JPH115730A - Bathing agent composition - Google Patents

Bathing agent composition

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Publication number
JPH115730A
JPH115730A JP9159831A JP15983197A JPH115730A JP H115730 A JPH115730 A JP H115730A JP 9159831 A JP9159831 A JP 9159831A JP 15983197 A JP15983197 A JP 15983197A JP H115730 A JPH115730 A JP H115730A
Authority
JP
Japan
Prior art keywords
oil
bathing
skin
rice
cationic polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP9159831A
Other languages
Japanese (ja)
Other versions
JP3272978B2 (en
Inventor
Tatsuo Oshima
龍雄 大島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanebo Ltd
Original Assignee
Kanebo Ltd
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Priority to JP15983197A priority Critical patent/JP3272978B2/en
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Abstract

PROBLEM TO BE SOLVED: To obtain the subject composition giving an excellent smoothness to the skin after bathing, moistening effects after bathing, free from a feeling of stickiness after bathing, by including plural kinds of lactose, rice germ oil or rice bran oil, a cationic polymer and isostearyl alcohol. SOLUTION: This composition comprises two or more components as indispensable components selected from the group of (A) 0.5-30.0 wt.% of a lactose (either α form or β form will do), (B) 0.05-10.00 wt.% of a rice germ oil or rice bran oil, (C) 0.2-5.0 wt.% of a cationic polymer (preferably a water-soluble, e.g. quaternary nitrogen-containing cellulose ether composed of a glycidyl trimethyl ammonium halide and hydroxy ethyl cellulose) and (D) 0.1-5.0 wt.% of isostearyl alcohol. To obtain an aimed formulation an inorganic salt, an inorganic acid, an organic acid, an oil and fat, a polyhydric alcohol, a crude medicine, a herb, a perfume, a natural coloring matter, etc., are additionally formulated as appropriate for the purpose.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、入浴後のべたつき
感がなく、入浴時の肌のなめらかさ、及び入浴後の肌の
しっとり効果に優れた、浴剤組成物に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a bath preparation composition which does not have a sticky feeling after bathing, has excellent skin smoothness during bathing, and has an excellent moisturizing effect after bathing.

【0002】[0002]

【従来の技術】浴剤組成物は一般に、硫酸ナトリウム、
炭酸水素ナトリウム等の無機塩混合物に、香料、色素、
保湿剤等を配合したもので、浴湯に香りや色調を与えた
り、無機塩の作用による血行促進効果や保温効果によっ
て疲労を回復しリラックス感を与えるものである。
2. Description of the Related Art Bath compositions generally include sodium sulfate,
Inorganic salt mixtures such as sodium bicarbonate, flavors, pigments,
A compound containing a moisturizing agent or the like, which imparts aroma and color tone to the bath water, recovers fatigue by the effect of promoting the blood circulation and the heat retaining effect by the action of inorganic salts, and gives a feeling of relaxation.

【0003】一方、最近では、消費者ニーズの多様化か
ら、美肌効果のある入浴剤が望まれてきている。
[0003] On the other hand, recently, diversification of consumer needs has demanded a bath agent having a beautiful skin effect.

【0004】[0004]

【発明が解決しようとする課題】このような要望に応え
るべく、各種の浴剤組成物が数多く提案されているが、
消費者の満足感を得られるものは少なく、それぞれに何
らかの問題点を有しているというのが実情である。例え
ば、油成分を利用したものがあるが、効果を得るには油
の配合量を多くせねばならず、それによって浴後、肌が
べたついたり、浴槽が油で汚れる等の問題を生じる場合
が多い。また、脱脂粉乳等の牛乳成分を配合したものも
提案されているが、製品の経日変化で牛乳成分が凝集し
湯面に浮遊したり、不快臭が発生する等の問題があっ
た。
In order to meet such demands, various bath compositions have been proposed.
Few consumers can get satisfaction, and each of them has some problems. For example, there is a case using an oil component, but in order to obtain the effect, it is necessary to increase the amount of the oil, which often causes problems such as sticky skin and bathtub stains with oil after bathing. . In addition, a composition containing a milk component such as skim milk powder has been proposed, but there were problems such as the milk component aggregating and floating on the surface of the hot water and generating an unpleasant odor due to the daily change of the product.

