JPH11246935A - Steel plate for hull excellent in impact energy absorbing power and its production - Google Patents

Abstract

PROBLEM TO BE SOLVED: To effectively improve the impact energy absorbing power of a steel plate by subjecting a slab whose chemical components and a carbon equivalent are specified to hot rolling, controlling the cooling rates after finish rolling to two stages and allowing residual γ to exist on the surface and back layers. SOLUTION: A steel having a compsn. contg., by weight, 0.05 to 0.2% C, 0.05 to 2.0% Si, 0.1 to 2.0%, Mn, 0.001 to 0.1% Al and the balance, and in which the carbon equivalent Ceq=(C+Mn/6+(Cu+Ni)/15+(V+Mo+Cr)/5+5B)% is regulated to 0.42 is cast. This slab is subjected to hot rolling finish rolling is completed within the temp. range of the Ar3 +100 deg.C to the Ar3 -50 deg.C, and it is cooled to the Ar1 +100 deg.C to the Ar1 deg.C at a cooling rate of 2 deg.C/sec. Moreover it is cooled at a cooling rate of >=10 deg.C/sec, an the cooling is stopped at 250 to 450 deg.C. In this way, the steel plate having >=8 mm plate thickness, and in which residual γ of 1.0 to 20% by area ratio is contained in the surface and back layers of at least >=1/8 of the plate thickness can be obtd.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a steel plate for a hull having a thickness of 8 mm or more and a method for manufacturing the same, and more particularly, to a case in which a ship accident such as an oil spill accident caused by a tanker collision occurs. TECHNICAL FIELD The present invention relates to a steel plate for a hull excellent in impact energy absorbing ability that can minimize the destruction of a ship, and a method for manufacturing the same.

[0002]

2. Description of the Related Art In recent years, oil spills due to marine accidents such as tanker collisions and groundings have caused marine pollution, which has become a social problem.

[0003] In a marine accident of a tanker, an oil spill accident is particularly high in a tanker of 60,000 tons or more, and an oil spill accident of a small tanker of 60,000 tons or less is small.

[0004] This is because a small tanker collision does not lead to a large-scale oil spill because the size of the tanker is so small that the colliding tanker moves to reduce the impact and reduce the possibility of a hole in the hull. Conceivable. On the other hand, 6
In the event of a collision of a tanker of 10,000 tons or more, a hole is formed in the hull of the tanker, causing a large-scale oil spill and causing marine pollution (environmental pollution), which is a major social problem.

Therefore, in the recent field of shipbuilding, in order to prevent marine pollution caused by oil spills of tankers,
Techniques are being studied to minimize the destruction of vessels even in the event of a collision, and to minimize damage such as oil spills from tankers and flooding from damaged areas.

As one of the techniques, it is conceivable to prevent the destruction of the hull in the event of a collision of a ship by giving the hull steel plate itself an energy absorbing ability. A steel sheet with improved energy absorption capacity at the time has not yet been proposed.

It is well known that collision safety of automobiles is required except for ships where collision safety is required. The mechanism of energy absorption during collision of automobiles has been studied, and energy at the time of collision is absorbed. Various proposals have been made for the structure of automobiles and steel plates for automobiles. However, at present, almost no studies have been made on the energy absorption capacity at the time of collisions with ships such as tankers from the viewpoint of steel materials.

That is, the mechanism of absorbing the collision energy of an automobile is to absorb energy in a buckling mode under a compressive load. The buckling mode protects the occupant by gently buckling with the section as a node.

On the other hand, the collision energy absorption mechanism of the tanker is schematically shown in FIGS. 1A to 1C as an example of the collision between the tankers as shown in FIG.
When the bow 2 of another tanker collides with the tanker side wall 1, first, as shown in (b), the entirety of the tanker's bow 2 sinks into the flat steel plate 1 on the tanker side wall. Undergoes large bending deformation, and then the steel sheet 1 is stretched to the back and pulled greatly, as shown in (c). If the steel sheet is destroyed (broken) in the course of the collision, an oil spill of the tanker or inundation of seawater may occur.

