JPH11115339A - Manufacture of support for lithographic printing plate, support for lithographic printing plate, and photo-sensitive lithographic printing plate - Google Patents

Manufacture of support for lithographic printing plate, support for lithographic printing plate, and photo-sensitive lithographic printing plate

Info

Publication number
JPH11115339A
JPH11115339A JP28640197A JP28640197A JPH11115339A JP H11115339 A JPH11115339 A JP H11115339A JP 28640197 A JP28640197 A JP 28640197A JP 28640197 A JP28640197 A JP 28640197A JP H11115339 A JPH11115339 A JP H11115339A
Authority
JP
Japan
Prior art keywords
roll
printing plate
lithographic printing
rollers
pair
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP28640197A
Other languages
Japanese (ja)
Other versions
JP3804032B2 (en
Inventor
Seiichi Sugano
清一 菅野
Jiro Fukushima
二郎 福島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Okamoto Chemical Industry Co Ltd
Original Assignee
Okamoto Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Okamoto Chemical Industry Co Ltd filed Critical Okamoto Chemical Industry Co Ltd
Priority to JP28640197A priority Critical patent/JP3804032B2/en
Publication of JPH11115339A publication Critical patent/JPH11115339A/en
Application granted granted Critical
Publication of JP3804032B2 publication Critical patent/JP3804032B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To make the surface smooth and easy to slip in despite of having a roughtened surface of a proper degree, and also, prevent sponge residue from arising by a method wherein in the middle of a process, a process wherein a printing plate is pressed from both surfaces by a pair of rollers is inserted at least at one location. SOLUTION: In the middle of a process wherein the surface of an aluminum plate is mechanically ground and/or electrochemically ground, and then, chemically ground, and an anode oxidation treatment is performed, a process wherein both surfaces are pressed by a pair of rollers is inserted at least at one location. That is, for the pair of the rollers, a roll which touches the grinding surface is made a metal roll or a resin roll of which the hardness based on a JISK6301 spring type hardness test is 90 deg. or higher. Also, the rear surface roll is a rubber roll of which the hardness is 50-90 deg., and a pressure pressed by the pair of the rollers from both surfaces is made 0.8 kg/cm or higher per roll width. In addition, the diameter of the pair of the rollers is made 100-300 mm, and the treatment is performed by changing the peripheral velocity of the rollers to be within ±10% based on the carrying speed of the aluminum plate.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、平版印刷版用支持
体の製造方法、該方法により得られた支持体及び該支持
体を用いた感光性平版印刷版に関するものである。詳し
くはアルミニウム板よりなる平版印刷版用支持体の製造
方法、該方法により得られた支持体及び該支持体を用い
た感光性平版印刷版に関するものである。
The present invention relates to a method for producing a lithographic printing plate support, a support obtained by the method, and a photosensitive lithographic printing plate using the support. More specifically, the present invention relates to a method for producing a lithographic printing plate support made of an aluminum plate, a support obtained by the method, and a photosensitive lithographic printing plate using the support.

【0002】[0002]

【従来の技術】従来、平版印刷版用支持体として、アル
ミニウム又はアルミニウム合金が広く使用されている。
そして、アルミニウム支持体の上に設けられる感光層と
の密着性を良好にし、かつ、アルミニウム支持体から製
造される平版印刷版の非画像部の保水性を改善すること
を目的とし、アルミニウム支持体の表面は、平均粗さR
aにして0.3〜1.0μm程度の粗面化処理がされて
いる。該粗面化(砂目立て)方法としては、ボール研
磨、ブラシ研磨、バフ研磨、ブラスト研磨等の機械的研
磨(粗面化)方法と、電解研磨と称される電気化学的粗
面化方法、あるいは化学的研磨(粗面化)方法、さらに
はこれらの研磨方法を組み合わせた方法等がある。
2. Description of the Related Art Conventionally, aluminum or aluminum alloy has been widely used as a support for a lithographic printing plate.
In order to improve the adhesiveness with the photosensitive layer provided on the aluminum support, and to improve the water retention of the non-image portion of a lithographic printing plate manufactured from the aluminum support, the aluminum support Has an average roughness R
The surface is roughened to a thickness of about 0.3 to 1.0 μm. Examples of the roughening (graining) method include mechanical polishing (roughening) methods such as ball polishing, brush polishing, buff polishing, and blast polishing, and electrochemical roughening method called electrolytic polishing. Alternatively, there are a chemical polishing (roughening) method, a method combining these polishing methods, and the like.

【0003】これらの研磨(砂目立て)方法の中では平
版印刷版用支持体としての性能に優れ、かつまた大量生
産に優れるという点からブラシ研磨による粗面化方法ま
たは電気化学的粗面化方法およびこの2種類の方法を組
み合わせた粗面化方法が有利である。しかし、これらの
方法には、それぞれ次のような問題点があった。
[0003] Among these polishing (graining) methods, the surface roughening method by brush polishing or the electrochemical surface roughening method is excellent in terms of excellent performance as a lithographic printing plate support and excellent in mass production. And a roughening method combining these two methods is advantageous. However, each of these methods has the following problems.

【0004】ブラシ研磨では、ナイロンブラシのような
ブラシの毛先と研磨材により、表面が複雑にかきむしら
れたような個所ができたり、アルミニウムが切削されず
に盛り上がったようなバリ状の鋭い突起が出来たり、あ
るいは局部的に深く鋭い凹部ができる場合がある。それ
によりアルミニウム版の取扱いの際に表面が傷つきやす
かったり、感光液を塗布する時に、鋭い突起のために感
光液がはじいたり、塗布ムラが生じたりする。更に、感
光液が塗布された感光性印刷版(PS版)においても、
該PS版同士がこすれ合った時に、突起部分がキズ付い
たり、感光膜が剥がれる等の問題点があった。
In the brush polishing, the bristles of a brush such as a nylon brush and an abrasive are used to form a portion where the surface is complicatedly scraped, or a burr-like sharp projection such that aluminum is raised without being cut. Or a locally deep and sharp recess may be formed. As a result, the surface of the aluminum plate is easily damaged when handling the aluminum plate, and when the photosensitive solution is applied, the photosensitive solution repels due to sharp projections, or application unevenness occurs. Furthermore, in a photosensitive printing plate (PS plate) coated with a photosensitive liquid,
When the PS plates rub against each other, there are problems such as scratches on the projections and peeling of the photosensitive film.

