JPH1180797A - Liquid detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a liquid detergent composition of compact type that shows mild skin stimulation with high mildness, excellent detergency and cold storage stability by formulating specific amounts of a specific noionic surfactant and a specific hydrotropic agent. SOLUTION: This liquid detergent composition contains 30-50 wt.% of a nonionic surfactant composition that comprises (A) 8-25 wt.% of higher fatty acid mono- and/or diethanolamide and (B) 8-25 wt.% of an alcohol ethoxylate where the ratio of the component (A) to the component (B) is 1/2-2/1, and contains (C) a compound selected from lower alcohol, polyalkylene glycol and water-soluble polyol, (D) an aromatic sulfonic acid or its salts where the weight ratio of the component C to the component D is 20/1-1/5 and the total amount of the components C and D is 5-30 wt.%. In a preferred embodiment more than 70% of the component A is lauric acid diethanolamine.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a compact type liquid cleaning composition which is extremely useful as a cleaning agent for kitchens and other hard surfaces, and a body or hair cleaning agent. Has a very mild and high mildness, and also has excellent detergent power,
Moreover, the present invention relates to a liquid detergent composition having excellent storage stability at low temperatures.

[0002]

2. Description of the Related Art In recent years, compact type liquid cleaners for kitchens and the like and liquid cleaners for the body or hair have become mainstream, giving great advantages to consumers and distributors. I have.

[0003] Many surfactants have been developed mainly on anionic surfactants in view of the fact that they have an excellent detergency, for example, in surfactants incorporated in conventional compact-type liquid detergent compositions. In general, it has been known that when a liquid detergent composition mainly composed of an anionic surfactant is used as a detergent for kitchen, there is a problem in that hand roughening occurs.

[0004] In order to solve the above-mentioned problems, a recent liquid detergent composition has been proposed and put to practical use in combination with an anionic surfactant and an amine oxide.
However, as kitchen detergents have become more compact and the surfactant concentration in detergents that can be directly touched has increased, it has been required again to further improve mildness.

As a liquid detergent composition further improved in mildness, a combination of an amphoteric surfactant such as amidopropyl betaine having high mildness is known (for example, JP-A-4-253943, And JP-A-7-6
2388 publication), the amphoteric surfactants also have an electric charge in nature, and have a problem in that they may be irritated when adsorbed on the skin or hair and enter the body.

[0006] It can be easily analogized that a large amount of nonionic surfactants having essentially no charge can be used to solve this problem. However, the nonionic surfactant alone can be used to generate foaming power. It was not possible to satisfy the functions originally required of a cleaning agent, such as cleaning power and detergency.

On the other hand, the present applicant has proposed a liquid detergent composition containing an alkanolamide having a very high detergency, despite being a nonionic surfactant (Japanese Patent Application Laid-Open No. 63-163). 112700, JP-A-3-18
8195). However, since this alkanolamide has a high melting point, if it is blended as a main component of a liquid detergent, the low-temperature storage stability is slightly inferior, and precipitates are generated, and there is a slight problem in that cloudiness and solidification are likely to occur. In addition, since it is nonionic, it does not cause protein denaturation,
It had some irritation to the skin.

For this reason, development of a liquid detergent composition containing an alkanolamide as a main component, which has mild mild irritation to the skin, has excellent detergency, and has good low-temperature stability. Recently, there is a strong demand.

[0009]

SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned problems of the prior art, and aims to solve the problem.
An object of the present invention is to provide a compact liquid detergent composition having mild and high mild irritation to the skin, excellent detergency, and good low-temperature stability.

[0010]

Means for Solving the Problems The present inventors have conducted intensive studies in order to solve the above-mentioned problems of the prior art, and as a result, have found that a liquid detergent composition containing a surfactant in an amount of 30 to 50% by weight, The inventor has found that by mixing a specific nonionic surfactant and a specific component in a specific amount, the liquid detergent composition of the above object can be obtained, thereby completing the present invention. That is, the liquid cleaning composition of the present invention is a liquid cleaning composition containing a surfactant in a range of 30 to 50% by weight, and the liquid cleaning composition includes:
(A) higher fatty acid mono- and / or diethanolamide 8
~ 25% by weight, and (b) alcohol ethoxylate 8 ~
25% by weight, and the compounding ratio of the above components (a) and (b) [(a) :( b)] is 1: 2 to 2: 1. (B) the total blending amount of the components is 16 to 40% by weight, and (c) at least one compound selected from lower alcohols, polyalkylene glycols, and water-soluble polyols; and (d) aromatic sulfonic acid or At least one compound selected from the salts thereof, and the compounding ratio of the component (c) to the component (d) [(c) :( d)] is 2
0: 1 to 1: 5, and the total amount of the components (c) and (d) is 5 to 30% by weight.