Therefore, in order to prevent oil spillage or the like from occurring at the time of collision between tankers, when a steel sheet is largely bent at the initial stage of a collision, it must be able to withstand the bending, and then the unbent portion is greatly stretched. Tensile deformation will occur, but it is necessary that the portion be stretched uniformly and not broken.

As described above, in the case of a collision of a tanker, the tank may be deformed. However, if the tanker is broken and broken, no oil spill accident or flood accident occurs.

As described above, automobiles and ships have completely different collision energy absorption mechanisms, and furthermore, in the case of ships, it is essential to weld a steel plate, which is seriously damaged by the hull. In addition, the strength of the welded joint that has a significant effect must be ensured.

For example, the strength of a marine thick steel plate is 350 to 550 MPa from the viewpoint of weldability, but the strength of a thin steel plate of a member for automobile crash safety is 600 to 1000 MPa.
However, since the weldability is poor due to its high strength, it cannot be used in shipbuilding that frequently uses arc welding because of both the problem of softening of the heat-affected zone of the weld and the problem of weld cracking.

[0014] Further, since the steel sheet applied to a member of the automobile which is required to have collision safety is a thin steel sheet, even if the technology relating to this thin steel sheet is applied to a thick steel sheet, the steel sheet is required from the viewpoint of securing the cooling rate. It is difficult to maintain uniformity in the thickness direction. For this reason, there has not been a hull steel plate having a plate thickness of 8 mm or more used for shipbuilding and taking into account the prevention of breakage at the time of collision.

For these reasons, it is impossible to use a steel plate for an automobile having completely different characteristics required for a steel plate as a steel plate for a hull as it is.

[0016]

SUMMARY OF THE INVENTION It is an object of the present invention to provide a steel plate for a hull excellent in impact energy absorbing ability and capable of minimizing the destruction of the hull when a tanker collides, and a method of manufacturing the same.

[0017]

The inventor of the present invention has proposed a steel plate for a hull excellent in impact energy absorption capacity for absorbing a large amount of energy at the time of a collision and preventing the hull from being destroyed. Found that it was necessary. (B) The bent portion has sufficient work hardening, and the subsequent deformation is shared by the parallel portions. (B) Especially in a welded joint portion, a bent portion that is likely to occur mainly is not embrittled by distortion and does not cause brittle fracture. (C) When the parallel portion is stretched, the resistance to the occurrence of ductile cracks is large. (D) When the parallel portion is stretched, the propagation resistance of the ductile crack is large. (E) Having high strength and elongation when the parallel portion is stretched. (F) Sufficient work hardening when the parallel part is stretched.

The present invention is intended to obtain a steel sheet having an improved characteristic (e), which greatly affects the energy absorption capacity at the time of collision, among the above properties (a) to (f). Research on the structure of steel, etc., and as a result, found that as a phenomenon peculiar to thick steel plates, it is possible to effectively improve the impact energy absorption capacity if residual γ is present only in at least the front and back layers of the steel plate, and completed the present invention. .

The gist of the present invention is as follows.

(1) C: 0.05 to 0.2% by weight
%, Si: 0.05 to 2.0%, Mn: 0.1 to 2.0
%, Al: 0.001 to 0.1%, and a carbon equivalent Ceq (= C + Mn / 6 + (Cu + Ni) / 15 +)
(V + Mo + Cr) / 5 + 5B) (%) is 0.42
(%) Or less, and a steel sheet having a thickness of 8 mm or more comprising a balance of Fe and unavoidable impurities, and having an area ratio of 1.0 to 20% in the front and back layers of at least 1/8 or more of the thickness of the steel sheet. A steel plate for hull excellent in impact energy absorption capacity characterized by containing γ.

(2) Further, Nb: 0.0% by weight.
01-0.1% V: 0.001-0.1%, Ti: 0.
001-0.05%, Ta: 0.001-0.1%, C
r: 0.01 to 1.0%, Ni: 0.01 to 1.0%,
Mo: 0.01 to 1.0%, Cu: 0.01 to 1.0%
The steel plate for a hull having excellent impact energy absorbing ability according to the above (1), which comprises one or more of the above.

