JPH11300867A - Sandwich board made of fiber reinforced plastic - Google Patents
Sandwich board made of fiber reinforced plasticInfo
- Publication number
- JPH11300867A JPH11300867A JP10109835A JP10983598A JPH11300867A JP H11300867 A JPH11300867 A JP H11300867A JP 10109835 A JP10109835 A JP 10109835A JP 10983598 A JP10983598 A JP 10983598A JP H11300867 A JPH11300867 A JP H11300867A
- Authority
- JP
- Japan
- Prior art keywords
- sandwich board
- resin
- material layer
- reinforced plastic
- area
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
- Investigating Strength Of Materials By Application Of Mechanical Stress (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、繊維強化プラスチ
ック製（以下、ＦＲＰ製という。）サンドイッチボード
に関する。更に詳細には、十分な耐食性を有し、信頼性
の高い機械的強度を実現したＦＲＰ製サンドイッチボー
ドに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fiber reinforced plastic (hereinafter, referred to as FRP) sandwich board. More specifically, the present invention relates to an FRP sandwich board having sufficient corrosion resistance and realizing highly reliable mechanical strength.
【０００２】[0002]
【従来の技術】ＦＲＰ製サンドイッチボードは、その軽
量性と低コスト性から有用な構造であり、軽量、高強度
な構造を必要とする車両、航空機等には特に好適に使用
されている。2. Description of the Related Art FRP sandwich boards have a useful structure because of their light weight and low cost, and are particularly suitably used for vehicles, aircraft, and the like that require a lightweight and high-strength structure.
【０００３】このような構造で最も重要なのは、表面材
と芯材との接着の信頼性であり、この接着の信頼性がＦ
ＲＰ製サンドイッチボードの耐久性等に大きく影響す
る。事実上、ＦＲＰ製サンドイッチボードの製造時に表
面材と芯材はいくらかの剥離部、接着強度不足部等の欠
陥部分を有し、１００％完全な構造を得ることは不可能
である。ガラス繊維強化プラスチックを表面材に用い、
塗装が無く、表面材が透明である場合では、表面材と芯
材の剥離は目視でも確認出来るため、検査は比較的容易
である。しかしながら、炭素繊維強化プラスチック、ア
ラミド繊維強化プラスチック等の複合材料を用いた場
合、及びガラス繊維強化プラスチックでも着色樹脂、表
面コートを用いた場合には、材料が不透明であり、表面
材と芯材との界面を目視で確認出来ない問題点があっ
た。The most important factor in such a structure is the reliability of bonding between the surface material and the core material.
This greatly affects the durability and the like of the RP sandwich board. In fact, the surface material and the core material during the production of the FRP sandwich board have some defective parts such as peeled parts and insufficient adhesive strength, and it is impossible to obtain a 100% complete structure. Using glass fiber reinforced plastic for the surface material,
In the case where there is no coating and the surface material is transparent, the inspection is relatively easy since the peeling of the surface material and the core material can be visually confirmed. However, when a composite material such as carbon fiber reinforced plastic or aramid fiber reinforced plastic is used, or when a colored resin or surface coat is used even for glass fiber reinforced plastic, the material is opaque, and the surface material and the core material are There was a problem that the interface of the sample could not be visually confirmed.
【０００４】実際に全く欠陥の無いＦＲＰ製サンドイッ
チボードを得ることは非常に難しいことから、実用上耐
久性に支障の無い欠陥レベルを規定し、支障のある欠陥
部分を非破壊的に評価し、欠陥のあるＦＲＰ製サンドイ
ッチボードを除くことが求められているが、従来、この
ような信頼性の高いＦＲＰ製サンドイッチボードは知ら
れていない。Since it is very difficult to actually obtain an FRP sandwich board having no defect at all, a defect level that does not hinder the durability in practical use is specified, and the faulty defect portion is evaluated nondestructively. There is a need to remove defective FRP sandwich boards, but no such highly reliable FRP sandwich boards have been known.
【０００５】[0005]
【発明が解決しょうとする課題】本発明は、性能に有害
な表面材と芯材との界面の欠陥部分を非破壊的に検出、
除去した信頼性の高く、耐久性に優れたＦＲＰ製サンド
イッチボードを提供するものである。SUMMARY OF THE INVENTION The present invention non-destructively detects defects at the interface between a surface material and a core material, which are harmful to performance.
