JPH11263606A - Sulfuric acid producing equipment - Google Patents
Sulfuric acid producing equipmentInfo
- Publication number
- JPH11263606A JPH11263606A JP6322698A JP6322698A JPH11263606A JP H11263606 A JPH11263606 A JP H11263606A JP 6322698 A JP6322698 A JP 6322698A JP 6322698 A JP6322698 A JP 6322698A JP H11263606 A JPH11263606 A JP H11263606A
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- JP
- Japan
- Prior art keywords
- gas
- sulfuric acid
- combustion furnace
- combustion
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、硫酸製造設備に関
するものである。[0001] The present invention relates to a sulfuric acid production facility.
【０００２】[0002]
【従来の技術】図３は従来の硫酸製造設備の一例を表わ
すものであって、硫黄溶解槽１に貯留された溶融硫黄２
（単体硫黄）を燃焼炉３でブロワ４からの燃焼用空気５
と混合して燃焼させることによりＳＯ2ガス６を生成
し、該ＳＯ2ガス６を排熱ボイラ７を通して排熱を回収
した後、コンバータ８において白金等の触媒の作用によ
り前記ＳＯ2ガス６を酸化してＳＯ3ガス９に転化せし
め、その際に生ずる反応熱を熱交換器１０Ａで回収する
と共に、コンバータ８の出側にクーラとして配置した熱
交換器１０Ｂにより更に熱回収して温度を調節し、その
温度調整されたＳＯ3ガス９を吸収塔１１において希硫
酸１２に吸収させて濃硫酸１３を生成するようになって
おり、ここで生成された濃硫酸１３の一部を希釈水１４
を加えて希釈することにより希硫酸１２として前記吸収
塔１１にて循環使用させるようにしてある。2. Description of the Related Art FIG. 3 shows an example of a conventional sulfuric acid production facility, in which molten sulfur 2 stored in a sulfur dissolving tank 1 is removed.
(Combustion air) from the blower 4 in the combustion furnace 3
Generate SO 2 gas 6 by mixing to be burned and, after the SO 2 gas 6 to recover the exhaust heat through waste heat boiler 7, the SO 2 gas 6 by the action of a catalyst such as platinum in the converter 8 It is oxidized and converted into SO 3 gas 9, and the reaction heat generated at that time is recovered by a heat exchanger 10 A, and the heat is further recovered by a heat exchanger 10 B arranged as a cooler on the outlet side of the converter 8 to adjust the temperature. Then, the SO 3 gas 9 whose temperature has been adjusted is absorbed in diluted sulfuric acid 12 in an absorption tower 11 to generate concentrated sulfuric acid 13, and a part of the concentrated sulfuric acid 13 generated here is diluted with dilution water 14.
The diluted sulfuric acid is added to dilute sulfuric acid 12 so as to be circulated and used in the absorption tower 11.
【０００３】また、排熱ボイラ７及び熱交換器１０Ａ，
１０Ｂでは、回収した熱により給水１５をスチーム１６
として排出するようになっており、このスチーム１６を
設備内で有効に利用、例えば圧力の高いスチーム１６に
ついてはスチームタービン発電機に導いて発電に利用し
得るようにしてある。[0003] Further, a waste heat boiler 7 and a heat exchanger 10A,
In 10B, the supplied water 15 is converted into steam 16 by the recovered heat.
The steam 16 is effectively used in the facility. For example, the steam 16 having a high pressure is guided to a steam turbine generator to be used for power generation.
【０００４】更に、吸収塔１１からの排出ガス１８は、
図示しないガス処理設備で処理された後に大気放出され
るようになっている。Further, the exhaust gas 18 from the absorption tower 11 is
After being processed by a gas processing facility (not shown), it is released to the atmosphere.