(3) Further, by weight%, Ca: 0.0
001-0.01%, Mg: 0.0001-0.01
%, REM: 0.001 to 0.05% B: One or more of 0.0001 to 0.001% is contained, (1) or (2) above. A hull steel plate with a thickness of 8 mm or more and excellent in impact energy absorption capacity.

(4) In weight%, C: 0.05-0.2
%, Si: 0.05 to 2.0%, Mn: 0.1 to 2.0
%, Al: 0.001 to 0.1%, and a carbon equivalent Ceq (= C + Mn / 6 + (Cu + Ni) / 15 +)
(V + Mo + Cr) / 5 + 5B) (%) is 0.42
(%) Or less, and a slab composed of the balance of Fe and unavoidable impurities is subjected to hot rolling directly or after heating, and
_{3 + 100 ° C.} The finish rolling was terminated at a temperature range of _{to Ar 3} -50 ° C., then the cooling rate 2 ℃ from any lower temperature of Ar ₃ or the finish rolling temperature to a temperature of Ar ₁ + 100 ℃ ~Ar ₁ ℃ / S, and further cooling at a cooling rate of 10 ° C./s or more, and stopping the cooling in a temperature range of 250 to 450 ° C., producing a hull steel sheet excellent in impact energy absorbing ability. Method.

(5) The slab further contains Nb:
0.001 to 0.1% V: 0.001 to 0.1%, Ti: 0.001 to 0.0
5%, Ta: 0.001 to 0.1%, Cr: 0.01 to
1.0%, Ni: 0.01 to 1.0%, Mo: 0.01
The steel plate for a hull excellent in impact energy absorbing ability according to the above (4), characterized in that it contains one or more of Cu to 0.01% and Cu: 0.01 to 1.0%. Manufacturing method.

(6) The slab further contains Ca:
0.0001-0.01%, Mg: 0.0001-0.
(4) or (5), wherein one or more of REM: 0.001 to 0.05% B: 0.0001 to 0.001% is contained. Method for producing hull steel sheet with excellent impact energy absorption capacity.

[0026]

DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail.

The present inventors have investigated the relationship between the impact energy absorbing capacity of the hull and the mechanical properties of steel.

As a result, the impact energy absorption capacity (EA)
The relationship between the mechanical properties of steel and the elongation properties of steel (E
L) and strength properties (YP, TS) were found to be excellent in order to improve the impact energy absorption capacity (EA). The mechanical properties were evaluated using a U1 test piece in the Rules for Steel Ship Regulations of the Japan Maritime Association.

Generally, the energy absorption until the material breaks can be accurately determined by ∫σdε where σ is the stress and ε is the displacement. However, this is applied to a steel sheet, and the flow stress is obtained as the stress: (YP + TS) / 2 When EL is used as the displacement and elongation at break, the energy absorption can be approximately expressed as (YP + TS) × EL / 2. The fact that the ship-side deformation behavior at the time of a hull collision is governed by the tensile properties of the members is described in T.S. Ishikawa et al. 1
5th International Conference
ance on OMAE, 1996, Book No.
This is as shown in the numerical simulation of destruction in G00987-1996. Therefore, it can be said that the above-mentioned index corresponds to the energy absorbing ability of the steel plate for hull at the time of hull collision. Therefore, the impact energy absorbing ability EA can be expressed by EA = (YP + TS) / 2 × EL.

When the impact energy absorption capacity (EA) of the currently generally used hull steel plate was examined according to the above equation, the EA was about 100 MPa. The goal of the present invention is to improve the impact energy absorption capacity (E
The purpose is to obtain a steel sheet that is at least about 20% or more larger than that of A), that is, has an impact energy absorption capacity of 120 MPa or more.

