JPH11343156A - Lightweight scagliola containing inorganic expanded granule - Google Patents
Lightweight scagliola containing inorganic expanded granuleInfo
- Publication number
- JPH11343156A JPH11343156A JP18958998A JP18958998A JPH11343156A JP H11343156 A JPH11343156 A JP H11343156A JP 18958998 A JP18958998 A JP 18958998A JP 18958998 A JP18958998 A JP 18958998A JP H11343156 A JPH11343156 A JP H11343156A
- Authority
- JP
- Japan
- Prior art keywords
- artificial marble
- weight
- lightweight
- parts
- syrup
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、カウンタートップ
や浴槽等を成型するために使用する人工大理石であっ
て、特に無機質発泡粒状物が全体に均一に分散されて性
能が均一で軽量な人工大理石に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an artificial marble used for molding a countertop, a bathtub or the like, and more particularly, an artificial marble having a uniform performance and a light weight in which inorganic foam granules are uniformly dispersed throughout. It is about.
【０００２】[0002]
【従来の技術】一般に、人工大理石は人工大理石用シラ
ップ１００重量部に対してシリカや炭酸カルシウム等の
無機質微粉体を約１００重量部混合してなる配合物を加
熱重合して得られるが、人工大理石用シラップの比重が
約１ｇ／ｃｍ３に対して無機質微粉体の比重が約２．５
ｇ／ｃｍ３と大きいので、得られた人工大理石の比重も
約１．８ｇ／ｃｍ３と大きくて重たいものとなり、例え
ばカウンタートップや浴槽に用いた場合には、重量が１
台当り約４０〜６０Ｋｇと非常に重くなり、取付施工作
業等において人の負荷が大きいという欠点があった。2. Description of the Related Art Generally, artificial marble is obtained by heating and polymerizing a mixture of 100 parts by weight of an artificial marble syrup and about 100 parts by weight of an inorganic fine powder such as silica or calcium carbonate. The specific gravity of the inorganic fine powder is about 2.5, while the specific gravity of the marble syrup is about 1 g / cm 3 .
g / cm 3 , the specific gravity of the obtained artificial marble is also large and heavy at about 1.8 g / cm 3. For example, when the artificial marble is used for a countertop or a bathtub, the weight is 1%.
There is a drawback that the load becomes very heavy, about 40 to 60 kg per unit, and that the load on a person in the mounting work or the like is large.
【０００３】そこで、人工大理石の軽量化を図るため
に、例えば比重の小さい無機質発泡粒状物を無機質微粉
体の代わりに用いることが考えられるが、人工大理石シ
ラップの比重に比べてその比重が小さいため、該配合物
中で分離が生じてしまい、無機質発泡粒状物が均一に分
散された人工大理石を得ることができなかった。Therefore, in order to reduce the weight of artificial marble, it is conceivable to use, for example, an inorganic expanded granular material having a small specific gravity in place of the inorganic fine powder. However, since the specific gravity is small as compared with the specific gravity of the artificial marble syrup. Separation occurred in the composition, and it was not possible to obtain artificial marble in which the inorganic foamed granules were uniformly dispersed.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、このような
配合物における人工大理石用シラップと無機質発泡粒状
物の成型時の分離をなくし、無機質発泡粒状物が全体に
均一に分散されて均一な性能を有する軽量人工大理石を
提案するものである。DISCLOSURE OF THE INVENTION The present invention eliminates the separation of the artificial marble syrup and the inorganic foamed granules in such a composition at the time of molding, so that the inorganic foamed granules are uniformly dispersed throughout the composition. It is intended to propose a lightweight artificial marble having high performance.
【０００５】[0005]
【課題を解決するための手段】即ち、本発明は人工大理
石用シラップ１００重量部に対して比重が０．５〜１．
５ｇ／ｃｍ３で平均粒径が３ｍｍ以下である無機質発泡
粒状物を２０〜１８０重量部を混合してなる配合物及び
又は該配合物１００重量物に対して更に１５０重量部以
下の無機質微粉体を混合してなる配合物を加熱重合する
ことによって、人工大理石用シラップと無機質発泡粒状
物との分離のない該無機質発泡粒状物が全体に均一に分
散されて均一な性能を有する軽量人工大理石とするもの
である。In other words, the present invention has a specific gravity of 0.5 to 1 to 100 parts by weight of artificial marble syrup.
