JPH11124599A - Detergent for hair brush or comb - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a detergent with which a hair brush or a comb can be cleaned by a simple and easy operation in a short time with a small amt. of it used and which enables a hair brush or a comb after cleaning to be moved smoothly through hair by filling an aerosol container with a detergent soln. contg. a surfactant and water and a propellant. SOLUTION: Any type of soap and anonic, cationic, nonionic, and ampholytic surfactants can be used as the surfactant. Water contained in the detergent soln. is not specifically limited. The soln. may further contain an org solvent, which facilitates sebum deposited on a hair brush or a comb to be dissolved and enhances the cleaning power of the soln. The soln. may also contain a mercapto compd., which facilitates the removal of hair twining around a hair brush or a comb. If necessary, a silicone is incorporated into the soln. to further smoothen the movement of a hair brush or a comb through hair.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cleaning agent for a hairbrush or a comb, and more particularly, to a simple operation, a short-time cleaning, and a good cleaning of a hairbrush or a comb after cleaning. And a hair brush or comb cleaning agent.

[0002]

2. Description of the Related Art In general, dirt adhering to a hairbrush, a comb, etc., includes sebum, sweat,
It is thought to be dandruff, dust, hair styling, hair and bacteria, or a mixture thereof. Performing hairdressing with such stains attached is unpleasant and unsanitary. The most convenient means for removing dirt attached to a hairbrush, a comb or the like is a means for wiping with paper, cloth, or the like. However, since the structure of the hairbrush or comb is inevitably made up of fine hairs and teeth, it is difficult to clean the details in this method. It is unsanitary to remove dirt or hair that contains oils of sebum and gets into hairbrush or comb details, and it is a daily experience that it is uncomfortable.

[0003] The difficulty in cleaning hairbrushes, combs and the like depends on their structure. For the purpose of facilitating cleaning, Japanese Patent Application Laid-Open No. 55-163008 discloses a structure of a hairbrush having a hollow structure. Discloses a large number of holes. In the hairbrush described in the publication, tap water is fed through a hollow hairbrush body at the time of washing, and dirt can be removed by the water pressure when the tap water is jetted from the pores. However, this structure cannot be applied to a hairbrush that has already been manufactured, and in order to manufacture a brush having the structure described above, cost increase and brush design due to complexity in the manufacturing process are required. It's not hard to imagine being restricted. Also,
In some cases, the hairbrush is cleaned with a cleaning agent for the purpose of cleaning the hairbrush. Depending on the material of the hairbrush or comb, cleaning with a neutral detergent may be recommended,
Further, Japanese Patent No. 1229217 discloses a cleaning agent for achieving the above object. However,
When cleaning a hairbrush or a comb using the cleaning agent described in the publication, a container capable of immersing the entire hairbrush or the comb is filled with the cleaning agent, and the hairbrush or the like is filled with the cleaning agent for a long time (60 minutes to one hour). Evening) It is necessary to soak and then wash with water. According to such a method, it is possible to wash the details of the hairbrush and the comb, but on the other hand, an extra detergent is required. It is a rather complicated operation to prepare a detergent in a container in which a hairbrush or comb can be immersed, and to immerse the hairbrush or the like in this container for a long time. Therefore, an object of the present invention is to provide a hairbrush or a comb cleaning agent that can be easily operated, can be washed in a short time with a small amount of use, and can further improve the hairbrush and comb combability after washing. is there.

[0004]

Means for Solving the Problems The present inventors have conducted intensive studies to solve the above-mentioned problems, and as a result, have found that a cleaning agent in which a specific cleaning liquid and a propellant are filled in an aerosol container can achieve the above object. I got The present invention has been made based on the above findings, and provides a cleaning agent for a hair brush or a comb, wherein a cleaning solution containing a surfactant and water and a propellant are filled in an aerosol container. Things.