An object of the present invention is to provide an FRP sandwich board which has been removed and has high reliability and excellent durability.
【０００６】[0006]
【課題を解決するための手段】本発明の要旨は、芯材層
と、炭素繊維強化材に樹脂を含浸した表面材層と、チョ
ップドストランドマットに耐食性樹脂を含浸した耐食性
樹脂層と、これらの外側にあり、サーフェーシングマッ
トに耐食性樹脂を含浸した保護材層を有する繊維強化プ
ラスチック製サンドイッチボードであって、非破壊試験
法により求めた欠陥部分の個々の面積がサンドイッチボ
ードの面積の５％未満であり、且つ欠陥部分の面積合計
がサンドイッチボードの面積の５０％未満であることを
特徴とする繊維強化プラスチック製サンドイッチボード
にある。The gist of the present invention is to provide a core material layer, a surface material layer in which carbon fiber reinforcing material is impregnated with a resin, and a corrosion-resistant resin layer in which a chopped strand mat is impregnated with a corrosion-resistant resin. A sandwich board made of fiber-reinforced plastic having a protective material layer on the outside and impregnated with a corrosion-resistant resin in a facing mat, wherein an individual area of a defective portion determined by a non-destructive test method is less than 5% of an area of the sandwich board. And the total area of the defective portions is less than 50% of the area of the sandwich board.
【０００７】本発明において、発明者らは、耐久性能と
してＦＲＰ製サンドイッチボードの曲げ疲労強度を用い
れば実用時の耐久性と良く対応することを見い出した。In the present invention, the inventors have found that if the bending fatigue strength of a sandwich board made of FRP is used as the durability performance, the durability of the FRP sandwich board corresponds well to the durability in practical use.
【０００８】[0008]
【発明の実施の形態】本発明のＦＲＰ製サンドイッチボ
ードを構成する芯材層としては、比重が小さく軽量の、
望ましくは機械的強度の高い、硬質樹脂発泡体、気泡を
散在させた繊維綿体、又は木材などが挙げられる。BEST MODE FOR CARRYING OUT THE INVENTION The core layer constituting the sandwich board made of FRP of the present invention has a small specific gravity and a light weight.
Desirably, a hard resin foam, a fibrous cotton body in which bubbles are dispersed, or a wood having high mechanical strength is used.
【０００９】硬質樹脂発泡体しては、好適には、降伏
（破断）点強度で表して、圧縮、引張、曲げ及び剪断が
それぞれ、１．５ｋｇ／ｃｍ2 、３．５ｋｇ／ｃｍ2 、
４．０ｋｇ／ｃｍ2 、及び２．０ｋｇ／ｃｍ2 以上の機
械的強度を有し、見かけ密度７０ｋｇ／ｍ3 以下の硬質
樹脂発泡体が用いることができる。例えば、鐘淵化学工
業社製の塩化ビニル発泡体、商品名クレゲセル（登録商
標）Ｈ１００やＨ７５が好適に使用できる。[0009] with a rigid resin foam body, preferably, expressed in yield (fracture) point strength, compression, tension, respectively bending and shearing, 1.5kg / cm 2, 3.5kg / cm 2,
4.0 kg / cm 2, and has a 2.0 kg / cm 2 or more mechanical strength, it can be apparent density 70 kg / m 3 or less of the hard resin foam used. For example, a vinyl chloride foam manufactured by Kanegabuchi Chemical Industry Co., Ltd., trade name of Kregecel (registered trademark) H100 or H75 can be preferably used.
【００１０】ここで、気泡を散在させた繊維綿体とは、
気体を閉じ込めたカプセル又はバルーンを繊維綿中に散
在させたもので、軽量かつ一応の機械的強度を備えた材
料である。このような材料としては、例えば、日本ユピ
カ社製の商品名：ユピカマット又はランター社製の商品
名：コアマットＩＩのようにポリエステル繊維綿にマイ
クロカプセルを入れたもの、又はＧＰＰ社製の商品名：
スペアマットのようにガラス繊維綿にマイクロバルーン
を入れたもの等が好適に使用できる。Here, the fiber cotton body in which bubbles are dispersed is:
It is a material that is light and has a certain degree of mechanical strength, in which capsules or balloons containing gas are scattered in fiber cotton. As such a material, for example, a product name manufactured by Nippon Yupika Co., Ltd .: a product name manufactured by Yupika Mat or Lanter Co., Ltd .: a product obtained by putting microcapsules in polyester fiber cotton like Core Mat II, or a product name manufactured by GPP:
A material in which microballoons are put in glass fiber cotton like a spare mat can be suitably used.