【0005】一方、電気化学的粗面化(電解研磨)方法
においても、電解研磨した時に発生するスマットを取り
除くために、強度のアルカリ剤等による化学的研磨(エ
ッチング)が必要であり、この時にエッチングによる部
分的に鋭く尖った所がアルミニウム面上にでき、そのた
め、アルミニウム表面が傷付いたり、スポンジ等でこの
版面上を拭いた時に、スポンジが鋭く尖った所にひっか
かり、スムースに移動できなかったり、スポンジカスが
版面上に残るなどの問題点があった。
On the other hand, also in the electrochemical surface roughening (electropolishing) method, chemical polishing (etching) using a strong alkaline agent or the like is necessary in order to remove smut generated at the time of electrolytic polishing. Partially sharp points are formed on the aluminum surface by etching, so when the aluminum surface is scratched, or when this plate surface is wiped with a sponge, the sponge gets stuck on the sharp point and cannot be moved smoothly. And the sponge residue remains on the printing plate.

【0006】また、上記のブラシ研磨のような機械的研
磨と電解研磨および化学的研磨を組合わせた粗面化方法
においても、これらの問題点を解消することはできなか
った。平版印刷版用支持体は、上記のような粗面化処理
の後、陽極酸化処理、親水化処理などが行われ、その都
度、水洗工程が組み込まれて製造されている。そして、
各処理間には、通常、上下一対のローラーで仕切られて
おり、使用されているローラーは、研磨面を傷つけない
ように柔らかいゴムロールとか柔らかいスポンージロー
ルなどが用いられ、ロール間の圧力は、各処理液が液切
れ出来る程度に軽く掛けられている。
[0006] In addition, these problems cannot be solved by a roughening method combining mechanical polishing such as the above-mentioned brush polishing, electrolytic polishing and chemical polishing. The lithographic printing plate support is subjected to anodizing treatment, hydrophilization treatment and the like after the above-mentioned surface roughening treatment, and is manufactured by incorporating a water washing step each time. And
Between each treatment, a pair of upper and lower rollers are usually used, and the rollers used are soft rubber rolls or soft sponge rolls so as not to damage the polished surface. It is hung lightly enough to drain the liquid.

【0007】このような時に用いられるロールは、例え
ば1200〜1500mm幅の場合で、硬度は70度前
後で、自重圧で掛けられるかあるいはロールがしならな
い程度の重量(50kg以下)を掛けて用いられている
ので、研磨処理で出来た砂目表面の鋭い突起物を平らに
することは出来ない。また、アルミニウムを処理中、角
度を変えるために、変換ロールを使用し、全圧力が数百
kgの張力で引く場合があるが、この場合にはロールと
アルミニウム板との接面積が大きいため、アルミニウム
表面に出来た鋭い突起などを直すことは出来ない。
[0007] The roll used in such a case is, for example, 1200 to 1500 mm wide, has a hardness of about 70 degrees, and is applied under its own weight or with a weight (50 kg or less) that does not allow the roll to be applied. Therefore, it is not possible to flatten the sharp protrusions on the grain surface formed by the polishing process. Also, during the processing of aluminum, in order to change the angle, using a conversion roll, the total pressure may be pulled with a tension of several hundred kg, but in this case, the contact area between the roll and the aluminum plate is large, It is not possible to fix sharp protrusions on the aluminum surface.

【0008】[0008]

【発明が解決しようとする課題】本発明の目的は、適度
の粗面化表面を有しているにもかかわらず、表面が滑ら
かで、滑りやすく、そのために表面が傷付きにくく、上
記のようなスポンジカスが発生しない平版印刷版用支持
体の製造方法及びその様にして得られたアルミニウム支
持体を提供するものである。さらに別の目的は、感光液
の塗布ムラやハジキがなく、印刷版として用いた場合
に、耐刷性や汚れにくさにおいて優れた感光性平版印刷
版を提供するものである。
SUMMARY OF THE INVENTION An object of the present invention is to provide a smooth and slippery surface despite having a moderately roughened surface. An object of the present invention is to provide a method for producing a lithographic printing plate support which does not generate any sponge scum and an aluminum support thus obtained. Still another object is to provide a photosensitive lithographic printing plate which is free from unevenness or cissing of a photosensitive solution and which is excellent in printing durability and resistance to contamination when used as a printing plate.

【0009】[0009]

【課題を解決するための手段】本発明者らは、平版印刷
版用支持体を製造する際、上記のような研磨後の数々の
処理工程の途中に用いられる搬送ロールや仕切りロール
部分に強い圧力を加え、更にロール径などをある数値以
下にして、ロールとアルミニウム板との接面積を小さく
することによって、アルミニウム表面の鋭角な凸部を丸
くすることが出来ることを見出し本発明に至ったもので
ある。
The present inventors have found that when manufacturing a lithographic printing plate support, the present invention has a strong resistance to a transport roll or a partition roll used during the various processing steps after polishing as described above. By applying pressure, further reducing the roll diameter and the like to a certain value or less, and reducing the contact area between the roll and the aluminum plate, it was found that the sharp projections on the aluminum surface could be rounded, and the present invention was reached. Things.

【0010】本発明は、アルミニウム板の表面を機械的
研磨および/または電気化学的研磨、次いで化学的研
磨、陽極酸化処理を行う平版印刷用支持体の製造方法お
よびそのようにして得られた支持体において、前記諸工
程の途中に、少なくとも一ヶ所以上、一対のローラーに
て両面より圧する工程を入れることを特徴とする平版印
刷版用支持体の製造方法及びその様にして得られた支持
体を提供するものであり、前記一対のローラーにおい
て、研磨表面に来るロールが、金属ロールまたはJIS K
6301スプリング式硬さ試験に基づく硬度90度以上の樹
脂ロールとし、裏面ロールが硬度50〜90度のゴムロ
ールであり、前記一対のローラーにて両面より圧する圧
が、ロール幅当たり0.8kg/cm以上であり、前記
一対のローラーの径は100〜300mmとし、当該ロ
ーラーの周速度をアルミニウム板の搬送速度に対して±
10%以内に変化させて処理する平版印刷版用支持体の
製造方法であり、さらにその様にして得られた支持体に
感光性組成物を塗設した感光性平版印刷版を提供するも
のである。
[0010] The present invention provides a method for producing a lithographic printing support in which the surface of an aluminum plate is subjected to mechanical polishing and / or electrochemical polishing, followed by chemical polishing and anodic oxidation treatment, and the support thus obtained. A method for producing a support for a lithographic printing plate, characterized by including a step of pressing from both sides with a pair of rollers, at least one place in the middle of the above steps, and the support thus obtained. In the pair of rollers, the roll coming to the polishing surface is a metal roll or JIS K
A resin roll having a hardness of 90 degrees or more based on a 6301 spring-type hardness test, a back roll being a rubber roll having a hardness of 50 to 90 degrees, and a pressure applied from both sides by the pair of rollers is 0.8 kg / cm per roll width. That is, the diameter of the pair of rollers is 100 to 300 mm, and the peripheral speed of the rollers is ±
A method for producing a lithographic printing plate support which is processed by changing the content to 10% or less, and further provides a photosensitive lithographic printing plate obtained by coating a photosensitive composition on the support thus obtained. is there.

