JPH11256076A - Coating agent for termite control - Google Patents
Coating agent for termite controlInfo
- Publication number
- JPH11256076A JPH11256076A JP5489798A JP5489798A JPH11256076A JP H11256076 A JPH11256076 A JP H11256076A JP 5489798 A JP5489798 A JP 5489798A JP 5489798 A JP5489798 A JP 5489798A JP H11256076 A JPH11256076 A JP H11256076A
- Authority
- JP
- Japan
- Prior art keywords
- water
- repellent
- agent
- termite
- colloidal silica
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- Paints Or Removers (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は白蟻防除用コーティ
ング材、更に詳しくは、バインダーとしての、コロイダ
ルシリカを含有する通気性および撥水性に優れた無機系
通気型撥水塗材に、木材を加害する白蟻の防蟻剤を配合
したもので、特に安全性の高い防蟻剤の長期にわたる防
蟻効果を保持せしめることができるコーティング材に関
する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a coating material for termite control, and more particularly, to an inorganic air-permeable water-repellent coating material containing colloidal silica as a binder and having excellent air-permeability and water-repellency. The present invention relates to a coating material containing a termite repellent for termites, which can maintain the termite-control effect of a highly safe termite repellent for a long period of time.
【０００２】[0002]
【従来の技術と発明が解決しようとする課題】最近、木
造家屋や他の建物、構築物等における木材を加害する白
蟻に対し、その予防もしくは駆除対策(防除対策)が高ま
りつつあり、一つの社会問題として叫ばれている。こう
した中で、白蟻の予防剤もしくは駆除剤として、たとえ
ばi)木材に加圧注入して使用するＣＣＡ系薬剤(クロム
・銅・ヒ素の化合物)や、ii)乳剤あるいは油剤の形で木
部に直接塗布して使用するクロルピリフォス等の有機リ
ン系薬剤が主に知られている。しかしながら、上記i)の
ＣＣＡ系薬剤においては焼却廃棄時に新たな毒物の発生
による環境汚染の問題があり、一方、ii)の有機リン系
薬剤においては人体に対する毒性が高く、健康被害の発
生が報告されている。また、塗布・噴霧するタイプの乳
剤または油剤では薬剤が塗布面から垂れて十分な塗布量
を維持できなかったり、あるいは揮発性が高く長期間の
防蟻効果を保持できないという欠点がある。2. Description of the Related Art Recently, measures to prevent or control termites that damage wood in wooden houses, other buildings, structures, and the like (control measures) have been increasing. Screamed as a problem. Under these circumstances, as a termite preventive or pesticide, for example, i) CCA drugs (compounds of chromium, copper, and arsenic) which are used by injecting into wood under pressure, and ii) xylem in the form of emulsions or oils Organophosphorus drugs such as chlorpyrifos that are directly applied and used are mainly known. However, the CCA-based drug described in i) above has a problem of environmental pollution due to the generation of new toxic substances at the time of incineration disposal, while the ii) organophosphorus-based drug has a high toxicity to the human body, and a health hazard has been reported. Have been. In addition, in the case of an emulsion or an oil which is applied and sprayed, there is a disadvantage that the medicine drips from the application surface and a sufficient application amount cannot be maintained, or the volatility is high and a long term ant-control effect cannot be maintained.
【０００３】[0003]
【課題を解決するための手段】そこで、本発明者らは、
かかる白蟻の防除対策について種々検討を進めたとこ
ろ、上記予防剤もしくは駆除剤(以下、防蟻剤と総称す
る)のバインダーとして、コロイダルシリカを含有する
通気性および撥水性に優れた無機系通気型撥水塗材を用
いれば、コロイダルシリカなどからなる微多孔質の塗膜
が防蟻剤を吸着保持し、また塗布後に形成されるコーテ
ィング膜の通気性によって徐放効果が発現し、さらには
撥水性付与によって耐水性や耐候性を含む耐久性を高め
るのみならず、防蟻剤の流出を有効に防止できることか
ら、長期にわたる防蟻効果を保持せしめうることを見出
し、本発明を完成させるに至った。Means for Solving the Problems Accordingly, the present inventors have:
As a result of various studies on the control measures of such termites, as a binder of the above-mentioned preventive agent or pesticide (hereinafter, collectively referred to as termiticide), colloidal silica-containing inorganic air-permeable type having excellent air permeability and water repellency was used. If a water-repellent coating material is used, a microporous coating made of colloidal silica or the like absorbs and holds the termiticide, and the coating film formed after application exhibits a sustained release effect due to the gas permeability. It was found that by imparting water, not only the durability including water resistance and weather resistance was improved but also the outflow of the termiticide could be effectively prevented, and it was found that the termite-controlling effect could be maintained for a long time, and the present invention was completed. Was.