【0005】本発明は、このような実情のもとでなされ
たものであって、入浴後のべたつき感がなく、入浴時の
肌のなめらかさ、及び入浴後の肌のしっとり効果に優れ
た浴剤組成物を提供することを目的とする。
The present invention has been made under such circumstances, and has no sticky feeling after bathing, and has excellent skin smoothness at the time of bathing and an excellent moisturizing effect after bathing. It is intended to provide an agent composition.

【0006】[0006]

【課題を解決するための手段】本発明者は、種々の化合
物の組合せについて鋭意検討した結果、驚くべきこと
に、ラクトース、米胚芽油又は米糠油、カチオン性ポリ
マー、イソステアリルアルコールからなる群より二種以
上を併用することが本発明の上記目的を達成できること
を見出した。すなわち、本発明は、ラクトース、米胚芽
油又は米糠油、カチオン性ポリマー、イソステアリルア
ルコールからなる群より選ばれる少なくとも二種以上を
含有することを特徴とする浴剤組成物にある。
Means for Solving the Problems As a result of intensive studies on the combinations of various compounds, the present inventors have surprisingly found that lactose, rice germ oil or rice bran oil, a cationic polymer, and isostearyl alcohol are included. It has been found that the combination of two or more can achieve the above object of the present invention. That is, the present invention resides in a bath agent composition containing at least two or more selected from the group consisting of lactose, rice germ oil or rice bran oil, a cationic polymer, and isostearyl alcohol.

【0007】[0007]

【発明の実施の形態】以下、本発明を詳細に説明する。
本発明に用いられるカチオン性ポリマーとしては、水溶
性であることが好ましく、例えばグリシジルトリメチル
アンモニウムハライドとヒドロキシエチルセルロースか
らなる、第4級窒素含有セルロースエーテル(例えば、
ユニオンカーバイド社製ポリマーJR−400)、ジア
リルジメチルアンモニウムハライド/ヒドロキシエチル
セルロースグラフト共重合体(例えば、NSC社製セル
コートL200)、ヒドロキシプロピルグァーガム第4
級アンモニウム誘導体(例えば、MEYHALL社製J
aguarC13S)、ポリ(ジメチルジアリルアンモ
ニウムハライド)型カチオンポリマー(例えば、メルク
社製マーコートH)、ジメチルジアリルアンモニウムハ
ライドとアクリルアミド共重合体型カチオンポリマー
(例えば、メルク社製マーコート550)、ポリグリコ
ールポリアミン縮合物(例えば、ヘンケル社製ポリコー
トH)、ビニルピロリドン・ジメチルアミノエチルメタ
アクリレート共重合体カチオン化物(例えば、GAF社
製ガフコート755N、ガフコート734)等が挙げら
れる。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail.
The cationic polymer used in the present invention is preferably water-soluble, for example, a quaternary nitrogen-containing cellulose ether composed of glycidyltrimethylammonium halide and hydroxyethylcellulose (for example,
Union Carbide polymer JR-400), diallyldimethylammonium halide / hydroxyethylcellulose graft copolymer (eg, NSC Cellcoat L200), hydroxypropyl guar gum No. 4
Grade ammonium derivative (for example, JYHALL J
aguarC13S), poly (dimethyldiallylammonium halide) type cationic polymer (for example, Mercoat H manufactured by Merck), dimethyldiallylammonium halide and acrylamide copolymer type cationic polymer (for example, Mercoat 550 manufactured by Merck), polyglycolpolyamine condensate ( For example, polycoat H manufactured by Henkel Co., and cationized vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer (for example, Guff Coat 755N and Guff Coat 734 manufactured by GAF) are exemplified.

