JPH11322524A - Material having antibacterial activity - Google Patents
Material having antibacterial activityInfo
- Publication number
- JPH11322524A JPH11322524A JP11062579A JP6257999A JPH11322524A JP H11322524 A JPH11322524 A JP H11322524A JP 11062579 A JP11062579 A JP 11062579A JP 6257999 A JP6257999 A JP 6257999A JP H11322524 A JPH11322524 A JP H11322524A
- Authority
- JP
- Japan
- Prior art keywords
- antibacterial
- glaze layer
- layer
- sol
- photocatalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
- C04B41/5105—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal with a composition mainly composed of one or more of the noble metals or copper
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/60—Agents for protection against chemical, physical or biological attack
- C04B2103/67—Biocides
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、抗菌機能を有する
部材に関する。TECHNICAL FIELD The present invention relates to a member having an antibacterial function.
【０００２】[0002]
【従来の技術】紫外線の照射を受けて脱臭反応を進行さ
せる光触媒としてアナターゼ型のＴiＯ2が知られてい
る。そして、光触媒粒子をバインダに混練した原料を居
住空間の壁面を構成する部材の表面に塗布した後に焼成
することで、居住空間の壁面に脱臭壁機能を持たせるよ
うにした提案を本出願人は先に行なっている。2. Description of the Related Art Anatase-type TiO2 is known as a photocatalyst for promoting a deodorizing reaction upon irradiation with ultraviolet rays. The applicant has proposed a proposal in which the raw material obtained by kneading the photocatalyst particles into a binder is applied to the surface of the member constituting the wall surface of the living space and then fired, so that the wall surface of the living space has a deodorizing wall function. I have done it first.
【０００３】[0003]
【発明が解決しようとする課題】図５は脱臭壁の一部部
分拡大断面図であり、壁材１００の表面にはバインダ層
１０１が形成され、このバインダ層１０１内に光触媒粒
子１０２が保持されている。FIG. 5 is a partially enlarged cross-sectional view of a deodorizing wall. A binder layer 101 is formed on the surface of a wall material 100, and photocatalyst particles 102 are held in the binder layer 101. ing.
【０００４】従来にあってはバインダ層１０１内に光触
媒粒子１０２が完全に埋まっているため、脱臭壁全体と
しては、全ての光触媒粒子１０２に直接紫外線が照射さ
れず、また、光触媒粒子１０２の平均粒径も比較的大き
く、十分な触媒作用を発揮することができない。このこ
とは、脱臭機能を有する光触媒粒子の代りに殺菌機能を
有するＣuやＡgをバインダ層内に配合した場合にも言え
ることである。In the prior art, since the photocatalyst particles 102 are completely buried in the binder layer 101, the entire deodorizing wall does not directly irradiate all the photocatalyst particles 102 with ultraviolet rays. The particle size is relatively large, and a sufficient catalytic action cannot be exhibited. This is also true when Cu or Ag having a sterilizing function is blended in the binder layer instead of the photocatalytic particles having the deodorizing function.
【０００５】[0005]
【課題を解決するための手段】上記課題を解決すべく本
発明に係る抗菌機能を有する部材は、基材表面にバイン
ダ層を介してＣuまたはＡgを担持するとともに、前記バ
インダ層の表面からＣuまたはＡgの一部が露出する構成
とした。In order to solve the above-mentioned problems, a member having an antibacterial function according to the present invention carries Cu or Ag on the surface of a base material via a binder layer, and Cu from the surface of the binder layer. Alternatively, a configuration was adopted in which part of Ag was exposed.
【０００６】このように、バインダ層を介してＣuまた
はＡgを保持することで、空気中の菌が直接ＣuまたはＡ
gに接触する。[0006] As described above, by holding Cu or Ag through the binder layer, bacteria in the air can be directly Cu or A.
Touch g.
