JPH11290867A - Vitamin c-containing ceramic and its production - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a neutralizing, decomposing and removing material continuing long-term effect with respect to chlorine, a harmful organochlorine compd. such as a chlorine compd., dioxins or the like, environmental hormone, a virus or the like. SOLUTION: Vitamine C, a vitamine C-containing plant and alkali metal or alkaline earth metal minerals, silicate minerals and other minerals are combined to obtain a neutralizing material comprising vitamine C-containing ceramics. This neutralizing material neutralizes and decomposes bromine, chlorine, a chlorine compd., other harmful organochlorine compd., environmental hormone or a virus almost instantaneously to keep its effect for a long period of time.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a technology relating to a method for producing a neutralizer for toxic organic chlorine-based compounds such as chlorine, chlorine-based compounds, and dioxins, which are ceramics containing vitamin C.

[0002]

2. Description of the Related Art Conventionally, there are many vitamin Cs, but there are no ceramics that occlude vitamin C.

[0003] In addition, the only substance that removes toxic organic chlorine-based compounds such as chlorine, chlorine-based compounds, and dioxin is an adsorbent such as activated carbon, and secondary pollution occurs when buried in soil after use. There was a danger to do.

[0004] Further, these adsorbents have a narrow target for adsorption,
At the same time, the effect did not last for a long time.

In addition, dioxins and toxic gases in water having different properties are mutually compatible and cannot neutralize and decompose these components.

Further, even if chlorine-based detergent flows into a river and is diluted, it cannot neutralize and decompose these substances without decreasing its toxicity.

At present, deterioration of the global environment has become a problem. In particular, dioxins generated in garbage incinerators adhere to vegetables and the like, and household detergents contaminate rivers and seas and accumulate in fish. These toxic substances accumulate in the human body that uses them as food, and these have been raised as problems such as environmental hormones. At present, neutralization, decomposition and removal of these toxic substances are essential.

[0008]

SUMMARY OF THE INVENTION In order to solve the above-mentioned conventional technical drawbacks, the present invention provides a ceramic containing vitamin C / vitamin C, which is obtained by compounding various kinds of mineral products and vitamin C / vitamin C. In, chlorine, chlorine compounds,
It is an object of the present invention to provide a neutralizing material that has a wide range of neutralizing decomposition removal effects of toxic organic chlorinated compounds such as dioxins, environmental hormones and the like, and has a long-lasting effect.

[0009]

SUMMARY OF THE INVENTION In order to solve the above-mentioned problems, the present invention provides a process for producing a vitamin C / vitamin C-containing plant or a synthetic vitamin C / vitamin C salt and various minerals and then processing them with glue. Thus, a vitamin C-containing ceramic neutralizing material that maintains the effect of vitamin C for a long period of time.

[0010]

BEST MODE FOR CARRYING OUT THE INVENTION According to the present invention, as described in the first aspect of the present invention, there is provided a neutralizing material made of alkali, alkaline earth mineral and silicate mineral which absorb vitamin Cs. In water, toxic organic chlorine-based compounds such as chlorine, chlorine-based compounds, and dioxins, and those compounds are brought into contact with ceramics containing the vitamin Cs in the air to neutralize, decompose and remove them. Since the vitamin C-containing ceramics are mainly composed of inorganic minerals, they do not cause any pollution even when buried in soil after use.

Feldspar, zeolite, zeolite, boron mineral, borax, boric acid, clay, kaolin, bentonite, acid clay, activated clay, apatite, sepiolite, diatomaceous earth, sulfate band, zinc white, calcium carbonate, calcium phosphate, barium sulfate, carbonate Strontium, magnesium, zirconium, lithium, lithium carbonate, soda, sodium carbonate, rare earth minerals, plants containing vitamin C, rose hips, tea, synthetic ascorbic acid,
Raw materials selected from a large number of raw materials such as synthetic sodium ascorbate, konjac, and sizing material can be combined to form the neutralizing material according to claim 1.