As apparent from the above equation, the impact energy absorbing ability is greatly affected by the elongation characteristic EL. Therefore, in the present invention, in order to secure the elongation of the steel sheet, the structure of the steel is used as a matrix of the ferrite phase (α). However, steel having a ferrite phase (α) as a matrix has a low yield point (YP) and a low tensile strength (TS), which are strength properties, and therefore cannot increase the impact energy absorbing capacity. Moreover, the strength characteristics YP and TS are the same as the elongation characteristics E.
L is a contradictory property, and it is generally difficult to improve both at the same time.

That is, the elongation characteristics are improved by using a ferrite phase steel as the matrix. However, if the elongation is improved, the strength characteristics such as tensile strength are reduced. Then, there is a limit to the improvement of the impact energy absorbing ability.

Therefore, as a means for increasing the yield point YP + tensile strength TS, which is the strength characteristic, while maintaining the elongation characteristics, attention is paid to finely dispersing the residual γ in the ferrite phase. And so on.

As a technique for improving the balance between strength and elongation in a thin steel sheet, a residual γ steel is known. However, even if this technique is applied to a thick steel sheet having a thickness of 8 mm or more, it is necessary to secure a sufficient cooling rate. It is difficult to maintain uniformity in the thickness direction, and the technology for thin steel sheets cannot be applied as it is. Therefore, in the present invention, a test was conducted to improve the strength properties while maintaining the elongation properties by controlling the presence of residual γ in the thickness direction, which is a particular problem of thick steel sheets. As a result, it has been found that the strength characteristics can be improved if the residual γ is present only in at least the front and back layers of the steel sheet.

In the present invention, a method of measuring the amount of residual γ (area ratio) was performed as follows in order to identify the presence of residual γ.

First, a Z section at a distance a from the steel sheet surface is formed by cutting or cutting, and then the Z section is etched, the etched structure is observed with a microscope, and the residual γ
Confirmed that exists. Next, the area ratio of the residual γ to the entire Z section was measured. The measurement can be performed by point counting, image analysis by a computer, or the like.

According to the above measuring method, the area ratio of the residual γ was measured while changing the position of the distance a from the steel sheet surface, and as shown in FIG. A diagram of the relationship is obtained.

In this manner, the relationship between the distance a from the steel sheet surface and the residual γ area ratio was measured for various steel sheets having different thicknesses t. Based on the measurement result, distance / plate thickness (a
/ T) and the residual γ area ratio F (%) are shown in FIG.
It became as shown in.

Next, in order to improve the strength characteristics of the steel sheet, at least 1% of residual γ is required, and the maximum value is limited to 20%. The thickness was defined as aγ, and the relationship between the maximum thickness aγ and the impact energy absorbing ability EA was determined.

FIG. 4 is a diagram showing the relationship between the maximum thickness aγ and the impact energy absorbing ability EA.

As shown in FIG. 4, aγ is １ ／ of the plate thickness.
(= 0.125) or more, the impact energy absorbing ability is found to be 120 MPa or more which is the target of the present invention.

As described above, in order to make residual γ exist in the steel sheet, a steel material containing a large amount of C, which is an austenite stabilizing element, is used and heated to form a stable γ phase in a high temperature range. Is rapidly cooled to obtain a stable residual γ at room temperature. The limit cooling rate of rapid cooling is 10 ° C /
s, below which no residual γ can be produced.

As is clear from the above test results, if a steel component is selected and at least 1/8 or more of the steel plate thickness contains a residual γ of 1.0 to 20% in area ratio, It was confirmed that a steel sheet having high impact energy absorbing ability was obtained.

Further, by finely dispersing the residual γ in the ferrite matrix, the ductility resistance to fracture can be improved. In other words, in general, the mechanism of ductile fracture of steel material is that when a steel material in which a hard second phase is present in a ferrite matrix is stretched, the hard second phase is not deformed and the area around the second phase is peeled off. Holes (voids)
Is generated, and a large number of voids are generated in the steel material with the second phase as a nucleus. And upon further stretching, a number of voids coalesce, forming a visible crack, which is then usually propagated, resulting in ductile fracture.