【0008】上記カチオン性ポリマーは1種又は2種以
上を配合することができるが、配合量としては本発明の
浴剤組成物総量に対して、好ましくは0.2〜5.0重
量%(以下、wt%と略する)、更に好ましくは0.5
〜3.0wt%配合される。配合量が0.2wt%未満
では、入浴時の肌のなめらかさに良好な効果が得られな
い場合があり、5.0wt%を超えると入浴時の肌にぬ
るつきが生じ、入浴後の肌のしっとり効果が得られず、
好ましくない場合がある。
The cationic polymer may be used alone or in combination of two or more. The amount is preferably 0.2 to 5.0% by weight based on the total amount of the bath composition of the present invention. Hereinafter, abbreviated as wt%), more preferably 0.5%.
33.0 wt%. If the amount is less than 0.2% by weight, good effects on the smoothness of the skin during bathing may not be obtained. Moist effect is not obtained,
May not be preferred.

【0009】本発明に用いられるイソステアリルアルコ
ールの配合量は、当該浴剤組成物の総量に対して好まし
くは0.1〜5.0wt%、更に好ましくは0.3〜
3.0wt%配合される。配合量が0.1%未満では、
入浴時の肌のなめらかさ、及び入浴後の肌のしっとり効
果に良好な効果が得られない場合があり、5.0wt%
を超えると入浴後の肌がべたつき、好ましくない傾向が
ある。
The amount of isostearyl alcohol used in the present invention is preferably 0.1 to 5.0% by weight, more preferably 0.3 to 5.0% by weight based on the total amount of the bath composition.
3.0 wt% is blended. If the amount is less than 0.1%,
Good effect may not be obtained on the smoothness of the skin when taking a bath and the moistening effect of the skin after taking a bath.
If it exceeds 300, the skin after bathing tends to be sticky and unfavorable.

【0010】本発明に用いられる米胚芽油は、イネ[Or
yza sativa L.(Gramineae)] の胚芽より得た脂肪油であ
る。オリザノールやビタミンA,Eを含み、ボーソー玄
米胚芽油やボーソーライスジャームオイルOZ(丸善製
薬社)、オリザオイルS−1(一丸ファルコス社)等の
名称にて市販されている。米糠油の配合量は当該浴剤組
成物の総量に対して好ましくは0.05〜10.00w
t%、更に好ましくは0.1〜7.0wt%配合され
る。配合量が0.05%未満では、入浴時の肌のなめら
かさ、及び入浴後の肌のしっとり効果に良好な効果が得
られない場合があり、10.00wt%を超えると入浴
後の肌がべたつき好ましくない傾向がある。
The rice germ oil used in the present invention is rice [Or
yza sativa L. (Gramineae)]. It contains oryzanol and vitamins A and E, and is commercially available under the names such as Bosseau brown rice germ oil, Bossoi rice germ oil OZ (Maruzen Pharmaceutical Co., Ltd.), and ORYZA OIL S-1 (Ichimaru Falcos). The amount of the rice bran oil is preferably 0.05 to 10.00 w with respect to the total amount of the bath agent composition.
t%, more preferably 0.1 to 7.0 wt%. If the amount is less than 0.05%, the smoothness of the skin during bathing and the effect of moistening the skin after bathing may not be obtained. If it exceeds 10.00% by weight, the skin after bathing may not be obtained. Stickiness tends to be undesirable.

【0011】本発明に用いられる米糠油は、米油とも呼
ばれ、米(Oryza sativa L.)の種子の精米直後の米糠か
ら得られる半乾性油である。トコフェロールやオリザノ
ール、ステロール等を含み、オリザオイルS−1(一丸
ファルコス社)やライスオイル(野田ワックス社)等の
名称にて市販されている。米糠油の配合量は当該浴剤組
成物の総量に対して好ましくは0.05〜10.00w
t%、更に好ましくは0.1〜7.0wt%配合され
る。配合量が0.05%未満では、入浴時の肌のなめら
かさ、及び入浴後の肌のしっとり効果に良好な効果が得
られない場合があり、10.00wt%を超えると入浴
後の肌がべたつき好ましくない傾向がある。
[0011] The rice bran oil used in the present invention is also called rice oil and is a semi-dry oil obtained from rice bran immediately after milling of rice (Oryza sativa L.) seeds. It contains tocopherol, oryzanol, sterol, and the like, and is commercially available under the names of ORYZA OIL S-1 (Ichimaru Falcos) and Rice Oil (NODA WAX). The amount of the rice bran oil is preferably 0.05 to 10.00 w with respect to the total amount of the bath agent composition.
t%, more preferably 0.1 to 7.0 wt%. If the amount is less than 0.05%, the smoothness of the skin during bathing and the effect of moistening the skin after bathing may not be obtained. If it exceeds 10.00% by weight, the skin after bathing may not be obtained. Stickiness tends to be undesirable.