A blend obtained by mixing 20 to 180 parts by weight of an inorganic expanded granular material having an average particle diameter of 3 mm or less at 5 g / cm 3 and / or an inorganic fine powder of 150 parts by weight or less based on 100 parts by weight of the blend By heating and polymerizing the mixture obtained by mixing the above, the inorganic foamed granules having no separation between the artificial marble syrup and the inorganic foamed granules are uniformly dispersed throughout the lightweight artificial marble having uniform performance. Is what you do.
【０００６】ここでいう、無機質発泡粒状物としては、
ガラス質と粘土の混合物に発泡剤を混入して焼成された
無機質発泡粒状で、ガラス質と粘土の混合比率や発泡剤
の添加量の調整によって比重が調整された、例えば内外
セラミック（株）製のＮライト（商品名）を使用する。[0006] Here, the inorganic foamed particulates include:
Inorganic expanded granules obtained by mixing a foaming agent into a mixture of vitreous and clay and calcined. The specific gravity is adjusted by adjusting the mixing ratio of vitreous and clay and the amount of foaming agent added. N light (product name) is used.
【０００７】無機質発泡粒状物の比重は０．５〜１．５
ｇ／ｃｍ３が好ましく、この範囲を越えると人工大理石
用シラップと無機質発泡粒状物との分離が発生してしま
う。[0007] The specific gravity of the inorganic expanded granular material is 0.5 to 1.5.
g / cm 3 is preferable, and if it exceeds this range, separation between the artificial marble syrup and the inorganic foamed granular material occurs.
【０００８】また、無機質発泡粒状物の粒径は３ｍｍ以
下が好ましく、３ｍｍを越えると該配合物の金型内での
流動性が悪くなってしまう。Further, the particle diameter of the inorganic expanded granular material is preferably 3 mm or less, and if it exceeds 3 mm, the fluidity of the compound in the mold becomes poor.
【０００９】無機質発泡粒状物の添加量が人工大理石用
シラップ１００重量部に対して１８０重量物を越える
と、耐衝撃性が小さくなって実用に耐えられないものと
なってしまい、２０重量部未満の場合は、軽量性が得ら
れなくなってしまう。If the amount of the inorganic foamed particulates exceeds 180 parts by weight with respect to 100 parts by weight of the artificial marble syrup, the impact resistance becomes small and the material cannot be put to practical use. In this case, the lightness cannot be obtained.
【００１０】また、ここでいう人工大理石用シラップと
しては、不飽和ポリエステルやアクリル系のアクリル酸
アルキルエステル、例えばアクリル酸メチル，アクリル
酸エチル，アクリル酸ｎ−プロピル、アクリル酸ｎ−ブ
チル単量体やメタクリル酸アルキルエステル、例えばメ
タクリル酸メチル，メタクリル酸エチル，メタクリル酸
ｎ−プロピル，メタクリル酸ｎ−ブチル，メタクリル酸
２−エチルヘキシル単量体又はその部分重合体やその単
量体にステンレス等の単量体を共重合してなる部分重合
体を使用する。The syrup for artificial marble referred to herein includes unsaturated polyesters and acrylic alkyl esters such as methyl acrylate, ethyl acrylate, n-propyl acrylate and n-butyl acrylate monomer. And alkyl methacrylates, for example, methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, n-butyl methacrylate, 2-ethylhexyl methacrylate monomer or a partial polymer thereof, or a monomer such as stainless steel. A partial polymer obtained by copolymerizing a monomer is used.
【００１１】なお、この人工大理石用シラップには、粘
土や比重の調整のために前記単量体にその重合体を溶解
しても良い。また、人工大理石用シラップには、重合開
始剤を適宜量添加するが、更に架橋剤も適宜量添加する
ことは一向に構わない。In this artificial marble syrup, its polymer may be dissolved in the above-mentioned monomer for the purpose of adjusting the specific gravity or the clay. In addition, an appropriate amount of a polymerization initiator is added to the artificial marble syrup, and an appropriate amount of a crosslinking agent may be further added.
【００１２】また、ここでいう無機質微粉体とは、シリ
カや炭酸カルシウム，ガラスフィラー，水酸化アルミニ
ウム，タルク，水酸化マグネシウム等の微粉体である。
無機質微粉体は、人工大理石用シラップと無機質発泡粒
状物との配合物１００重量部に対して１５０重量部以下
が好ましく、１５０重量部を越えると軽量性が得られな
くなってしまう。The inorganic fine powder referred to here is a fine powder of silica, calcium carbonate, glass filler, aluminum hydroxide, talc, magnesium hydroxide and the like.
