JPH11335966A - Tourmaline powder-containing sheet like material and its production - Google Patents
Tourmaline powder-containing sheet like material and its productionInfo
- Publication number
- JPH11335966A JPH11335966A JP15995098A JP15995098A JPH11335966A JP H11335966 A JPH11335966 A JP H11335966A JP 15995098 A JP15995098 A JP 15995098A JP 15995098 A JP15995098 A JP 15995098A JP H11335966 A JPH11335966 A JP H11335966A
- Authority
- JP
- Japan
- Prior art keywords
- paper
- tourmaline powder
- cloth
- sheet
- tourmaline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Paper (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、布及び／又は紙よ
りなるよりなるトルマリン粉末含有シート状材及びその
製造方法に係り、特に内装材、インテリア材、包装材又
は梱包材として用いられるトルマリン粉末含有シート状
材及びその製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a tourmaline powder-containing sheet made of cloth and / or paper and a method for producing the same, and particularly to an interior material, an interior material, a packaging material, or a tourmaline powder used as a packaging material. Field of the Invention The present invention relates to a sheet-like material and a method for producing the same.
【０００２】[0002]
【従来の技術】従来より布又は紙は、内装材、インテリ
ア材又は包装材として用いられており、耐火性、耐水
性、耐熱性等を付与している。例えば、布、紙を化学薬
品で処理した耐火材、シェラック溶液、カゼインとシェ
ラックとの混合溶液を塗付した防水材、また抗菌性ある
いは防水性等にキトサンを含有させたものが知られてい
る。2. Description of the Related Art Conventionally, cloth or paper has been used as an interior material, interior material, or packaging material, and imparts fire resistance, water resistance, heat resistance, and the like. For example, a refractory material obtained by treating cloth and paper with a chemical agent, a shellac solution, a waterproof material coated with a mixed solution of casein and shellac, and a material containing chitosan for antibacterial or waterproof properties are known. .
【０００３】[0003]
【発明が解決しようとする課題】最近の建物は高気密化
されており、従来の内装材、インテリア材が有している
耐火性、耐水性、耐熱性に加え、居住者の健康への影響
を考慮し、脱臭、抗菌、防カビ、及び化学物質過敏症に
対する効果等の特性も要求されている。また包装材、梱
包材においても防水性等に加え、脱臭、抗菌、防カビ、
鮮度保持等の特性が要求されている。本発明は、トルマ
リン（電気石）を含有させ、遠赤外線、マイナスイオ
ン、脱臭、防虫、抗菌、防カビ、鮮度保持等の特性を付
与した布及び／又は紙のシート状材、及びその製造方法
を提供するものである。Recently, buildings are highly airtight, and in addition to the fire resistance, water resistance and heat resistance of conventional interior materials and interior materials, the impact on the health of the occupants is affected. In view of the above, characteristics such as deodorization, antibacterial, antifungal, and effects on chemical sensitivity are also required. In addition, in addition to waterproofing, etc. in packaging materials and packaging materials, deodorization, antibacterial, anti-mold,
Characteristics such as freshness retention are required. The present invention relates to a sheet material of cloth and / or paper containing tourmaline (an tourmaline) and imparting properties such as far infrared rays, negative ions, deodorization, insect repellent, antibacterial, antifungal, and keeping freshness, and a method for producing the same. Is provided.
【０００４】[0004]
【課題を解決するための手段】本発明は、布及び／又は
紙よりなるシート状材に、トルマリン粉末を重量比で
０．１％〜７０％含有させたことを特徴とする布及び／
又は紙よりなるトルマリン粉末含有シート状材である。
また本発明は、シート状材が、内装材、インテリア材、
包装材又は梱包材として用いられることを特徴とするも
のである。また本発明は、布及び／又は紙よりなるシー
ト状材を、トルマリンの粉末を混在させた溶液に浸漬
し、含浸、乾燥させることを特徴とする布及び／又は紙
よりなるトルマリン粉末含有シート状材の製造方法であ
る。さらに本発明において、布及び／又は紙よりなるシ
ート状材に含浸、含有させるトルマリンの粉末の粒径
は、０．１〜１０μｍが好ましい。According to the present invention, a sheet material made of cloth and / or paper contains 0.1% to 70% by weight of tourmaline powder.
Or a sheet material containing tourmaline powder made of paper.
In the present invention, the sheet-shaped material is an interior material, an interior material,
It is characterized by being used as a packaging material or a packaging material. The present invention also provides a tourmaline powder-containing sheet made of cloth and / or paper, wherein the sheet material made of cloth and / or paper is immersed in a solution mixed with tourmaline powder, and impregnated and dried. It is a method of manufacturing a material. Further, in the present invention, the particle size of the tourmaline powder impregnated and contained in the sheet material made of cloth and / or paper is preferably 0.1 to 10 μm.