【０００４】すなわち、本発明は、コロイダルシリカ、
シラン系撥水剤、水性樹脂エマルジョンおよび他の無機
物質などから成る無機系通気型撥水塗料に、防蟻剤を配
合したことを特徴とする白蟻防除用コーティング材を提
供するものである。That is, the present invention relates to a colloidal silica,
An object of the present invention is to provide a coating material for termite control, wherein a termite-controlling agent is added to an inorganic air-permeable water-repellent paint composed of a silane-based water-repellent, an aqueous resin emulsion, and other inorganic substances.
【０００５】[0005]
【発明の実施の形態】本発明に用いる上記無機系通気型
撥水塗料は、コロイダルシリカ(粒径約１〜１００ミリ
μmのシリカの水性分散体)を含有する水性樹脂エマルジ
ョンに、シラン系撥水剤および他の無機物質を添加し、
さらに必要に応じて適量の有機物質(メチルエチルセル
ロース、ポリ酢酸ビニル系エマルジョン、ポリスチレン
−ブタジエン系エマルジョン、ポリアミド系エマルジョ
ンなど)、有色顔料、体質顔料、サビ止め顔料、増粘
剤、充填剤、分散剤、粘度調整剤、消泡剤を配合した系
で構成され、優れた耐久性、接着性、水蒸気透過性(透
湿性)、撥水性および耐汚染性を付与する。上記コロイ
ダルシリカの含有量は通常、該塗料全量中１〜２０％
(重量％、以下同様)に設定されておればよい。BEST MODE FOR CARRYING OUT THE INVENTION The above-mentioned inorganic air-permeable water-repellent paint used in the present invention is prepared by adding a silane-based water-repellent coating to an aqueous resin emulsion containing colloidal silica (an aqueous dispersion of silica having a particle diameter of about 1 to 100 mm). Add liquids and other inorganic substances,
Furthermore, if necessary, an appropriate amount of an organic substance (methyl ethyl cellulose, polyvinyl acetate emulsion, polystyrene-butadiene emulsion, polyamide emulsion, etc.), colored pigment, extender pigment, rust stopper pigment, thickener, filler, dispersant It is composed of a system containing a viscosity modifier and an antifoaming agent, and provides excellent durability, adhesiveness, water vapor permeability (moisture permeability), water repellency and stain resistance. The content of the colloidal silica is usually 1 to 20% of the total amount of the paint.
(Weight%, the same applies hereinafter).
【０００６】上記水性樹脂エマルジョンとしては、各種
の樹脂を含む水分散体であって、水除去(乾燥)により連
続した皮膜を形成しうるものであればいずれであっても
よく、特にアクリル系水性エマルジョンが好適である。
かかるアクリル系水性エマルジョンとは、(メタ)アクリ
レート類(たとえばエチルアクリレート、エチルメタク
リレート、２−エチルヘキシルアクリレート、ヒドロキ
シプロピルメタクリレートなど)の少なくとも１種単
独、又はこれと約１０モル％以下のスチレン、エチレ
ン、酢酸ビニル、アクリロニトリル、ブタジエン等の他
のモノマーとの混合物を、水中で乳化重合することによ
り得られる水性エマルジョンである。[0006] The aqueous resin emulsion may be any aqueous dispersion containing various resins, as long as it can form a continuous film by removing (drying) water. Emulsions are preferred.
Such an acrylic aqueous emulsion refers to at least one of (meth) acrylates (eg, ethyl acrylate, ethyl methacrylate, 2-ethylhexyl acrylate, hydroxypropyl methacrylate, etc.) alone, or about 10 mol% or less of styrene, ethylene, This is an aqueous emulsion obtained by emulsion-polymerizing a mixture of vinyl acetate, acrylonitrile, butadiene and other monomers with water.