[0005]

BEST MODE FOR CARRYING OUT THE INVENTION The hair brush or comb cleaning agent of the present invention will be described in detail below. The cleaning agent for hairbrush or comb of the present invention is obtained by filling a cleaning solution containing a surfactant and water and a propellant into an aerosol container. The surfactant contained in the cleaning liquid is not particularly limited, and any of soaps, anionic surfactants, cationic surfactants, nonionic surfactants, and amphoteric surfactants may be used. it can. Examples of the above soaps include fatty acid salts such as oleate, stearate, linoleate and linolenate. Examples of the anionic surfactant include alkyl benzene sulfonate, alkyl naphthalene sulfonate, alkyl sulfate, polyoxyethylene alkyl ether sulfate, dialkyl sulfosuccinate, N-alkyl sulfosuccinate, and alkyl methyl tauride. , Alginate, polystyrene sulfonate and N-acyl-N-
Methyl-β-alanine sodium and the like. Examples of the cationic surfactant include polyoxyethylene alkylamine, cationized cellulose, alkyl quaternary ammonium salt, primary, secondary or tertiary alkylamine, and polyoxyethylene added amine. Examples of the nonionic surfactant include polyethylene glycol, polypropylene glycol, poly (ethylene glycol) (propylene glycol) copolymer, polyoxy (ethylene) (propylene) glycol, higher alcohol, polyoxyethylene fatty acid ester, and polyoxyethylene alkyl. Ether, polyoxyethylene alkylphenol ether, polyoxy (ethylene) (propylene) alkyl ether, fatty acid polyhydric alcohol ester, polyoxyethylene addition amide, amine oxide, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyacetylene and its alkyl ether, N-alkylpyrrolidone, polyoxyethylene sorbitol fatty acid ester,
Mono- and di-fatty acid glycerides and the like. Examples of the amphoteric surfactant include linear alkyl betaine, alkyl-N-carboxyalkyl-N-hydroxyethylimidazolinium betaine, and fatty acid amidopropyldimethylaminoacetate betaine.

The above surfactant may be used alone,
Alternatively, two or more kinds may be used as a mixture. The content of the surfactant in the cleaning solution is preferably 70% by weight or less, more preferably 50% by weight or less, further preferably 25% by weight or less, and most preferably 10% by weight.
It is as follows. Further, the content of the surfactant is preferably 0.001% by weight or more, more preferably 0.01% by weight in the cleaning solution.
It is at least 1% by weight, more preferably at least 0.1% by weight, further preferably at least 0.3% by weight, most preferably at least 1.0% by weight. When the content of the surfactant exceeds 70% by weight, the surfactant may easily remain after the hairbrush or comb is washed with water, and when the content is less than 0.001% by weight, a sufficient cleaning effect is obtained. May not be possible. In this specification, "in the cleaning solution" is described as
It means the concentration in the components excluding the weight of the propellant from the contents to be filled in the aerosol container. The water contained in the washing liquid is not particularly limited, and purified water, distilled water, tap water, and the like can be used. The water content in the washing liquid is preferably 60% by weight or more, more preferably 70% by weight or more, and still more preferably 8% by weight or more.
It is at least 0% by weight, most preferably at least 85% by weight. The water content is preferably 99.5% by weight.
Or less, more preferably 99% by weight or less, and most preferably 98% by weight or less.

[0007] The washing liquid may contain builders as required. Since the hairbrush or comb stains contain calcium deposited and attached to the hair and the like during hair washing, it is particularly effective to use builders that chemically mask the calcium. It is also known that calcium deposited on hair impairs combability of hairbrushes and combs, and the addition of builders also has the effect of making it easier to remove hair entangled with hairbrushes and combs. Examples of the builders include phosphoric acid and phosphonic acid such as phosphoric acid, polyphosphoric acid, hexametaphosphoric acid, 1-hydroxyethylidene-1,1-diphosphonic acid, and aminotrimethylenephosphonic acid, or two or more molecules thereof are dehydrated and condensed. Condensates; glycine, cystine, cysteine, asparagine, aspartic acid, alanine, arginine, isoleucine, glutamine, glutamic acid, serine, thyroxine, tyrosine, tryptophan, threonine, valine, histidine, hydroxyproline, hydroxylysine, phenylalanine, proline, methionine, Lysine, leucine, iminodiacetic acid, dihydroxyethylglycine, hydroxyethyliminodiacetic acid, nitrilotriacetic acid, ethylenediaminetetraacetic acid, hydroxyethylethylenediaminetriacetic acid, diethylenetol Amine fifth such as acetic acid and triethylenetetraminehexaacetic acid, -N in the molecule
Compounds having a -CH-COOH group; silicic acids such as silicic acid and metasilicic acid; carbonic acid, picolinic acid, dipicolinic acid,
Examples include, but are not limited to, magnesium silicate, gluconates, zeolites, and the like.