【０００５】尚、前記燃焼炉３での反応は、The reaction in the combustion furnace 3 is as follows:
【数１】Ｓ＋Ｏ2→ＳＯ2 であり、コンバータ８での反応は、S + O 2 → SO 2 , and the reaction in the converter 8 is
【数２】２ＳＯ2＋Ｏ2→２ＳＯ3 であり、吸収塔１１での反応は、2SO 2 + O 2 → 2SO 3 , and the reaction in the absorption tower 11 is as follows:
【数３】ＳＯ3＋Ｈ2Ｏ→Ｈ2ＳＯ4 である。## EQU3 ## SO 3 + H 2 O → H 2 SO 4
【０００６】[0006]
【発明が解決しようとする課題】しかしながら、上記従
来の硫酸製造設備においては、排熱ボイラ７や熱交換器
１０Ａ，１０ＢによりＳＯ2ガス６やＳＯ3ガス９の排熱
及び反応熱を回収するようにしているが、燃焼炉３から
送出される熱回収前のＳＯ2ガス６が潜在的に有してい
る運動エネルギーや熱エネルギーについては効率的に回
収していないのが実情である。However, in the above-mentioned conventional sulfuric acid production facility, the exhaust heat and reaction heat of the SO 2 gas 6 and SO 3 gas 9 are recovered by the exhaust heat boiler 7 and the heat exchangers 10A and 10B. However, in reality, the kinetic energy and the heat energy potentially contained in the SO 2 gas 6 before the heat recovery sent from the combustion furnace 3 are not efficiently recovered.
【０００７】即ち、燃焼炉３に対し燃焼に必要な支燃性
ガスとして送給される燃焼用空気５は、単に硫酸製造の
プロセスガスとしてＳＯ2ガスを生成する上では格別昇
圧の必要がないものであり、ブロワ４により大気圧を若
干上回る程度の送給圧で燃焼炉３に導かれているにすぎ
ず、このような低圧の燃焼用空気５による溶融硫黄２の
燃焼では、例えばガスタービン発電機などを支障なく駆
動するのに十分なほど圧力の高いＳＯ2ガス６を生成す
ることができない為、燃焼炉３からのＳＯ2ガス６の運
動エネルギーや熱エネルギーを具体的に回収する術がな
く、このような運動エネルギーや熱エネルギーを回収し
得るようにするという設計思想自体が全く欠落してい
た。That is, the combustion air 5 supplied to the combustion furnace 3 as a supporting gas required for combustion does not need to be specially pressurized simply to generate SO 2 gas as a process gas for sulfuric acid production. In the combustion of the molten sulfur 2 by the combustion air 5 having a low pressure, the blower 4 merely guides the supply pressure to the combustion furnace 3 at a feed pressure slightly higher than the atmospheric pressure. Since it is not possible to generate SO 2 gas 6 having a pressure high enough to drive a generator or the like without hindrance, a technique for specifically recovering kinetic energy and heat energy of SO 2 gas 6 from combustion furnace 3 is not described. However, the design concept of recovering such kinetic energy and thermal energy was completely lacking.
【０００８】本発明は上述の実情に鑑みてなしたもの
で、燃焼炉からのＳＯ2ガスの運動エネルギーや熱エネ
ルギーを効率的に回収し得る硫酸製造設備を提供するこ
とを目的としている。The present invention has been made in view of the above circumstances, and has as its object to provide a sulfuric acid production facility capable of efficiently recovering kinetic energy and thermal energy of SO 2 gas from a combustion furnace.
【０００９】[0009]
【課題を解決するための手段】本発明は、単体硫黄を燃
焼炉で燃焼してＳＯ2ガスを生成し、該ＳＯ2ガスを酸化
してＳＯ3ガスに転化し、該ＳＯ3ガスを希硫酸に吸収さ
せて濃硫酸を生成する硫酸製造設備において、燃焼炉に
対し燃焼に必要な支燃性ガスを昇圧して導く昇圧送給手
段を接続し、燃焼炉からのＳＯ2ガスを動力源として駆
動するガスタービン発電機を設けたことを特徴とするも
のである。Means for Solving the Problems The present invention generates the SO 2 gas by burning the elemental sulfur in the combustion furnace, and converted to SO 3 gas to oxidize the SO 2 gas, a rare the SO 3 gas In a sulfuric acid production facility that generates concentrated sulfuric acid by absorbing it with sulfuric acid, the combustion furnace is connected to a pressurizing and feeding means that pressurizes and guides a supporting gas required for combustion, and the SO 2 gas from the combustion furnace is used as a power source. And a gas turbine generator that is driven as.
