JPH11280767A - Rolling bearing - Google Patents

Rolling bearing

Info

Publication number
JPH11280767A
JPH11280767A JP8669198A JP8669198A JPH11280767A JP H11280767 A JPH11280767 A JP H11280767A JP 8669198 A JP8669198 A JP 8669198A JP 8669198 A JP8669198 A JP 8669198A JP H11280767 A JPH11280767 A JP H11280767A
Authority
JP
Japan
Prior art keywords
zirconia
rolling
alumina
added
zro
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP8669198A
Other languages
Japanese (ja)
Inventor
Toshiaki Kaneko
敏昭 兼子
Hirokazu Nakajima
碩一 中島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NTN Corp
Original Assignee
NTN Corp
NTN Toyo Bearing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NTN Corp, NTN Toyo Bearing Co Ltd filed Critical NTN Corp
Priority to JP8669198A priority Critical patent/JPH11280767A/en
Publication of JPH11280767A publication Critical patent/JPH11280767A/en
Withdrawn legal-status Critical Current

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  • Rolling Contact Bearings (AREA)

Abstract

PROBLEM TO BE SOLVED: To secure the excellent rolling service life, and maintain density small by forming at least either of a bearing ring and a rolling body out of ceramics having the composition by adding zirconia by a specific quantity to alumina. SOLUTION: When zirconia is added to alumina as ceramics used for either of a bearing ring and a rolling body, a grain boundary of alumina is strengthened, strength is increased, and the rolling service life is also lengthened. It is necessary to add zirconia by at least 5 wt.% or more therefor. However, since the rolling service life is shortened when an adding quantity of zirconia too much, it is necessary to set a zirconia adding quantity not more than 50 wt.%. When the adding quantity of zirconia is not more than 50 wt.%, density of zirconia-added alumina can be maintained small as illustrated to thereby restrain an increase in a rolling body load by centrifugal force generated when the rolling body rotates at a high speed.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、転がり軸受に関
し、より具体的には、軌道輪と転動体との少なくともい
ずれかがセラミックスからなる転がり軸受に関するもの
である。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a rolling bearing, and more particularly to a rolling bearing in which at least one of a race and a rolling element is made of ceramics.

【0002】[0002]

【従来の技術】セラミックス製の転がり軸受は、セラミ
ックスの耐食性を活かした水中や腐食雰囲気、耐熱性を
活かした高温下、非磁性の特徴を活かした強磁界中、セ
ラミックスが鉄より低密度であることを活かした工作機
械・HDDなどの分野において使用されている。またこ
のセラミックス製の転がり軸受は、鋼製の転がり軸受と
比較して耐食性・高剛性・高速性・絶縁性、非磁性など
に優れた特徴を持っており、これらの特徴を活かした用
途への展開が期待される。この転がり軸受に使用される
セラミックスとしては、窒化珪素、ジルコニア、アルミ
ナ、炭化珪素が挙げられる。
2. Description of the Related Art Ceramic rolling bearings have a lower density than iron in water and corrosive atmospheres utilizing the corrosion resistance of ceramics, at high temperatures utilizing heat resistance, and in strong magnetic fields utilizing non-magnetic characteristics. It is used in fields such as machine tools and HDDs that take advantage of this fact. In addition, these ceramic rolling bearings have excellent characteristics such as corrosion resistance, high rigidity, high speed, insulation, and non-magnetism compared to steel rolling bearings. Expansion is expected. Ceramics used for this rolling bearing include silicon nitride, zirconia, alumina, and silicon carbide.

【0003】[0003]

【発明が解決しようとする課題】上記の転がり軸受に使
用されるセラミックスの中で、窒化珪素は転動寿命が最
も長寿命を示し、転がり軸受の素材として最も適してい
るために一般的に使用される。しかし、コストが高いこ
とが窒化珪素の用途の拡大を阻んでいる。また、ジルコ
ニアは密度が6g/ccと大きいため、その使用は限ら
れる。これは、密度が大きくなると転動体が高速で回転
しているときに発生する遠心力による転動体荷重が増加
してしまうからである。
Among the ceramics used in the above-mentioned rolling bearings, silicon nitride is generally used because it has the longest rolling life and is most suitable as a material for rolling bearings. Is done. However, the high cost is preventing the use of silicon nitride from expanding. Zirconia has a large density of 6 g / cc, so its use is limited. This is because, as the density increases, the rolling element load due to centrifugal force generated when the rolling element rotates at high speed increases.

