JPH11343473A - Adhesive containing tourmaline - Google Patents

Adhesive containing tourmaline

Info

Publication number
JPH11343473A
JPH11343473A JP18803398A JP18803398A JPH11343473A JP H11343473 A JPH11343473 A JP H11343473A JP 18803398 A JP18803398 A JP 18803398A JP 18803398 A JP18803398 A JP 18803398A JP H11343473 A JPH11343473 A JP H11343473A
Authority
JP
Japan
Prior art keywords
tourmaline
adhesive
formalin
plywood
formaldehyde
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP18803398A
Other languages
Japanese (ja)
Inventor
Yoshio Kusakari
良雄 草苅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TM TECHNO KK
Original Assignee
TM TECHNO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TM TECHNO KK filed Critical TM TECHNO KK
Priority to JP18803398A priority Critical patent/JPH11343473A/en
Publication of JPH11343473A publication Critical patent/JPH11343473A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide an adhesive contributive to the diminution of anaphylaxis to chemical matters and sick house syndrome, by utilizing the function and characteristics of tourmaline. SOLUTION: This adhesive is produced by blending a formalin-based adhesive with 0.1-30 wt.% tourmaline powder having the size of 0.9-100 μm and by kneading. It is possible to restrain the evaporation of formaldehyde and to maintain a semipermanent effect against anaphylaxis to chemical matters and sick house syndrome by applying the adhesive to building materials (e.g. plywood, laminated lumber, flooring), furniture, wallpaper, etc.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】ホルマリン系接着剤にトルマリン(電気
石)の微粉(0.9μm〜100μmサイズ)を混入し
混練し製造され、それを建材、家具類、壁紙等の内装材
の接着剤に関する。
[0001] The present invention relates to an adhesive for interior materials such as building materials, furniture, wallpaper, etc., which is produced by mixing and kneading fine powder (0.9 μm to 100 μm size) of tourmaline (formal stone) into a formalin-based adhesive.

【0002】従来は各種ホルマリン系接着剤(尿素、フ
ェノール、メラミン、レゾールシノール)は作業性、性
能、コストのバランスが良く建材用合板、集成材、家具
等に常用され又壁紙やワックスの防腐剤として使われて
いるが、これらがVOC(揮発性有機化合物)の発散源
となり「化学物質過敏症」、「シックハウス症候群」の
原因と考えられている。これらの人体に有害であると考
えられるVOC(揮発性有機化合物)の放散を防ぐ有効
な手段は少ない。
Conventionally, various formalin-based adhesives (urea, phenol, melamine, resorcinol) are well-balanced in workability, performance and cost, and are commonly used in plywood for construction materials, glulam, furniture, etc., and as a preservative for wallpaper and wax. However, these are considered to be sources of VOCs (volatile organic compounds) and cause "chemical sensitivity" and "sick house syndrome". There are few effective means for preventing the emission of VOCs (volatile organic compounds) considered to be harmful to the human body.

【0003】現在建材、家具類、壁紙等の家屋の内装材
及び内部にあって使用する物に用いられているホルマリ
ン系接着剤(尿素、フェノール、メラミン、レジールシ
ノール)によって起こる「化学物質過敏症」、「シック
ハウス症候群」が問題になっている。
[0003] "Chemical hypersensitivity" caused by formalin-based adhesives (urea, phenol, melamine, resircinol) currently used for interior materials of houses, such as building materials, furniture, and wallpaper, and those used inside. "," Sick house syndrome "is a problem.

【0004】本発明はホルマリン系接着剤(尿素、フェ
ノール、メラミン、レジールシノール)の中にトルマリ
ン(電気石)の微粉(0.9μm〜100μmサイズ)
を添加混入させ製造することを特徴としトルマリンのも
つ機能性(水の電気分解能)によって材料等に含まれる
水分が変化しHガスが発生し化1のような化学反応が
起こり、臭い毒性の強いホルムアルデヒドが、臭いが比
較的弱く毒性の少ないメタノールに変化する。
The present invention relates to a fine powder of tourmaline (an tourmaline) in a formalin-based adhesive (urea, phenol, melamine, resircinol) (0.9 μm to 100 μm size).
Characterized in that to produce the addition is mixed functionality with the tourmaline chemical reaction takes place as moisture changes H 2 gas contained in the material or the like is generated by the chemical formula 1 (electric resolution of water), the smell of toxicity The strong formaldehyde is transformed into a less toxic and less toxic methanol.

【0005】[0005]

【化1】 Embedded image

【0006】トルマリン(電気石)は天然の鉱物であり
モース硬度7.0〜7.5で比較的硬く接着剤等に混入
させる為に超微粒子にしなければならない。
Tourmaline (tourmaline) is a natural mineral and has a Mohs hardness of 7.0 to 7.5, is relatively hard, and must be formed into ultrafine particles to be mixed into an adhesive or the like.

【0007】トルマリン(電気石)は粒子が細かい程表
面積が多くなり効果が大きいため0.9μmの微粒子に
する技術が必要になる。又半永久的に機能性が持続する
ことが特徴である。
For tourmaline (tourmaline), the finer the particles, the larger the surface area and the greater the effect. Also, it is characterized in that the functionality is maintained semipermanently.