【0012】本発明に用いられるラクトースは、α体、
β体のいずれの化合物をも使用できる。ラクトースの配
合量としては、本発明に係る浴剤組成物総量に対して、
好ましくは0.5〜30.0wt%、更に好ましくは
1.0〜20.0wt%配合される。配合量が0.5w
t%未満では、入浴時の肌のなめらかさ、入浴後の肌の
しっとり効果に良好な効果が得られない場合があり、3
0.0wt%を超えると入浴時の肌にぬるつきが生じ、
入浴後の肌のしっとり効果が得られず、好ましくない場
合がある。
Lactose used in the present invention is an α-form,
Any compound in β-form can be used. The amount of lactose, based on the total amount of the bath composition according to the present invention,
Preferably, the content is 0.5 to 30.0 wt%, more preferably 1.0 to 20.0 wt%. 0.5w
If it is less than t%, good effects may not be obtained on the smoothness of the skin at the time of bathing and the moisturizing effect of the skin after bathing.
If it exceeds 0.0 wt%, the skin at the time of bathing becomes slimy,
The moisturizing effect of the skin after bathing cannot be obtained, which may be undesirable.

【0013】本発明に係る浴剤組成物は、上述した成分
以外に、下記の他の成分等を本発明の目的を達成する範
囲で適宜配合することができる。
[0013] In addition to the above-mentioned components, the bath agent composition according to the present invention can be appropriately blended with the following other components as long as the object of the present invention is achieved.

【0014】1)無機塩類 炭酸ナトリウム、セスキ炭酸ナトリウム、炭酸水素ナト
リウム、塩化ナトリウム、硫酸ナトリウム、チオ硫酸ナ
トリウム、硫酸アンモニウム、炭酸マグネシウム、ホウ
砂、硝酸カルシウム、硝酸カリウム、硝酸ナトリウム、
硫酸アルミニウム、ポリリン酸ナトリウム、塩化アンモ
ニウム、硫酸鉄、リン酸ナトリウム、硫酸マグネシウ
ム、酸化カルシウム、炭酸マグネシウム、硫化ナトリウ
ム、硫化カリウム等。
1) Inorganic salts: sodium carbonate, sodium sesquicarbonate, sodium hydrogen carbonate, sodium chloride, sodium sulfate, sodium thiosulfate, ammonium sulfate, magnesium carbonate, borax, calcium nitrate, potassium nitrate, sodium nitrate,
Aluminum sulfate, sodium polyphosphate, ammonium chloride, iron sulfate, sodium phosphate, magnesium sulfate, calcium oxide, magnesium carbonate, sodium sulfide, potassium sulfide, etc.

【0015】2)無機酸類 無水ケイ酸、メタケイ酸、ホウ酸等。2) Inorganic acids Silicic anhydride, metasilicic acid, boric acid and the like.

【0016】3)有機酸類 安息香酸、クエン酸、フマル酸、酒石酸、リンゴ酸、サ
リチル酸等及びこれらの塩。
3) Organic acids Benzoic acid, citric acid, fumaric acid, tartaric acid, malic acid, salicylic acid and the like and salts thereof.

【0017】4)油脂類 オリーブ油、大豆油、アーモンド油、ひまし油、やし
油、パーム油、タートル油、ミンク油、ホホバ油、卵黄
油、スクワラン、ラノリン、流動パラフィン、白色ワセ
リン等。
4) Fats and oils Olive oil, soybean oil, almond oil, castor oil, coconut oil, palm oil, turtle oil, mink oil, jojoba oil, egg yolk oil, squalane, lanolin, liquid paraffin, white petrolatum, etc.