However, when the residual γ, which is a nucleus for generating voids, is finely dispersed as a small colony (hardness) as in the present invention, the generation of voids is suppressed and the film is easily stretched and hardly cut.

That is, when the space factor of the finely dispersed residual γ increases, the critical strain at which ductile cracks occur is reduced, and even when the steel plate yields, the deformation of the α phase is restrained and the strength of the steel plate is increased. There is.

Therefore, in order to improve the impact energy absorbing ability and prevent the ductile fracture, the size of the residual γ is preferably 5 μm or less, particularly preferably 3 μm or less in terms of the average particle diameter equivalent to a circle.

Next, the reasons for limiting the components of the steel of the present invention will be described.

C is a gamma phase stabilizing element in a high temperature range and is the cheapest and effective element for increasing the strength of a steel sheet.
5% or more is necessary, but if it exceeds 0.2%, weldability,
It is not preferable because it deteriorates the weld joint toughness. Therefore, C is set to 0.05 to 0.2%. Note that C is 0.0
The content is preferably set to 5 to 0.17%.

Si is required to be 0.05% or more as an element to facilitate deoxidation of steel and generation of a residual γ phase.
If it exceeds 0%, the weldability and the weld joint toughness deteriorate, so the content was made 0.05 to 2.0%.

Mn is required to be 0.1% or more in order to secure the toughness of the steel and to increase the strength, but if it exceeds 2.0%, the weldability is deteriorated. 0%.

Al is the most important element as a deoxidizing element in steel and is required to be 0.001% or more. However, if it exceeds 0.1%, the weldability is deteriorated. did.

The steel of the first invention of the present invention has the above basic components. P, which is an impurity element inevitably contained in the current steelmaking technology, does not need to be particularly restricted, but it has toughness and weldability. From the viewpoint of securing, it is preferably 0.04% or less, more preferably 0.01% or less (including 0%).
Similarly, with respect to S and N, which are impurity elements, from the viewpoint of ensuring toughness and elongation, 0.25% or less (0%).
% And 0.1% or less (including 0%). However, it is desirable that all of these impurity elements are low from the viewpoint of impact energy absorbing ability. However, N may coexist with elements such as Ti to improve the weldability, in which case, for example, 0.002 to 0.
It may be controlled in the range of 006%.

The second invention of the present invention is that one or more selected elements, which are reinforcing components of the base material, are further added to the above basic components.

The reason for limiting the selected element which is the reinforcing component will be described.

Nb is effective for increasing the strength of the base material by adding 0.001% or more. However, if it exceeds 0.1%, the weldability is deteriorated.

V is effective in increasing the strength of the base material when added in an amount of 0.001% or more, but when it exceeds 0.1%, the weldability is deteriorated.

When Ti is added in an amount of 0.001% or more, it is effective to increase the strength of the base material by forming a composite oxide, Ti nitride and the like, but when it exceeds 0.05%, the HAZ toughness is reduced. Since the weldability is deteriorated, the content is set to 0.001 to 0.05%.

Ta is effective in increasing the strength of the base material by adding 0.001% or more, but when it exceeds 0.1%, the weldability is deteriorated.

When Cr is added in an amount of 0.01% or more, the hardenability is improved and the base material is effective in securing the strength. However, if it exceeds 1.0%, the weldability is deteriorated and the low-temperature toughness is also deteriorated. , 0.1 to 1.0%.

Ni is effective in improving the toughness and strength of the base material when added in an amount of 0.01% or more. However, if it exceeds 1.0%, the weldability is deteriorated and the cost is increased.
1.0%.

Mo, when added in an amount of 0.01% or more, is effective in improving the hardenability of the base material and ensuring strength. However, when it exceeds 1.0%, the weldability is deteriorated and the low-temperature toughness is deteriorated. , 0.01 to 1.0%.

When Cu is added in an amount of 0.01% or more, it is effective in increasing the strength of the base material. However, when it exceeds 1.0%, hot cracking is likely to occur and weldability is deteriorated. ~ 1.
0%.