[0008] Among the above builders, acidic compounds can be used in the form of their salts. Such salts include, for example, lithium, sodium, magnesium, aluminum, potassium, ammonium, mono, di, tri or tetraalkyl ammonium salts, mono, di, tri or tetra (2-hydroxyethyl) salts. ) Ammonium salts, mono, di, tri or tetra (2-hydroxypropyl) ammonium salts, mono, di,
Examples include, but are not limited to, tri- or tetra (3-hydroxypropyl) ammonium salts, morpholinium salts, pyridinium salts, piperidinium salts, and the like. The above builders may be used alone or as a mixture of two or more. Further, the condensate may be a condensate of the same molecule or a cross-condensate such as a condensate of phosphoric acid and 1-hydroxyethylidene-1,1-diphosphonic acid. In the present invention, among the above builders, -N-CH-COOH is contained in the molecule.
It is preferable to use a compound having a group. The content of the builder in the washing solution is preferably 40% by weight or less, more preferably 30% by weight or less, further preferably 20% by weight or less, and most preferably 15% by weight or less. Further, the content of the above builders is preferably 0.01% by weight or more, more preferably 0.05% by weight or more, further preferably 0.1% by weight or more, more preferably 0.01% by weight or more, in the washing liquid. Is at least 1% by weight, most preferably at least 3% by weight.

Further, the above-mentioned washing solution may contain a compound having a mercapto group in the molecule, if necessary. The compound having a mercapto group cuts a cystine bond that is often present in hair and softens the hair,
The removal of the hair entangled with the hairbrush or the comb can be facilitated. The compound having a mercapto group in the molecule is not particularly limited, but a carboxylic acid having a mercapto group in the molecule is preferable, and examples thereof include thioglycolic acid, thiomalic acid, and salts thereof. Examples of the salt include a lithium salt, a sodium salt, a magnesium salt, an aluminum salt, a potassium salt,
Ammonium salts, mono, di, tri or tetraalkyl ammonium salts, mono, di, tri or tetra (2-hydroxyethyl) ammonium salts, mono, di, tri or tetra (2-hydroxypropyl) ammonium salts and mono,
Examples include, but are not limited to, di, tri or tetra (3-hydroxypropyl) ammonium salts. The compound having a mercapto group in the molecule may be used alone or in combination of two or more. The content of the compound having a mercapto group in the molecule is, in the washing solution,
Preferably it is 60% by weight or less, more preferably 50% by weight.
% By weight, more preferably 40% by weight or less, and most preferably 35% by weight or less. The content of the compound having a mercapto group in the molecule is preferably 0.01% by weight or more, more preferably 0.05% by weight or more, and still more preferably 0.1% by weight in the washing solution. Or more, more preferably 1% by weight or more, and most preferably 3% by weight or more.

