra:hydro-phthalic anhydride prepn. - by isomerism of 1,2,3,6-isomer with palladium catalyst and inorganic salt |
JPH03188073A (en) * | 1989-12-15 | 1991-08-16 | New Japan Chem Co Ltd | Purification of 3,4,5,6-tetrahydrophthalic anhydride |
Also Published As
Publication number | Publication date |
---|---|
JPS5854144B2 (en) | 1983-12-02 |
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