[0011]

Embodiments of the present invention will be described below in detail. The higher fatty acid mono- and / or diethanolamide [component (a)] used in the present invention is a kind of nonionic surfactant, and is not particularly limited by its structure or production method. It is desirable that the residue has 8 to 18 carbon atoms, more preferably 10 to 14 carbon atoms. Specifically, decanoic acid monoethanolamide, decanoic acid diethanolamide, lauric acid monoethanolamide, lauric acid diethanolamide,
Examples thereof include myristic acid monoethanolamide, myristic acid diethanolamide, coconut fatty acid monoethanolamide, and coconut fatty acid diethanolamide, and these can be used alone or in combination. Among these, lauric acid diethanolamide is particularly preferred because it has a specifically high detergency, and among the higher fatty acid mono- and / or diethanolamides used in the present invention, (a)
It is particularly desirable that at least 50% by weight or more, more preferably 70% by weight or more, of the amount of the component is lauric acid diethanolamide.

The amount of the higher fatty acid mono- and / or diethanolamide in the present invention is 8 to the total amount of the composition.
-25% by weight, preferably 9-20% by weight. If the amount is less than 8% by weight, sufficient detergency cannot be exhibited, while if it exceeds 25% by weight, precipitation and solidification tend to occur, which is not preferable.

The alcohol ethoxylate (component (b)) used in the present invention is an ethylene oxide adduct of alcohol, and is a kind of nonionic surfactant. The alcohol ethoxylate in the present invention is not particularly limited by its structure, production method and the like, and preferably has an alkyl hydrophobic group having 8 to 18 carbon atoms and a hydrophilic group having an average degree of polymerization of oxyethylene group of 1 to 1. 50 is preferred. More preferably, the number of carbon atoms in the hydrophobic group is preferably 10 to 14, and the average degree of polymerization of the hydrophilic group is preferably 12 or more. Specifically, polyoxyethylene (12) lauryl ether, polyoxyethylene (12) decyl ether, polyoxyethylene (15) lauryl ether, polyoxyethylene (15) myristyl ether, polyoxyethylene (20) lauryl ether, Polyoxyethylene (20) myristyl ether, polyoxyethylene (3
0) Lauryl ether and the like, and these can be used alone or in combination. Among these, polyoxyethylene (12) lauryl ether and polyoxyethylene (15) lauryl ether are particularly preferable in terms of satisfying both mildness and low-temperature stability.

The amount of the alcohol ethoxylate in the present invention is 8 to 25% by weight, preferably 9 to 20% by weight. In the present invention, since the blending of the high EO addition type alcohol ethoxylate particularly contributes to mildness, if the blending amount is less than 8% by weight, skin irritation cannot be completely reduced, Conversely, high EO addition type alcohol ethoxylate has low detergency,
If the blending amount is too large, that is, if the blending amount exceeds 25% by weight, the detergency decreases, which is not preferable. Also,
The present invention is characterized by a combination that maximizes the effects of both (component (a) and component (b)). Specifically, the mixing ratio of the above components (a) and (b) [(A) :( b), weight ratio] is 1: 2 to 2: 1, and the total amount [(a) + (b), weight%] is 16% based on the total amount of the composition. It needs to be ４０40% by weight.
If the mixing ratio and the mixing amount exceed the above ranges, the desired mildness and detergency cannot be achieved at the same time, which is not preferable.

In the present invention, the above component (a) and the above
The component (b) further comprises a lower alcohol, a polyalkylene glycol, at least one compound selected from among water-soluble polyols (component (c)), and at least one compound selected from aromatic sulfonic acids (( d) component] as essential components. At least one compound selected from the above components (c) and (d) is as described above.
It has a role as a hydrotrope agent for effectively improving the low-temperature stability of the component (a).

Examples of the lower alcohol to be the component (c) include, but are not limited to, ethanol, idpropanol, and ethylene glycol mono-lower alkyl (1-4 carbon atoms) ether. As the polyalkylene glycol to be the component (c),
For example, ethylene glycol, molecular weight 50 to 10,000
0 polyethylene glycol, propylene glycol,
Examples include, but are not limited to, polypropylene glycol having a molecular weight of 80 to 10,000. As the water-soluble polyol serving as the component (c), for example,
Examples include, but are not limited to, glycerin, polyglycerin having a molecular weight of 100 to 10,000, glucose, polyglucose, mannose, galactose, fructose, sucrose, lower alkyl glucose, and pentaerythritol.

