JPS5441816A - Preparation of methacrylate - Google Patents

Preparation of methacrylate

Info

Publication number
JPS5441816A
JPS5441816A JP10770277A JP10770277A JPS5441816A JP S5441816 A JPS5441816 A JP S5441816A JP 10770277 A JP10770277 A JP 10770277A JP 10770277 A JP10770277 A JP 10770277A JP S5441816 A JPS5441816 A JP S5441816A
Authority
JP
Japan
Prior art keywords
reaction
methacrylamide
methacrylate
reaction system
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10770277A
Other languages
Japanese (ja)
Other versions
JPS5938937B2 (en
Inventor
Joji Nishikido
Nobuhiro Tamura
Yohei Fukuoka
Tsutomu Kawabata
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP52107702A priority Critical patent/JPS5938937B2/en
Publication of JPS5441816A publication Critical patent/JPS5441816A/en
Publication of JPS5938937B2 publication Critical patent/JPS5938937B2/en
Expired legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To obtain the titled compound useful as an industrial material in high yield and with high selectivity by the reaction of methacrylamide with an alcohol in the presence of a specific catalyst without formation of polymers, while removing produced NH3 from the reaction system.
CONSTITUTION: A methacrylate is obtained by the reaction of methacrylamide with a primary alcohol, e.g. methanol, at 50W300°C under a pressure of 5W100 kg/cm2 in the presence of a small amount of water and at least one type of catalyst selected from a Zn bromide, a Zn nitrate, a Zn sulfate, a Zn borate, a Zn phosphate, and a Zn iodede, a Zn carboxylate, while removing formed NH3 from the reaction system intermittently or continuously.
EFFECT: No need to use conc. H2SO4 as ever, and no problems of the material of the reaction equipment and by-product formation of a great amount of ammosulfate.
COPYRIGHT: (C)1979,JPO&Japio
JP52107702A 1977-09-09 1977-09-09 Method for producing methacrylic acid ester Expired JPS5938937B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP52107702A JPS5938937B2 (en) 1977-09-09 1977-09-09 Method for producing methacrylic acid ester

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP52107702A JPS5938937B2 (en) 1977-09-09 1977-09-09 Method for producing methacrylic acid ester

Publications (2)

Publication Number Publication Date
JPS5441816A true JPS5441816A (en) 1979-04-03
JPS5938937B2 JPS5938937B2 (en) 1984-09-20

Family

ID=14465775

Family Applications (1)

Application Number Title Priority Date Filing Date
JP52107702A Expired JPS5938937B2 (en) 1977-09-09 1977-09-09 Method for producing methacrylic acid ester

Country Status (1)

Country Link
JP (1) JPS5938937B2 (en)

Also Published As

Publication number Publication date
JPS5938937B2 (en) 1984-09-20

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