【０００７】上記シラン系撥水剤としては、たとえばト
リメチルシリルスルホン酸ソーダ、トリエチルシリルス
ルホン酸ソーダ、トリメチルシリルアミン、トリメチル
シリルアセトアミド、トリメチルシリルカルボン酸ソー
ダ等が挙げられる。添加量は通常、上記コロイダルシリ
カおよび水性樹脂エマルジョンの両固形分合計量１００
部(重量部、以下同様)に対して１０〜３０部に設定され
ておればよい。上記他の無機物質としては、たとえば無
定形シリカ、石英、クリストバライト、溶融シリカ、ベ
ントナイト、アルミナ粉、溶融アルミナ、シリマナイ
ト、ムライト、ジルコニア、チタン、マグネシア等が挙
げられる。添加量は通常、上記コロイダルシリカおよび
水性樹脂エマルジョンの両固形分とシラン系撥水剤の合
計量１００部に対して１００〜１０００部に設定されて
おればよい。Examples of the silane-based water repellent include sodium trimethylsilylsulfonate, sodium triethylsilylsulfonate, trimethylsilylamine, trimethylsilylacetamide, sodium trimethylsilylcarboxylate, and the like. The amount of addition is usually 100% of the total solid content of the colloidal silica and the aqueous resin emulsion.
Parts (parts by weight, hereinafter the same) may be set to 10 to 30 parts. Examples of the other inorganic substance include amorphous silica, quartz, cristobalite, fused silica, bentonite, alumina powder, fused alumina, sillimanite, mullite, zirconia, titanium, magnesia, and the like. Usually, the addition amount may be set to 100 to 1000 parts with respect to 100 parts of the total amount of both the solid content of the colloidal silica and the aqueous resin emulsion and the silane-based water repellent.
【０００８】本発明で用いる防蟻剤とは、白蟻の予防お
よび／または駆除を目的とする、日本白蟻協会認定の薬
剤を指称し、その中で白蟻の種類に応じて適宜選択して
使用することができる。特に人体への安全性の高い、た
とえばピレスロイド系もしくはピレスロイド様、具体的
にはペルメトリン、アレスリン、トラロメスリン、シラ
フルオフェン、エトフェンプロックス、フェノトリンな
どの使用が好適である。なお、ピレスロイド系を用いる
場合、通常、有機ヨード系防腐剤(たとえば４−クロル
フェニル−３−ヨードプロパギルフォルマール、ジヨー
ドメチル−p−トリスルホン、１−ブロム−３−エトキ
シカルボニルオルキシ−１,２−ジヨード−１−プロペ
ン、３−ヨード−２−プロピニル・Ｎ−ブチルカーバメ
ートなど)や共力剤(たとえばオクタクロルジプロピルエ
ーテル、Ｎ−(２−エチルヘキシル)−ビシクロ[２．
２．１]−ヘプタ−５−エン−２,３−ジカルボキシイミ
ドなど)が適量で併用される。防蟻剤の配合量は通常、
上記無機系通気型撥水塗料１００部に対して０．０１〜
１０部の範囲で選定すればよい。０．０１部未満では、
白蟻防除効果が不十分であり、また１０部を越えると、
経済的に不利となる傾向にある。The termiticide used in the present invention refers to a chemical approved by the Japanese Termite Association for the purpose of preventing and / or controlling termites, and is appropriately selected and used depending on the type of termite. be able to. In particular, use of pyrethroids or pyrethroid-like, which are highly safe for the human body, such as permethrin, allethrin, tralomethrin, silafluofen, etofenprox, and phenothrin, are preferred. When a pyrethroid is used, usually, an organic iodine preservative (for example, 4-chlorophenyl-3-iodopropargyl formal, diiodomethyl-p-trisulfone, 1-bromo-3-ethoxycarbonyloloxy-1, 2-diiodo-1-propene, 3-iodo-2-propynyl / N-butyl carbamate, etc.) and synergists (for example, octachlorodipropyl ether, N- (2-ethylhexyl) -bicyclo [2.
2.1] -hepta-5-ene-2,3-dicarboximide) in an appropriate amount. The termiticide compounding amount is usually
0.01 to 100 parts of the inorganic ventilation type water-repellent paint
What is necessary is just to select in the range of 10 parts. If less than 0.01 part,
Termite control effect is insufficient, and if it exceeds 10 parts,
It tends to be economically disadvantaged.