【００１０】このようにすれば、燃焼炉において昇圧送
給手段から昇圧して導かれた支燃性ガスにより単体硫黄
が燃焼され、燃焼炉内で圧力の高いＳＯ2ガスが生成さ
れることになるので、この圧力の高いＳＯ2ガスを燃焼
炉からガスタービン発電機に導くと、該ガスタービン発
電機が支障なく駆動されて効率良く発電が成され、ＳＯ
2ガスの運動エネルギーや熱エネルギーが電力として効
率的に回収されることになる。[0010] With this configuration, in the combustion furnace, the elemental sulfur is burned by the supportive gas which is pressurized and guided from the pressurized feeding means, and SO 2 gas having a high pressure is generated in the combustion furnace. Therefore, when this high-pressure SO 2 gas is guided from the combustion furnace to the gas turbine generator, the gas turbine generator is driven without hindrance and power is efficiently generated, and SO 2 gas is generated.
The kinetic energy and heat energy of the two gases are efficiently recovered as electric power.
【００１１】更に、本発明においては、昇圧送給手段
を、大気を圧縮して燃焼炉に導く圧縮機により構成する
ことが可能であり、このようにすれば、従来におけるブ
ロワを圧縮機に変更するだけの簡単な設備変更で、大気
圧の数倍程度に圧縮した圧縮空気を支燃性ガスとして燃
焼炉に送給し、燃焼炉内で圧力の高いＳＯ2ガスを生成
してガスタービン発電機を支障なく駆動することが可能
となる。Further, in the present invention, the pressurizing and feeding means can be constituted by a compressor that compresses the atmosphere and guides the compressed air to the combustion furnace. In this case, the conventional blower is replaced with a compressor. With a simple equipment change, compressed air compressed to several times the atmospheric pressure is sent as a supporting gas to the combustion furnace, and high-pressure SO 2 gas is generated inside the combustion furnace to generate gas turbine power. The machine can be driven without hindrance.
【００１２】また、昇圧送給手段を、大気を液化した液
体空気から酸素以外の成分を分留して液体酸素を生成す
る空気分留装置と、該空気分留装置から液体酸素を導い
て昇圧するポンプと、該ポンプからの液体酸素を気化さ
せて燃焼炉に導く気化器とにより構成することも可能で
あり、空気分留装置で生成した液体酸素を液相状態でポ
ンプにより昇圧すれば、最終的に気化器で気化されて燃
焼炉に送られる純酸素を大気圧の数倍程度に容易に昇圧
することが可能となり、しかも、燃焼炉での燃焼に必要
な支燃性ガスとして純酸素が使用されることになるの
で、従来の如く燃焼用空気を使用していた場合と比較し
てＳＯ2ガスの生成に不要な酸素以外の空気成分（主と
して窒素）の流通容積分を考慮する必要がなくなり、硫
酸製造設備を構成する各種機器類や配管系の容積を生産
性を落とすことなく縮小化することが可能となる。The pressurizing and feeding means includes an air fractionating device that fractionates components other than oxygen from liquid air obtained by liquefying the atmosphere to produce liquid oxygen, and a pressure boosting device that guides liquid oxygen from the air fractionating device to increase the pressure. Pump, and a vaporizer that vaporizes the liquid oxygen from the pump and guides it to the combustion furnace.If the liquid oxygen generated by the air fractionator is pressurized in the liquid phase by the pump, Finally, it is possible to easily increase the pressure of pure oxygen vaporized by the vaporizer and sent to the combustion furnace to several times the atmospheric pressure, and furthermore, pure oxygen is used as a supporting gas required for combustion in the combustion furnace. Therefore, it is necessary to consider a flow volume of an air component (mainly nitrogen) other than oxygen unnecessary for generation of SO 2 gas as compared with a case where combustion air is conventionally used. And the construction of sulfuric acid production facilities It becomes possible to shrink without reducing the productivity of the volume of the various equipment and piping systems.
【００１３】[0013]
【発明の実施の形態】以下本発明の実施の形態を図面を
参照しつつ説明する。Embodiments of the present invention will be described below with reference to the drawings.
【００１４】図１は本発明を実施する形態の一例を示す
もので、図３と同一の符号を付した部分は同一物を表わ
している。FIG. 1 shows an example of an embodiment of the present invention, and portions denoted by the same reference numerals as those in FIG. 3 represent the same components.