【0008】従来のホルマリン系接着剤が環境(温度、
湿度)等によって永い期間発生し続けるVOCについて
も持続してその効果が期待できる。
Conventional formalin-based adhesives are used in the environment (temperature,
The effect can be expected for the VOC which continues to be generated for a long time due to humidity or the like.

【0009】従来のホルマリン系接着剤による合板1及
びトルマリン(電気石)を混入した合板2を製造しホル
ムアルデヒドの放散量を測定したところ従来品は2.0
mg/L(ブランクテスト)に対して0.19〜0.2
1mg/Lと約1/10程度に低減した。
A plywood 1 made of a conventional formalin-based adhesive and a plywood 2 mixed with tourmaline (tourmaline) were manufactured and the emission amount of formaldehyde was measured.
0.19 to 0.2 for mg / L (blank test)
It was reduced to about 1/10 of 1 mg / L.

【0010】[0010]

【合板1】[Plywood 1]

【0011】[0011]

【合板2】[Plywood 2]

【0012】ホルマリン系接着剤にトルマリン(電気
石)微粉を混入し練り込んだ接着剤によって作られた建
材、家具類、壁紙等はホルムアルデヒドの発散が低く抑
えられそれが半永久的に効果があり「化学物質過敏
症」、「シックハウス症候群」等の障害を大幅に低減し
安全性の高い快適な居住空間環境を提供する。
Building materials, furniture, wallpaper, and the like made of an adhesive obtained by mixing and kneading tourmaline (an tourmaline) fine powder into a formalin-based adhesive have a low emission of formaldehyde, which is semipermanently effective. It significantly reduces obstacles such as "chemical sensitivity" and "sick house syndrome" and provides a safe and comfortable living space environment.

【手続補正書】[Procedure amendment]

【提出日】平成10年11月24日[Submission date] November 24, 1998

【手続補正1】[Procedure amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0009[Correction target item name] 0009

【補正方法】追加[Correction method] Added

【補正内容】[Correction contents]

【0009】従来のホルマリン系接着剤による合板1及
びトルマリン(電気石)を混入した合板2を製造しホル
ムアルデヒドの放散量を測定したところ従来品は2.0
mg/L(ブランクテスト)に対して0.19〜0.2
1mg/Lと約1/10程度に低減し、又日本農林規格
(JAS)特殊合板のホルムアルデヒド放散量試験を準
用したテストでは、ブランク1.20mg/Lに対して
トルマリン粒子0.60mg/L、トルマリン粒子
0.47mg/L、トルマリン粒子0.43mg/
L、天然石0.92mg/Lとトルマリン粒子〜
の平均値0.50mg/Lでブランクテストに対して放
散量は約58%低下し、天然石に対しては約46%低下
した。
A plywood 1 made of a conventional formalin-based adhesive and a plywood 2 mixed with tourmaline (an tourmaline) were manufactured, and the emission amount of formaldehyde was measured.
0.19 to 0.2 for mg / L (blank test)
1mg / L and reduced to about 1/10, and Japan Agricultural Standards
(JAS) Based on formaldehyde emission test for special plywood
In the test used, the blank was 1.20 mg / L
Tourmaline particles 0.60 mg / L, tourmaline particles
0.47 mg / L, tourmaline particles 0.43 mg / L
L, natural stone 0.92mg / L and tourmaline particles ~
Of the blank test at an average value of 0.50 mg / L
Dispersion is reduced by about 58% and natural stone by about 46%
did.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】ホルマリン系接着剤(尿素、フェノール、
メラミン、レゾールシノール)等にトルマリン(天然
石)の微粉を混入し建材、家具類、壁紙等の内装材接着
剤、塗料等に応用しこの接着剤によってホルムアルデヒ
ド、トルエン、キシレン等VOC(揮発性有機化合物)
の放散、発生量を抑制し、「化学物質過敏症」、「シッ
クハウス症候群」等を防ぐ接着剤。
1. A formalin-based adhesive (urea, phenol,
Mix fine powder of tourmaline (natural stone) into melamine, resorcinol, etc. and apply it to adhesives and paints for interior materials such as building materials, furniture, wallpaper, etc. Using this adhesive, VOCs (volatile organic compounds such as formaldehyde, toluene, xylene, etc.) )
Adhesive that suppresses the emission and generation of water and prevents "chemical sensitivity" and "sick house syndrome".
JP18803398A 1998-05-29 1998-05-29 Adhesive containing tourmaline Pending JPH11343473A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18803398A JPH11343473A (en) 1998-05-29 1998-05-29 Adhesive containing tourmaline

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18803398A JPH11343473A (en) 1998-05-29 1998-05-29 Adhesive containing tourmaline

Publications (1)

Publication Number Publication Date
JPH11343473A true JPH11343473A (en) 1999-12-14

Family

ID=16216500

Family Applications (1)

Application Number Title Priority Date Filing Date
JP18803398A Pending JPH11343473A (en) 1998-05-29 1998-05-29 Adhesive containing tourmaline

Country Status (1)

Country Link
JP (1) JPH11343473A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100607717B1 (en) * 2004-11-03 2006-08-09 디에스지대동월페이퍼 주식회사 Negative ion and far infrared ray emmitable wallpaper and production method therefor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100607717B1 (en) * 2004-11-03 2006-08-09 디에스지대동월페이퍼 주식회사 Negative ion and far infrared ray emmitable wallpaper and production method therefor

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