Further, since all of the raw materials according to the second aspect are inexpensive and easily available, the neutralizing material according to the first aspect can be provided at low cost.

[0013] As shown in the invention according to the third aspect, if the raw material selected from the group of the raw materials according to the second aspect is calcined, a ceramic containing vitamin C is obtained. All effects can be exerted as the neutralizing materials listed.

[0014] Vitamin C-containing foods or mineral products mixed with synthetic ascorbic acid / sodium ascorbate must be carefully selected because they greatly affect the vitamin C content of the final product.

Further, by processing so that a large amount of vitamin C remains after baking, the effect of vitamin C is maximized, and toxic substances such as chlorine, chlorine-based compounds, dioxin and the like adhered to vegetables and fish. Organic chlorine compounds and these gases can be neutralized, decomposed and removed.

As shown in the invention according to claim 4, a plant containing vitamin C selected from the group of raw materials according to claim 2 and ascorbic acid are mixed, kneaded, molded and mixed. The method of producing a neutralizing material according to claim 4, wherein a large amount of sodium ascorbate is contained in the ceramics through a firing step, whereby the effect of vitamin C can be maximized.

However, when used in water, such as for washing off chlorine-based compounds attached to a live fish tank or vegetables, etc., a large amount of vitamin C may be eluted. Can be maintained for a long time.

As shown in the invention according to claim 5, vitamin Cs and minerals selected from the group of raw materials according to claim 2 are mixed, pre-fired at a low temperature, and mixed with the raw material for main firing. Mixing, stirring, kneading with water, molding, drying and firing at a temperature higher than the preliminary firing to obtain a ceramic containing more vitamin Cs, the method for producing a neutralizing material according to claim 5, The effect can be exhibited.

By performing the preliminary firing, a ceramic containing a large amount of vitamin C can be produced even when firing at a higher temperature.

Further, when used in water for a long period of time, it is necessary to perform a coating process with a safe and harmless paste material after the main baking.

As shown in the invention according to claim 6, vitamin Cs selected from the group of raw materials according to claim 2 and other minerals are mixed, stirred, kneaded with water, molded and dried. After that, it is fired at a relatively low temperature, and as a ceramic containing a large amount of vitamin Cs, chlorine, chlorine-based compounds,
The method for producing a neutralizing material according to claim 6, wherein the gas of a toxic organic chlorine-based compound such as dioxin is neutralized and decomposed, whereby the effects of vitamin Cs can be maximized.

In the case of neutralizing and decomposing toxic organic chlorine-based gas such as chlorine-based compound gas and dioxin, temporary baking is not required, and the effect is maximized by low-temperature baking.

In the vitamin C-containing ceramics and the method for producing the same according to the present invention, low-temperature or low-temperature firing refers to 250 to 350 ° C., and medium-temperature or medium-temperature firing refers to 400 to 600 ° C.

[0024]

EXAMPLES Specific examples of the medium temperature firing of the present invention will be described below.

The composition ratio of the intermediate temperature calcined product is as follows by weight ratio. Note that impurities are included.

Vitamin C (rose hips) 10%, Vitamin C (tea) 5%, synthetic ascorbic acid 0.3%,
Apatite 3%, zeolite 3%, bentonite 10
%, Activated clay 3%, soda ash 5%, feldspar 40%, borax 1
0%, sodium ascorbate 0.2%, glue 10.5
%.

The material was selected from the group of raw materials according to claim 2 and manufactured according to the manufacturing method according to claim 5.

Hereinafter, specific examples of the low-temperature fired product of the present invention will be described.

The composition ratio of the low-temperature fired product is as follows by weight ratio. Note that impurities are included.

Vitamin C (rose hips) 10%, ascorbic acid 0.5%, apatite 9%, zeolite 5
%, Bentonite 10%, activated clay 5%, feldspar 45%,
Borax 15%, sodium ascorbate 0.5%.