【０００５】[0005]
【作用】本発明においては、布及び／又は紙よりなるシ
ート状材の内部にトルマリンの０．１〜１０μｍの粉末
を重量比で０．１％〜７０％含有させることにより、布
又は紙の有している本来の特性は実質的に変えず、本来
の布又は紙の特性に加え、トルマリン（電気石）の持つ
電位的、電磁的特性により遠赤外線、マイナスイオン、
脱臭、防虫、抗菌、防カビ、鮮度保持等の特質を付与す
るものである。According to the present invention, 0.1% to 70% by weight of a tourmaline powder of 0.1 to 10 μm is contained in a sheet material made of cloth and / or paper so that the weight of the cloth or paper is reduced. The original properties possessed are not substantially changed. In addition to the properties of the original cloth or paper, the potential and electromagnetic properties of tourmaline (tourmaline) have far-infrared rays, negative ions,
It imparts properties such as deodorization, insect repellent, antibacterial, antifungal and freshness preservation.
【０００６】[0006]
【発明の実施の形態】本発明において、布、紙よりなる
シート状材としては、繊維、不織布、紙類（和紙を含
む）又はこれらを積層したもので、内装材、空気清浄用
フィルター、インテリア材、包装材、梱包材として用い
られるもので、布、不織布は例えば、ビル、住宅等の内
装材、カーテン、エアーフィルター、テーブルクロス、
カーペットとして用いられる。紙、和紙は例えば、ビ
ル、住宅、等の壁紙、障子紙、襖紙などに用いられる。
また包装材は、菓子、生花、各種食品の包装に用いら
れ、梱包材、段ボール材、緩衝材等は生鮮食品の包装、
梱包等に用いられるものである。BEST MODE FOR CARRYING OUT THE INVENTION In the present invention, as a sheet-like material made of cloth or paper, fibers, non-woven fabrics, papers (including Japanese paper) or a laminate thereof are used. Materials, packaging materials, used as packaging materials, cloth, non-woven fabric, for example, interior materials such as buildings, houses, curtains, air filters, table cloths,
Used as carpet. Paper and Japanese paper are used, for example, as wallpaper for buildings and houses, shoji paper, sliding paper, and the like.
In addition, packaging materials are used for packaging confectionery, fresh flowers, various foods, and packaging materials, cardboard materials, cushioning materials, etc. are used for packaging fresh foods,
It is used for packing and the like.
【０００７】本発明において、布又は紙よりなるシート
状材に、含浸、含有させるトルマリン（ｔｏｕｒｍａｌ
ｉｎｅ）は、電気石ともいわれ、遠赤外線電磁波放射特
性をを有するもので、次のように示される。 組成一般式 ＸＹ９Ｂ３Ｓｉ６Ｏ２７（Ｏ，ＯＨ，Ｆ）４で表されもので、 Ｘ＝Ｃａ，Ｎａ，Ｋ，Ｍｎ， Ｙ＝Ｍｇ，Ｆｅ，Ａｌ，Ｃｒ，Ｍｎ，Ｔｉ，Ｌｉ また、組成一般式 ＸＹ３Ａｌ６（ＯＨ）４（ＢＯ３）３（Ｓｉ６Ｏ１８）
で表されものもある。これらは、化学成分により、例え
ば次のように分けられるものである。 ドラバイト（Ｄｒａｖｉｔｅ）、 Ｘ，Ｙ＝Ｎａ，Ｍｇ ＮａＭｇ3Ａｌ6Ｂ３Ｓｉ6(Ｏ，Ｈ）30（ＯＨ，Ｆ） ショール （Ｓｃｈｏｒｉ）、 Ｘ，Ｙ＝Ｎａ，Ｆｅ （Ｎａ，Ｋ，Ｃａ）（Ｆｅ，Ｍｎ）3Ａｌ6Ｂ3Ｓｉ6（Ｏ，Ｈ）30（ＯＨ，Ｆ） エルバイト（Ｅｌｂａｉｔｅ）、 Ｘ，Ｙ＝Ｎａ，Ｌｉ （Ｎａ，Ｋ，Ｃａ）（Ｌｉ，Ａｌ）3Ａｌ6Ｂ3Ｓｉ6（Ｏ，Ｈ）30（ＯＨ，Ｆ）In the present invention, tourmaline is impregnated and contained in a sheet material made of cloth or paper.