The amount of the inorganic fine powder is preferably 150 parts by weight or less based on 100 parts by weight of the mixture of the artificial marble syrup and the inorganic foamed granules, and if it exceeds 150 parts by weight, the lightness cannot be obtained.
【００１３】本発明の無機質発泡粒状物入り軽量人工大
理石を得るための加熱重合成形用の型としては、金属，
プラスチック，木製等のいずれでもよく、またその形状
は平板状，箱型状等の種々のものであり、更に連続生産
をする場合には、金属製のベルト型を用いる。以下、本
発明の具体的な実施形態を説明する。The heat polymerization mold for obtaining the lightweight artificial marble containing the inorganic foamed granules of the present invention includes metals,
Any of plastic, wood, etc. may be used, and the shape is various such as a flat plate shape, a box shape and the like. In the case of continuous production, a metal belt type is used. Hereinafter, specific embodiments of the present invention will be described.
【００１４】[0014]
【発明の実施の形態】重合開始剤としてジ−２エチルヘ
キシルパーオキシカーボネート及びメチルメタアクリル
レートを適宜量を含有するメタクリル酸メチルの人工大
理石用シラップ１００重量部に対して比重１．０１、平
均粒径０．９ｍｍの無機質発泡粒状物（内外セラミック
（株）製のＮライト）を１００重量部混合してなる配合
物１００重量部に対して、炭酸カルシウム微粉体５０重
量部を混合してなる配合物を３００ｍｍ×３００ｍｍ×
１０ｍｍの金属製の箱型凹形状の下金型に注入し、平板
状の凸形状の上金型を上方から載せ、端部をシャコマン
で挟んで固定したまま、該金型を温度８０℃のオーブン
に入れて３０分加熱重合させた後、オーブンから金型を
取出して室温まで除冷し、上下金型を分離して、厚さ１
０ｍｍの人工大理石板を得た。DESCRIPTION OF THE PREFERRED EMBODIMENTS Methyl methacrylate containing appropriate amounts of di-2ethylhexyl peroxycarbonate and methyl methacrylate as polymerization initiators has a specific gravity of 1.01 and an average particle size of 100 parts by weight of artificial marble syrup. A composition obtained by mixing 50 parts by weight of calcium carbonate fine powder with 100 parts by weight of a mixture obtained by mixing 100 parts by weight of an inorganic expanded granular material having a diameter of 0.9 mm (N-lite manufactured by Inner and External Ceramics Co., Ltd.) 300mm x 300mm x
A 10 mm metal box-shaped concave lower mold is poured into the mold, a flat convex upper mold is placed from above, and the mold is held at 80 ° C. After heating and polymerization for 30 minutes in an oven, the mold was taken out of the oven, cooled to room temperature, the upper and lower molds were separated, and the
A 0 mm artificial marble plate was obtained.
【００１５】得られた人工大理石板は、無機質発泡粒状
物が全体に均一に分散されて均一な性能を有し、比重も
１．３ｇ／ｃｍ３と小さく、一般の人工大理石に比べて
重量が３０％減のものが得られた。The obtained artificial marble plate has a uniform performance in which the inorganic foamed granules are uniformly dispersed throughout, has a specific gravity as small as 1.3 g / cm 3, and has a weight smaller than that of general artificial marble. A 30% reduction was obtained.
【００１６】[0016]
【発明の効果】本発明による無機質発泡粒状物入り軽量
人工大理石は上述のようにしてなり、無機質発泡粒状物
が全体均一に分散されていて均一な性能を有し、しかも
比重も小さく軽量であるので、例えばカウンタートップ
や浴槽に用いた場合には、その取付け施工作業等におい
て取扱いが容易となる効果がある。As described above, the lightweight artificial marble containing inorganic foamed granules according to the present invention is as described above. The inorganic foamed granules are uniformly dispersed throughout and have uniform performance. For example, when used in a countertop or a bathtub, there is an effect that the handling is easy in the work of attaching and installing the same.
Claims (4)
して比重が０．５〜１．５ｇ／ｃｍ３で平均粒径が３ｍ
ｍ以下の無機質発泡粒状物を２０重量部〜１８０重量部
を混合してなる配合物を加熱重合してなる軽量人工大理
石。1. A specific gravity of 0.5 to 1.5 g / cm 3 and an average particle size of 3 m with respect to 100 parts by weight of artificial marble syrup.