【００１１】本発明のＦＲＰ製サンドイッチボードにお
いて、炭素繊維強化材に樹脂を含浸した表面材層は、炭
素繊維に樹脂を含浸し、樹脂を硬化したものである。そ
の強化形態としては、炭素繊維を一方向に引き揃えたも
の、炭素繊維を製織しクロス材としたもの、炭素繊維を
ステッチしたロービングクロス、炭素繊維に接着剤を用
いてマット状に仕上げたコンティニュアスストランドマ
ット、炭素繊維を５〜５０ｍｍ程度に切断した短繊維を
無定方向に分散してチョップドストランドマット等が用
いることができるIn the FRP sandwich board of the present invention, the surface material layer in which the carbon fiber reinforced material is impregnated with the resin is obtained by impregnating the carbon fiber with the resin and curing the resin. The reinforcement forms include carbon fiber aligned in one direction, carbon fiber woven cloth material, roving cloth stitched with carbon fiber, and matte finish using carbon fiber adhesive. New strand mat, chopped strand mat or the like can be used by dispersing short fibers obtained by cutting carbon fibers to about 5 to 50 mm in an indeterminate direction.
【００１２】本発明の表面材層に用いる樹脂としては、
不飽和ポリエステル樹脂、ビニルエステル樹脂、エポキ
シ樹脂、フラン樹脂、フェノール樹脂等の既知の樹脂を
用いることができる。本発明では、通常、後述する耐食
性樹脂層と同じ樹脂を表面材層に用いる。これにより耐
食性が向上する。The resin used for the surface material layer of the present invention includes:
Known resins such as unsaturated polyester resin, vinyl ester resin, epoxy resin, furan resin, and phenol resin can be used. In the present invention, the same resin as the corrosion-resistant resin layer described later is usually used for the surface material layer. Thereby, corrosion resistance is improved.
【００１３】本発明のＦＲＰ製サンドイッチボードにお
いては、表面材層の外側表面に、チョップドストランド
マットに耐食性樹脂を含浸した耐食性樹脂層を設けるこ
とが必要である。In the FRP sandwich board of the present invention, it is necessary to provide a corrosion-resistant resin layer obtained by impregnating a chopped strand mat with a corrosion-resistant resin on the outer surface of the surface material layer.
【００１４】ここで、チョップドストランドマットと
は、強化繊維を５〜５０ｍｍ程度に切断した短繊維を無
定方向に均一に分散させ、接着剤にて接着させた薄いマ
ットを意味する。Here, the chopped strand mat means a thin mat in which staple fibers obtained by cutting reinforcing fibers to about 5 to 50 mm are uniformly dispersed in an indeterminate direction and adhered with an adhesive.
【００１５】本発明で耐食性樹脂層に含浸する耐食性樹
脂としては、本発明のＦＲＰ製サンドイッチボードが接
触する流体等に対して所定の耐食性を有する樹脂、例え
ば、不飽和ポリエステル樹脂、ビニルエステル樹脂、エ
ポキシ樹脂、フラン樹脂、フェノール樹脂等の既知の樹
脂を挙げることができる。As the corrosion-resistant resin impregnated in the corrosion-resistant resin layer in the present invention, a resin having a predetermined corrosion resistance to a fluid or the like contacted by the FRP sandwich board of the present invention, for example, an unsaturated polyester resin, a vinyl ester resin, Known resins such as an epoxy resin, a furan resin, and a phenol resin can be used.
【００１６】本発明においては、耐食性樹脂層の外側表
面に、サーフェーシングマットに上述の耐食性樹脂を含
浸した保護材層を形成することが必要である。In the present invention, it is necessary to form, on the outer surface of the corrosion-resistant resin layer, a protective material layer in which the above-mentioned corrosion-resistant resin is impregnated in a surfacing mat.
【００１７】サーフェーシングマットは、表面材層の外
側表面に樹脂リッチな層を設けるために使用されるマッ
ト等の不織布であり、旭ファイバーグラス社製グラスロ
ン等が好適に用いられる。The surfacing mat is a nonwoven fabric such as a mat used for providing a resin-rich layer on the outer surface of the surface material layer, and Glaslon manufactured by Asahi Fiberglass Corporation is preferably used.