【００１５】本形態例の硫酸製造設備においては、燃焼
炉３とコンバータ８との間における排熱ボイラ７の上流
に、ＳＯ2ガス６を動力源として駆動するガスタービン
発電機１９を設けると共に、該ガスタービン発電機１９
のタービン２０の同軸上に、大気を圧縮して送出する圧
縮機２１を設け、前述した図３の従来設備で燃焼炉３に
対し燃焼用空気５を送給していたブロワ４に替えて、前
記圧縮機２１を燃焼炉３に対し燃焼に必要な支燃性ガス
を昇圧して導く昇圧送給手段として接続するようにして
いる。In the sulfuric acid production facility of this embodiment, a gas turbine generator 19 driven by the SO 2 gas 6 as a power source is provided upstream of the waste heat boiler 7 between the combustion furnace 3 and the converter 8. The gas turbine generator 19
A compressor 21 for compressing and sending the atmosphere is provided on the same axis as the turbine 20 of the above, and instead of the blower 4 which supplies the combustion air 5 to the combustion furnace 3 in the conventional equipment of FIG. The compressor 21 is connected to the combustion furnace 3 as a pressurizing and feeding means for pressurizing and guiding the supporting gas required for combustion.
【００１６】而して、このような構成を採用すれば、圧
縮機２１により大気圧の数倍程度の圧縮空気２２が支燃
性ガスとして燃焼炉３に送給され、この圧縮空気２２に
より単体硫黄が燃焼されて燃焼炉３内で圧力の高いＳＯ
2ガス６が生成されるので、この圧力の高いＳＯ2ガス６
を燃焼炉３からガスタービン発電機１９に導くと、該ガ
スタービン発電機１９が支障なく駆動されて効率良く発
電が成され、ＳＯ2ガス６の運動エネルギーや熱エネル
ギーが電力として効率的に回収されることになる。If such a configuration is adopted, compressed air 22 several times higher than the atmospheric pressure is supplied to the combustion furnace 3 by the compressor 21 as a combustion supporting gas. Sulfur is burned and SO 2 having a high pressure in the combustion furnace 3
Since two gases 6 are generated, this high-pressure SO 2 gas 6
Is guided from the combustion furnace 3 to the gas turbine generator 19, the gas turbine generator 19 is driven without hindrance to efficiently generate power, and the kinetic energy and heat energy of the SO 2 gas 6 are efficiently recovered as electric power. Will be done.
【００１７】尚、本形態例においては、大気を圧縮して
燃焼炉３に導く圧縮機２１をガスタービン発電機１９の
タービン２０と同軸上に設けているので、起動初期だけ
図示しない電動機でガスタービン発電機１９を駆動する
ようにすれば、これ以降はＳＯ2ガス６を動力源として
ガスタービン発電機１９と一緒に圧縮機２１が駆動され
ることになる。In this embodiment, the compressor 21 which compresses the atmosphere and guides the compressed air to the combustion furnace 3 is provided coaxially with the turbine 20 of the gas turbine generator 19. If the turbine generator 19 is driven, the compressor 21 is driven together with the gas turbine generator 19 using the SO 2 gas 6 as a power source thereafter.
【００１８】従って、上記形態例によれば、燃焼炉３内
で生成した圧力の高いＳＯ2ガス６によりガスタービン
発電機１９を支障なく駆動し、燃焼炉３からのＳＯ2ガ
ス６の運動エネルギーや熱エネルギーを電力として効率
的に回収することができるので、この電力を設備内で利
用することにより製造コストを下げることができ、安価
に濃硫酸１３を製造することができる。Therefore, according to the above embodiment, the gas turbine generator 19 is driven by the high pressure SO 2 gas 6 generated in the combustion furnace 3 without any trouble, and the kinetic energy of the SO 2 gas 6 from the combustion furnace 3 is increased. Since heat and heat energy can be efficiently recovered as electric power, the production cost can be reduced by using this electric power in the facility, and the concentrated sulfuric acid 13 can be produced at low cost.
【００１９】特に本形態例においては、従来におけるブ
ロワ４（図３参照）をガスタービン発電機１９のタービ
ン２０の同軸上に配置した圧縮機２１に変更するだけの
簡単な設備変更で、大気圧の数倍程度に圧縮した圧縮空
気２２を支燃性ガスとして燃焼炉３に送給し、燃焼炉３
内で圧力の高いＳＯ2ガス６を生成してガスタービン発
電機１９を支障なく駆動することができるので、設備コ
ストを高騰することなく安価に実施することができる。In this embodiment, in particular, a simple equipment change in which the conventional blower 4 (see FIG. 3) is replaced with a compressor 21 arranged coaxially with the turbine 20 of the gas turbine generator 19, and the atmospheric pressure is reduced. Is supplied to the combustion furnace 3 as a supporting gas, and the compressed air
Since the gas turbine generator 19 can be driven without any trouble by generating the SO 2 gas 6 having a high pressure inside, it can be implemented inexpensively without increasing the equipment cost.