【0018】5)多価アルコール グリセリン、プロピレングリコール、ソルビトール、ポ
リエチレングリコール、1,3−ブチレングリコール、
イソプレングリコール等。
5) Polyhydric alcohols glycerin, propylene glycol, sorbitol, polyethylene glycol, 1,3-butylene glycol,
Isoprene glycol and the like.

【0019】6)生薬、ハーブ類 チンピ、トウキ、ニンジン、シャクヤク、ショウブ、シ
ソ、ヨモギ、カミツレ、ハッカ、オオバク、モモ、アロ
エ、ヘチマ、イチョウ、アシタバ、オウゴン、マロニ
エ、レイシ、アルニカ等。
6) Herbal medicines, herbs, chimpanzees, touki, carrots, peonies, shobu, perilla, mugwort, chamomile, peppermint, psyllium, peach, aloe, loofah, ginkgo, ashitaba, ougon, malonier, reishi, arnica and the like.

【0020】7)香料類 ラベンダー油、ジャスミン油、ローズ油、レモン油、オ
レンジ油、ハッカ油、タイム油、ショウブ油、ヒバ油、
ヒノキ油、バラ油、ユーカリ油、カンファー、ペパーミ
ント油、スペアミント油、ゲラニオール、シトロネロー
ル等の天然及び合成香料等。
7) Flavors Lavender oil, jasmine oil, rose oil, lemon oil, orange oil, peppermint oil, thyme oil, shobu oil, hiba oil,
Natural and synthetic flavors such as hinoki oil, rose oil, eucalyptus oil, camphor, peppermint oil, spearmint oil, geraniol, citronellol and the like.

【0021】さらに、本発明に係る浴剤組成物は、上記
の成分以外にも、酸化チタン、タルク、界面活性剤、殺
菌剤、ビタミン類、厚生省令に定められたタール色素別
表I及びIIの色素、クロロフィル、リボフラビン、紅
花、アントラキノン等の食品添加物として認められてい
る天然色素等を適宜配合できる。
Further, in addition to the above-mentioned components, the bath agent composition according to the present invention contains titanium oxide, talc, a surfactant, a bactericide, vitamins and tar dyes specified in the Ordinance of the Ministry of Health and Welfare. Natural pigments recognized as food additives such as pigments, chlorophyll, riboflavin, safflower, and anthraquinone can be appropriately compounded.

【0022】本発明に係る浴剤組成物は常法により、散
剤、顆粒剤、錠剤、液状等の剤型とすることができる。
The bath agent composition according to the present invention can be made into a powder, granule, tablet, liquid or other dosage form by a conventional method.

【0023】[0023]

【実施例】以下、実施例を挙げ本発明を説明するが、本
発明はこれら実施例に限定されるものではない。尚、本
実施例中で用いた評価方法は下記の通りである。
The present invention will be described below with reference to examples, but the present invention is not limited to these examples. The evaluation method used in this example is as follows.

【0024】(評価方法)被験者10名に実施例または
比較例を配合したお湯に入浴させ、入浴中の感触、入浴
後の肌の状態について感触で評価した。
(Evaluation Method) Ten subjects were bathed in hot water containing Examples or Comparative Examples, and the feeling during bathing and the condition of the skin after bathing were evaluated by feeling.

【0025】実施例1〜16、比較例1〜4 表1、2に示す各成分をリボンミキサーにて30分間混
合攪拌し、浴剤組成物を調製した。ついで41℃のお湯
180lに各浴剤組成物30gを溶解し、被験者10名
を10分間入浴させた後、評価した。
Examples 1 to 16 and Comparative Examples 1 to 4 The components shown in Tables 1 and 2 were mixed and stirred with a ribbon mixer for 30 minutes to prepare a bath agent composition. Then, 30 g of each bath agent composition was dissolved in 180 liters of hot water at 41 ° C., and 10 subjects were bathed for 10 minutes and evaluated.