【0011】[0011]

【発明の実施の形態】以下、本発明の実施形態について
順を追って詳しく説明する。本発明に使用されるアルミ
ニウム板はアルミニウムを主成分とする純アルミニウム
や微量の異原子を含むアルミニウム合金等の板状体であ
る。このような異原子には、珪素、鉄、銅、マンガン、
マグネシウム、ニッケル、亜鉛、チタンなどがある。本
発明に適用されるアルミニウム板は、その組成が特定さ
れるものでなく、従来公知、公用の素材のものを利用す
ることができる。本発明に用いられるアルミニウム板の
厚さは、およそ0.1〜0.4mm程度が好適である。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of the present invention will be described in detail in order. The aluminum plate used in the present invention is a plate-shaped body such as pure aluminum containing aluminum as a main component or an aluminum alloy containing a trace amount of foreign atoms. Such heteroatoms include silicon, iron, copper, manganese,
There are magnesium, nickel, zinc, titanium and the like. The composition of the aluminum plate applied to the present invention is not specified, and a conventionally known and publicly available material can be used. The thickness of the aluminum plate used in the present invention is preferably about 0.1 to 0.4 mm.

【0012】アルミニウム板は、圧延時に表面に付着し
た油分を除去するため、例えば、界面活性剤やアルカリ
水溶液により脱脂処理が行われる。次いで、水洗の後、
粗面化処理が行われ、粗面化方法としては、機械的に表
面を粗面化する方法、電気化学的に表面を粗面化する方
法およびこの両者を組み合わせた方法がある。機械的に
表面を粗面化する方法としては、ブラシ研磨、ボール研
磨法、ブラスト研磨法等と称される公知の方法を用いる
ことができるが、特にブラシ研磨法が大量生産の場合に
有利である。また電気化学的に表面を粗面化する方法
(電解研磨)としては、塩酸または硝酸電解液中で交流
または直流により行う方法がある。
The aluminum plate is subjected to a degreasing treatment with, for example, a surfactant or an aqueous alkali solution in order to remove oil adhering to the surface during rolling. Then, after washing with water,
A roughening treatment is performed, and as a roughening method, there are a method of mechanically roughening the surface, a method of electrochemically roughening the surface, and a method of combining both. As a method for mechanically roughening the surface, a known method called brush polishing, ball polishing, blast polishing, or the like can be used. In particular, the brush polishing is advantageous in mass production. is there. As a method of electrochemically roughening the surface (electropolishing), there is a method of performing alternating or direct current in a hydrochloric acid or nitric acid electrolytic solution.

【0013】このように粗面化されたアルミニウム板
は、水洗され、アルカリエッチングのような化学的研磨
(エッチング)が行われる。アルカリエッチングに使用
するアルカリ剤は、水酸化ナトリウム、水酸化カリウ
ム、第三燐酸ナトリウム、第三燐酸カリウム、アルミニ
ウムン酸ナトリウム、炭酸ナトリウム、メタケイ酸ナト
リウム、オルトケイ酸ナトリウム、グルコン酸ナトリウ
ムなどが挙げられ、これらの単独液あるいは二種以上の
混合液を用いることができる。
The aluminum plate thus roughened is washed with water and subjected to chemical polishing (etching) such as alkali etching. Examples of the alkali agent used for alkali etching include sodium hydroxide, potassium hydroxide, sodium tertiary phosphate, potassium tertiary phosphate, sodium aluminate, sodium carbonate, sodium metasilicate, sodium orthosilicate, sodium gluconate and the like. These can be used alone or as a mixture of two or more.

【0014】アルカリエッチング液の濃度は、1〜60
重量%が好ましく、30〜100℃の液温において、2
〜60秒間処理し、0.5〜13g/m2 エッチングす
る。エッチングを行う方法としては、アルミニウム板を
エッチング液浴に浸漬する方法、スプレーやノズルでエ
ッチング液をかける方法などがある。上記アルカリエッ
チングをした後、水洗し、必要に応じて硝酸、燐酸、硫
酸またはこれらの二種以上の酸を含む混酸でデスマット
するか、あるいは単なる水洗、場合によっては高圧力水
洗を行ってスマット除去を行う。
The concentration of the alkaline etching solution is 1 to 60.
% By weight, and at a liquid temperature of 30 to 100 ° C., 2% by weight.
Treated 60 seconds, 0.5~13g / m 2 is etched. As a method of performing etching, there is a method of immersing an aluminum plate in an etching solution bath, a method of applying an etching solution with a spray or a nozzle, and the like. After the above alkali etching, washing with water, desmutting with nitric acid, phosphoric acid, sulfuric acid or a mixed acid containing two or more of these acids as needed, or smut removal by simple washing with water or high pressure washing in some cases I do.

【0015】ブラシ研磨と電解研磨を併用する場合に
は、ブラシ研磨の後アルカリエッチングし、次いで、電
解研磨し、アルカリエッチングする工程を行う。当然な
がら、各処理間には必ず水洗工程を入れて処理を行う。
When the brush polishing and the electrolytic polishing are used in combination, a step of performing an alkaline etching after the brush polishing, and then performing an electrolytic polishing and an alkali etching is performed. As a matter of course, the treatment is always performed by inserting a water washing step between each treatment.

【0016】以上の各処理および水洗の前後には、液切
りのために、必ず一対のローラー等で仕切られており、
本発明はこの仕切りローラーあるいはその後の少なくと
も一ヶ所以上の個所において、圧ロールを設置し、表面
に出来た突起物を潰すことにより表面を滑らかにする方
法である。
Before and after each of the above treatments and washing with water, the liquid is always separated by a pair of rollers or the like for drainage.
The present invention is a method of smoothing the surface by installing a pressure roll at this partition roller or at least at one or more locations thereafter and crushing protrusions formed on the surface.