【００１８】本発明において、芯材層、表面材層、耐食
性樹脂層及び保護層を積層して、ＦＲＰ製サンドイッチ
ボードとする成型方法、或いは接着方法について、特に
限定するものではないが、本発明のＦＲＰ製サンドイッ
チボードが特徴とする高信頼性を奏するためには、非破
壊試験により求めた欠陥部分の個々の面積がサンドイッ
チボードの面積の５％未満、好ましくは３％未満、より
好ましくは２．６％未満であり、且つ欠陥部分の面積合
計がサンドイッチボードの面積の５０％未満、好ましく
は４０％未満、より好ましくは２５％未満であることが
耐久性に優れ、信頼性の高いＦＲＰ製サンドイッチボー
ドとする上で必要である。本発明で欠陥部分というの
は、ＦＲＰ製サンドイッチボードの芯材層と表面材層の
間の剥離部、接着強度不足部等をいうIn the present invention, there is no particular limitation on a molding method or a bonding method in which a core material layer, a surface material layer, a corrosion-resistant resin layer and a protective layer are laminated to form an FRP sandwich board. In order to achieve the high reliability characteristic of the FRP sandwich board, the individual area of the defective portion determined by the nondestructive test is less than 5%, preferably less than 3%, more preferably less than 2% of the area of the sandwich board. Less than 0.6%, and the total area of the defective portions is less than 50%, preferably less than 40%, and more preferably less than 25% of the area of the sandwich board. Necessary for making a sandwich board. In the present invention, the defective portion means a peeled portion between the core material layer and the surface material layer of the FRP sandwich board, a portion having insufficient adhesive strength, and the like.
【００１９】本発明のＦＲＰ製サンドイッチボードの非
破壊試験法としては、ＦＲＰ製サンドイッチボード中の
欠陥部分の面積を測定することができればよく、特に限
定はしないが、従来から公知のＸ線法、レーザホログラ
フィー法、アコースチックエミッション法、超音波法、
又はタッピング法等を用いることができる。The non-destructive test method of the FRP sandwich board of the present invention is not particularly limited as long as the area of a defective portion in the FRP sandwich board can be measured. Laser holography method, acoustic emission method, ultrasonic method,
Alternatively, a tapping method or the like can be used.
【００２０】その中でもＦＲＰ製サンドイッチボードを
軽く打撃してその反発係数の差により表面材層と芯材層
の界面特性を特定し、健全な部分と不健全な部分を差別
化するタッピング法、又は、ＦＲＰ製サンドイッチボー
ドに超音波をあて、欠陥部分からの反射により表面材層
と芯材層の界面特性を特定し、健全な部分と不健全な部
分を差別化する超音波法が、多くのケースにおいて有効
且つ実用的であり特に好ましい。Among them, a tapping method of tapping an FRP sandwich board lightly to identify the interface characteristics between the surface material layer and the core material layer based on the difference in the coefficient of restitution, and to differentiate a sound part from an unhealthy part, or The ultrasonic method of applying ultrasonic waves to a sandwich board made of FRP, specifying the interface characteristics between the surface material layer and the core material layer by reflection from a defective portion, and differentiating a sound portion from an unhealthy portion, has been widely used. It is effective and practical in the case and is particularly preferred.
【００２１】所望の板厚で非破壊試験によって欠陥部分
の面積を正確に測定するには、前もって、同じ板厚のＦ
ＲＰ製サンドイッチボードの成形時に芯材層と表面材層
との間に任意の大きさの油含浸紙又はプラスチックフィ
ルムを挟み込み人工的に欠陥部分を入れた供試体を用
い、測定条件を調整しておくことが肝要である。In order to accurately measure the area of a defective portion by a non-destructive test at a desired thickness, it is necessary to previously measure F area having the same thickness.
Adjust the measurement conditions by using a specimen in which an oil-impregnated paper or plastic film of any size is inserted between the core material layer and the surface material layer during molding of the RP sandwich board and an artificially defective portion is inserted. It is important to keep it.
【００２２】非破壊試験を行うピッチが有害な剥離寸法
以下のピッチであれば、より信頼性高く繊維強化プラス
チック製サンドイッチボードの評価を行うことができる
ので好ましい。It is preferable that the pitch at which the nondestructive test is performed has a pitch equal to or less than a harmful peeling size, because the sandwich board made of fiber reinforced plastic can be evaluated more reliably.