【0026】[0026]

【表1】 [Table 1]

【0027】[0027]

【表2】 [Table 2]

【0028】入浴後のアンケート結果を表3に示す。
尚、表中の記号の意味は下記の通りである。 A)入浴時の肌のなめらかさがあると答えた人数 B)入浴後の肌のしっとり効果があると答えた人数 C)べたつき感を訴えた人数
Table 3 shows the results of the questionnaire after bathing.
The meanings of the symbols in the table are as follows. A) The number of people who answered that the skin was smooth when bathing B) The number of people who answered that the skin had a moisturizing effect after bathing C) The number of people who reported stickiness

【0029】[0029]

【表3】 [Table 3]

【0030】表3に記載の通り、実施例は全ての項目に
わたって、比較例と比して優れていた。
As shown in Table 3, the Examples were superior to the Comparative Examples in all items.

【0031】[0031]

【発明の効果】本発明の浴剤組成物は、入浴後のべたつ
き感がなく、入浴時の肌のなめらかさ、及び入浴後の肌
のしっとり効果に優れた、有用なる浴剤組成物を提供す
ることは明らかである。
EFFECT OF THE INVENTION The bath composition of the present invention provides a useful bath composition having no sticky feeling after bathing, excellent skin smoothness at the time of bathing, and excellent skin moisturizing effect after bathing. It is clear that.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 ラクトース、米胚芽油又は米糠油、カチ
オン性ポリマー、イソステアリルアルコールからなる群
より選ばれる少なくとも二種以上を含有することを特徴
とする浴剤組成物。
1. A bath composition comprising at least two members selected from the group consisting of lactose, rice germ oil or rice bran oil, a cationic polymer, and isostearyl alcohol.
【請求項2】 イソステアリルアルコールとカチオン性
ポリマーとを含有することを特徴とする浴剤組成物。
2. A bath composition comprising isostearyl alcohol and a cationic polymer.
【請求項3】 イソステアリルアルコールと米胚芽油及
び/又は米糠油とを含有することを特徴とする浴剤組成
物。
3. A bath composition comprising isostearyl alcohol and rice germ oil and / or rice bran oil.
【請求項4】 イソステアリルアルコールとラクトース
とを含有することを特徴とする浴剤組成物。
4. A bath composition comprising isostearyl alcohol and lactose.
JP15983197A 1997-01-29 1997-06-17 Bath composition Expired - Fee Related JP3272978B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15983197A JP3272978B2 (en) 1997-01-29 1997-06-17 Bath composition

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP3120897 1997-01-29
JP9-123418 1997-04-25
JP9-31208 1997-04-25
JP12341897 1997-04-25
JP15983197A JP3272978B2 (en) 1997-01-29 1997-06-17 Bath composition

Publications (2)

Publication Number Publication Date
JPH115730A true JPH115730A (en) 1999-01-12
JP3272978B2 JP3272978B2 (en) 2002-04-08

Family

ID=27287246

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15983197A Expired - Fee Related JP3272978B2 (en) 1997-01-29 1997-06-17 Bath composition

Country Status (1)

Country Link
JP (1) JP3272978B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002241223A (en) * 2001-02-14 2002-08-28 Kose Corp Oily detergent
JP2006213676A (en) * 2005-02-07 2006-08-17 Gyunyu Sekken Kyoshinsha Kk Bathing agent composition
KR100957629B1 (en) * 2008-04-28 2010-05-13 조익장 material for bathing
JP2014024803A (en) * 2012-07-27 2014-02-06 Toyo Shinyaku Co Ltd Liquid bath agent

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7096969B1 (en) 2021-11-05 2022-07-07 三菱電機株式会社 Elevator system

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002241223A (en) * 2001-02-14 2002-08-28 Kose Corp Oily detergent
JP2006213676A (en) * 2005-02-07 2006-08-17 Gyunyu Sekken Kyoshinsha Kk Bathing agent composition
KR100957629B1 (en) * 2008-04-28 2010-05-13 조익장 material for bathing
JP2014024803A (en) * 2012-07-27 2014-02-06 Toyo Shinyaku Co Ltd Liquid bath agent

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