【0017】本発明の圧ロールに掛けられる圧力として
は、ロール幅当たり0.8kg/cm以上であり、上限
は使用するロールによっても異なるが、ロール受け軸が
破壊したり、ロールがしなかったり、アルミニウムを圧
延する程の圧は好ましくない。圧する圧力が、ロール幅
当たり0.8kg/cm未満の場合には、表面に出来た
突起物を潰すことが出来ないので好ましくない。圧は、
エヤーシリンダーまたは油圧等によって加えられるが、
ロールの自重が十分重い場合には、自重圧でも良い。
The pressure applied to the pressure roll of the present invention is 0.8 kg / cm or more per roll width, and the upper limit varies depending on the roll used, but the roll receiving shaft may break or the roll may not roll. However, the pressure at which aluminum is rolled is not preferable. If the pressing pressure is less than 0.8 kg / cm per roll width, it is not preferable because the protrusions formed on the surface cannot be crushed. The pressure is
Added by air cylinder or hydraulic pressure etc.
When the roll's own weight is sufficiently heavy, its own weight pressure may be used.

【0018】アルミニウム表面に接する上ロールは、金
属ロールまたは硬度90度以上の樹脂ロールが好まし
い。なお、本願明細書における硬度とは、JIS K 6301ス
プリング式硬さ試験に記載する試験方法により試験機A
形を用いて得た数値である。上記金属ロールとは、一般
的には鉄および鉄合金のクロームメッキ仕立てのものが
使用できる。また、硬度90度以上の樹脂ロールに加工
できる樹脂としては、ポリアセタール樹脂、テフロン樹
脂、フェノール樹脂、ポリカーボネート樹脂、高分子ポ
リエチレン樹脂、ウレタン樹脂、ナイロン樹脂、エボナ
イトなどが挙げられ、硬度の上限としては100度であ
る。
The upper roll in contact with the aluminum surface is preferably a metal roll or a resin roll having a hardness of 90 degrees or more. The hardness in the specification of the present application refers to a tester A according to a test method described in JIS K 6301 spring hardness test.
It is a numerical value obtained using the shape. As the metal roll, a roll made of chrome plating of iron or an iron alloy can be generally used. Examples of the resin that can be processed into a resin roll having a hardness of 90 degrees or more include polyacetal resin, Teflon resin, phenol resin, polycarbonate resin, high-molecular polyethylene resin, urethane resin, nylon resin, ebonite, and the like. 100 degrees.

【0019】アルミニウムの裏面に接する下ロールとし
ては、硬度90度以下のゴムロールが望ましい。より好
ましくは、80〜50度である。硬度が90度をこえる
と、上下共に硬くなるので、液切れが悪くなり、硬度が
50度未満の場合には、上から圧力をかけても下のロー
ルにめり込んで、表面を平らにすることが出来なくなる
ので好ましくない。下ロール用のゴムロールの材質とし
ては、スチレンゴム、ニトリルゴム、ネオプレンゴム、
シリコンゴム、ブチルゴム、天然ゴムなどが挙げられ
る。
As the lower roll in contact with the back surface of aluminum, a rubber roll having a hardness of 90 degrees or less is desirable. More preferably, it is 80 to 50 degrees. When the hardness exceeds 90 degrees, both upper and lower sides become hard, so the liquid drainage becomes worse, and when the hardness is less than 50 degrees, even if pressure is applied from the top, it is sunk into the lower roll to flatten the surface It is not preferable because it becomes impossible. Materials for the rubber roll for the lower roll include styrene rubber, nitrile rubber, neoprene rubber,
Silicone rubber, butyl rubber, natural rubber and the like can be mentioned.

【0020】上記圧ロールの径は、300mm以下が好
ましく、より好ましくは250〜100mmである。径
が300mmをこえると、アルミニウム板との接面積が
大きくなり、圧を掛けても表面の小さな突起物を潰すこ
とが出来ず、100mm未満の場合には、ロールがしな
り、中心部の圧が弱くなり、突起物を潰すことが出来
ず、また液切れも悪くなるので好ましくない。
The diameter of the pressure roll is preferably 300 mm or less, more preferably 250 to 100 mm. If the diameter exceeds 300 mm, the contact area with the aluminum plate increases, and even if pressure is applied, small projections on the surface cannot be crushed. Is weakened, and the protrusions cannot be crushed, and the running out of liquid becomes worse.

【0021】上記圧ロールの周速度は、処理するアルミ
ニウム板の搬送速度に対して、±10%以内に速度を変
化させると、圧ロールとアルミニウム板との間に僅かな
ズレが生じ、表面の突起物をよりきれに潰すことが出来
る。速度変化が±10%をこえると、逆にズレ幅が大き
くなり、表面にキズが発生するので好ましくない。より
好ましい範囲としては、±5%以内である。
If the peripheral speed of the pressure roll is changed within ± 10% of the conveying speed of the aluminum plate to be processed, a slight displacement occurs between the pressure roll and the aluminum plate, and The protrusions can be crushed more clearly. If the speed change exceeds ± 10%, on the contrary, the deviation width becomes large and the surface is flawed, which is not preferable. A more preferred range is within ± 5%.

【0022】以上のように処理されたアルミニウム板
は、表面の耐摩耗性や印刷時の保水性や耐刷性をアップ
させる目的で陽極酸化処理される。この時使用される電
解質としては、一般に硫酸、燐酸、シュウ酸、クロム酸
あるいはこれらの混酸が用いられる。
The aluminum plate treated as described above is subjected to anodizing for the purpose of improving the abrasion resistance of the surface, the water retention during printing and the printing durability. As the electrolyte used at this time, sulfuric acid, phosphoric acid, oxalic acid, chromic acid or a mixed acid thereof is generally used.

【0023】陽極酸化の処理条件は用いる電解質により
種々かわるので特性し得ないが、一般的には電解質の濃
度が1〜50重量%、液温は5〜45℃、電流密度が1
〜40A/dm2 、電圧5〜50Vおよび処理時間5秒
〜5分の範囲ならば好適である。陽極酸化皮膜の量は
0.5g/m2 以上が好適であるが、より好ましくは
1.0〜4.0g/m2 の範囲である。陽極酸化皮膜が
0.5g/m2 未満の場合には、表面に傷がつき易くな
り、印刷時に、傷の部分にインキが付着して、汚れにな
り易くなる。また逆に陽極酸化皮膜が4.0g/m2
こえると、現像速度が遅くなり、感度の低下が生じるの
で好ましくない。
The anodic oxidation treatment conditions vary depending on the electrolyte used and thus cannot be set. However, in general, the concentration of the electrolyte is 1 to 50% by weight, the liquid temperature is 5 to 45 ° C., and the current density is 1%.
~40A / dm 2, it is preferable if the voltage 5~50V and processing time of 5 seconds to 5 minutes range. The amount of the anodized film is suitably 0.5 g / m 2 or more, but more preferably in the range of 1.0~4.0g / m 2. When the anodic oxide film is less than 0.5 g / m 2 , the surface is apt to be scratched, and at the time of printing, the ink adheres to the scratched portion, and is likely to be stained. Conversely, if the thickness of the anodic oxide film exceeds 4.0 g / m 2 , the developing speed becomes slow and sensitivity is lowered, which is not preferable.