In the present invention, a third invention is to add one or more selective elements for improving elongation of the base material.

The reasons for limiting the selected elements for improving elongation will be described.

When Ca is added in an amount of 0.0001% or more, S that is harmful to elongation is fixed and is effective in improving elongation.
If the content exceeds 0.01%, the weldability deteriorates.
01-0.01%.

Mg is effective in improving elongation by fixing S harmful to elongation by adding 0.0001% or more.
If the content exceeds 0.01%, the weldability deteriorates.
01-0.01%.

REM (rare earth element) is effective in improving elongation by fixing S harmful to elongation by adding 0.001% or more, but when it exceeds 0.05%, weldability is deteriorated and expensive. Therefore, the content was set to 0.001 to 0.05%.

B is an element for improving hardenability,
It is effective at 0.0001% or more, but if it exceeds 0.001%, the weldability deteriorates.
1%.

Further, in the steel of the present invention, the carbon equivalent (Ceq) according to the following equation is an index indicating the effect of the component elements on the hardenability of the welded portion. Sensitivity deteriorates. Therefore, the upper limit is set to 0.
42. If it exceeds this, cracks are likely to occur in the welded portion, and in order to prevent the cracks, preheating and post-heating are required, resulting in a significant increase in cost.

Ceq (%) = C + Mn / 6 + (Cu + N
i) / 15 + (V + Mo + Cr) / 5 + 5B In the present invention, the thickness of the steel plate is limited to 8 mm or more, but this causes a hole in the hull due to the collision of a tanker, causing an oil spill or flooding. A tanker having a tanker size of 60,000 tons or more is required to use a steel plate having a thickness of 8 mm or more, particularly 8 to 25 mm, as a hull steel plate for a tanker of this class from the viewpoint of securing strength and the like. is there. Therefore, in the present invention, the thickness of the steel sheet is set to 8 mm or more. The upper limit of the plate thickness is determined according to the size of the hull.

Next, the production method of the present invention for finely dispersing the residual γ in the ferrite matrix will be described.

Control rolling is effective for finely dispersing the residual γ. That is, after the slab is heated directly or after heating to a temperature of Ac ₃ or more, hot rolling is performed, and the rolling end temperature is set to Ar ₃ +
The temperature range is 100 ° C. to Ar ₃ −50 ° C. This makes the γ grains finer. When the finishing rolling temperature is higher than Ar ₃ + 100 ° C., the γ grains grow and become coarse, and the γ grains cannot be refined. If the temperature is lower than Ar ₃ -50 ° C., the concentration of C, Si, and the like into γ due to generation of fine particles α becomes insufficient, and residual γ is not generated. Therefore, in the present invention, the rolling finishing temperature is set to a temperature range of Ar ₃ + 100 ° C. to Ar ₃ -50 ° C.

Then, after rolling, Ar ₁ + 100 ° C. to Ar ₁
By slow cooling or air cooling at a cooling rate of 2 ° C./s or less to the temperature of
Subsequent quenching yields a steel sheet in which the residual γ is finely dispersed. The reason why the cooling rate is set to 2 ° C./s or less is that ferrite (α) can be stably generated and the amount thereof can be easily controlled. When the temperature exceeds 2 ° C / s, ferrite (α)
Is not preferable because a phase such as bainite is generated instead.

Therefore, in order to set the space factor of ferrite in the structure of steel at 80 to 99%, it is necessary to use Ar ₁ + 100 ° C.
It is necessary to cool to a temperature range of Ar ₁ at a cooling rate of 2 ° C./s or less.

After gradual cooling, the cooling rate was further reduced to 10 ° C. /
s or more to rapidly cool to a stable residual γ. That is, in the coexistence region of the two phases α and γ at a high temperature, the amount of C dissolved in α is limited to a maximum of 0.02%, and excess C is moved into γ. If quenching is performed at a cooling rate of 10 ° C./s or more in this state, residual γ will precipitate.