【０００９】[0009]
【発明の実施の形態】本発明に係る白蟻防除用コーティ
ング材は、上記所定割合の無機系通気型撥水塗料に防蟻
剤を配合した系で構成され、適用に際しては、木材面に
対し一般に、５０〜６００g／m2の塗布量で塗布し(噴
霧、刷毛塗り、ローラー塗り等による)、次いで自然条
件下で養生乾燥することにより、所望耐久性の防蟻性能
を有するコーティング膜が形成される。BEST MODE FOR CARRYING OUT THE INVENTION The termite controlling coating material according to the present invention is composed of a system in which a termite-controlling agent is blended with the above-mentioned predetermined ratio of inorganic ventilation type water-repellent paint. A coating film having a desired durability and termite-controlling performance is formed by applying a coating amount of 50 to 600 g / m 2 (by spraying, brushing, roller coating, etc.) and then curing and drying under natural conditions. You.
【００１０】[0010]
【実施例】次に、実施例および比較例を挙げて、本発明
を具体的に説明する。 実施例１ (１)無機系通気型撥水塗料 該塗料の組成は、以下の通りである。 組成 部 アクリル系水性エマルジョン ３０ コロイダルシリカ １０ 増粘剤水溶液 １０ 石英微粉末 １００ クレー ２００ 微粉化寒水石 ５０ 酸化チタン ５０ 水 ５０ 計５００ (２)白蟻防除用コーティング材 上記(１)の無機系通気型撥水塗料１００部に、ピレスロ
イド系防蟻剤(シラフルオフェン)０．１部および有機ヨ
ード系防腐剤(３−ヨード−２−プロピニル・Ｎ−ブチ
ルカーバメート)１部を加え、均一撹拌する。Next, the present invention will be specifically described with reference to examples and comparative examples. Example 1 (1) Inorganic air-permeable water-repellent paint The composition of the paint is as follows. The composition of the acrylic water-based emulsion 30 colloidal silica 10 thickening aqueous 10 quartz powder 100 clay 200 micronized white marble 50 titanium oxide 50 Water 50 Total 500 (2) inorganic vented termite controlling coating material (1) To 100 parts of the water-repellent paint, 0.1 part of a pyrethroid-based termiticide (silafluofen) and 1 part of an organic iodine-based preservative (3-iodo-2-propynyl / N-butylcarbamate) are added, followed by uniform stirring.
【００１１】比較例１ 実施例１／(１)の無機系通気型撥水塗料そのものを使用
する。 比較例２ 実施例１で用いたピレスロイド系防蟻剤および有機ヨー
ド系防腐剤を溶剤に希釈したものを使用する。 比較例３ 従来より多用されている有機リン系薬剤を有機溶媒に希
釈したものを使用する。 比較例４ 未処理の木材を試験に供した。Comparative Example 1 The inorganic air-permeable water-repellent paint of Example 1 / (1) itself was used. Comparative Example 2 A solution prepared by diluting a pyrethroid-based termiticide and an organic iodine-based preservative used in Example 1 with a solvent is used. Comparative Example 3 An organic phosphorus-based drug, which has been frequently used, is diluted with an organic solvent. Comparative Example 4 Untreated wood was subjected to the test.
【００１２】性能試験 下記試験Ａ〜Ｃを行ない、結果を表１に示す。 Ａ．防蟻効力試験 ２０×２０×１０mmのアカマツの木片に、実施例１およ
び比較例１〜３の各処理剤を１００〜１２０g／m2の塗
布量で塗布し、室温で１０日間乾燥(初期);または３０
秒水浸漬→２６℃湿潤デシケーター×４hr→４０℃×２
０hrのサイクルを３０回繰返した後(耐候操作)、常温下
で養生せしめ、防蟻性能を評価する。 ○:木片の重量減少率＜３％ △:木片の重量減少率が３〜２０％ ×:木片の重量減少率＞２０％ Performance Tests The following tests A to C were performed, and the results are shown in Table 1. A. Termite Control Efficacy Test Each of the treatment agents of Example 1 and Comparative Examples 1 to 3 was applied to a 20 × 20 × 10 mm red pine wood chip at an application amount of 100 to 120 g / m 2 and dried at room temperature for 10 days (initial stage). ; Or 30
Second water immersion → 26 ° C wet desiccator × 4hr → 40 ° C × 2
After repeating the cycle of 0 hr 30 times (weather-proof operation), the mixture is cured at room temperature, and the termite control performance is evaluated. :: Weight loss rate of wood piece <3% △: Weight loss rate of wood piece is 3 to 20% ×: Weight loss rate of wood piece> 20%
【００１３】Ｂ．安全性 下記の基準で評価する。 ○:使用薬剤のマウス急性毒性(ＬＤ50)が１０００mg／k
g以上もしくは薬剤を使用しない △:上記ＬＤ50が３００mg／kg以上 ×:上記ＬＤ50が３００mg／kg未満 Ｃ．垂直面塗布性 表面をカンナがけしたヒノキ材を垂直に立て、実施例１
および比較例１〜３の各処理剤を１００〜１２０g／m2
の塗布量でスプレー塗布し、その時の垂れ状況を目視に
て評価した。 ○:処理剤の垂れが認められない ×:処理剤の垂れが認められるB. Safety Evaluate according to the following criteria. :: Acute toxicity (LD 50 ) of the drug used in mice was 1000 mg / k
g do not use more or agent △: the LD 50 is 300 mg / kg or more ×: the LD 50 is 300 mg / less than kg C. Vertical surface applicability Example 1
And 100 to 120 g / m 2 of each of the treating agents of Comparative Examples 1 to 3.