【0024】上記のように陽極酸化処理され、水洗され
たアルミニウム板は、必要に応じて親水化または不活性
化のために沸騰水処理、水蒸気処理、珪酸塩処理、燐酸
塩処理あるいは親水性高分子化合物を含有する水溶液中
への浸漬処理等を行うことができる。このようにして得
られたアルミニウム板には、常法に従って感光性組成物
を設けて感光性平版印刷版を得ることができる。
The aluminum plate which has been anodized and washed as described above may be subjected to a boiling water treatment, a steam treatment, a silicate treatment, a phosphate treatment or a hydrophilic treatment for hydrophilization or deactivation as required. Dipping treatment in an aqueous solution containing a molecular compound can be performed. The photosensitive plate can be obtained by providing a photosensitive composition on the thus obtained aluminum plate according to a conventional method.

【0025】ここで適用される感光性組成物は、特に限
定されるものでなく、一般的に周知のものが適用でき、
例えば、o−キノンジアジド化合物を主成分とするポジ
型のもの、ジアゾ樹脂を主成分とするネガ型のもの、不
飽和二重結合含有モノマーを主成分とする光重合性化合
物、桂皮酸またはジメチルマレイミド基を含む光架橋性
化合物のもの、あるいはヒートモード書込み型化合物な
どを感光物とするネガまたはポジ型のものが用いられ
る。また特開昭55−161250号、特開平4−10
0052号等に記載の電子写真感光層や物理現像核層と
ハロゲン化銀乳剤層を設けた銀錯塩拡散転写法を利用し
た感光層も使用することができる。
The photosensitive composition applied here is not particularly limited, and generally known photosensitive compositions can be applied.
For example, a positive type having an o-quinonediazide compound as a main component, a negative type having a diazo resin as a main component, a photopolymerizable compound having an unsaturated double bond-containing monomer as a main component, cinnamic acid or dimethylmaleimide A photo-crosslinkable compound containing a group, or a negative or positive type using a heat mode writing type compound as a photosensitive material is used. JP-A-55-161250, JP-A-4-10
No. 0052 and the like, and a photosensitive layer using a silver complex salt diffusion transfer method provided with a physical development nucleus layer and a silver halide emulsion layer can also be used.

【0026】上記感光性組成物は、通常、水、有機溶剤
またはこれらの混合物の溶液として、本発明による支持
体上に塗布して、乾燥されて感光性平版印刷版が作成さ
れるが、本発明の支持体上に塗布される感光性組成物の
塗布量が1〜5g/m2 の場合には、総ての塗布液は、
均一にきれいに塗布される。
The above photosensitive composition is usually applied as a solution of water, an organic solvent or a mixture thereof on the support according to the present invention and dried to prepare a photosensitive lithographic printing plate. When the coating amount of the photosensitive composition applied on the support of the invention is 1 to 5 g / m 2 , all the coating solutions are
It is applied uniformly and neatly.

【0027】[0027]

【実施例】以下、本発明を実施例により更に詳細に説明
するが、本発明はこれに限定するものではない。なお、
実施例に記載された硬度とは、JIS K 6301に記載するス
プリング式硬さ試験方法によりA形試験機を用いて得た
数値である。表面粗さに関して、平均粗さRaは通常の
中心線平均粗さを示し、最大山高さRpは粗さ曲線(断
面曲線)の中心線と最高山頂の間隔を意味する。従っ
て、最大山高さRpは、粗さ曲線の最高山頂と最深谷底
の間隔であるRmax とは異なる。
EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. In addition,
The hardness described in the examples is a value obtained by a spring type hardness test method described in JIS K 6301 using an A-type testing machine. Regarding the surface roughness, the average roughness Ra indicates a normal center line average roughness, and the maximum peak height Rp means a distance between the center line of the roughness curve (cross-sectional curve) and the highest peak. Therefore, the maximum peak height Rp is different from Rmax , which is the distance between the highest peak and the deepest valley of the roughness curve.

【0028】実施例1、比較例1 厚さ0.24mm、幅1000mmのアルミニウム板を
良く脱脂、水洗したのち、ナイロンブラシとパーミスト
ンの水懸濁液を用いて、その表面をブラシ研磨し、水洗
した。次いで、15重量%水酸化ナトリウムに80℃で
10秒間浸漬してアルカリエッチングし、水洗の後、2
0重量%硝酸70℃で10秒間酸洗浄してから水洗し
た。この水洗水の水切りロール用として、上下共に幅1
200mm、ロール径120mm、自重45kg、硬度
65度のニトリルゴムを使用し、かける圧は自重程度の
幅当たり0.4kg/cmで水切りした。その後で、上
ロールとして、幅1200mm、ロール径180mm、
自重120kgの鉄ロールにクロームメッキした金属ロ
ールを用い、下ロールは、上ロールと同じ幅と径を有す
る硬度70度の天然ゴムロールを用い、エヤーシリンダ
ーで圧を全重量250kg掛けた。この時の圧は、ロー
ル幅当たり2kg/cm強になった。また、この時の上
下ロールの周速度は、アルミニウム板の搬送速度より、
5%遅くして回転させた。このようにして処理した支持
体を実施例1(基板I)とする。
Example 1 and Comparative Example 1 An aluminum plate having a thickness of 0.24 mm and a width of 1000 mm was thoroughly degreased and washed with water, and then its surface was polished with a nylon brush and an aqueous suspension of permiston, and the surface thereof was polished and washed with water. did. Next, the substrate was immersed in 15% by weight sodium hydroxide at 80 ° C. for 10 seconds to perform alkali etching.
Acid washing was performed for 10 seconds at 70% by weight of 0% by weight nitric acid, followed by water washing. The width of the top and bottom is 1
Nitrile rubber having a diameter of 200 mm, a roll diameter of 120 mm, its own weight of 45 kg, and a hardness of 65 degrees was used, and the applied pressure was 0.4 kg / cm per width of its own weight. Then, as an upper roll, width 1200mm, roll diameter 180mm,
A chrome-plated metal roll was used for an iron roll having its own weight of 120 kg, and a natural rubber roll having a hardness of 70 degrees and the same width and diameter as the upper roll was used as a lower roll, and a pressure of 250 kg was applied by an air cylinder to a total weight. The pressure at this time was slightly over 2 kg / cm per roll width. Also, the peripheral speed of the upper and lower rolls at this time is more
Rotated 5% slower. The support thus treated is referred to as Example 1 (substrate I).