The material was selected from the group of raw materials according to claim 2 and was produced according to the purpose according to claim 6.

When the material of the present invention was incorporated into a water purifier and passed through water containing chlorine and a chlorine-based detergent, these substances could be almost instantaneously neutralized and decomposed.

As a result of a similar test after use for half a year, it was found that chlorine and chlorine-based detergents were almost instantaneously neutralized and decomposed as in the first case, and that they could be used for a long time.

[0034]

As described above, the neutralizing material of the present invention can be used in a vitamin C-containing ceramic in which a vitamin C-containing plant and a vitamin C-containing plant are combined with an alkali, alkaline earth mineral, or silicate mineral. It is useful for neutralizing and removing toxic organic chlorine-based compounds such as chlorine, chlorine-based compounds and dioxins, or environmental hormones.It is also inexpensive and can be mass-produced. Can be buried in the soil. And it leads to the protection and preservation of the environment.

────────────────────────────────────────────────── ───

[Procedure amendment]

[Submission date] July 28, 1998

[Procedure amendment 1]

[Document name to be amended] Statement

[Correction target item name] Full text

[Correction method] Change

[Correction contents]

[Document Name] Statement

Patent application title: Vitamin C-containing ceramics and method for producing the same

[Claims]

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a technology relating to a method for producing a neutralizer for toxic organic chlorine-based compounds such as chlorine, chlorine-based compounds, and dioxins, which are ceramics containing vitamin C.

[0002]

2. Description of the Related Art Conventionally, there are many vitamin Cs, but there are no ceramics that occlude vitamin C.

[0003] In addition, the only substance that removes toxic organic chlorine-based compounds such as chlorine, chlorine-based compounds, and dioxin is an adsorbent such as activated carbon, and secondary pollution occurs when buried in soil after use. There was a danger to do.

[0004] Further, these adsorbents have a narrow target for adsorption,
At the same time, the effect did not last for a long time.

In addition, dioxins and toxic gases in water having different properties are mutually compatible and cannot neutralize and decompose these components.

Further, even if chlorine-based detergent flows into a river and is diluted, it cannot neutralize and decompose these substances without decreasing its toxicity.

At present, deterioration of the global environment has become a problem. In particular, dioxins generated in garbage incinerators adhere to vegetables and the like, and household detergents contaminate rivers and seas and accumulate in fish. These toxic substances accumulate in the human body that uses them as food, and these have been raised as problems such as environmental hormones. At present, neutralization, decomposition and removal of these toxic substances are essential.

[0008]

SUMMARY OF THE INVENTION In order to solve the above-mentioned conventional technical drawbacks, the present invention provides a ceramic containing vitamin C / vitamin C, which is obtained by compounding various kinds of mineral products and vitamin C / vitamin C. In, chlorine, chlorine compounds,
It is an object of the present invention to provide a neutralizing material that has a wide range of neutralizing decomposition removal effects of toxic organic chlorinated compounds such as dioxins, environmental hormones and the like, and has a long-lasting effect.

[0009]

SUMMARY OF THE INVENTION In order to solve the above-mentioned problems, the present invention provides a process for producing a vitamin C / vitamin C-containing plant or a synthetic vitamin C / vitamin C salt and various minerals and then processing them with glue. Thus, a vitamin C-containing ceramic neutralizing material that maintains the effect of vitamin C for a long period of time.

[0010]

BEST MODE FOR CARRYING OUT THE INVENTION According to the present invention, as described in the first aspect of the present invention, there is provided a neutralizing material made of alkali, alkaline earth mineral and silicate mineral which absorb vitamin Cs. In water, toxic organic chlorine-based compounds such as chlorine, chlorine-based compounds, and dioxins, and those compounds are brought into contact with ceramics containing the vitamin Cs in the air to neutralize, decompose and remove them. Since the pitamine C-containing ceramics are mainly composed of inorganic minerals, no pollution occurs even when buried in soil after use.