【００２３】本発明の好適な実施態様としては、芯材層
と、ＦＲＰからなる表面材層とが、繊維マットに樹脂を
含浸させてなる接着層を介して接着、積層してなること
が挙げられる。この接着剤層は力学特性の異なる芯材層
と表面材層を強固に接着するために挿入するもので、芯
材層と表面材層間の接着性が良好な場合は必ずしも必要
ではない。ここで、繊維マットとしては上記のコンティ
ニュアスストランドマットやチョップドストランドマッ
トが好適に用いられる。ただし、繊維マットを構成する
繊維は強化繊維のように高強度高弾性率の強化繊維であ
る必要はない。接着層を構成する樹脂としては、芯材層
と表面材層を強固に接着するものであればよく特に限定
しないが、一般に表面材層と同じ樹脂であることが接着
性の向上に役立つ。In a preferred embodiment of the present invention, a core material layer and a surface material layer made of FRP are bonded and laminated via an adhesive layer obtained by impregnating a fiber mat with a resin. Can be This adhesive layer is inserted in order to firmly bond the core material layer and the surface material layer having different mechanical properties, and is not always necessary when the adhesion between the core material layer and the surface material layer is good. Here, as the fiber mat, the above-mentioned continuous strand mat or chopped strand mat is suitably used. However, the fibers constituting the fiber mat need not be high-strength and high-modulus reinforced fibers unlike reinforced fibers. The resin constituting the adhesive layer is not particularly limited as long as it strongly adheres the core material layer and the surface material layer, but generally the same resin as the surface material layer helps to improve the adhesiveness.
【００２４】[0024]
【実施例】以下、実施例により本発明をさらに具体的に
説明する。 （材料）ＦＲＰ製サンドイッチボードの各層に使用する
樹脂以外の材料を表１に示した。実施例において各材料
は略号をもって呼ぶことにする。The present invention will be described more specifically with reference to the following examples. (Materials) The materials other than the resin used for each layer of the sandwich board made of FRP are shown in Table 1. In the examples, each material is referred to by an abbreviation.
【００２５】[0025]
【表１】 [Table 1]
【００２６】（樹脂組成）昭和高分子社製リポキシ＃８
０２ビニルエステル樹脂１００重量部、ナフテン酸コバ
ルト１重量部、日本化薬社製過酸化物、商品名カヤック
３２８Ｅを配合した樹脂を用意した。(Resin composition) Lipoxy # 8 manufactured by Showa Polymer Co., Ltd.
A resin was prepared by blending 100 parts by weight of 02 vinyl ester resin, 1 part by weight of cobalt naphthenate, peroxide manufactured by Nippon Kayaku Co., Ltd., and Kayak 328E (trade name).
【００２７】（非破壊試験の評価）ＦＯの上下面に用意
した樹脂を含浸しながらＭを積層した。その上から所望
の厚みになるようにＣに用意した樹脂を含浸しながら積
層し、次に樹脂を含浸しながらＭを積層し、更にＳに用
意した樹脂を含浸しながら、Ｓ／Ｍ／Ｃ／Ｍ／ＦＯ／Ｍ
／Ｃ／Ｍ／Ｓからなる積層構成とした。この積層物を２
５℃で５時間放置して硬化し、保護材層、耐食性樹脂層
及び表面材（Ｓ／Ｍ／Ｃ／Ｍ）の厚さ４ｍｍ、全厚み３
０ｍｍのＦＲＰ製サンドイッチボードを得た。(Evaluation of Nondestructive Test) M was laminated while impregnating the prepared resin on the upper and lower surfaces of the FO. From above, lamination is performed while impregnating the resin prepared in C to a desired thickness, then M is laminated while impregnating the resin, and S / M / C is further impregnated with the resin prepared in S. / M / FO / M
/ C / M / S. This laminate is
It is cured by leaving it at 5 ° C. for 5 hours, and the protective material layer, the corrosion-resistant resin layer and the surface material (S / M / C / M) have a thickness of 4 mm and a total thickness of 3
A 0 mm FRP sandwich board was obtained.