The aromatic sulfonic acid serving as the component (d) includes, for example, toluenesulfonic acid, xylenesulfonic acid, cumenesulfonic acid and the like, and these can be used alone or in combination.

At least one type of hydrotrope (compound) selected from the above-mentioned components (c) and (d) is more preferably used when compounded at a specific ratio than when used alone. It was found that the effect of the hydrotrope was high. That is, it is inferred that the functions of the component (c) and the component (d) as the hydrotrope agent are different. Specifically, the lower alcohol or the like of the component (c) exerts a hydrotrope effect by breaking the hydration structure of water as a solvent and weakening hydrogen bonds, whereas the lower alcohol of the component (d) Aromatic sulfonic acid is an organic compound that easily crystallizes, and in the present invention, is coordinated in the vicinity of a hydrophilic group such as an alkanolamide to suppress coalescence and phase separation from water. Therefore, the present invention is characterized by a combination that maximizes the effects of both of them, and specifically, the compounding ratio of the components (c) and (d) [(c) :( d) , Weight ratio] is 2
0: 1 to 1: 5, preferably 5: 1 to 1: 4,
The total amount of the mixed hydrotrope (component (c) + component (d)) is 5 to the total amount of the composition.
It is necessary that the content be 30 to 30% by weight, preferably 8 to 20% by weight. If the mixing ratio is less than 20: 1 and the total amount is less than 5% by weight, the effect as a hydrotrope becomes insufficient, and if the mixing ratio exceeds 1: 5 and the total amount exceeds 30% by weight, If it is present, the cleaning power is reduced, which is not preferable.

The cleaning composition of the present invention may further contain a surfactant or other additives other than the above-mentioned components (a) and (b) which impair the effects of the present invention. Any combination may be used within a range that does not exist.

In the present invention, examples of the nonionic surfactant other than the components (a) and (b) that can be blended include, for example, a cyclic or acyclic polyol having two or more free hydroxyl groups in the molecule. A nonionic surfactant having a hydrophilic group is exemplified. Specifically, alkyl polyglucoside, methyl glucoside fatty acid ester, ethyl glucoside fatty acid ester, sucrose fatty acid ester, alkyl mannoside, alkyl fructoside, methyl glucamine fatty acid amide, alkyl polyglyceride, etc. Is not limited.

Further, anionic surfactants and amphoteric surfactants can be preferably added to the detergent composition of the present invention as long as the effects of the present invention are not impaired. The anionic surfactant that can be used is not particularly limited by its type or structure, but specifically, polyoxyethylene alkyl ether sulfate, α olefin sulfonate, α
Examples include, but are not limited to, sulfo fatty acid salts, alkyl benzene sulfonates, fatty acid soaps, sulfosuccinates, alkyl ether carboxylates, and the like.

Examples of the amphoteric surfactant include, for example,
Examples include, but are not limited to, amine oxides, alkyl betaines, alkyl hydroxysulfo betaines, alkyl amide betaines, imidazolinium betaines, alkyl amino acids, and the like.

These surfactants may be used alone or as appropriate.
It can be blended in combination of more than one kind. In the present invention, the above-mentioned various surfactants and the above-mentioned component (a), (b)
The total weight of the components is 30 to 50 relative to the total amount of the detergent composition.
It must be contained in the range of% by weight, so that the intended compact type liquid detergent composition is provided. If the total weight exceeds 50% by weight, skin irritation is undesirably increased. Also, 3
If the content is less than 0% by weight, the cleaning power of a compact type liquid detergent is reduced, which is not preferable.

The solvent of the detergent composition of the present invention is not particularly limited, but is preferably water (purified water).
Can be used. Further, other preferable components that can be blended include, for example, cationic surfactants such as alkylamine hydrochloride and quaternary ammonium salt, chelating agents such as citric acid, builders such as inorganic salts, and viscosity modifiers. , Coloring agents, antioxidants, preservatives, bactericides, anti-inflammatory agents,
Commonly used substances such as medicinal ingredients and fragrances may be added.

[0025]

Next, the present invention will be described in more detail with reference to Examples and Comparative Examples. Note that the present invention is not limited to these examples.

(Examples 1 to 8, Comparative Examples 1 to 18) A liquid detergent composition was prepared according to the composition shown in Tables 1 and 2 below, and skin irritation (sensory evaluation) was performed according to the following test methods. Detergency and low-temperature stability were evaluated. The results are shown in Tables 1 and 2 below. In addition, the compounding quantity in a table | surface is "weight%", and pH adjusted the composition to 6.5.