【0029】なお、上記水切りロールを通った後、圧ロ
ールを掛けず、圧ロールをパスして作製した支持体を比
較例1(基板II)とする。その後、(基板I)、(基板
II)を15重量%硫酸水溶液中で陽極酸化処理を行い、
水洗の後乾燥した。この時の陽極酸化皮膜厚は2.0g
/m2 であった。この時の(基板I)、(基板II)の表
面粗さを測定し、平均粗さRaと最大山高さRpの数値
で表1に示す。また、表面を電子顕微鏡(SEM)によ
る3000倍での観察した様子を表1に示す。表1よ
り、基板IのRp値が低いことは、鋭く突起した個所が
少ないことを示している。
After passing through the draining roll, the support produced by passing the pressure roll without applying the pressure roll is referred to as Comparative Example 1 (substrate II). Then, (Substrate I), (Substrate I)
II) is anodized in a 15% by weight aqueous sulfuric acid solution,
After washing with water, it was dried. The thickness of the anodic oxide film at this time is 2.0 g
/ M 2 . The surface roughness of (substrate I) and (substrate II) at this time was measured, and the values of the average roughness Ra and the maximum peak height Rp are shown in Table 1. Table 1 shows how the surface was observed at a magnification of 3000 with an electron microscope (SEM). From Table 1, the fact that the Rp value of the substrate I is low indicates that there are few sharply protruding portions.

【0030】このようにして作製した(基板I)、(基
板II)に下記組成の感光液(1)を乾燥後の塗布重量が
1.8g/m2 となるように塗布して感光層を設けた。 感光液(1) ナフトキノン−1,2−ジアジド−5−スルホニルクロライドと 2,3,4−トリヒドロキシベンゾフェノンとのエステル化物 2.5g m−クレゾール・ホルムアルデヒドノボラック樹脂 6.0g ナフトキノン−1,2−ジアジド−4−スルホニルクロライド 0.1g オイルブルー613(オリエント化学工業社製) 0.2g メチルセロソルブ 50g プロピレングリコールモノメチルエーテル 50g この時の(基板I)、(基板II)の感光液塗布状況を表
1に示す。
The thus prepared (substrate I) and (substrate II) were coated with the photosensitive solution (1) having the following composition so that the coating weight after drying was 1.8 g / m 2 to form a photosensitive layer. Provided. Photosensitive solution (1) Esterified product of naphthoquinone-1,2-diazido-5-sulfonyl chloride and 2,3,4-trihydroxybenzophenone 2.5 g m-cresol-formaldehyde novolak resin 6.0 g naphthoquinone-1,2- Diazido-4-sulfonyl chloride 0.1 g Oil Blue 613 (manufactured by Orient Chemical Industries) 0.2 g Methyl cellosolve 50 g Propylene glycol monomethyl ether 50 g At this time, the coating conditions of (substrate I) and (substrate II) with the photosensitive solution are shown in Table 1. Shown in

【0031】[0031]

【表1】 [Table 1]

【0032】(基板I)および(基板II)から得られた
感光性平版印刷版に網点及び細線を有するポジ原稿フィ
ルムを密着し、光源として3kwメタルハライドランプ
を使用し、距離1mより40秒間照射することにより露
光した。この露光済みの感光性平版印刷版を、市販され
ている現像液(シルバンポジ現像液No.4、岡本化学工業
社製、主成分として水酸化カリウムと珪酸ナトリウムお
よび水から成る現像液)の10倍希釈液で25℃で30
秒間浸漬現像した。得られた平版印刷版を用いて、校正
刷り並びに印刷機により印刷を行い、下記の評価方法に
よりスポンジ適性、耐刷性、汚れ性において評価を行っ
た。その結果を表2に示す。
A positive original film having halftone dots and fine lines is adhered to the photosensitive lithographic printing plate obtained from (Substrate I) and (Substrate II), and a 3 kW metal halide lamp is used as a light source, and irradiation is performed from a distance of 1 m for 40 seconds. Exposure was performed. The exposed photosensitive lithographic printing plate is 10 times as large as a commercially available developer (Sylvan Positive Developer No. 4, a developer consisting of potassium hydroxide, sodium silicate and water as main components, manufactured by Okamoto Chemical Industry Co., Ltd.). 30 at 25 ° C with diluent
Immersion development was performed for 2 seconds. Using the obtained lithographic printing plate, proof printing and printing with a printing machine were performed, and evaluation was made on sponge suitability, printing durability, and stain resistance by the following evaluation methods. Table 2 shows the results.

【0033】〔スポンジ適性の評価〕校正機上に(基板
I)および(基板II)から得られた印刷版を置き、水を
含んだスポンジで前後左右数回擦った。 ○:表面の滑り性が良く、スポンジカスがでない。 △:スポンジカスは出ないが、表面の滑り性が悪い。 ×:表面の滑り性が悪く、スポンジカスがでる。
[Evaluation of Sponge Suitability] The printing plates obtained from (Substrate I) and (Substrate II) were placed on a proofing machine, and rubbed several times back and forth and right and left with a sponge containing water. :: The surface has good slipperiness and no sponge residue. Δ: No sponge scum appeared, but the surface slippage was poor. ×: Poor surface slipperiness, sponge scum appears.

【0034】〔耐刷性の評価〕(基板I)および(基板
II)から得られた印刷版をオフセット印刷機にかけ、約
2万部刷った後、画像部を評価する。 ○:画像部には何ら異常なく、インキの乗りも良く、高
耐刷性が見込まれる。 ×:画像部のベタ部に、非常に細かいが、画像が剥がれ
て砂目が見える個所が有り、印刷物中、その部分がピン
ホール状にヌケている。
[Evaluation of Printing Durability] (Substrate I) and (Substrate I)
The printing plate obtained in II) is set on an offset printing machine, and after printing about 20,000 copies, the image area is evaluated. :: There is no abnormality in the image area, ink is well applied, and high printing durability is expected. ×: There is a very fine portion in the solid portion of the image portion, but there is a portion where the image is peeled and a grain is visible, and the portion is missing in a pinhole shape in the printed matter.

【0035】〔汚れ性の評価〕(基板I)および(基板
II)から得られた印刷版をオフセット印刷機にかけ、2
万部刷った後、非画像部を評価する。 ○:非画像部には何ら異常なく、点々状の汚れもない。 ×:非画像部の細かい一部に、表面が摩耗して光ってい
る所があり、その部分が点々状に汚れる。
[Evaluation of Contamination] (Substrate I) and (Substrate I)
The printing plate obtained from II) is set on an offset printing machine,
After printing all copies, the non-image portions are evaluated. :: There is no abnormality in the non-image portion, and there is no dot-like stain. ×: A part of the non-image portion is shining due to abrasion on the surface, and the portion is stained dotted.