[0010] The washing liquid may contain an organic solvent, if necessary. By thus containing an organic solvent, the solubility of sebum deposited and adhered to the hairbrush or comb can be increased, and the cleaning performance can be improved. The organic solvent is not particularly limited,
For example, saturated and unsaturated hydrocarbons such as hexane, cyclohexane, hexene, octane, octene, isooctane, nonane, nonene, decane and decene; petroleum fractions such as gasoline, ligroin, kerosene and gas oil; benzene, toluene, xylene, cumene And aromatic compounds such as methylnaphthalene, ethylnaphthalene, pseudocumene, mesitylene, pyridine, picoline and nitrobenzene; methanol, ethanol, propanol, isopropanol, butanol, sec-butanol, tert-butanol, amyl alcohol, isoamyl alcohol, active amyl alcohol and Alcohols such as benzyl alcohol; polyhydric alcohols such as ethylene glycol, propylene glycol, butylene glycol, glycerin, pentanediol and hexylene glycol Lumpur like; ethyl ether, methyl ethyl ether, dipropyl ether, diethylene glycol, diethylene glycol monomethyl ether,
Diethylene glycol dimethyl ether, diethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol monobutyl ether, diethylene glycol dibutyl ether, ethylene glycol monophenyl ether, ethylene glycol monomethyl ether, ethylene glycol dimethyl ether, ethylene glycol monoethyl ether, ethylene glycol diethyl ether, ethylene glycol monobutyl ether , Ethylene glycol dibutyl ether, tetrahydrofuran, dioxane, propylene glycol monomethyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether, propylene glycol mono-tert-butyl ether, trifluoropropylene Ethers such as glycol methyl ether, propylene glycol methyl ether acetate, propylene glycol ethyl ether acetate, ethylene glycol ethyl ether acetate, 3-methyl-3-methoxybutanol and 3-methyl-3-methoxybutyl ether acetate; acetone, methyl ethyl ketone, methyl Ketones such as isopropyl ketone, diisopropyl ketone, cyclopentanone, cyclohexanone, acetylacetone, acetophenone and propiophenone; ethyl formate, propyl formate, butyl formate, amyl formate, methyl acetate, ethyl acetate, diethylene glycol monomethyl acetate, diethylene glycol monoethyl acetate , Ethyl acetoacetate, esters such as monoacetin, diacetin and triacetin; formamide Amides such as monomethyl formamide and dimethylformamide; dimethyl sulfoxide, and sulfoxides such as sulfolane; methylene chloride, chloroform, carbon tetrachloride, trichloroethane, trichlorethylene, bromoform,
Halides such as tetrachloroethylene, chlorobenzene and bromobenzene; and the like, but are not limited thereto.

The above organic solvents may be used alone or as a mixture of two or more. The content of the organic solvent in the washing solution is preferably 90% by weight or less,
It is more preferably at most 70% by weight, further preferably at most 60% by weight, further preferably at most 50% by weight, most preferably at most 30% by weight. Also,
The content of the organic solvent is preferably 0.01 in the washing solution.
% By weight, more preferably 0.05% by weight or more, still more preferably 0.1% by weight or more, further preferably 1% by weight or more, and most preferably 3% by weight or more.

Further, the above-mentioned cleaning liquid may contain a compound having lubricity as required. By including such a compound having lubricity, it is possible to further improve the combability of the hairbrush or comb. As the compound having lubricity, for example,
Polysiloxanes (silicone) such as polydimethylsiloxane, polyphenylmethylsiloxane, dimethylsiloxane-phenylmethylsiloxane copolymer, amino-modified silicone oil, epoxy-modified silicone oil and fatty acid-modified silicone oil; camellia oil, tung oil, olive oil, castor oil, etc. Examples include, but are not limited to, natural fats and oils. The above compounds having lubricity may be used alone or in combination of two or more. Further, it is preferable to use silicone as the compound having lubricity. The content of the compound having lubricity in the cleaning solution is preferably 80% by weight or less, more preferably 60% by weight or less, further preferably 50% by weight or less, and further preferably 40% by weight.
Or less, and most preferably 30% by weight or less. Further, the content of the compound having lubricating property is, in the cleaning liquid,
Preferably it is 0.01% by weight or more, more preferably 0.01% by weight.
It is at least 05% by weight, more preferably at least 0.1% by weight, even more preferably at least 1% by weight, most preferably at least 3% by weight.

In the hair brush or comb cleaning agent of the present invention, an antifoaming agent is added to the cleaning liquid, and the foam retention time after the cleaning liquid is sprayed from an aerosol container to form bubbles is adjusted. Is also good. The defoaming agent is not particularly limited, and for example, an activator-type defoaming agent such as polyoxyalkyl glycol alkyl ether, polyoxyalkyl glycol alkyl ester and polyoxyethylene polyoxypropylene block copolymer; machine oil, silicone An antifoaming agent in which a powder such as silica gel or celite is dispersed in oils such as oil or natural fats and oils, and those obtained by emulsifying them in water. In addition, a commercially available antifoaming agent can be used. The above-mentioned antifoaming agents may be used alone or in combination of two or more.