【０００７】[0007]
【発明の実施の形態】以下に本発明の実施の形態を添付
図面に基づいて説明する。ここで、図１はセラミック、
陶器、ガラス、金属等の基材表面に光触媒層を形成し、
この光触媒層に本発明の抗菌効果機能を持たせた部材の
製造方法を工程順に示した図である。Embodiments of the present invention will be described below with reference to the accompanying drawings. Here, FIG.
Form a photocatalyst layer on the surface of a substrate such as pottery, glass, metal, etc.
It is the figure which showed the manufacturing method of the member which made this photocatalyst layer have the antibacterial effect function of this invention in process order.
【０００８】本発明方法にあっては先ず図１（ａ）に示
すように、壁面、床面或いは天井面を構成する板状部材
としてのタイル素地１の表面に光触媒粒子による光触媒
機能によって分解されにくい材料である釉薬層２を塗布
し、次いで図１（ｂ）に示すように釉薬層２の表面にス
プレー等を用いて光触媒粒子としてのアナターゼ型Ｔi
Ｏ2粒子３をゾル状にして吹き付け、次いで図１（ｃ）
に示すように釉薬層２を加熱溶融せしめた後、冷却して
固化せしめる。In the method of the present invention, first, as shown in FIG. 1 (a), the surface of a tile substrate 1 as a plate-like member constituting a wall surface, a floor surface or a ceiling surface is decomposed by a photocatalytic function of photocatalytic particles. A glaze layer 2, which is a difficult material, is applied, and then, as shown in FIG. 1B, the surface of the glaze layer 2 is sprayed or the like to form anatase Ti as photocatalyst particles.
The O2 particles 3 are sprayed in the form of a sol, and then FIG.
After the glaze layer 2 is heated and melted as shown in FIG. 3, it is cooled and solidified.
【０００９】尚、本発明にあっては、前記ＴiＯ2ゾルに
ＣuやＡg等を添加している。添加の方法としては例えば
ＣuＳＯ4をＮＨ3溶液でｐＨ１１程度に調整したＴiＯ2
ゾルに添加する。In the present invention, Cu, Ag or the like is added to the TiO 2 sol. As a method of addition, for example, TiO 2 in which CuSO 4 is adjusted to about pH 11 with an NH 3 solution is used.
Add to sol.
【００１０】そして、ＴiＯ2ゾルを前記したように釉薬
層２の表面に吹き付けた後に、３００〜９００℃の範囲
で加熱することで、釉薬層２上にアナターゼ型ＴiＯ2粒
子３上にＣuやＡg等が固定された抗菌機能を備えた層が
形成される。After the TiO 2 sol is sprayed on the surface of the glaze layer 2 as described above, the sol is heated in the range of 300 to 900 ° C., so that Cu or the like is formed on the anatase type TiO 2 particles 3 on the glaze layer 2. A layer having an antibacterial function to which Ag or the like is fixed is formed.
【００１１】図２乃至図４は別実施例を示す図であり、
図２に示す実施例にあっては、釉薬層２の表面に印刷に
よってインク層４を形成し、このインク層４の表面にＣ
uやＡg等を添加したＴiＯ2ゾルを吹き付け、その後は前
記と同様に加熱し冷却することで、ＣuやＡgの一部を露
出せしめる。2 to 4 show another embodiment.
In the embodiment shown in FIG. 2, an ink layer 4 is formed on the surface of the glaze layer 2 by printing, and a C
By spraying a TiO 2 sol to which u, Ag, or the like is added, and then heating and cooling in the same manner as described above, a part of Cu or Ag is exposed.