【００２０】図２は本発明の別の形態例を示すもので、
燃焼炉３に対し燃焼に必要な支燃性ガスを昇圧して導く
昇圧送給手段として、臨界温度以下に冷却し且つ同時に
加圧して液化した液体空気から窒素などの酸素より沸点
の高い成分を分留して液体酸素２３を生成する空気分留
装置２４と、該空気分留装置２４から液体酸素２３を導
いて昇圧するポンプ２５と、該ポンプ２５により送給さ
れた液体酸素２３を設備排熱などを利用して気化せしめ
る気化器２６とを備えている。FIG. 2 shows another embodiment of the present invention.
As a pressurized supply means for pressurizing and introducing a supporting gas required for combustion to the combustion furnace 3, a component having a boiling point higher than oxygen such as nitrogen, such as nitrogen, is cooled from a liquid air which is cooled to a critical temperature or lower and simultaneously pressurized and liquefied. An air fractionation device 24 that fractionates to produce liquid oxygen 23, a pump 25 that guides liquid oxygen 23 from the air fractionation device 24 and pressurizes the liquid oxygen 23, and discharges the liquid oxygen 23 supplied by the pump 25 to a facility. A vaporizer 26 for vaporizing using heat or the like.
【００２１】而して、このような硫酸製造設備におい
て、空気分留装置２４で生成した液体酸素２３を液相状
態でポンプ２５により昇圧すれば、最終的に気化器２６
で気化されて燃焼炉３に送られる純酸素２７を大気圧の
数倍程度に容易に昇圧することが可能となり、しかも、
燃焼炉３での燃焼に必要な支燃性ガスとして純酸素２７
が使用されることになるので、従来の如く燃焼用空気５
を使用していた場合と比較してＳＯ2ガス６の生成に不
要な酸素以外の空気成分（主として窒素）の流通容積分
を考慮する必要がなくなり、硫酸製造設備を構成する各
種機器類や配管系の容積を生産性を落とすことなく縮小
化することが可能となる。In such a sulfuric acid production facility, if the pressure of the liquid oxygen 23 generated by the air fractionator 24 in the liquid state is increased by the pump 25, the vaporizer 26
It is possible to easily increase the pressure of the pure oxygen 27 vaporized in the combustion furnace 3 and sent to the combustion furnace 3 to about several times the atmospheric pressure.
Pure oxygen 27 is used as a supporting gas required for combustion in the combustion furnace 3.
Is used, so that the combustion air 5
It is no longer necessary to consider the flow volume of air components (mainly nitrogen) other than oxygen unnecessary for the generation of SO 2 gas 6 as compared with the case where sulfur is used, and various devices and piping constituting the sulfuric acid production facility It is possible to reduce the volume of the system without reducing productivity.
【００２２】尚、本発明の硫酸製造設備は、上述の形態
例にのみ限定されるものではなく、燃焼炉に溶融硫黄を
導いて燃焼させる場合で説明したが、例えば単体硫黄を
微粉化して固体のまま燃焼させるようにしても良いこ
と、その他、本発明の要旨を逸脱しない範囲内において
種々変更を加え得ることは勿論である。The sulfuric acid production equipment of the present invention is not limited to the above-described embodiment, but has been described in the case where molten sulfur is introduced into a combustion furnace for combustion. It is needless to say that combustion may be performed as it is, and that various changes may be made without departing from the spirit of the present invention.
【００２３】[0023]
【発明の効果】上記した本発明の硫酸製造設備によれ
ば、下記の如き種々の優れた効果を奏し得る。According to the above-mentioned sulfuric acid production equipment of the present invention, the following various excellent effects can be obtained.
【００２４】（Ｉ）本発明の請求項１に記載の発明によ
れば、燃焼炉内で生成した圧力の高いＳＯ2ガスにより
ガスタービン発電機を支障なく駆動し、燃焼炉からのＳ
Ｏ2ガスの運動エネルギーや熱エネルギーを電力として
効率的に回収することができるので、この電力を設備内
で利用することにより製造コストを下げることができ、
安価に濃硫酸を製造することができる。(I) According to the first aspect of the present invention, the gas turbine generator is driven without any trouble by the high-pressure SO 2 gas generated in the combustion furnace, and the S
Since the kinetic energy and heat energy of O 2 gas can be efficiently recovered as electric power, the production cost can be reduced by using this electric power in the facility,
Concentrated sulfuric acid can be produced at low cost.