【0004】これに対して、アルミナは価格的には最も
低価格であり、かつ密度もそれほど大きくない。しか
し、アルミナは、強度が低く寿命も短い、破壊靱性値が
低く加工後の表面粗さが良くないなどの理由から軸受と
して使用するには難しいという問題があった。
On the other hand, alumina is the cheapest in terms of price and its density is not so high. However, alumina has a problem that it is difficult to use as a bearing because it has low strength, short life, low fracture toughness and poor surface roughness after processing.

【0005】本発明の目的は、転動寿命に優れ、密度が
小さく、かつ安価なセラミックス製の転がり軸受を提供
することである。
An object of the present invention is to provide an inexpensive ceramic rolling bearing having excellent rolling life, low density and low cost.

【0006】[0006]

【課題を解決するための手段】本願発明者らは鋭意検討
した結果、アルミナにジルコニアを所定量添加すること
で、強度が高く、密度が小さく、かつ安価で長寿命なセ
ラミックス製の転がり軸受が得られることを見出した。
Means for Solving the Problems As a result of intensive studies, the present inventors have found that by adding a predetermined amount of zirconia to alumina, a ceramic rolling bearing having high strength, low density, low cost and long life can be obtained. It was found that it could be obtained.

【0007】それゆえ本発明の転がり軸受は、軌道輪と
転動体とを有する転がり軸受において、軌道輪と転動体
との少なくともいずれかがアルミナにジルコニアを5w
t%以上50wt%以下添加した組成のセラミックスか
らなっている。
Therefore, a rolling bearing according to the present invention is characterized in that in a rolling bearing having a race and a rolling element, at least one of the race and the rolling element is made of alumina and 5 watts of zirconia.
It is made of ceramics with a composition of at least t% and not more than 50 wt%.

【0008】アルミナにジルコニアを添加すると、アル
ミナの粒界が強化されてアルミナの強度が上昇して転動
寿命も長くなる。アルミナの強度を上げるためには、ジ
ルコニアを少なくとも5wt%以上添加することが必要
である。しかし、ジルコニアの添加量が多すぎると、か
えって転動寿命が短くなってしまう。このため、ジルコ
ニアの添加量は50wt%以下であることが必要であ
る。
When zirconia is added to alumina, the grain boundaries of alumina are strengthened, the strength of alumina is increased, and the rolling life is extended. In order to increase the strength of alumina, it is necessary to add at least 5 wt% of zirconia. However, if the added amount of zirconia is too large, the rolling life is rather shortened. For this reason, the amount of zirconia added needs to be 50 wt% or less.

【0009】また、ジルコニアの添加量が50wt%以
下であれば、ジルコニアを添加したアルミナの密度も5
g/cc以下と小さく維持することができる。このた
め、転動体が高速で回転しているときに発生する遠心力
による転動体荷重の増加を抑制することができる。特に
アンギュラ玉軸受のように接触角を持っている軸受では
ジャイロ滑りが生ずるが、このような低密度の材料を転
動体に使用すればジャイロ滑りも小さく抑えることがで
きる。
If the amount of zirconia added is 50 wt% or less, the density of alumina to which zirconia is added is also 5%.
g / cc or less. Therefore, it is possible to suppress an increase in the rolling element load due to the centrifugal force generated when the rolling element is rotating at a high speed. In particular, a gyro-slip occurs in a bearing having a contact angle such as an angular ball bearing. If such a low-density material is used for the rolling element, the gyro-slip can be suppressed to a small value.

【0010】このようにジルコニアを5wt%以上50
wt%以下とすることで転動寿命を長くすることができ
とともに、密度も小さく維持することができ、かつ低価
格のアルミナをベースとしているため安価に製造するこ
とができる。
As described above, zirconia is contained in an amount of 5 wt% or more and
By setting the content to not more than wt%, the rolling life can be extended, the density can be kept small, and it can be manufactured at low cost because it is based on low-cost alumina.

【0011】また、アルミナのみでは破壊靱性値も低く
研磨仕上げをすると破砕しながらの加工となるために仕
上げ面の表面粗さはよくない。しかし、破壊靱性が大き
いジルコニアを添加することによって延性的研削で加工
されるために加工面の粗さは改善されて加工性もよくな
る。
[0011] In addition, when only alumina is used, the fracture toughness value is low, and when polishing is performed, the processing is performed while crushing, so the surface roughness of the finished surface is not good. However, by adding zirconia having high fracture toughness, the surface is processed by ductile grinding, so that the roughness of the processed surface is improved and the workability is improved.

