JPS54148768A - Novel tricyclic alpha,beta-unsaturated ketone - Google Patents

Novel tricyclic alpha,beta-unsaturated ketone

Info

Publication number
JPS54148768A
JPS54148768A JP5526778A JP5526778A JPS54148768A JP S54148768 A JPS54148768 A JP S54148768A JP 5526778 A JP5526778 A JP 5526778A JP 5526778 A JP5526778 A JP 5526778A JP S54148768 A JPS54148768 A JP S54148768A
Authority
JP
Japan
Prior art keywords
formula
exo
unsaturated ketone
beta
alpha
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5526778A
Other languages
Japanese (ja)
Inventor
Naotake Takaishi
Yoshiaki Inamoto
Masamoto Matsukane
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to JP5526778A priority Critical patent/JPS54148768A/en
Priority to GB7915496A priority patent/GB2020656B/en
Priority to FR7911610A priority patent/FR2425419A1/en
Priority to CH434879A priority patent/CH639060A5/en
Priority to DE19792918747 priority patent/DE2918747A1/en
Publication of JPS54148768A publication Critical patent/JPS54148768A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • C11B9/0042—Essential oils; Perfumes compounds containing condensed hydrocarbon rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/28—Saturated compounds having —CHO groups bound to carbon atoms of rings other than six—membered aromatic rings
    • C07C47/34—Saturated compounds having —CHO groups bound to carbon atoms of rings other than six—membered aromatic rings polycyclic
    • C07C47/347—Saturated compounds having —CHO groups bound to carbon atoms of rings other than six—membered aromatic rings polycyclic having a —CHO group on a condensed ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/38—Unsaturated compounds having —CHO groups bound to carbon atoms of rings other than six—membered aromatic rings
    • C07C47/44—Unsaturated compounds having —CHO groups bound to carbon atoms of rings other than six—membered aromatic rings polycyclic
    • C07C47/445—Unsaturated compounds having —CHO groups bound to carbon atoms of rings other than six—membered aromatic rings polycyclic containing a condensed ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/21—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing rings other than six-membered aromatic rings

Abstract

NEW MATERIAL:A tricyclic α,β-unsaturated ketone of formula I: (R1 and R2 are H, 1W5C alkyl groups, and at least one of them is H; group of formula II is bonded to the exo side of the norbornane ring at the 8- or 9-position; the dotted line bond may not be present).
EXAMPLE: 4-(Endo-tricyclo [5.2.1.02,6] deca-3-ene-8-exo-yl)-but-3ene-2-one.
USE: Perfuming components haing woody fragrances. Perfume compositions, soaps, shampoos, and cosmetics.
PROCESS: 8- or 9-Exo-formyl-endotricyclo[5.2.1.02,6] dec-3-ene is condensed with an aliphatic methyl ketone (formula IV) in the presence of a catalyst, and dehydrated to give the compound of formula I.
COPYRIGHT: (C)1979,JPO&Japio
JP5526778A 1978-05-10 1978-05-10 Novel tricyclic alpha,beta-unsaturated ketone Pending JPS54148768A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP5526778A JPS54148768A (en) 1978-05-10 1978-05-10 Novel tricyclic alpha,beta-unsaturated ketone
GB7915496A GB2020656B (en) 1978-05-10 1979-05-03 Tricyclo a s unsaturated ketones
FR7911610A FR2425419A1 (en) 1978-05-10 1979-05-08 TRICYCLOCETONE A, B-UNSATURA, THEIR PREPARATION PROCESS AND THEIR APPLICATION IN THE MANUFACTURE OF PERFUMES AND PERFUME PRODUCTS
CH434879A CH639060A5 (en) 1978-05-10 1979-05-09 Ketone tricyclic alpha beta unsaturated.
DE19792918747 DE2918747A1 (en) 1978-05-10 1979-05-09 TRICYCLO-ALPHA, BETA-UNSATABLED KETONE

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5526778A JPS54148768A (en) 1978-05-10 1978-05-10 Novel tricyclic alpha,beta-unsaturated ketone

Publications (1)

Publication Number Publication Date
JPS54148768A true JPS54148768A (en) 1979-11-21

Family

ID=12993823

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5526778A Pending JPS54148768A (en) 1978-05-10 1978-05-10 Novel tricyclic alpha,beta-unsaturated ketone

Country Status (5)

Country Link
JP (1) JPS54148768A (en)
CH (1) CH639060A5 (en)
DE (1) DE2918747A1 (en)
FR (1) FR2425419A1 (en)
GB (1) GB2020656B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104024202A (en) * 2011-10-11 2014-09-03 威·曼父子有限公司 Novel cycloalkane aldehydes, methods for preparing same, and use thereof in the perfume industry

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2928313A1 (en) * 1979-07-13 1981-02-05 Ruhrchemie Ag METHOD OF MAKING 3-(4)-FORMYLTRICYCLO- SQUARE BRACKET TO 5,2,1,0 UP 2,6 SQUARE BRACKET TO -DECEN-8
DE3303893C2 (en) * 1983-02-05 1985-01-24 Dragoco Gerberding & Co Gmbh, 3450 Holzminden 2,6-Exo-configured tricyclo [5.2.1.0 → 2 → →, → → 6 →] decane derivatives with a functionalized side chain at C-9 and their use as odoriferous substances
EP0215799B1 (en) * 1984-12-19 1988-08-24 Dragoco Gerberding & Co. GmbH Tricyclo [5.2.1.0/2,6] decane/decene derivatives with functionalized alkylidene side chains and utilization thereof as perfuming substances
DE10144816A1 (en) * 2001-09-12 2003-03-27 Dragoco Gerberding Co Ag Fragrance and aroma

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3270061A (en) * 1964-04-16 1966-08-30 Norda Essential Oil & Chemical Oxygen-containing dicyclodiene derivatives
FR1416209A (en) * 1964-04-16 1965-10-29 Norda Essential Oil & Chemical Oxygenated derivatives of dicyclodiene
US3542877A (en) * 1967-01-24 1970-11-24 Universal Oil Prod Co Acyl substituted 4,7-methanoindenes
JPS5268168A (en) * 1975-12-04 1977-06-06 Kao Corp Preparation of 8- and 9-exo-formyl-endo-tricyclo 5,2,1,0 -dec-3-ene

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS=1966 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104024202A (en) * 2011-10-11 2014-09-03 威·曼父子有限公司 Novel cycloalkane aldehydes, methods for preparing same, and use thereof in the perfume industry

Also Published As

Publication number Publication date
FR2425419A1 (en) 1979-12-07
GB2020656A (en) 1979-11-21
CH639060A5 (en) 1983-10-31
FR2425419B1 (en) 1984-04-27
DE2918747A1 (en) 1979-11-22
GB2020656B (en) 1982-09-22

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