【００２８】上記の積層の途中で、ＭとＦＯの間に１０
０、１５０、２００、２５０ｍｍφに切った厚み０．１
ｍｍの油含浸紙を挿入しておき、剥離直径１００、１５
０、２００、２５０ｍｍφの人工剥離をいれたモデルＦ
ＲＰ製サンドイッチボードを作製した。In the middle of the above-mentioned lamination, between M and FO, 10
Thickness 0.1 cut to 0, 150, 200, 250 mmφ
mm oil-impregnated paper is inserted and the peeling diameter is 100, 15
Model F with artificial peeling of 0, 200, 250 mmφ
An RP sandwich board was produced.
【００２９】また、Ｃの積層枚数を４、６、８、１０、
及び１２枚に変更し、表面材（Ｓ／Ｍ／Ｃ／Ｍ）厚さ
６、８、１０、１２、１４ｍｍのＦＲＰ製サンドイッチ
ボードをそれぞれ得た。Further, the number of laminated layers of C is 4, 6, 8, 10,
And 12 sheets, and FRP sandwich boards having surface material (S / M / C / M) thicknesses of 6, 8, 10, 12, and 14 mm were obtained.
【００３０】（１）タッピング法 上記の様にして製作したＦＲＰ製サンドイッチボードを
タッピング非破壊試験装置（三井造船社製ＷＯＯＤＰＥ
ＣＫＥＲ ＷＰ−６３１）を用いてタッピングピッチ２
０ｍｍで測定した。その結果を表２に示した。この評価
結果よりタッピング法での表面材厚さに応じた剥離に対
する感度が判明した。すなわち、表面材厚さ８ｍｍ以下
であれば有害である２００ｍｍφの大きさの剥離が検出
できることが判明した。(1) Tapping method A non-destructive tapping test device (WOODPE manufactured by Mitsui Engineering & Shipbuilding Co., Ltd.) was used for the FRP sandwich board manufactured as described above.
Tapping pitch 2 using CKER WP-631)
It was measured at 0 mm. The results are shown in Table 2. From this evaluation result, the sensitivity to peeling according to the surface material thickness in the tapping method was found. That is, it has been found that a harmful peeling of 200 mmφ can be detected if the surface material thickness is 8 mm or less.
【００３１】[0031]
【表２】 [Table 2]
【００３２】（２）超音波法 上記の様にして製作したＦＲＰ製サンドイッチボードを
超音波非破壊試験装置（ＮＤＴ ｓｙｓｔｅｍ社製 Ｑ
ＵＡＮＴＵＭ ＱＢＴ−２＋）を用いてピッチ２０ｍｍ
で測定した。その結果を表３に示した。この評価結果よ
り超音波法での表面材厚さに応じた剥離に対する感度が
判明した。すなわち、表面材厚さ１２ｍｍ以下であれば
有害である２００ｍｍφの大きさの剥離が検出できるこ
とが判明した。(2) Ultrasonic method The sandwich board made of FRP manufactured as described above was subjected to an ultrasonic non-destructive test apparatus (Q made by NDT system).
20mm pitch using UANTUM QBT-2 +)
Was measured. Table 3 shows the results. From this evaluation result, the sensitivity to peeling according to the surface material thickness in the ultrasonic method was found. That is, it has been found that a harmful peeling of 200 mmφ can be detected if the surface material thickness is 12 mm or less.
【００３３】[0033]
【表３】 [Table 3]
【００３４】（実施例）１０００×１２００ｍｍのＦＯ
を用意し、その上に４０ｍｍφに切った厚み０．１ｍｍ
の油含浸紙を重ならないように４７８枚ランダムに配置
し、その上からＣに用意した樹脂を含浸しながら積層
し、さらに樹脂を含浸しながらＭを積層した。ＦＯの逆
の面には油含浸紙を配置せず樹脂を含浸しながらＭ、
Ｃ、Ｍ及びＳを順に積層し、Ｓ／Ｍ／Ｃ／Ｍ／ＦＯ／Ｍ
／Ｃ／Ｍ／Ｓからなる積層構成とした。(Example) 1000 × 1200 mm FO
Prepared and cut on it to a thickness of 40 mmφ 0.1 mm
Of the 478 oil-impregnated papers were arranged at random so as not to overlap with each other, and laminated thereon while impregnating the resin prepared in C, and further laminated M while impregnating the resin. M, while impregnating resin without oil-impregnated paper on the opposite side of the FO
C, M and S are laminated in order, and S / M / C / M / FO / M
/ C / M / S.