【0036】[0036]

【表2】 [Table 2]

【0037】実施例2、比較例2 実施例1と同様にアルミニウム板を、ブラシ研磨とアル
カリエッチングした後、実施例1と同じ圧ローラーで、
同じように圧を掛け、次いで1N塩酸浴中で200クー
ロン/dm2 で電解研磨した。水洗の後、実施例1と同
じ組成でアルカリエッチングし、水洗後、水切りロール
と兼用に硬度95度の樹脂ロールを上ロールに用い、下
ロールには硬度70度のニトリルゴムロールを用いて、
全重量100kg圧で、幅1cm当たり0.8kg加え
た。この上下ロールの周速度は、アルミニウム板の搬送
速度より、5%早くして回転させた。このように2回の
圧ロールを掛けて処理した支持体を実施例2(基板III)
とする。これら2回の圧ロールを掛けず、圧ロールをパ
スして処理した支持体を比較例2(基板IV)とする。そ
の後、(基板III)、(基板IV)を実施例1と同じように
陽極酸化処理し、水洗乾燥した。この時の(基板III)、
(基板IV)の表面粗さを測定し、平均粗さRaと最大山
高さRpの数値で表1に示す。また、表面を電子顕微鏡
(SEM)による3000倍での観察した様子を表1に
示す。表1より、基板III のRp値が低いことは、鋭く
突起した個所が少ないことを示している。
Example 2 and Comparative Example 2 An aluminum plate was brush-polished and alkali-etched in the same manner as in Example 1, and then the same pressure roller as in Example 1 was used.
The same pressure was applied and then electropolished at 200 coulombs / dm 2 in a 1N hydrochloric acid bath. After washing with water, alkali etching was performed with the same composition as in Example 1. After washing with water, a resin roll having a hardness of 95 was used as an upper roll also as a draining roll, and a nitrile rubber roll having a hardness of 70 was used as a lower roll.
At a total weight of 100 kg, 0.8 kg was added per 1 cm width. The peripheral speed of the upper and lower rolls was rotated 5% faster than the transport speed of the aluminum plate. The support treated in this manner by applying the pressure roll twice was used in Example 2 (substrate III).
And A support treated by passing the pressure roll without applying the pressure roll twice is referred to as Comparative Example 2 (substrate IV). Thereafter, (Substrate III) and (Substrate IV) were anodized in the same manner as in Example 1, washed with water and dried. At this time (substrate III),
The surface roughness of (Substrate IV) was measured, and the values of average roughness Ra and maximum peak height Rp are shown in Table 1. Table 1 shows how the surface was observed at a magnification of 3000 with an electron microscope (SEM). From Table 1, the low Rp value of the substrate III indicates that there are few sharply protruding portions.

【0038】引き続き、下記組成の感光液(2)を乾燥
後の塗布重量が1.8g/m2 となるようにゴムコータ
ーにて塗布して感光層を設けた。 感光液(2) 2−ヒドロキシ−3−フェノキシプロピルメタクリレート/2−ヒドロキシエ チルメタクリレート/メタクリル酸/メチルメタクリレート/アクリロニトリル =30/20/5/20/25重量比の共重合体: 30g 4−ジアゾジフェニルアミンとホルムアルデヒドの縮合物の2−メトキシ−4 −ヒドロキシ−5−ベンゾイルベンゼンスルホン酸: 3g ビクトリアピュアーブルーBOH(保土ヶ谷化学工業社製): 0.1g シュウ酸: 0.3g エチレングリコールモノメチルエーテル: 90g N,N−ジメチルホルミアミド 10g
Subsequently, a photosensitive solution (2) having the following composition was applied by a rubber coater so that the applied weight after drying was 1.8 g / m 2 to provide a photosensitive layer. Photosensitive solution (2) 2-hydroxy-3-phenoxypropyl methacrylate / 2-hydroxyethyl methacrylate / methacrylic acid / methyl methacrylate / acrylonitrile = copolymer having a weight ratio of 30/20/5/20/25: 30 g 4-diazo 2-Methoxy-4-hydroxy-5-benzoylbenzenesulfonic acid as a condensate of diphenylamine and formaldehyde: 3 g Victoria Pure Blue BOH (manufactured by Hodogaya Chemical Industries): 0.1 g oxalic acid: 0.3 g ethylene glycol monomethyl ether: 90 g N, N-dimethylformamide 10g

【0039】この時の(基板III)、(基板IV)の感光液
塗布状況を表1に示す。(基板III)および(基板IV) か
ら得られた感光性平版印刷版に網点及び細線を有するネ
ガ原稿フィルムを密着し、光源として3kwメタルハラ
イドランプを使用し、距離1mより40秒間照射するこ
とにより露光した。この露光済みの感光性平版印刷版
を、市販されている現像液(シルバンネガ現像液、岡本
化学工業社製、主成分としてフェニルセロソルブと珪酸
カリウムと陰イオン界面活性剤および水から成る現像
液)の2倍希釈液で25℃で30秒間浸漬現像した。得
られた平版印刷版を用いて、校正刷り並びに印刷機によ
り印刷を行い、実施例1と同じくスポンジ適性、耐刷
性、汚れ性において評価を行った。その結果を表2に示
す。なお、評価基準は実施例1と同じである。
Table 1 shows the application state of the photosensitive liquid on (substrate III) and (substrate IV) at this time. The negative lithographic printing plate obtained from (Substrate III) and (Substrate IV) is brought into close contact with a negative original film having halftone dots and fine lines, and irradiated with light from a distance of 1 m for 40 seconds using a 3 kW metal halide lamp as a light source. Exposure. The exposed photosensitive lithographic printing plate is treated with a commercially available developer (Sylvan Negative Developer, Okamoto Chemical Industries, Ltd., a developer mainly composed of phenyl cellosolve, potassium silicate, anionic surfactant and water). It was immersed and developed with a 2 × dilution at 25 ° C. for 30 seconds. Using the obtained lithographic printing plate, proof printing and printing with a printing machine were performed, and evaluation was performed on sponge suitability, printing durability, and stain resistance in the same manner as in Example 1. Table 2 shows the results. The evaluation criteria are the same as in the first embodiment.