【００２５】（ＩＩ）本発明の請求項２に記載の発明に
よれば、従来におけるブロワを圧縮機に変更するだけの
簡単な設備変更で、大気圧の数倍程度に圧縮した圧縮空
気を支燃性ガスとして燃焼炉に送給し、燃焼炉内で圧力
の高いＳＯ2ガスを生成してガスタービン発電機を支障
なく駆動することができるので、設備コストを高騰する
ことなく安価に実施することができる。(II) According to the invention described in claim 2 of the present invention, compressed air compressed to about several times the atmospheric pressure is supported by a simple equipment change by simply changing the conventional blower to a compressor. Since the gas can be sent to the combustion furnace as flammable gas and high-pressure SO 2 gas can be generated in the combustion furnace to drive the gas turbine generator without any trouble, the cost can be reduced without increasing equipment costs. be able to.
【００２６】（ＩＩＩ）本発明の請求項３に記載の発明
によれば、空気分留装置で生成した液体酸素を液相状態
でポンプにより昇圧することによって、最終的に気化器
で気化されて燃焼炉に送られる純酸素を大気圧の数倍程
度に容易に昇圧することができ、しかも、燃焼炉での燃
焼に必要な支燃性ガスとして純酸素を使用することによ
り、従来の如く燃焼用空気を使用していた場合と比較し
てＳＯ2ガスの生成に不要な酸素以外の空気成分（主と
して窒素）の流通容積分を考慮する必要がなくなり、硫
酸製造設備を構成する各種機器類や配管系の容積を生産
性を落とすことなく縮小化することができる。(III) According to the third aspect of the present invention, the liquid oxygen generated by the air fractionating apparatus is pressurized in a liquid phase by a pump, and finally vaporized by a vaporizer. The pressure of pure oxygen sent to the combustion furnace can be easily increased to about several times the atmospheric pressure. In addition, by using pure oxygen as a supporting gas required for combustion in the combustion furnace, combustion can be performed as in the past. In comparison with the case where air for use is used, there is no need to consider the flow volume of air components other than oxygen (mainly nitrogen) that are not necessary for the generation of SO 2 gas, and various devices constituting sulfuric acid production equipment and The volume of the piping system can be reduced without reducing productivity.
【図１】本発明を実施する形態の一例を示す系統図であ
る。FIG. 1 is a system diagram showing an example of an embodiment for implementing the present invention.
【図２】本発明の別の形態例を示す系統図である。FIG. 2 is a system diagram showing another embodiment of the present invention.
【図３】従来例を示す系統図である。FIG. 3 is a system diagram showing a conventional example.
２ 溶融硫黄（単体硫黄） ３ 燃焼炉 ６ ＳＯ2ガス ９ ＳＯ3ガス １２ 希硫酸 １３ 濃硫酸 １９ ガスタービン発電機 ２１ 圧縮機（昇圧送給手段） ２２ 圧縮空気（支燃性ガス） ２３ 液体酸素 ２４ 空気分留装置（昇圧送給手段） ２５ ポンプ（昇圧送給手段） ２６ 気化器（昇圧送給手段） ２７ 純酸素（支燃性ガス）2 Molten sulfur (single sulfur) 3 Combustion furnace 6 SO 2 gas 9 SO 3 gas 12 Dilute sulfuric acid 13 Concentrated sulfuric acid 19 Gas turbine generator 21 Compressor (pressurized feeding means) 22 Compressed air (combustible gas) 23 Liquid oxygen Reference Signs List 24 Air fractionation device (Pressure supply means) 25 Pump (Pressure supply means) 26 Vaporizer (Pressure supply means) 27 Pure oxygen (combustible gas)
Claims (3)
を生成し、該ＳＯ2ガスを酸化してＳＯ3ガスに転化し、
該ＳＯ3ガスを希硫酸に吸収させて濃硫酸を生成する硫
酸製造設備において、燃焼炉に対し燃焼に必要な支燃性
ガスを昇圧して導く昇圧送給手段を接続し、燃焼炉から
のＳＯ2ガスを動力源として駆動するガスタービン発電
機を設けたことを特徴とする硫酸製造設備。1. A elemental sulfur was burned in the combustion furnace to generate SO 2 gas, and converted to SO 3 gas to oxidize the SO 2 gas,
In a sulfuric acid production facility for producing concentrated sulfuric acid by absorbing the SO 3 gas into dilute sulfuric acid, a pressurizing and feeding means is connected to the combustion furnace to pressurize and guide the supporting gas required for combustion, and A sulfuric acid production facility provided with a gas turbine generator driven by using SO 2 gas as a power source.