A lightweight artificial marble obtained by heating and polymerizing a composition obtained by mixing 20 to 180 parts by weight of an inorganic expanded granular material having a particle size of m or less.
１５０重量部以下の無機質微粉体を混合した配合物を加
熱重合してなる軽量人工大理石。2. A lightweight artificial marble obtained by heating and polymerizing a composition obtained by mixing 150 parts by weight or less of inorganic fine powder with respect to 100 parts by weight of the composition of claim 1.
ル系人工大理石用シラップを用いてなる請求項１又は２
記載の軽量人工大理石。3. The artificial marble syrup is an acrylic artificial marble syrup.
The described lightweight artificial marble.
ポリエステルを用いてなる請求項１又は２記載の軽量人
工大理石。4. The lightweight artificial marble according to claim 1, wherein the artificial marble syrup is made of unsaturated polyester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18958998A JPH11343156A (en) | 1998-06-01 | 1998-06-01 | Lightweight scagliola containing inorganic expanded granule |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18958998A JPH11343156A (en) | 1998-06-01 | 1998-06-01 | Lightweight scagliola containing inorganic expanded granule |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11343156A true JPH11343156A (en) | 1999-12-14 |
Family
ID=16243859
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18958998A Pending JPH11343156A (en) | 1998-06-01 | 1998-06-01 | Lightweight scagliola containing inorganic expanded granule |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11343156A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007142391A1 (en) | 2006-06-02 | 2007-12-13 | Lg Chem, Ltd. | Artificial marble using low specific gravity material as chip and process for preparing the same |
| JP2008524103A (en) * | 2004-12-17 | 2008-07-10 | チェイル インダストリーズ インコーポレイテッド | Foamed marble molded article and manufacturing method thereof |
| JP2008540326A (en) * | 2005-05-30 | 2008-11-20 | チェイル インダストリーズ インコーポレイテッド | Composition for artificial marble having natural marble appearance |
| US9196896B2 (en) | 2012-07-24 | 2015-11-24 | Lg Chem, Ltd. | Porous silicon-based electrode active material and secondary battery comprising the same |
| US9512523B2 (en) | 2012-04-19 | 2016-12-06 | Lg Chem, Ltd. | Porous electrode active material and secondary battery including the same |
| US9780357B2 (en) | 2012-04-19 | 2017-10-03 | Lg Chem, Ltd. | Silicon-based anode active material and secondary battery comprising the same |
| US9879344B2 (en) | 2012-07-26 | 2018-01-30 | Lg Chem, Ltd. | Electrode active material for secondary battery |
-
1998
- 1998-06-01 JP JP18958998A patent/JPH11343156A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008524103A (en) * | 2004-12-17 | 2008-07-10 | チェイル インダストリーズ インコーポレイテッド | Foamed marble molded article and manufacturing method thereof |
| JP4857282B2 (en) * | 2004-12-17 | 2012-01-18 | チェイル インダストリーズ インコーポレイテッド | Foamed marble molded article and manufacturing method thereof |
| JP2008540326A (en) * | 2005-05-30 | 2008-11-20 | チェイル インダストリーズ インコーポレイテッド | Composition for artificial marble having natural marble appearance |
| JP4691593B2 (en) * | 2005-05-30 | 2011-06-01 | チェイル インダストリーズ インコーポレイテッド | Composition for artificial marble having natural marble appearance |
| WO2007142391A1 (en) | 2006-06-02 | 2007-12-13 | Lg Chem, Ltd. | Artificial marble using low specific gravity material as chip and process for preparing the same |
| US8088489B2 (en) | 2006-06-02 | 2012-01-03 | Lg Chem, Ltd. | Artificial marble using low specific gravity material as chip and process for preparing the same |
| US9512523B2 (en) | 2012-04-19 | 2016-12-06 | Lg Chem, Ltd. | Porous electrode active material and secondary battery including the same |
| US9780357B2 (en) | 2012-04-19 | 2017-10-03 | Lg Chem, Ltd. | Silicon-based anode active material and secondary battery comprising the same |
| US9831500B2 (en) | 2012-04-19 | 2017-11-28 | Lg Chem, Ltd. | Porous electrode active material and secondary battery including the same |
| US9196896B2 (en) | 2012-07-24 | 2015-11-24 | Lg Chem, Ltd. | Porous silicon-based electrode active material and secondary battery comprising the same |
| US9879344B2 (en) | 2012-07-26 | 2018-01-30 | Lg Chem, Ltd. | Electrode active material for secondary battery |
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