In the case where the washing liquid is sprayed in the form of a foam and held on a hair brush or a comb for a certain period of time and then washed with water, the content of the defoamer is preferably 20% by weight or less in the washing liquid. It is preferably at most 15% by weight, more preferably at most 10% by weight, further preferably at most 5% by weight, most preferably at most 3% by weight.
In this case, the content of the defoaming agent in the cleaning solution is preferably 0.001% by weight or more, more preferably 0.1% by weight.
It is at least 01% by weight, more preferably at least 0.1% by weight, even more preferably at least 0.3% by weight, and most preferably at least 1% by weight. Also, spray the cleaning liquid,
When the removal of dirt is promoted by utilizing the physical force, the content of the defoaming agent in the cleaning liquid is preferably 40% by weight or less, more preferably 30% by weight or less, It is more preferably at most 20% by weight, more preferably at most 15% by weight, most preferably at most 10% by weight. In this case, the content of the defoaming agent in the cleaning liquid is preferably 0.01% by weight or more, more preferably 0.03% by weight or more, and further preferably
It is at least 0.5% by weight, more preferably at least 1% by weight, most preferably at least 2% by weight. In this case, it is preferable to use dimethyl ether as a propellant described later.

As the propellant used in the hair brush or comb cleaning agent of the present invention, conventionally known propellants can be used without any particular limitation. Examples thereof include liquefied hydrocarbon gas, dimethyl ether, carbon dioxide gas, nitrogen gas, and argon gas. Examples include gas, compressed air, and HFC-based gas represented by 134a. The propellant may be used alone,
Alternatively, two or more kinds may be used as a mixture. Among the above propellants, liquefied hydrocarbon gas, nitrogen gas, argon gas and compressed air have the effect of increasing the foaming property of the injected cleaning liquid. In addition, dimethyl ether and carbon dioxide gas have an effect of suppressing foaming when sprayed. By combining these effects with the above-described defoaming effect of the defoaming agent, it is possible to arbitrarily adjust the retention time of bubbles formed when the cleaning liquid is sprayed. The content of the propellant is such that the pressure in the container at 25 ° C. when the aerosol container is filled together with the above-mentioned cleaning liquid containing the surfactant and water is preferably 9 atm or less, more preferably 8 atm.
m, more preferably 7 atm or less, more preferably 6 atm or less, most preferably 5.5 atm or less. The content of the propellant is such that the pressure in the container at 25 ° C. when filled in the aerosol container together with the cleaning liquid is preferably 0.05 atm or more, more preferably 0.1 atm or more. Amount, more preferably
0.5 atm or more, more preferably 1.0 atm
The amount is at least 1.5 atm, most preferably at least 1.5 atm.

As the aerosol container used in the hair brush or comb cleaning agent of the present invention, any conventionally known aerosol container can be used without any limitation, for example, a steel can (including tin plating and TFS etc.), an aluminum can, a duralumin Cans and glass bottles. The size of the aerosol container to be used is not particularly limited, and one having an inner volume of 30 ml to 450 ml is generally used.

In the case where the cleaning liquid is sprayed in the form of a foam and is held on a hairbrush or comb for a certain period of time and then washed with water,
The above-mentioned antifoaming agent and builder or the like are contained in the cleaning liquid comprising the above-mentioned surfactant and water, or the amount of the propellant is adjusted, and the retention time of foam formed when the cleaning liquid is jetted is set to an appropriate range. It is preferable to adjust to. In such a case, the holding time of the foam is such that the cleaning liquid filled in the aerosol container is sprayed for 10 seconds to form a foam, and the time until the volume of the foam becomes 1/2 immediately after the spraying is preferably used. The time is 5 seconds or more, more preferably 10 seconds or more, further preferably 15 seconds or more, further preferably 20 seconds or more, and most preferably 30 seconds or more. Further, the time is preferably 6 minutes or less, more preferably 5 minutes or less, further preferably 4 minutes or less, further preferably 3 minutes or less, and most preferably 2 minutes or less.