【0012】[0012]

【実施例】以下、本発明の実施例について説明する。Embodiments of the present invention will be described below.

【0013】(1) 焼結体の製造方法とその特性 Al2 3 (アルミナ)原料粉にZrO2 (ジルコニ
ア)粉末を重量比で15%、50%、80%添加したも
のを、均一に混合した後、成形し焼結を行なった。焼結
は大気中で焼結温度1600〜1700℃として行なっ
た。得られた焼結体はサイズ3/8″のボールであり、
ボール表面をサブミクロンの粒度のダイヤモンド砥粒で
仕上げた。
(1) Method for producing a sintered body and its characteristics A mixture of Al 2 O 3 (alumina) raw material powder and ZrO 2 (zirconia) powder added at a weight ratio of 15%, 50% and 80% is uniformly prepared. After mixing, molding and sintering were performed. Sintering was performed in the atmosphere at a sintering temperature of 1600 to 1700 ° C. The resulting sintered body is a ball of size 3/8 ",
The ball surface was finished with submicron diamond abrasive grains.

【0014】比較のために、ZrO2 粉末を添加しない
Al2 3 100%のボールおよびZrO2 100%の
ボールも同様な製造方法で作製した。
For comparison, 100% Al 2 O 3 balls and 100% ZrO 2 balls without the addition of ZrO 2 powder were produced in the same manner.

【0015】Al2 3 にZrO2 を15wt%、50
wt%、80wt%添加したときの、セラミックスの特
性(密度、破壊靱性、硬さ、熱伝導率)を表1に示す。
比較のために、Al2 3 100%とZrO2 100%
との特性も併せて表1に示す。
15 wt% of ZrO 2 in Al 2 O 3 , 50
Table 1 shows the properties (density, fracture toughness, hardness, and thermal conductivity) of the ceramic when wt% and 80 wt% were added.
For comparison, 100% of Al 2 O 3 and 100% of ZrO 2
Table 1 also shows the characteristics.

【0016】[0016]

【表1】 [Table 1]

【0017】表1の結果より、ZrO2 の添加量が増す
に従って、密度や破壊靱性値が大きくなることがわかっ
た。これは、ZrO2 がAl2 3 と比較して密度や破
壊靱性値が大きいことに起因していると考えられる。
From the results shown in Table 1, it was found that the density and the fracture toughness increased as the amount of ZrO 2 added increased. This is considered to be because ZrO 2 has a higher density and a higher fracture toughness value than Al 2 O 3 .

【0018】またZrO2 の添加量を変化させた場合の
ZrO2 を添加したAl2 3 の密度は図1のように変
化した。
When the amount of ZrO 2 added was changed, the density of Al 2 O 3 added with ZrO 2 changed as shown in FIG.

【0019】また、硬さや熱伝導率は、ZrO2 の添加
量が増すと小さくなった。硬さは高い方が転動寿命を長
くするには有利であるが、いずれの硬さも軸受鋼の硬さ
HV800と比べて十分高いため特に問題はない。熱伝
導率についてはAl2 3 の熱伝導率は大きいがZrO
2 の熱伝導率は小さい。軸受は使用中に発熱するが、軸
受内部の温度が不均一にならずに冷却性を上げるには熱
伝導率は大きい方が良いため、ZrO2 の添加量はあま
り多くない方が良い。
Further, the hardness and the thermal conductivity decreased as the amount of ZrO 2 added increased. A higher hardness is advantageous for increasing the rolling life, but any hardness is sufficiently higher than the hardness HV800 of the bearing steel, so that there is no particular problem. Regarding the thermal conductivity, the thermal conductivity of Al 2 O 3 is large, but ZrO
2 has low thermal conductivity. Although the bearing generates heat during use, the higher the thermal conductivity is, the better the cooling performance is without increasing the temperature inside the bearing. Therefore, the addition amount of ZrO 2 should not be too large.

【0020】(2) ボール圧砕強度と寿命試験 次に上記のように製造したAl2 3 100%のボール
と、Al2 3 にZrO2 を15wt%、50wt%、
80wt%添加した各ボールとの表面粗さを測定すると
ともに圧砕強度試験および転がり寿命試験を行なった。
なお、Al2 3 にZrO2 を50wt%、80wt%
添加したボールについては表面粗さの測定と転がり寿命
試験のみを行なった。
(2) Ball crushing strength and life test Next, the Al manufactured as described above was used.TwoOThree100% ball
And AlTwoOThreeTo ZrOTwo15 wt%, 50 wt%,
When the surface roughness of each ball to which 80wt% is added is measured,
In both cases, a crushing strength test and a rolling life test were performed.
In addition, AlTwoO ThreeTo ZrOTwo50 wt%, 80 wt%
Measurement of surface roughness and rolling life of the added ball
Only tests were performed.