Was spray-coated at a coating amount of, and the dripping state at that time was visually evaluated. :: No dripping of the treating agent was observed ×: Dripping of the treating agent was observed
【００１４】[0014]
【表１】 [Table 1]
【００１５】[0015]
【発明の効果】表１の結果から、実施例１の処理剤(本
発明コーティング材)によれば、安全性の高い防蟻剤を
用いて耐候操作での防蟻効果(すなわち、長期にわたる
防蟻効果)を保持しうることが認められ、このため人体
や動植物に危険度の高い薬剤を使用する必要がなく、換
言すれば、多少防蟻効果が低くても安全性の高い薬剤の
使用が可能となる。また、垂直面塗布においても垂れ落
ちの問題が大巾に緩和され、薬剤の節約が可能となる。According to the results shown in Table 1, the treatment agent of Example 1 (the coating material of the present invention) shows that the termite-controlling effect in weathering operation using a highly safe termite-controlling agent (that is, long-term protection). (Ant effect) can be maintained, so there is no need to use drugs with a high risk for the human body, animals and plants, in other words, the use of drugs that are safe even with a slightly lower It becomes possible. In addition, the problem of dripping is also greatly reduced in the vertical surface application, and it is possible to save the medicine.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 小森 勇 大阪府高槻市明田町７番１号 サンスター 技研株式会社内 (72)発明者 杉 茂 大阪府高槻市明田町７番１号 サンスター 技研株式会社内 (72)発明者 田中 愛益 大阪府高槻市明田町７番１号 サンスター 技研株式会社内 (72)発明者 小林 智紀 大阪府大阪市此花区梅町２−１−48 ケミ プロ化成株式会社内 (72)発明者 土井 正 大阪府大阪市住之江区南港中３−３−36− 1010 ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Isamu Komori 7-1, Akita-cho, Takatsuki-shi, Osaka Sunstar Giken Co., Ltd. (72) Inventor Shigeru Shigeru 7-1, Akita-cho, Takatsuki-shi, Osaka Sunstar Giken Co., Ltd. (72) Inventor Ai Tanaka 7-1, Akita-cho, Takatsuki-shi, Osaka Sunstar Giken Co., Ltd. (72) Inventor Tomoki Kobayashi 2-1-48 Umecho, Konohana-ku, Osaka, Osaka (72) Inventor Tadashi Doi 3-3-36-1010 Nanko Naka, Suminoe-ku, Osaka-shi, Osaka
Claims (3)
性樹脂エマルジョンおよび他の無機物質などから成る無
機系通気型撥水塗料に、防蟻剤を配合したことを特徴と
する白蟻防除用コーティング材。1. A termite-controlling coating material characterized in that a termite-controlling agent is added to an inorganic air-permeable water-repellent coating comprising colloidal silica, a silane-based water-repellent, an aqueous resin emulsion and other inorganic substances. .
ロイド様の防蟻剤であって、その配合量が無機系通気型
撥水塗料１００重量部に対して０．０１〜１０重量部で
ある請求項１に記載の白蟻防除用コーティング材。2. The termiticide is a pyrethroid or pyrethroid-like termiticide, and its compounding amount is 0.01 to 10 parts by weight based on 100 parts by weight of the inorganic air-permeable water-repellent paint. 2. The coating material for termite control according to 1.