[0018]

EXAMPLES The present invention will be described more specifically with reference to the following examples, but the present invention is not limited to the following examples. [Examples 1 to 11] A cleaning liquid was prepared by dissolving or dispersing the formulation shown in Table 1 below in water, and then the cleaning liquid and LPG (liquefied hydrocarbon gas; 3.0 at
m, 20 ° C.) into a test steel spray container (100 ml) so that the concentration of LPG was 15% by weight, to obtain a hair brush or comb cleaning agent of the present invention. The numbers in the table represent the concentration (% by weight) in the cleaning liquid containing no propellant. The concentration of the propellant is a concentration based on the total weight of the propellant and the cleaning liquid. When the component is a salt, it is expressed as a concentration as an anhydrous salt.
The pressure inside the aerosol container is also shown.

[0019]

[Table 1] Example 1 2 3 4 5 6 7 8 9 10 11 AES 5.0 5.0 5.0 TWEEN 5.0 5.0 5.0 OLE.M 5.0 5.0 5.0 TMAL 5.0 5.0 EX 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Pressure (atm) 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2

Examples 12 to 22 The same procedure as in Examples 1 to 11 was carried out except that the following formulation shown in Table 2 was used to obtain a hair brush or comb cleaning agent of the present invention.

[0021]

[Table 2] Example 12 13 14 15 16 17 18 19 20 21 22 AES 5.0 5.0 5.0 TWEEN 5.0 5.0 5.0 OLE.M 5.0 5.0 TMAL 5.0 5.0 5.0 EDTA 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 HEDP 0.5 0.5 EX 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 MMB 5.0 5.0 5.0 5.0 5.0 5.0 PDMS 3.0 3.0 Pressure (atm) 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2

Examples 23 to 32 The same procedure as in Examples 1 to 11 was carried out except that the formulations shown in Table 3 below were used, to obtain a hair brush or comb cleaning agent of the present invention.

[0023]

[Table 3] Example 23 24 25 26 27 28 29 30 32 33 AES 5.0 5.0 TWEEN 5.0 5.0 OLE.M 5.0 5.0 5.0 TMAL 5.0 5.0 5.0 EDTA 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 HEDP 0.5 0.5 EX 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 MMB 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 PDMS 3.0 3.0 3.0 3.0 3.0 3.0 TGMA 10.0 10.0 10.0 10.0 Pressure (atm) 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2

[Examples 33 to 36] A 7: 3 (vol./vol.) Mixture of dimethyl ether and liquefied hydrocarbon gas (3.0 atm, 20 ° C.) in place of LPG using the formulation shown in Table 4 below. Was used in the same manner as in Examples 1 to 11 except that the concentration was adjusted to 15% to obtain a hair brush or comb cleaning agent of the present invention.

[0025]

[Table 4] Example 33 34 35 36 AES 5.0 TWEEN 5.0 OLE.M 5.0 TMAL 5.0 EDTA 5.0 5.0 5.0 5.0 EX 0.2 0.2 0.2 0.2 MEG 5.0 5.0 5.0 5.0 PDMS 3.0 3.0 3.0 3.0 Pressure (atm) 3.2 3.2 3.2 3.2

Examples 37 to 40 Examples 1 to 1 were repeated except that dimethyl ether was used in place of LPG so as to have a concentration of 25% using the formulation shown in Table 5 below.
The same operation as in Example 1 was carried out to obtain a hair brush or comb cleaning agent of the present invention.

[0027]

[Table 5] Example 37 38 39 40 AES 5.0 TWEEN 5.0 OLE.M 5.0 TMAL 5.0 EDTA 5.0 5.0 5.0 5.0 EX 0.2 0.2 0.2 0.2 MMB 5.0 5.0 5.0 5.0 MEG PDMS 3.0 3.0 3.0 3.0 pressure(atm) 3.2 3.2 3.2 3.2

Examples 41 to 48 The same procedure as in Examples 1 to 11 was carried out except that the following formulation shown in Table 6 was used to obtain a hair brush or comb cleaning agent of the present invention.