【0021】圧砕強度試験は、図2に示すように2個の
ボール1、1を積み重ねて、ボール1が破損するまで荷
重を増やしながら負荷し、ボール1が破損したときの荷
重を求めることで行なった。
The crushing strength test is carried out by stacking two balls 1 and 1 as shown in FIG. 2 and applying a load while increasing the load until the ball 1 breaks, and obtaining the load when the ball 1 breaks. Done.

【0022】転がり寿命試験は、図3に示すようにプー
リ18からカップリング17を介してシャフト15に駆
動力を伝達させ、シャフト15を支持するサポート軸受
(型番6312)14と試験軸受4とに負荷用ばね16
を介して一定の荷重をかけながらボール1が破損するま
で行なった。なお、サポート軸受14と試験軸受4と
は、各々ボール11、1と、内輪12、2と、外輪1
3、3とからなっている。この転がり寿命試験の条件を
表2に示す。
In the rolling life test, as shown in FIG. 3, a driving force is transmitted from a pulley 18 to a shaft 15 via a coupling 17 to provide a support bearing (model number 6312) 14 for supporting the shaft 15 and the test bearing 4. Load spring 16
The test was performed until the ball 1 was broken while applying a constant load through the ball. The support bearing 14 and the test bearing 4 are respectively composed of balls 11, 1; inner rings 12, 2;
It consists of three and three. Table 2 shows the conditions of the rolling life test.

【0023】また上記の表面粗さ、圧砕値および転がり
寿命の測定の結果を表3に示す。
Table 3 shows the results of the measurements of the surface roughness, crushing value and rolling life.

【0024】[0024]

【表2】 [Table 2]

【0025】[0025]

【表3】 [Table 3]

【0026】表3の結果より、Al2 3 100%のボ
ール1の場合は、ごく短時間でボール1の表面に表層剥
離を生じて、運転を停止した。これに対して、ZrO2
の添加量を15wt%、50wt%と増加させていった
場合には、Al2 3 100%のボール1の場合よりも
寿命が長くなる傾向が見られ、ボール1の破損形態は通
常の軸受と同様の剥離であることがわかった。しかし、
ZrO2 の添加量を80wt%まで増加させるとかえっ
て寿命が短くなる傾向が見られた。このことより、Zr
2 の添加量は50wt%以下にする必要があることが
わかった。
According to the results shown in Table 3, in the case of the ball 1 of 100% Al 2 O 3 , the surface was separated from the surface of the ball 1 in a very short time, and the operation was stopped. On the other hand, ZrO 2
In the case where the addition amount of Al is increased to 15 wt% and 50 wt%, the life tends to be longer than in the case of the ball 1 of 100% Al 2 O 3 , and the broken form of the ball 1 is a normal bearing. It turned out that it was the same peeling as. But,
When the amount of ZrO 2 added was increased to 80 wt%, the life tended to be shortened. From this, Zr
It has been found that the added amount of O 2 needs to be 50 wt% or less.

【0027】また、Al2 3 へのZrO2 の添加量を
50wt%以下にすれば、図1の結果より、ZrO2
添加したAl2 3 の密度を5g/cc以下と低くでき
ることもわかる。
If the amount of ZrO 2 added to Al 2 O 3 is set to 50 wt% or less, the density of Al 2 O 3 to which ZrO 2 is added can be reduced to 5 g / cc or less from the results shown in FIG. Recognize.

【0028】またAl2 3 100%のボール1では、
Al2 3 の破壊靱性値が小さく加工面を破砕しながら
の加工のために表面粗さはRa0.082μmと大きか
った。しかし、破壊靱性が大きいZrO2 を15wt
%、50wt%と増加させていった場合には、加工面が
滑らかとなる傾向が見られ、かつ50wt%以上では加
工面が滑らかになる効果が飽和していることがわかっ
た。
In the case of a ball 1 made of 100% Al 2 O 3 ,
The fracture toughness value of Al 2 O 3 was small, and the surface roughness was as large as Ra 0.082 μm for processing while crushing the processed surface. However, 15wt the fracture toughness is greater ZrO 2
% And 50 wt%, the processed surface tended to be smooth, and it was found that the effect of smoothing the processed surface was saturated at 50 wt% or more.