【００１２】図３に示す実施例は、離型紙５の表面に水
溶性バインダ６を介して釉薬層２を形成し、この釉薬層
２の表面にバインダ層７を形成し、このバインダ層７の
表面にＣuやＡg等を添加したＴiＯ2ゾルを吹き付けてシ
ートＳを得る。そして、離型紙５を剥離してシートＳを
タイル素地１表面に貼着し、この後前記と同様にして加
熱し冷却する。このようにシートＳを別体として用意し
ておけば、既存のタイル等にも所定の機能を簡単に付与
することができる。In the embodiment shown in FIG. 3, the glaze layer 2 is formed on the surface of the release paper 5 via the water-soluble binder 6, and the binder layer 7 is formed on the surface of the glaze layer 2. A sheet S is obtained by spraying a TiO 2 sol to which Cu, Ag or the like is added on the surface. Then, the release paper 5 is peeled off, the sheet S is adhered to the surface of the tile substrate 1, and then heated and cooled in the same manner as described above. By preparing the sheet S as a separate body in this way, a predetermined function can be easily given to existing tiles and the like.
【００１３】図４に示す実施例は、インク層４の表面に
部分的にＣuやＡg等を添加したＴiＯ2ゾルを吹き付けて
絵柄とし、装飾効果を高めるようにしたものである。In the embodiment shown in FIG. 4, the surface of the ink layer 4 is partially sprayed with a TiO 2 sol to which Cu, Ag or the like is added to form a picture, thereby enhancing the decorative effect.
【００１４】[0014]
【発明の効果】以上に説明した如く、本発明に係る抗菌
機能を有する部材は、基材表面にバインダ層を設け、こ
のバインダ層の表面からＣuやＡgの一部が露出する構成
としたので、ＣuやＡgの離脱を防止しつつ、露出した部
分に直接菌が接触するので、抗菌作用を十分に発揮する
ことができる。As described above, the member having an antibacterial function according to the present invention has a structure in which a binder layer is provided on the surface of a base material and a part of Cu or Ag is exposed from the surface of the binder layer. , Cu and Ag are prevented from coming off and bacteria are directly in contact with the exposed portions, so that the antibacterial action can be sufficiently exerted.
【図１】本発明に係る抗菌機能を有する部材の製造方法
を工程順に示した図。FIG. 1 is a view showing a method of manufacturing a member having an antibacterial function according to the present invention in the order of steps.
【図２】別実施例を示す部材の断面図。FIG. 2 is a sectional view of a member showing another embodiment.
【図３】別実施例を示す部材の断面図。FIG. 3 is a sectional view of a member showing another embodiment.
【図４】別実施例を示す部材の断面図。FIG. 4 is a sectional view of a member showing another embodiment.
【図５】従来の製造方法によって得られた光触媒機能を
有する部材の断面図。FIG. 5 is a cross-sectional view of a member having a photocatalytic function obtained by a conventional manufacturing method.
１…タイル素地、２…釉薬層、３…ＴiＯ2粒子、４…イ
ンク層、５…離型紙、６…水溶性バインダ、７…バイン
ダ層、８…紫外線反射層、Ｓ…シート、１００…壁材、
１０１…バインダ層、１０２…光触媒粒子。1 ... tile base material, 2 ... glaze layer, 3 ... TiO 2 particles, 4 ... ink layer, 5 ... release paper 6 ... water-soluble binder, 7 ... binder layer, 8 ... UV-reflecting layer, S ... sheet, 100 ... wall Timber,
101: binder layer, 102: photocatalyst particles.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 小島 栄一 福岡県北九州市小倉北区中島２丁目１番１ 号 東陶機器株式会社内 (72)発明者 佐伯 義光 福岡県北九州市小倉北区中島２丁目１番１ 号 東陶機器株式会社内 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Eiichi Kojima 2-1, 1-1 Nakajima, Kokurakita-ku, Kitakyushu-shi, Fukuoka Prefecture Inside Totoki Equipment Co., Ltd. (72) Yoshimitsu Saeki 2 Nakajima, Kokurakita-ku, Kitakyushu-shi, Fukuoka No.1-1, Totoki Kiki Co., Ltd.