[0029]

[Table 6] Example 41 42 43 44 45 46 47 48 AES 5.0 5.0 TWEEN 5.0 5.0 OLE.M 5.0 5.0 TMAL 5.0 5.0 EDTA 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 EX 0.1 0.1 0.1 0.1 0.5 0.5 0.5 0.5 MMB 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MEG PDMS 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Pressure (atm) 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2

[Examples 49 to 52] The same procedure as in Examples 1 to 11 was carried out except that the following formulation shown in [Table 7] was used, to obtain a hair brush or comb cleaning agent of the present invention.

[0031]

[Table 7] Example 49 50 51 52 AES 5.0 TWEEN 5.0 OLE.M 5.0 TMAL 5.0 EDTA 5.0 5.0 5.0 5.0 HEDP EX 0.2 0.2 0.2 0.2 MMB MEG 5.0 5.0 5.0 5.0 PDMS 3.0 3.0 3.0 3.0 pressure(atm) 3.2 3.2 3.2 3.2

[Comparative Examples 1 to 4] Example 1 was repeated except that the formulation shown in Table 8 below was used and the concentration of LPG was 10%.
The same operation as in Examples 11 to 11 was performed to obtain a hair brush or comb cleaning agent.

[0033]

[Table 8] Comparative Example 1 2 3 4 EDTA 5.0 MMB 5.0 5.0 MEG 5.0 PDMS 5.0 pressure(atm) 3.2 3.2 3.2 3.2

The abbreviations used in the above [Table 1] to [Table 8] mean the following. AES = Sodium polyoxyethylene (20) alkyl ether sulfate TWEEN = Polyoxyethylene (20) sorbitan oleate OLE.M = Morpholine oleate soap TMAL = Lauryl betaine EDTA = Trisodium ethylenediaminetetraacetate HEDP = 1-Hydroxyethylidene- 1,1-Diphosphonic acid trisodium EX = Pronal EX3000 (manufactured by Toho Chemical Co., Ltd .; silicone type antifoaming agent) MMB = 3-methyl-3-methoxybutanol MEG = ethylene glycol monomethyl ether PDMS = polydimethylsiloxane (1000cs) TGMA = thioglycolic acid monoethanolamine

[Evaluation of Hairbrush or Comb Detergent] (1) Detergency The same standard in which the hairbrush or comb detergent obtained in Examples 1 to 52 and Comparative Examples 1 to 4 was used for hair for 3 days. Was sprayed on three plastic hairbrushes, and after 3 minutes, washed with standing water, and the remaining stains were evaluated according to the following evaluation criteria. A: The cleanability was extremely good. ：: About 10% of stains remained, but cleanability was generally good. Δ: About 10 to 30% of stains remained. X: 30% or more of the stains remained. (2) Comb-like The brush washed in (1) was completely dried with a dryer, and the hair was brushed. The result was evaluated according to the following evaluation criteria. The judgment was performed by three judges using a brush one by one, and the results were comprehensively judged. A: Very good. ：: good. Δ: There is some resistance, but it can be used. X: Strong sense of resistance.

(3) Defoaming time The cleaning agent for hair brush or comb obtained in the above Examples 1 to 52 and Comparative Examples 1 to 4 was sprayed into a measuring cylinder for 10 seconds, and the volume of the foam was reduced immediately after the spraying. The time until it became 1/2 was visually judged. The results were shown by the following evaluation criteria. Direct: Time required for the volume of the foam to become 1/2 immediately after injection is 5
Seconds. 1: The time until the volume of the foam becomes 1/2 immediately after the injection is 5
It took more than one second and less than one minute. 2: The time until the volume of the foam becomes 1/2 immediately after the injection is 1
More than 2 minutes. 3: Time required for the volume of the foam to be １ ／ immediately after the injection is 2
More than 4 minutes. 4: The time until the volume of the foam becomes 1/2 immediately after the injection is 4
Minutes exceeded. The results of the above evaluation are shown in [Table 9] (Examples 1 to 24) and [Table 1].
0] (Examples 25 to 44) and [Table 11] (Example 45)
To 52 and Comparative Examples 1 to 4).