Ine) is also called tourmaline and has far-infrared electromagnetic wave radiation characteristics, and is shown as follows. A composition represented by the general formula XY 9 B 3 Si 6 O 27 (O, OH, F) 4 , wherein X = Ca, Na, K, Mn, Y = Mg, Fe, Al, Cr, Mn, Ti, Li In addition, the composition general formula XY 3 Al 6 (OH) 4 (BO 3 ) 3 (Si 6 O 18 )
Some are represented by These are classified, for example, as follows according to the chemical components. Dravite, X, Y = Na, Mg NaMg 3 Al 6 B 3 Si 6 (O, H) 30 (OH, F) Shoal (Schori), X, Y = Na, Fe (Na, K, Ca) (Fe, Mn) 3 Al 6 B 3 Si 6 (O, H) 30 (OH, F) Elbaite, X, Y = Na, Li (Na, K, Ca) (Li, Al) 3 Al 6 B 3 Si 6 (O, H) 30 (OH, F)
【０００８】本発明において、布及び／又は紙のシート
状材に含有させるトルマリンの粒子の量を重量比で０．
１％〜７０％と限定した理由は、０．１％より少ない含
有量では、遠赤外線、マイナスイオン、脱臭、抗菌、防
カビ、鮮度保持等の特性が得られない。７０％より多い
と布又は紙のシート状材の本来の特性が失われ、また布
又は紙のシート状材にトルマリンの粒子を均一に含浸、
含有させることが困難になるのでこの範囲に限定し、好
ましくは、すなわち最適含有率は、５％〜１０％であ
る。[0008] In the present invention, the amount of tourmaline particles contained in the sheet material of cloth and / or paper is set at 0.
The reason for limiting the content to 1% to 70% is that if the content is less than 0.1%, characteristics such as far infrared rays, negative ions, deodorization, antibacterial properties, antifungal properties, and freshness retention cannot be obtained. If it exceeds 70%, the original properties of the cloth or paper sheet are lost, and the cloth or paper sheet is uniformly impregnated with tourmaline particles.
Since it is difficult to make the content, it is limited to this range, and preferably, that is, the optimum content is 5% to 10%.
【０００９】また、布又は紙のシート状材に含浸、含有
させるトルマリンの粒子を、０．１μｍ〜１０μｍとし
たのは、０．１μｍより小さいものでは、遠赤外線の機
能が得られず、１０μｍより大きいと、布又は紙よりな
るシート状材に、均一に含有されないので、トルマリン
粉末の粒径は０．１μｍ〜１０μｍの範囲が好ましい。
和紙に含浸、含有させるトルマリンの粒子は、０．９μ
ｍ程度のものが好ましい。また、遠赤外線効果を向上さ
せる為トルマリン粉末に、さらに天然鉱石（黒曜石、大
理石、水晶等）粉末を含有させてもよい。Further, the tourmaline particles impregnated and contained in the sheet material of cloth or paper are set to 0.1 μm to 10 μm. If the size is smaller than 0.1 μm, the function of far infrared rays cannot be obtained, and If it is larger, it is not uniformly contained in a sheet material made of cloth or paper, so that the particle size of the tourmaline powder is preferably in the range of 0.1 μm to 10 μm.
Tourmaline particles impregnated and contained in Japanese paper are 0.9μ
m is preferable. To improve the far-infrared effect, tourmaline powder may further contain natural ore (obsidian, marble, quartz, etc.) powder.
【００１０】本発明において、トルマリン粉末を混合さ
せた溶液に、布及び／又は紙よりなるシート状材を浸
漬、含浸して布及び／又は紙に吸収させ、布及び／又は
紙の繊維、繊維の間にトルマリンの粉末を支持させ、乾
燥させるものである。また、本発明のトルマリン粉末含
有シート状材は、防炎剤、難燃剤、防水剤、香料等を吸
収させて、あるいは塗布して耐火性、耐水性等を有する
内装材、インテリア材又は包装材として用いることがで
きる。In the present invention, a sheet material made of cloth and / or paper is immersed and impregnated in a solution in which tourmaline powder is mixed, and absorbed by the cloth and / or paper. During this time, the tourmaline powder is supported and dried. Further, the tourmaline powder-containing sheet material of the present invention is made of an interior material, interior material or packaging material having fire resistance, water resistance, etc. by absorbing or applying a flame retardant, a flame retardant, a waterproofing agent, a fragrance or the like. Can be used as
【００１１】[0011]
【実施例】本発明の実施例について、図１を参照して説
明する。トルマリンの粒径３μｍの粉末を混入、撹拌し
た混合溶液に、不織布を浸漬して含浸させ、トルマリン
を重量比で２％含有させ、トルマリン粉末含有不織布を
得た。An embodiment of the present invention will be described with reference to FIG. A nonwoven fabric was immersed and impregnated in a mixed solution in which tourmaline powder having a particle diameter of 3 μm was mixed and stirred, and tourmaline was contained at a weight ratio of 2% to obtain a tourmaline powder-containing nonwoven fabric.