【００３５】この積層物を２５℃で５時間放置して硬化
し、保護材層、耐食性樹脂層及び表面材（Ｓ／Ｍ／Ｃ／
Ｍ）厚さ３ｍｍ、全厚み３０ｍｍ、剥離大きさ４０ｍｍ
φ、剥離部面積比が５０％のＦＲＰ製サンドイッチボー
ドを得た。The laminate was cured by leaving it at 25 ° C. for 5 hours, and the protective material layer, the corrosion-resistant resin layer and the surface material (S / M / C /
M) Thickness 3 mm, total thickness 30 mm, peel size 40 mm
An FRP sandwich board having a φ and a peeling area ratio of 50% was obtained.
【００３６】このＦＲＰ製サンドイッチボードを１００
×１２００ｍｍの曲げ疲労試験片に切り分けた後、すべ
ての試験片に対して、スパン／板厚＝３０で片振り３点
曲げにより疲労試験を実施した。応力−繰り返し回数試
験の結果（最高値及び最低値）を図１に示した。This FRP sandwich board was used for 100
After being cut into × 1200 mm bending fatigue test pieces, all the test pieces were subjected to a fatigue test by oscillating three-point bending at span / plate thickness = 30. FIG. 1 shows the results (highest value and lowest value) of the stress-repetition number test.
【００３７】ＦＯとＭの間にランダムに配置する油含浸
紙の大きさ（４０、１００、及び２００ｍｍφ）と配置
する枚数を変化し、上記のようにＦＲＰ製サンドイッチ
ボードを成形して、剥離大きさ−剥離部面積比が、それ
ぞれ４０ｍｍφ−１０％、１００ｍｍφ−１０％、１０
０ｍｍφ−５０％、２００ｍｍφ−１０％、及び２００
ｍｍφ−５０％のＦＲＰ製サンドイッチボードを得た。
更に油含浸紙を配置しないＦＲＰ製サンドイッチボード
を成形した。これらのＦＲＰ製サンドイッチボードに対
して上記と同様にして３点曲げにより疲労試験を実施
し、応力−繰り返し回数試験の結果（最高値及び最低
値）を図１に併せて示した。The size (40, 100, and 200 mmφ) of the oil-impregnated paper randomly arranged between the FO and the M and the number of the oil-impregnated papers were changed. The area ratio of the peeled part is 40 mmφ-10%, 100 mmφ-10%, 10 mm, respectively.
0mmφ-50%, 200mmφ-10%, and 200
A mmφ-50% FRP sandwich board was obtained.
Further, a sandwich board made of FRP without oil-impregnated paper was formed. A fatigue test was performed on these FRP sandwich boards by three-point bending in the same manner as described above, and the results (highest value and lowest value) of the stress-repetition number test are also shown in FIG.
【００３８】この結果からＦＲＰ製サンドイッチボード
の疲労強度の低下は、非破壊試験により求めた欠陥部分
の個々の面積がサンドイッチボードの面積の２．６％の
２００ｍｍφ、且つ欠陥部分の面積合計がサンドイッチ
ボードの面積の５０％以上となると急激に低下すること
が判明した。From these results, the decrease in the fatigue strength of the sandwich board made of FRP was caused by the fact that the individual area of the defective portion determined by the nondestructive test was 200% of 2.6% of the area of the sandwich board, and the total area of the defective portion was the sandwich. It has been found that when the area is 50% or more of the board area, it rapidly decreases.
【００３９】[0039]
【発明の効果】本発明のＦＲＰ製サンドイッチボード
は、性能に有害な表面材と芯材との界面の剥離を非破壊
的に検出、除外しているので、信頼性の高く、耐久性に
優れたＦＲＰ製サンドイッチボードとなる。The FRP sandwich board of the present invention non-destructively detects and excludes the delamination of the interface between the surface material and the core material which is harmful to the performance, so that it is highly reliable and has excellent durability. FRP sandwich board.