Feldspar, zeolite, zeolite, boron mineral, borax, boric acid, clay, kaolin, bentonite, acid clay, activated clay, apatite, sepiolite, diatomaceous earth, sulfate band, zinc white, calcium carbonate, calcium phosphate, barium sulfate, carbonate Strontium, magnesium, zirconium, lithium, lithium carbonate, soda, sodium carbonate, rare earth minerals, plants containing vitamin C, rose hips, tea, synthetic ascorbic acid,
Raw materials selected from a large number of raw materials such as synthetic sodium ascorbate, konjac, and sizing material can be combined to form the neutralizing material according to claim 1.

Further, since all of the raw materials according to the second aspect are inexpensive and easily available, the neutralizing material according to the first aspect can be provided at low cost.

[0013] As shown in the invention according to the third aspect, if the raw material selected from the group of the raw materials according to the second aspect is calcined, a ceramic containing vitamin C is obtained. All effects can be exerted as the neutralizing materials listed.

[0014] Vitamin C-containing foods or mineral products mixed with synthetic ascorbic acid / sodium ascorbate must be carefully selected because they greatly affect the vitamin C content of the final product.

Further, by processing so that a large amount of vitamin C remains after baking, the effect of vitamin C is maximized, and chlorine, chlorine-based compounds, dioxin, etc. adhering to vegetables and fishes. Toxic organic chlorine compounds and these gases can be neutralized, decomposed and removed.

[0016] As shown in the invention according to claim 4, vitamin C alone or a plant containing vitamin C selected from the group of raw materials according to claim 2 and ascorbic acid and alkali and alkali Through the steps of mixing, kneading, molding and baking earth minerals and various mineral products, by converting vitamin C, which is unstable at high temperatures, to a substance that exists stably even at high temperatures, such as sodium ascorbate and calcium ascorbate The method of producing a neutralizing material according to claim 4, wherein the vitamin C compound is contained in the ceramics in a large amount, thereby maximizing the effect of vitamin C.

However, when used in water, such as for washing off chlorine-based compounds attached to a live fish tank or vegetables, etc., a large amount of vitamin C may be eluted. Can be maintained for a long time.

As shown in the invention according to claim 5, vitamin Cs and minerals selected from the group of raw materials according to claim 2 are mixed, pre-fired at a low temperature, and mixed with the raw material for main firing. Mixing, stirring, kneading with water, molding, drying and firing at a temperature higher than the preliminary firing to obtain a ceramic containing more vitamin Cs, the method for producing a neutralizing material according to claim 5, The effect can be exhibited.

By performing the preliminary firing, a ceramic containing a large amount of vitamin C can be produced even when firing at a higher temperature.

Further, when used in water for a long period of time, it is necessary to perform a coating process with a safe and harmless paste material after the main baking.

As shown in the invention according to claim 6, vitamin Cs selected from the group of raw materials according to claim 2 and other minerals are mixed, stirred, kneaded with water, molded and dried. After that, it is fired at a relatively low temperature, and as a ceramic containing a large amount of vitamin Cs, chlorine, chlorine-based compounds,
The method for producing a neutralizing material according to claim 6, wherein the gas of a toxic organic chlorine-based compound such as dioxin is neutralized and decomposed, whereby the effects of vitamin Cs can be maximized.

In the case of neutralizing and decomposing toxic organic chlorine-based gas such as chlorine-based compound gas and dioxin, temporary baking is not required, and the effect is maximized by low-temperature baking.

In the vitamin C-containing ceramics and the method for producing the same according to the present invention, low-temperature or low-temperature firing refers to 250 to 350 ° C., and medium-temperature or medium-temperature firing refers to 400 to 600 ° C.

[0024]

EXAMPLES Specific examples of the medium temperature firing of the present invention will be described below.

The composition ratio of the intermediate temperature calcined product is as follows by weight ratio. Note that impurities are included.