【００１２】このトルマリン粉末含有不織布の放射強度
について２５℃で測定し、図１に示す。図１は、横軸に
ＷＡＶＥＬＥＮＧＴＨ（ＭＩＣＲＯＮ）、縦軸に放射強
度、Ｒ（ｗ・ｃｍ−２・ｓｔｒ−１）×１０を示してい
る。図１に示す測定結果において、線（イ）は本発明実
施例のトルマリン粉末含有不織布のＲ（放射強度）を示
し、線（ロ）は黒体（Ｂｌａｃｋｂｏｄｙ）のＲ（放射
強度）であり、線（ハ）は比較例のトルマリン粉末含有
していない不織布のＲ（放射強度）である。The radiation intensity of this tourmaline powder-containing nonwoven fabric was measured at 25 ° C. and is shown in FIG. In FIG. 1, the abscissa axis indicates WAVELENGTH (MICRON), and the ordinate axis indicates radiation intensity, R (w · cm −2 · str −1 ) × 10. In the measurement results shown in FIG. 1, the line (a) shows R (radiant intensity) of the tourmaline powder-containing nonwoven fabric of the present invention, and the line (b) shows R (radiant intensity) of a black body (Blackbody). The line (c) shows the R (radiation intensity) of the nonwoven fabric containing no tourmaline powder of the comparative example.
【００１３】図１から明らかなように、線（ハ）の比較
例に比べ、線（イ）の実施例のトルマリン粉末含有不織
布は、強い放射強度を示している。この実施例で放射強
度について説明すると、ここで放射強度として表示した
ものは放射輝度の測定で求めた放射率である。放射率と
は熱放射体の放射発散度と同じ温度の黒体の放射発散度
の比である。線（ロ）の黒体（Ｂｌａｃｋｂｏｄｙ）と
は完全放射体といわれるもので、放射率は（１００％）
である。これに対して線（イ）に示す本発明の実施例の
ものは、２５℃、波長１０μｍ附近をピークとして、分
光放射率は、トルマリンを含有させた不織布（線
（イ））は、含有していないもの（線（ハ）よりも放射
率で１２％向上した。As is clear from FIG. 1, the tourmaline powder-containing nonwoven fabric of the embodiment of the line (a) shows a higher radiation intensity than the comparative example of the line (c). Explaining the radiation intensity in this embodiment, what is indicated here as the radiation intensity is the emissivity obtained by measuring the radiance. Emissivity is the ratio of the radiant emittance of a blackbody at the same temperature as the radiant emittance of a thermal radiator. The black body of the line (b) is called a perfect radiator, and the emissivity is (100%)
It is. On the other hand, in the case of the embodiment of the present invention shown in the line (a), the peak at 25 ° C. and a wavelength of around 10 μm, and the spectral emissivity of the nonwoven fabric containing tourmaline (the line (a)) is contained. The emissivity was improved by 12% as compared with the case without (line (c)).
【００１４】[0014]
【発明の効果】以上説明したように、本発明によれば、
布又は紙及び和紙よりなるシート状材の内部にトルマリ
ンの０．１〜１０μｍの粉末を重量比で０．１％〜７０
％含有させることにより、トルマリン（電気石）の持つ
電位的、電磁的特性により遠赤外線、マイナスイオン、
脱臭、抗菌、防カビ、鮮度保持、静電気の防止等の特質
を付与するもので内装材、空気清浄用フィルター、イン
テリア材又は包装材、梱包材として優れた効果を奏する
ものである。As described above, according to the present invention,
0.1 to 10 μm powder of tourmaline in a weight ratio of 0.1 to 70 μm is contained in a sheet material made of cloth or paper and Japanese paper.
%, The far-infrared ray, negative ion,
It provides properties such as deodorization, antibacterial, antifungal, freshness, and prevention of static electricity, and has excellent effects as an interior material, an air cleaning filter, an interior material or a packaging material, and a packaging material.
【図１】本発明の実施例を説明する図FIG. 1 is a diagram illustrating an embodiment of the present invention.