に導く圧縮機により構成したことを特徴とする請求項１
に記載の硫酸製造設備。2. The pressurizing and feeding means is constituted by a compressor that compresses air and guides the compressed air to a combustion furnace.
2. A sulfuric acid production facility according to item 1.
気から酸素以外の成分を分留して液体酸素を生成する空
気分留装置と、該空気分留装置から液体酸素を導いて昇
圧するポンプと、該ポンプからの液体酸素を気化させて
燃焼炉に導く気化器とにより構成したことを特徴とする
請求項１に記載の硫酸製造設備。3. A pressurizing and feeding means, comprising: an air fractionating device that fractionates components other than oxygen from liquid air obtained by liquefying the atmosphere to produce liquid oxygen; 2. The sulfuric acid production equipment according to claim 1, wherein the sulfuric acid production equipment comprises:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6322698A JPH11263606A (en) | 1998-03-13 | 1998-03-13 | Sulfuric acid producing equipment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6322698A JPH11263606A (en) | 1998-03-13 | 1998-03-13 | Sulfuric acid producing equipment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11263606A true JPH11263606A (en) | 1999-09-28 |
Family
ID=13223094
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6322698A Pending JPH11263606A (en) | 1998-03-13 | 1998-03-13 | Sulfuric acid producing equipment |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11263606A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1329289C (en) * | 2005-10-13 | 2007-08-01 | 中国石油化工集团公司 | Method for preparing sulfuric acid by using sulfur from gas turbine |
| WO2008034229A1 (en) * | 2006-09-19 | 2008-03-27 | Bogdan Wojak | Gas turbine topping in sulfuric acid manufacture |
| EP2042470A3 (en) * | 2007-09-25 | 2010-01-27 | Bodgan Wojak | Gas turbine topping device in a sytem for manufacturing sulfuric acid and method of using turbine to recover energy in manufacture of sulphuric acid |
| CN103318850A (en) * | 2013-07-17 | 2013-09-25 | 上海奥格利环保工程有限公司 | Low-temperature waste heat recovery system for pyrite and metallurgical off-gas acid making device |
| CN103848403A (en) * | 2013-04-11 | 2014-06-11 | 襄阳泽东化工集团有限公司 | Medium-low-grade heat energy recycling system and method in acid production by using iron pyrite |
-
1998
- 1998-03-13 JP JP6322698A patent/JPH11263606A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1329289C (en) * | 2005-10-13 | 2007-08-01 | 中国石油化工集团公司 | Method for preparing sulfuric acid by using sulfur from gas turbine |
| WO2008034229A1 (en) * | 2006-09-19 | 2008-03-27 | Bogdan Wojak | Gas turbine topping in sulfuric acid manufacture |
| EP2069233A1 (en) * | 2006-09-19 | 2009-06-17 | Bogdan Wojak | Gas turbine topping in sulfuric acid manufacture |
| EP2069233A4 (en) * | 2006-09-19 | 2010-01-06 | Bogdan Wojak | Gas turbine topping in sulfuric acid manufacture |
| EP2042470A3 (en) * | 2007-09-25 | 2010-01-27 | Bodgan Wojak | Gas turbine topping device in a sytem for manufacturing sulfuric acid and method of using turbine to recover energy in manufacture of sulphuric acid |
| CN103848403A (en) * | 2013-04-11 | 2014-06-11 | 襄阳泽东化工集团有限公司 | Medium-low-grade heat energy recycling system and method in acid production by using iron pyrite |
| CN103848403B (en) * | 2013-04-11 | 2015-08-05 | 襄阳泽东化工集团有限公司 | A kind of pyrite-based sulfuric acid production produce in, recovery system of low-grade heat energy and method |
| CN103318850A (en) * | 2013-07-17 | 2013-09-25 | 上海奥格利环保工程有限公司 | Low-temperature waste heat recovery system for pyrite and metallurgical off-gas acid making device |
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