に有機ヨード系防腐剤を併用した請求項１または２に記
載の白蟻防除用コーティング材。3. The coating material for termite control according to claim 1, wherein the termiticide is pyrethroid-based, and an organic iodine-based preservative is used in combination therewith.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5489798A JPH11256076A (en) | 1998-03-06 | 1998-03-06 | Coating agent for termite control |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5489798A JPH11256076A (en) | 1998-03-06 | 1998-03-06 | Coating agent for termite control |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11256076A true JPH11256076A (en) | 1999-09-21 |
Family
ID=12983403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5489798A Pending JPH11256076A (en) | 1998-03-06 | 1998-03-06 | Coating agent for termite control |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11256076A (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007052754A1 (en) * | 2005-11-04 | 2007-05-10 | Japan Envirochemicals, Ltd. | Coating composition for termite control |
| JP2007146159A (en) * | 2005-11-04 | 2007-06-14 | Japan Enviro Chemicals Ltd | Coating material composition for preventing and exterminating termite |
| WO2008126636A1 (en) * | 2007-04-11 | 2008-10-23 | Digic & Co., Ltd. | Wood-treating agents and method of treating wood |
| JP2009543916A (en) * | 2006-07-17 | 2009-12-10 | ビーエーエスエフ ソシエタス・ヨーロピア | Use of aqueous composite particle dispersions as binders in wood coatings. |
| US7709016B2 (en) | 2005-08-31 | 2010-05-04 | Nichiha Corporation | Insect proof boards |
| WO2015037610A1 (en) * | 2013-09-13 | 2015-03-19 | 日本曹達株式会社 | Aqueous liquid composition for solid material treatment |
| JP2018100388A (en) * | 2016-12-21 | 2018-06-28 | 大阪ウイントン株式会社 | Birds evasion coating materials |
| US10093821B2 (en) | 2013-10-22 | 2018-10-09 | Dow Global Technologies Llc | Aqueous coating composition and process of making the same |
| JP2019073610A (en) * | 2017-10-16 | 2019-05-16 | 廣 閤田 | Deodorant paint |
| JP2019081822A (en) * | 2017-10-27 | 2019-05-30 | 菊水化学工業株式会社 | Insect repellent coating composition |
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-
1998
- 1998-03-06 JP JP5489798A patent/JPH11256076A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7709016B2 (en) | 2005-08-31 | 2010-05-04 | Nichiha Corporation | Insect proof boards |
| WO2007052754A1 (en) * | 2005-11-04 | 2007-05-10 | Japan Envirochemicals, Ltd. | Coating composition for termite control |
| JP2007146159A (en) * | 2005-11-04 | 2007-06-14 | Japan Enviro Chemicals Ltd | Coating material composition for preventing and exterminating termite |
| JP2009543916A (en) * | 2006-07-17 | 2009-12-10 | ビーエーエスエフ ソシエタス・ヨーロピア | Use of aqueous composite particle dispersions as binders in wood coatings. |
| WO2008126636A1 (en) * | 2007-04-11 | 2008-10-23 | Digic & Co., Ltd. | Wood-treating agents and method of treating wood |
| JPWO2015037610A1 (en) * | 2013-09-13 | 2017-03-02 | 日本曹達株式会社 | Aqueous liquid composition for solid material processing |
| WO2015037610A1 (en) * | 2013-09-13 | 2015-03-19 | 日本曹達株式会社 | Aqueous liquid composition for solid material treatment |
| US10093821B2 (en) | 2013-10-22 | 2018-10-09 | Dow Global Technologies Llc | Aqueous coating composition and process of making the same |
| JP2018100388A (en) * | 2016-12-21 | 2018-06-28 | 大阪ウイントン株式会社 | Birds evasion coating materials |
| US10501658B2 (en) | 2016-12-21 | 2019-12-10 | Winton Osaka Co., Ltd. | Bird-repellent coating material |
| JP2019073610A (en) * | 2017-10-16 | 2019-05-16 | 廣 閤田 | Deodorant paint |
| JP2019081822A (en) * | 2017-10-27 | 2019-05-30 | 菊水化学工業株式会社 | Insect repellent coating composition |
| JP2019127533A (en) * | 2018-01-25 | 2019-08-01 | リケンテクノス株式会社 | Active energy ray-curable resin composition having insect repellent function, and hard coat laminate film |
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