【図１】 ＦＲＰ製サンドイッチボードの曲げ疲労試験
の応力−繰り返し回数を示したグラフである。FIG. 1 is a graph showing stress versus the number of repetitions in a bending fatigue test of an FRP sandwich board.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 竹本 秀博 愛知県豊橋市牛川通四丁目１番地の２ 三 菱レイヨン株式会社豊橋事業所内 (72)発明者 石森 巧 愛知県豊橋市牛川通四丁目１番地の２ 三 菱レイヨン株式会社豊橋事業所内 (72)発明者 沼田 喜春 愛知県豊橋市牛川通四丁目１番地の２ 三 菱レイヨン株式会社豊橋事業所内 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Hidehiro Takemoto 4-1, Ushikawa-dori, Toyohashi-shi, Aichi Pref. Inside the Toyohashi Works of Mitsubishi Rayon Co., Ltd. (72) Inventor Takumi Ishimori 4-1-1 Ushikawa-dori, Toyohashi-shi, Aichi Prefecture (2) Inventor Yoshiharu Numata 4-1-1 Ushikawa-dori, Toyohashi-shi, Aichi Prefecture Inside the Toyohashi office
Claims (4)
した表面材層と、チョップドストランドマットに耐食性
樹脂を含浸した耐食性樹脂層と、これらの外側にあり、
サーフェーシングマットに耐食性樹脂を含浸した保護材
層を有する繊維強化プラスチック製サンドイッチボード
であって、非破壊試験法により求めた欠陥部分の個々の
面積がサンドイッチボードの面積の５％未満であり、且
つ欠陥部分の面積合計がサンドイッチボードの面積の５
０％未満であることを特徴とする繊維強化プラスチック
製サンドイッチボード。1. A core material layer, a surface material layer obtained by impregnating a carbon fiber reinforcing material with a resin, a corrosion-resistant resin layer obtained by impregnating a chopped strand mat with a corrosion-resistant resin,
A fiber reinforced plastic sandwich board having a protective material layer impregnated with a corrosion resistant resin in a surfacing mat, wherein the area of each defective portion determined by a non-destructive test method is less than 5% of the area of the sandwich board, and The total area of the defective part is 5 of the area of the sandwich board.
A sandwich board made of fiber reinforced plastic, which is less than 0%.
に樹脂を含浸させてなる接着層を介して接着、積層して
なることを特徴とする請求項１記載の繊維強化プラスチ
ック製サンドイッチボード。2. The fiber reinforced plastic according to claim 1, wherein the core material layer and the surface material layer are bonded and laminated via an adhesive layer obtained by impregnating a fiber mat with a resin. Sandwich board.
繊維強化プラスチック製サンドイッチボード表面の局所
的な反発係数の差異により上記欠陥部分を知る試験法で
あることを特徴とする請求項１又は請求項２記載の繊維
強化プラスチック製サンドイッチボード。3. The non-destructive test method according to claim 1, wherein said defective portion is detected by a difference in a local coefficient of restitution of the surface of the sandwich board made of fiber reinforced plastic by tapping. 2. The sandwich board made of fiber-reinforced plastic according to 2.
の反射の差異により上記欠陥部分を知る試験法であるこ
とを特徴とする請求項１又は請求項２項記載の繊維強化
プラスチック製サンドイッチボード。4. The fiber reinforced plastic according to claim 1, wherein said non-destructive test method is a test method in which said defective portion is detected by a difference in reflection of ultrasonic waves from each layer. Sandwich board.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10983598A JP4108179B2 (en) | 1998-04-20 | 1998-04-20 | Evaluation method of fiber reinforced plastic sandwich board |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10983598A JP4108179B2 (en) | 1998-04-20 | 1998-04-20 | Evaluation method of fiber reinforced plastic sandwich board |
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| Publication Number | Publication Date |
|---|---|
| JPH11300867A true JPH11300867A (en) | 1999-11-02 |
| JP4108179B2 JP4108179B2 (en) | 2008-06-25 |
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ID=14520421
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10983598A Expired - Fee Related JP4108179B2 (en) | 1998-04-20 | 1998-04-20 | Evaluation method of fiber reinforced plastic sandwich board |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11300870A (en) * | 1998-04-20 | 1999-11-02 | Mitsubishi Rayon Co Ltd | Sandwich board made of fiber reinforced plastic |
| CN109725060A (en) * | 2019-01-31 | 2019-05-07 | 中国民用航空飞行学院 | One kind being based on the cured real time monitoring ultrasound wave system of Joule heat and monitoring method |
-
1998
- 1998-04-20 JP JP10983598A patent/JP4108179B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11300870A (en) * | 1998-04-20 | 1999-11-02 | Mitsubishi Rayon Co Ltd | Sandwich board made of fiber reinforced plastic |
| CN109725060A (en) * | 2019-01-31 | 2019-05-07 | 中国民用航空飞行学院 | One kind being based on the cured real time monitoring ultrasound wave system of Joule heat and monitoring method |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4108179B2 (en) | 2008-06-25 |
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