Vitamin C (rose hips) 10%, Vitamin C (tea) 5%, synthetic ascorbic acid 0.3%,
Apatite 3%, zeolite 3%, bentonite 10
%, Activated clay 3%, soda ash 5%, feldspar 40%, borax 1
0%, sodium ascorbate 0.2%, glue 10.5
%.

The material was selected from the group of raw materials according to claim 2 and manufactured according to the manufacturing method according to claim 5.

Hereinafter, specific examples of the low-temperature fired product of the present invention will be described.

The composition ratio of the low-temperature fired product is as follows by weight ratio. Note that impurities are included.

Vitamin C (rose hips) 10%, ascorbic acid 0.5%, apatite 9%, zeolite 5
%, Bentonite 10%, activated clay 5%, feldspar 45%,
Borax 15%, sodium ascorbate 0.5%.

The material was selected from the group of raw materials according to claim 2 and was produced according to the purpose according to claim 6.

When the material of the present invention was incorporated into a water purifier and passed through water containing chlorine and a chlorine-based detergent, these substances could be almost instantaneously neutralized and decomposed.

As a result of a similar test after use for half a year, it was found that chlorine and chlorine-based detergents were almost instantaneously neutralized and decomposed as in the first case, and that they could be used for a long time.

[0034]

As described above, the neutralizing material of the present invention can be used in a vitamin C-containing ceramic in which a vitamin C-containing plant and a vitamin C-containing plant are combined with an alkali, alkaline earth mineral, or silicate mineral. Odor, chlorine,
It is useful for neutralization and removal of toxic organic chlorine compounds such as chlorine compounds and dioxins, environmental hormones, viruses, etc., and can be mass-produced at a low cost. it can. And it leads to the protection and preservation of the environment.

Claims (6)

[Claims] 1. Vitamin Cs and vitamin C-containing plants,
A neutralizing material that combines the powder and solid materials of alkali and alkaline earth minerals, silicate minerals, and other minerals and takes advantage of the characteristics of vitamin C-containing ceramics. 2. Feldspar, zeolite and zeolites, boron minerals, borax, boric acid, clay, kaolin, bentonite, acid clay, activated clay, apatite, sepiolite,
Plants containing diatomaceous earth, sulfate bands, zinc white, calcium carbonate, calcium phosphate, barium sulfate, strontium carbonate, magnesium, zirconium, lithium, lithium carbonate, soda, sodium carbonate, rare earth minerals, vitamin C (rose hips, tea) 2. The neutralizing material according to claim 1, wherein a raw material selected from the group consisting of a large number of raw materials consisting of synthetic ascorbic acid, synthetic sodium ascorbate, konjac and a paste material is used. 3. A raw material selected from the group of raw materials according to claim 2, which is a powder or solid ceramic containing vitamin C by baking at a medium temperature, wherein the effect of vitamin C is maximized and chlorine, The neutralizing material according to claim 1, wherein toxic organic chlorine compounds such as chlorine compounds and dioxins are neutralized and decomposed. 4. A calcined plant containing vitamin C and various minerals selected from the group of raw materials according to claim 2 and ascorbic acid / sodium ascorbate. The method for producing a neutralizing material according to claim 3, which can be used in water in which vitamin C is appropriately eluted for the purpose. 5. A mixture of vitamin Cs selected from the group of raw materials according to claim 2 and a vitamin C-occluding mineral, and preliminarily calcined at a low temperature, followed by mixing with raw materials for main calcining, stirring, and water. 4. The method for producing a neutralizing material according to claim 3, wherein vitamin Cs produced through the steps of kneading, molding, drying and medium-temperature baking are occluded. 6. A process comprising mixing, stirring, mixing with water, kneading with water, molding, drying, and low-temperature calcination of a plant containing vitamin C selected from the group of raw materials according to claim 2. 4. The method for producing a neutralizing material according to claim 3, wherein the characteristics of vitamin Cs are maximized to neutralize and decompose toxic organic chlorine-based compounds such as chlorine, chlorine-based compounds, and dioxins.