However, at a cooling rate of less than 10 ° C./s, bainite is formed and no residual γ remains. Further, unless the quenching cooling stop temperature is in the range of 250 to 450 ° C. so as not to cause martensitic transformation, the area ratio of the front and back layers of at least ８ or more of the steel sheet thickness is 1.0 to 2 in terms of area ratio.
0% residual γ cannot be produced. That is, 25
When cooled below 0 ° C., martensitic transformation occurs, and no residual γ is generated. When the temperature exceeds 450 ° C., the temperature inside the steel sheet after cooling is still high, and the residual γ, which is in an unstable state, is decomposed into α and carbide by natural reheating of the steel sheet, and the residual γ disappears. It is because.

[0078]

EXAMPLES Examples of the present invention will be described in comparison with comparative examples.

Table 1 shows the chemical components of the test steel used in the test. In Table 1, steel types A and B correspond to the first invention, steel types CE correspond to the second invention, and steel type F falls within the specified range of the steel composition of the present invention corresponding to the third invention. belongs to.

Using the test steels shown in Table 1, steel sheets were manufactured by hot rolling. Table 2 shows various production conditions at that time. Table 2 also shows the residual γ area ratio and mechanical properties of the obtained steel sheet.

As is clear from Table 2, the steel sheets (Example Nos. 1 to 6) manufactured using the test steels having the steel components within the specified range of the present invention under the manufacturing conditions specified by the present invention are as follows. In any case, at least 1/8 or more of the sheet thickness of the steel sheet contains a residual γ of 1.3 to 14.5% in area ratio in the front and back layers, and an impact energy absorption value of more than 120 MPa
It was 161.3 MPa. In particular, Example No. In No. 4, the residual γ area ratio was as high as 14.5%, and the impact energy absorption value was as high as 161.3 MPa.

On the other hand, in Comparative Example No. which was out of the production conditions specified in the present invention. Nos. 7 to 14 all have a residual γ area ratio of less than 1% and an impact energy absorption value of 93.
It showed only a low value of 0 to 116.0 MPa.

That is, in Comparative Example No. No. 7 has a high finish rolling temperature, and Comparative Example No. 7 Sample No. 8 had low residual γ area ratios of 0.6% and 0.5%, respectively, because the finish rolling temperature was low. Comparative Example No. 9 is 2.5 where the slow cooling rate is 2 ° C./s or more.
° C / s, the residual γ area ratio was as low as 0.5%. Comparative Example No. In Comparative Example No. 10, the cooling stop temperature during slow cooling was high. 11 is a low example,
The residual γ area ratio was as low as 0.7% and 0.7%, respectively. Comparative Example No. In No. 12, the quenching at a cooling rate of 10 ° C./s or more was not performed, so the residual γ area ratio was as low as 0.9%. Then, in Comparative Example No. Comparative Example No. 13 has a high cooling stop temperature during rapid cooling. 14 is an example in which it is low, but the residual γ area ratio was as low as 0.7% and 0.5%, respectively.

As is clear from the above test results, the steel compositions of the present invention satisfying the steel composition and production conditions specified in the present invention all have a residual γ area ratio in the range of 1 to 20%. Also, the impact energy absorbing ability also showed a value of 120 MPa or more, and it was confirmed that the steel plate for a hull had excellent impact energy absorbing ability.

Further, since all of the steel sheets having the steel component specified in the present invention have a carbon equivalent (Ceq) of 0.42 or less, it was confirmed by the oblique Y-type weldability test that they were all good. did it.

[0086]

[Table 1]

[0087]

[Table 2]

[0088]

According to the present invention, it is possible to provide a steel sheet having excellent impact energy absorption capacity of 120 MPa or more. If the steel sheet of the present invention is used for a hull such as a tanker, a collision accident between hulls should be avoided. In the case where hulls occur, it is possible to prevent the hull from breaking and making holes, or to reduce the breaking area as compared with the case of the conventional steel plate.

Therefore, the present invention has excellent effects in terms of environmental protection and safety, such as reduction of marine pollution due to oil spill at the time of a tanker collision accident, or reduction of water infiltration from a collision damaged portion.