【0029】また、圧砕値は、ZrO2 を15wt%添
加することによって強度17.02kNとなり、Al2
3 100%の強度8.67kNと比べて大幅に増加す
ることがわかった。
Further, crushing value becomes intensity 17.02kN by adding ZrO 2 15wt%, Al 2
O 3 as compared to 100% of the intensity 8.67kN was found to increase significantly.

【0030】なお、上記の実施例では、軸受のボール
に、ZrO2 を添加したAl2 3 を用いた場合につい
て説明したが、内輪もしくは外輪がこのようなセラミッ
クスよりなっていてもよい。
In the above embodiment, the case where Al 2 O 3 added with ZrO 2 is used for the ball of the bearing has been described, but the inner ring or the outer ring may be made of such ceramics.

【0031】また、上記の実施例では、転動体としてボ
ールを用いた場合について説明したが、これに限定され
るものではなく、広く転がり軸受一般に本発明は適用す
ることができる。
In the above embodiment, the case where a ball is used as a rolling element has been described. However, the present invention is not limited to this, and the present invention can be widely applied to rolling bearings in general.

【0032】今回開示された実施例はすべての点で例示
であって制限的なものではないと考えられるべきであ
る。本発明の範囲は上記した説明ではなくて特許請求の
範囲によって示され、特許請求の範囲と均等の意味およ
び範囲内でのすべての変更が含まれることが意図され
る。
The embodiment disclosed this time is to be considered in all respects as illustrative and not restrictive. The scope of the present invention is defined by the terms of the claims, rather than the description above, and is intended to include any modifications within the scope and meaning equivalent to the terms of the claims.

【0033】[0033]

【発明の効果】以上説明したように、本発明の転がり軸
受では、軌道輪と転動体との少なくともいずれかが、ア
ルミナにジルコニアを5wt%以上50wt%以下添加
した組成のセラミックスからなっているため、転動寿命
に優れ、密度が小さく、かつ安価なセラミックス製の転
がり軸受を得ることができる。
As described above, in the rolling bearing of the present invention, at least one of the race and the rolling element is made of a ceramic having a composition in which zirconia is added to alumina in an amount of 5 wt% to 50 wt%. An inexpensive ceramic rolling bearing having excellent rolling life, low density and low cost can be obtained.

【図面の簡単な説明】[Brief description of the drawings]

【図1】ZrO2 の添加量を変えた場合のZrO2 が添
加されたAl2 3 の密度の変化を示すグラフである。
1 is a graph showing changes in Al 2 O 3 of density ZrO 2 is added when changing the addition amount of ZrO 2.

【図2】ボールの圧砕強度の測定の様子を示す図であ
る。
FIG. 2 is a diagram showing how a crushing strength of a ball is measured.

【図3】転がり寿命試験測定器の構成を示す図である。FIG. 3 is a diagram showing a configuration of a rolling life test measuring instrument.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 軌道輪と転動体とを有する転がり軸受に
おいて、 前記軌道輪と前記転動体との少なくともいずれかは、ア
ルミナにジルコニアを5wt%以上50wt%以下添加
した組成のセラミックスからなる、転がり軸受。
1. A rolling bearing having a bearing ring and a rolling element, wherein at least one of the bearing ring and the rolling element is made of a ceramic having a composition in which zirconia is added to alumina in an amount of 5 wt% to 50 wt%. bearing.
JP8669198A 1998-03-31 1998-03-31 Rolling bearing Withdrawn JPH11280767A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8669198A JPH11280767A (en) 1998-03-31 1998-03-31 Rolling bearing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8669198A JPH11280767A (en) 1998-03-31 1998-03-31 Rolling bearing

Publications (1)

Publication Number Publication Date
JPH11280767A true JPH11280767A (en) 1999-10-15

Family

ID=13894002

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8669198A Withdrawn JPH11280767A (en) 1998-03-31 1998-03-31 Rolling bearing

Country Status (1)

Country Link
JP (1) JPH11280767A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110985531A (en) * 2019-11-20 2020-04-10 中国科学院上海硅酸盐研究所 Corrosion-resistant and wear-resistant ceramic bearing and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110985531A (en) * 2019-11-20 2020-04-10 中国科学院上海硅酸盐研究所 Corrosion-resistant and wear-resistant ceramic bearing and preparation method thereof
CN110985531B (en) * 2019-11-20 2021-05-25 中国科学院上海硅酸盐研究所 Corrosion-resistant and wear-resistant ceramic bearing and preparation method thereof

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