Claims (1)
した部材であって、前記バインダ層にはＣuまたはＡgが
その一部を露出するように保持されていることを特徴と
する抗菌機能を有する部材。1. A member having a binder layer such as a glaze layer formed on a surface of a substrate, wherein Cu or Ag is held in the binder layer so as to expose a part thereof. A member having a function.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11062579A JPH11322524A (en) | 1999-03-10 | 1999-03-10 | Material having antibacterial activity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11062579A JPH11322524A (en) | 1999-03-10 | 1999-03-10 | Material having antibacterial activity |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11014879A Division JPH11347420A (en) | 1999-01-22 | 1999-01-22 | Member having photocatalytic function |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11322524A true JPH11322524A (en) | 1999-11-24 |
Family
ID=13204379
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11062579A Pending JPH11322524A (en) | 1999-03-10 | 1999-03-10 | Material having antibacterial activity |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11322524A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010084204A (en) * | 2000-02-24 | 2001-09-06 | 박현식 | Tile and manufacturing method thereof |
| WO2007026387A2 (en) * | 2005-09-01 | 2007-03-08 | NM TECH LTD. - Nanomaterials and Microdevices Technology | Photocatalytic filters that are coated with titanium dioxide suspensions and other substances and methods for obtaining such filters |
| WO2007116302A2 (en) * | 2006-04-11 | 2007-10-18 | Nm Tech Nanomaterials Microdevice Technology Ltd. | Semifinished products, footwear elements, apparatuses and methods for obtaining footwear elements, and footwear |
| WO2007147842A2 (en) * | 2006-06-21 | 2007-12-27 | Agc Flat Glass Europe Sa | Substrate with antimicrobial properties and process for the production of an antimicrobial substrate |
| US8530056B2 (en) | 2004-12-16 | 2013-09-10 | Agc Glass Europe | Substrate with antimicrobial properties |
| CN108360779A (en) * | 2018-03-09 | 2018-08-03 | 昆山市聚光装饰材料有限公司 | Wallpaper |
-
1999
- 1999-03-10 JP JP11062579A patent/JPH11322524A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010084204A (en) * | 2000-02-24 | 2001-09-06 | 박현식 | Tile and manufacturing method thereof |
| US8530056B2 (en) | 2004-12-16 | 2013-09-10 | Agc Glass Europe | Substrate with antimicrobial properties |
| US8741437B2 (en) | 2004-12-16 | 2014-06-03 | Agc Glass Europe | Substrate with antimicrobial properties |
| WO2007026387A2 (en) * | 2005-09-01 | 2007-03-08 | NM TECH LTD. - Nanomaterials and Microdevices Technology | Photocatalytic filters that are coated with titanium dioxide suspensions and other substances and methods for obtaining such filters |
| WO2007026387A3 (en) * | 2005-09-01 | 2007-05-31 | Nm Tech Ltd | Photocatalytic filters that are coated with titanium dioxide suspensions and other substances and methods for obtaining such filters |
| WO2007116302A2 (en) * | 2006-04-11 | 2007-10-18 | Nm Tech Nanomaterials Microdevice Technology Ltd. | Semifinished products, footwear elements, apparatuses and methods for obtaining footwear elements, and footwear |
| WO2007116302A3 (en) * | 2006-04-11 | 2008-08-14 | Nm Tech Nanomaterials Microdev | Semifinished products, footwear elements, apparatuses and methods for obtaining footwear elements, and footwear |
| WO2007147842A2 (en) * | 2006-06-21 | 2007-12-27 | Agc Flat Glass Europe Sa | Substrate with antimicrobial properties and process for the production of an antimicrobial substrate |
| WO2007147842A3 (en) * | 2006-06-21 | 2008-03-06 | Agc Flat Glass Europe Sa | Substrate with antimicrobial properties and process for the production of an antimicrobial substrate |
| CN108360779A (en) * | 2018-03-09 | 2018-08-03 | 昆山市聚光装饰材料有限公司 | Wallpaper |
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