[Brief description of the drawings]

FIG. 1 is a diagram schematically showing destruction of a side surface of a tanker at the time of collision between tankers.

FIG. 2 is a diagram showing a relationship between a distance a from a steel sheet surface and a residual γ area ratio F.

FIG. 3 shows distance / plate thickness (a / t) and residual γ area ratio F (%)
FIG.

FIG. 4 is a diagram showing the relationship between the maximum thickness aγ where residual γ exists and the impact energy absorbing ability EA.

[Explanation of symbols]

 1 Side wall of tanker 2 Bow of tanker

Continuing from the front page (72) Inventor Tadashi Ishikawa Oita-shi Nishinosu 1 Nippon Steel Corporation Oita Works Ltd. (72) Inventor Tsuguo Imai 2-6-3 Otemachi, Chiyoda-ku, Tokyo New Nippon Steel Corporation

Claims (6)

[Claims] 1. C .: 0.05 to 0.2% by weight, S
i: 0.05 to 2.0%, Mn: 0.1 to 2.0%, A
l: 0.001 to 0.1%, and carbon equivalent C
eq (= C + Mn / 6 + (Cu + Ni) / 15 + (V +
(Mo + Cr) / 5 + 5B) (%) is 0.42 (%) or less, and the plate thickness of 8 m comprising the balance of Fe and unavoidable impurities
m or more, and at least 1 / th of the thickness of the steel sheet.
A steel plate for a hull excellent in impact energy absorption, characterized in that at least 8 front and back layers contain 1.0 to 20% of residual γ in area ratio. 2. Nb: 0.001 to 1.0% by weight
0.1% V: 0.001 to 0.1%, Ti: 0.001
-0.05%, Ta: 0.001-0.1%, Cr:
0.01-1.0%, Ni: 0.01-1.0%, M
2. The composition according to claim 1, which contains one or more of o: 0.01 to 1.0% and Cu: 0.01 to 1.0%. Hull steel plate. 3. The composition according to claim 1, further comprising:
-0.01%, Mg: 0.0001-0.01%, RE
M: 0.001 to 0.05% B: One or more of 0.0001 to 0.001% is contained, the plate thickness of 8 mm or more according to claim 1 or 2, A hull steel plate with excellent impact energy absorption capacity. 4. C: 0.05 to 0.2% by weight, S
i: 0.05 to 2.0%, Mn: 0.1 to 2.0%, A
l: 0.001 to 0.1%, and carbon equivalent C
eq (= C + Mn / 6 + (Cu + Ni) / 15 + (V +
Mo + Cr) / 5 + 5B) (%) is 0.42 (%) or less, and a slab composed of the balance of Fe and unavoidable impurities is
Direct or after heating, hot rolling is performed and Ar ₃ +100
° C. to Ar ₃ ends the finish rolling within a temperature range of -50 ° C., then, from any lower temperature of Ar ₃ or the finish rolling temperature Ar ₁ + 100 ℃ ~Ar cooling rate 2 ℃ to a temperature of ₁ ° C. / s or less, and further cooling at a cooling rate of 10 ° C./s or more, and stopping cooling in a temperature range of 250 to 450 ° C. . 5. The slab further comprises Nb: 0.0% by weight.
01-0.1% V: 0.001-0.1%, Ti: 0.001-0.0
5%, Ta: 0.001 to 0.1%, Cr: 0.01 to
1.0%, Ni: 0.01 to 1.0%, Mo: 0.01
The steel sheet for a hull having excellent impact energy absorbing ability according to claim 4, wherein the steel sheet contains one or more of Cu to 0.01% and Cu: 0.01 to 1.0%. Production method. 6. The slab further comprises Ca: 0.0% by weight.
001-0.01%, Mg: 0.0001-0.01
%, REM: 0.001 to 0.05% B: 0.0001 to 0.001%, one or more of which are contained, the impact energy absorption according to claim 4 or 5, wherein A method of manufacturing high quality steel plates for hulls.