[0037]

[Table 9] Example Detergency As a comb Defoaming time 1 ○ △ 52 2 ○ △ 53 3 ○ △ 54 ○ △ 55 5 ○ △ 46 ○ △ 47 ○ △ 38 ○ △ 49 ○ ○ 4 10 ○ △ 411 ○ △ 412 ○ △ 413 ○ ◎ 314 ○ ○ 315 ○ ◎ 416 ○ ○ 217 ◎ ◎ 118 ◎ ○ 2 19 ○ ◎ 3 20 ◎ ○ 221 ◎ ◎ 222 ◎ ◎ 2 23 ◎ ◎ 4 24 ◎ ◎ 2

[0038]

[Table 10] Example Detergency According to the comb, defoaming time 25 ◎ ○ 326 ◎ ○ 227 ○ ○ 1 28 ○ ○ 229 ◎ ◎ 230 ◎ ◎ 231 ◎ ◎ 332 ◎ ◎ 233 ◎ ◎ ◎ 1 34 ◎ ◎ 135 ◎ ◎ 236 ◎ ◎ 1 37 ◎ ◎ Straight 38 ◎ ◎ Straight 39 ◎ ◎ Straight 40 ◎ ◎ Straight 41 ◎ ◎ 4 42 ◎ ◎ 4 43 ◎ ◎ 4 44 ◎ ◎ ◎ 4

[0039]

[Table 11] Example Detergency According to the comb, defoaming time 45 ◎ ◎ 146 ◎ ◎ 1 47 ◎ ◎ 1 48 ◎ ◎ 1 49 ◎ ◎ 3 50 ◎ ◎ 3 51 ◎ ◎ 2 52 ◎ ◎ 2 Comparative Example 1 × × Straight 2 × × straight 3 × × straight 4 × × straight

Comparative Example 5 Sodium polyoxyethylene (20) alkyl ether sulfate was dissolved in water to a concentration of 0.2% by weight to obtain a hair brush or comb detergent. In the obtained cleaning agent, a plastic hairbrush 3 of the same standard as that used in the evaluation of Examples 1 to 52 and Comparative Examples 1 to 4 was used.
The book was immersed for 4 minutes, washed with water, and evaluated for the detergency and comb as described above in [Evaluation of Hairbrush or Comb Detergent]. The results of the evaluation are shown in [Table 12]. Comparative Example 6 Sodium polyoxyethylene (20) alkyl ether sulfate was dissolved in water to a concentration of 0.5% by weight to obtain a hair brush or comb detergent. In the obtained cleaning agent, three plastic hairbrushes of the same standard as those used in the evaluations of Examples 1 to 52 and Comparative Examples 1 to 4 were immersed for 4 minutes, washed with water, and washed with the above-mentioned [hair brush or comb cleaning] Evaluation of Detergent] was evaluated in terms of detergency and combability. The results of the evaluation are shown in [Table 12].

[0041]

[Table 12] Comparative example Detergency 5 × × 6 × ×

As is clear from the results shown in Tables 9 to 12, the cleaning agent for a hairbrush or comb of the present invention in which a cleaning solution containing a surfactant and water and a propellant were filled in an aerosol container. When the hairbrush (or comb) was washed by using, the cleaning property was better than that of the cleaning agents of Comparative Examples 1 to 6, and the comb of the hairbrush was better after washing.

[0043]

The cleaning agent for hairbrushes or combs of the present invention is simple in operation, can wash the hairbrushes or combs in a short time, and further improves the combability of the hairbrushes or combs after washing. is there. In addition, the hairbrush or comb cleaning agent of the present invention does not require dipping the hairbrush or comb to be cleaned in the cleaning agent, so that the amount of the cleaning agent used can be reduced.

Claims (5)

[Claims] 1. A cleaning agent for a hairbrush or a comb, wherein a cleaning solution containing a surfactant and water and a propellant are filled in an aerosol container. 2. The hair brush or comb cleaning agent according to claim 1, which contains an organic solvent. 3. The hair brush or comb cleaning agent according to claim 1, which contains a compound having a mercapto group in the molecule. 4. The hair brush or comb cleaning agent according to claim 1, which comprises silicone. 5. The cleaning solution filled in the aerosol container is sprayed for 10 seconds to form a foam, and the time required for the volume of the foam to be １ ／ immediately after the spraying is 6 minutes or less.
The cleaning agent for hair brushes or combs according to any one of claims 1 to 4.