(Evaluation of skin irritation) Surfactant composition 1
% Aqueous solution (35 ° C.) was evaluated by an immersion test by hand of 10 testers. That is, the immersion-drying operation was performed 15 times every minute, and the degree of skin roughness of the hand after 24 hours was visually judged according to the following evaluation criteria. Evaluation Criteria: ○: Almost no skin roughness △: Signs of rough skin such as dry desquamation and red spot change are observed on part of the keratinous surface of the skin ×: Hand rough symptoms such as dry desquamation and red spot change Clearly acknowledged

(Evaluation of detergency) 1 g of beef tallow is 10 cm × 1
The solution was evenly applied to a 5 cm tapper container to obtain a severely soiled hydrophobic surface stain. 11.5cm × 7.5cm
Take 38 g of water and 2 g of various cleaning compositions of Table 1 in a × 3 cm dishwashing sponge, rub them by hand several times, and remove the contaminated tapper container at 25 ° C. in the same manner as usual at home. And washed. After the washing, the well was rinsed with water, and the contaminated surface of the tapper container at that time was evaluated by the touch when touched by hand according to the following evaluation criteria. Evaluation criteria: ：: Touching any part of the tapper container gives a squeaky and frictional feeling, and no sliminess due to residual oil is felt. Δ: There is a feeling of friction when touching the smooth surface of the tapper container, and no oil remains, but lubricity remains at edges and corners. ×: The entire tapper container is felt slimy, and it is apparent that oil remains.

(Low Temperature Stability) The composition was filled in a 100 ml glass bottle, stored in a constant temperature bath at -20 ° C. for 1 day, frozen, then stored in a constant temperature bath at 0 ° C. for 1 day, thawed, and restored. The appearance at 0 ° C. was determined according to the following evaluation criteria. Evaluation was made based on the following evaluation criteria. Evaluation criteria: ○: uniformly transparent ×: cloudy or solid

[0030]

[Table 1]

[0031]

[Table 2]

(Consideration of Tables 1 and 2) Examples 1 to 8 which fall within the scope of the present invention have no skin irritation, and have detergency and low temperature as compared with Comparative Examples 1 to 18 which fall outside the scope of the present invention. It turned out to be excellent in stability. Specifically, in Examples 1 to 8, the components (a), (b), (c), and (d) were blended, and the components (a) and (b) were mixed. And the total amount of the above, and the above
When the compounding ratio and the total compounding amount of the component (c) and the component (d) fall within the range of the present invention, for the first time, there is no skin irritation, and the cleaning power and the low-temperature stability are excellent. On the other hand, in Comparative Examples 1 to 18, the components (a), (b), (c) and (d),
When at least one of the compounding ratio and the total compounding amount of the component (b) and the compounding ratio and the total compounding amount of the component (c) and the component (d) are out of the range of the present invention, skin irritation occurs. It was found that all of the properties, detergency and low-temperature stability could not be satisfied.

[0033]

Industrial Applicability According to the present invention, there is provided a detergent composition which has mild mild irritation to the skin, has excellent detergency, and also has good low-temperature stability. The present invention provides a liquid cleaning composition suitable as a hard surface cleaning agent such as an agent, a body cleaning agent, and a hair cleaning agent.

──────────────────────────────────────────────────の Continuation of the front page (51) Int.Cl. ⁶ Identification code FI C11D 3:20 1:12) (72) Inventor Masao Nishida 1-3-7 Honjo, Sumida-ku, Tokyo Lion Corporation Inside

Claims (1)

[Claims] 1. A liquid detergent composition containing a surfactant in an amount of 30 to 50% by weight, wherein the liquid detergent composition comprises (a) a higher fatty acid mono- and / or diethanolamide 8 to 25% by weight and (b) 8 to 25% by weight of an alcohol ethoxylate, and the compounding ratio of the above components (a) and (b) [(a) :( b)] is 1: 2 to 2 2: 1
And the total amount of component (a) and component (b) is 1
6 to 40% by weight, and (c) at least one compound selected from lower alcohols, polyalkylene glycols, and water-soluble polyols; and (d) at least one compound selected from aromatic sulfonic acids or salts thereof. And the compounding ratio of component (c) to component (d) [(c):
(d)] is 20: 1 to 1: 5, and the total blending amount of the component (c) and the component (d) is 5 to 30% by weight.