イ 本発明実施例のトルマリン粉末含有不織布のＲ（放
射強度）を示す線 ロ 黒体（Ｂｌａｃｋｂｏｄｙ）のＲ（放射強度）を示
す線 ハ 比較例のトルマリン粉末含有していない不織布のＲ
（放射強度）を示す線B. Line indicating R (radiant intensity) of tourmaline powder-containing nonwoven fabric of Example of the present invention b. Line indicating R (radiant intensity) of black body (Blackbody) c. R of nonwoven fabric containing no tourmaline powder of comparative example
Line indicating (radiation intensity)
───────────────────────────────────────────────────── フロントページの続き (72)発明者 池田 宏 山形県山形市北町１丁目５番１号 (72)発明者 池田 隆 山形県山形市立谷川３丁目140−２ ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Hiroshi Ikeda 1-5-1, Kitamachi, Yamagata City, Yamagata Prefecture (72) Inventor Takashi Ikeda 3-140-2, Tanigawa, Yamagata City, Yamagata Prefecture
Claims (3)
トルマリン粉末を重量比で０．１％〜７０％含有させた
ことを特徴とする布及び／又は紙よりなるトルマリン粉
末含有シート状材。1. A sheet material made of cloth and / or paper,
A tourmaline powder-containing sheet material made of cloth and / or paper, characterized by containing tourmaline powder in a weight ratio of 0.1% to 70%.
包装材又は梱包材として用いられることを特徴とする請
求項１に記載の布及び／又は紙よりなるトルマリン粉末
含有シート状材。2. The sheet-like material is an interior material, an interior material,
The tourmaline powder-containing sheet material made of the cloth and / or paper according to claim 1, which is used as a packaging material or a packaging material.
ルマリンの粉末を混在させた溶液に浸漬し、含浸、乾燥
させることを特徴とする請求項１又は２に記載の布及び
／又は紙よりなるトルマリン粉末含有シート状材の製造
方法。3. The cloth and / or paper according to claim 1, wherein the sheet material made of the cloth and / or paper is immersed in a solution mixed with tourmaline powder, impregnated and dried. A method for producing a sheet material containing tourmaline powder comprising:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15995098A JPH11335966A (en) | 1998-05-25 | 1998-05-25 | Tourmaline powder-containing sheet like material and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15995098A JPH11335966A (en) | 1998-05-25 | 1998-05-25 | Tourmaline powder-containing sheet like material and its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11335966A true JPH11335966A (en) | 1999-12-07 |
Family
ID=15704713
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15995098A Pending JPH11335966A (en) | 1998-05-25 | 1998-05-25 | Tourmaline powder-containing sheet like material and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11335966A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002106076A (en) * | 2000-09-28 | 2002-04-10 | Daiwa House Ind Co Ltd | Indoor structure, cloth and shoji (paper-sliding screen) paper |
| KR100377333B1 (en) * | 2000-06-10 | 2003-03-29 | 주식회사 크로스시스템 | Sheet production method including tourmaline and the sheet thereby |
| CN100439597C (en) * | 2006-11-21 | 2008-12-03 | 朱运彬 | Process for preparing fruit and vegetable fresh-keeping paper made from tourmaline |
| US7780816B2 (en) | 2004-10-12 | 2010-08-24 | Certainteed Corporation | Fibrous insulation with fungicide |
| US20140087040A1 (en) * | 2012-09-26 | 2014-03-27 | Multiple Energy Technologies Llc | Bioceramic compositions |
-
1998
- 1998-05-25 JP JP15995098A patent/JPH11335966A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100377333B1 (en) * | 2000-06-10 | 2003-03-29 | 주식회사 크로스시스템 | Sheet production method including tourmaline and the sheet thereby |
| JP2002106076A (en) * | 2000-09-28 | 2002-04-10 | Daiwa House Ind Co Ltd | Indoor structure, cloth and shoji (paper-sliding screen) paper |
| US7780816B2 (en) | 2004-10-12 | 2010-08-24 | Certainteed Corporation | Fibrous insulation with fungicide |
| CN100439597C (en) * | 2006-11-21 | 2008-12-03 | 朱运彬 | Process for preparing fruit and vegetable fresh-keeping paper made from tourmaline |
| US20140087040A1 (en) * | 2012-09-26 | 2014-03-27 | Multiple Energy Technologies Llc | Bioceramic compositions |
| US10252945B2 (en) * | 2012-09-26 | 2019-04-09 | Multiple Energy Technologies Llc | Bioceramic compositions |
| EP4129952A1 (en) * | 2012-09-26 | 2023-02-08 | Multiple Energy Technologies LLC | Bioceramic compositions |
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