【0040】実施例3、比較例3 厚さ0.30mm、幅1000mmのアルミニウム板を
良く脱脂、水洗したのち、1.5重量%硝酸浴中で18
00クーロン/dm2 で電解研磨した。水洗の後、実施
例1と同じ組成で5g/m2 アルカリエッチングし、水
洗後、30重量%硝酸で酸洗浄し、水洗の後、上ローラ
ーとして、実行幅1200mmで、鉄芯径150mmに
MCナイロン(日本ポリペンコ社製)を15mm被せた
ものを使用し、下ロールには硬度65度のニトリルゴム
を用いて、全重量200kg加重で、幅1cm当たり
1.5kg以上にして圧を掛けた。この上下ロールの周
速度は、アルミニウム板の搬送速度より、3%遅くして
回転させた。この圧ロールを掛けて処理した支持体を実
施例3(基板V)とする。一方、この圧ロールを掛け
ず、圧ロールをパスして処理した支持体を比較例3(基
板VI)とする。その後、(基板V)、(基板VI)を実施
例1と同じように陽極酸化処理し、水洗乾燥した。
Example 3 and Comparative Example 3 An aluminum plate having a thickness of 0.30 mm and a width of 1000 mm was thoroughly degreased and washed with water, and then placed in a 1.5 wt% nitric acid bath.
Electropolishing was performed at 00 coulomb / dm 2 . After washing with water, 5 g / m 2 alkali etching was carried out with the same composition as in Example 1. After washing with water, acid washing with 30% by weight of nitric acid was carried out. Nylon (manufactured by Nippon Polypenco Co.) was covered with 15 mm, and nitrile rubber having a hardness of 65 degrees was used for the lower roll, and a pressure of 1.5 kg or more per 1 cm width was applied under a total weight of 200 kg. The peripheral speed of the upper and lower rolls was rotated by 3% lower than the transport speed of the aluminum plate. The support processed by applying the pressure roll is referred to as Example 3 (substrate V). On the other hand, a support that was processed by passing through a pressure roll without applying the pressure roll is referred to as Comparative Example 3 (substrate VI). Thereafter, (Substrate V) and (Substrate VI) were anodized in the same manner as in Example 1, washed with water and dried.

【0041】この時の(基板V)、(基板VI)の表面粗
さを測定し、平均粗さRaと最大山高さRpの数値で表
1に示す。また、表面を電子顕微鏡(SEM)による3
000倍での観察した様子を表1に示す。表1より、基
板VのRp値が低いことは、鋭く突起した個所が少ない
ことを示している。引き続き、上記感光液(1)を乾燥
後の塗布重量が1.8g/m2 となるようにゴムコータ
ーにて塗布して感光層を設けた。この時の(基板V)、
(基板VI)の感光液塗布状況を表1に示す。
At this time, the surface roughness of (substrate V) and (substrate VI) was measured, and the values of average roughness Ra and maximum peak height Rp are shown in Table 1. In addition, the surface was measured with an electron microscope (SEM).
Table 1 shows the observation at a magnification of 000. From Table 1, the fact that the Rp value of the substrate V is low indicates that there are few sharply projected portions. Subsequently, the photosensitive solution (1) was applied by a rubber coater so that the applied weight after drying was 1.8 g / m 2 to form a photosensitive layer. At this time (substrate V),
Table 1 shows the state of application of the photosensitive solution on (Substrate VI).

【0042】(基板V)および(基板VI)から得られた
感光性平版印刷版を、実施例1と同様に露光、現像し
た。得られた平版印刷版を用いて、校正刷り並びに印刷
機により印刷を行い、実施例1と同じくスポンジ適性、
耐刷性、汚れ性において評価を行った。その結果を表2
に示す。なお、評価基準は実施例1と同じである。
The photosensitive lithographic printing plates obtained from (Substrate V) and (Substrate VI) were exposed and developed in the same manner as in Example 1. Using the obtained lithographic printing plate, proof printing and printing were performed by a printing machine, and the sponge suitability was the same as in Example 1,
Evaluation was made on printing durability and stain resistance. Table 2 shows the results.
Shown in The evaluation criteria are the same as in the first embodiment.

【0043】[0043]

【発明の効果】本発明の平版印刷版用支持体は、表面の
滑り性が良く、そのために表面のスリ傷も少なく、スポ
ンジ適性も優れ、更に当該支持体に感光性組成物を塗布
した場合には、塗布ムラやハジキもなく、印刷時には耐
刷性や点々状の汚れもない優れた版となる。
The support for a lithographic printing plate of the present invention has good surface slipperiness, and therefore has less surface scratches and excellent sponge suitability. Further, when the photosensitive composition is applied to the support, Is an excellent plate having no coating unevenness and cissing, and having no printing durability and dot-like stains during printing.

Claims (7)

【特許請求の範囲】[Claims] 【請求項1】 アルミニウム板の表面を機械的研磨およ
び/または電気化学的研磨し、次いで化学的研磨し、陽
極酸化処理を行う平版印刷版用支持体の製造方法におい
て、前記諸工程の途中に、少なくとも一ヶ所以上、一対
のローラーにて両面より圧する工程が含まれることを特
徴とする平版印刷版用支持体の製造方法。
In a method for producing a lithographic printing plate support, wherein the surface of an aluminum plate is mechanically and / or electrochemically polished, then chemically polished, and then subjected to anodizing treatment, the method may be carried out in the course of the various steps. A method for producing a lithographic printing plate support, comprising a step of pressing at least one or more locations from both sides with a pair of rollers.
【請求項2】 上記一対のローラにおいて、上記アルミ
ニウム板の研磨表面に接するロールが金属ロールまたは
JIS K 6301スプリング式硬さ試験に基づく硬度が90度
以上の樹脂ロールとし、上記アルミニウム板の裏面に接
するロールが硬度50〜90度のゴムロールであること
を特徴とする請求項1に記載の平版印刷版用支持体の製
造方法。
2. A pair of rollers, wherein a roll in contact with a polishing surface of the aluminum plate is a metal roll or
The lithographic printing plate according to claim 1, wherein the resin roll has a hardness of 90 degrees or more based on a JIS K 6301 spring hardness test, and the roll in contact with the back surface of the aluminum plate is a rubber roll having a hardness of 50 to 90 degrees. A method for producing a printing plate support.
【請求項3】 上記一対のローラーにて両面より圧する
圧が、ロール幅当たり0.8kg/cm以上であること
を特徴とする請求項1に記載の平版印刷版用支持体の製
造方法。
3. The method for producing a lithographic printing plate support according to claim 1, wherein the pressure applied from both sides by the pair of rollers is 0.8 kg / cm or more per roll width.
【請求項4】 上記一対のローラーの径が100〜30
0mmであることを特徴とする請求項1に記載の平版印
刷版用支持体の製造方法。
4. The diameter of the pair of rollers is 100 to 30.
The method for producing a lithographic printing plate support according to claim 1, wherein the thickness is 0 mm.
【請求項5】 上記一対のローラーの周速度をアルミニ
ウム板の搬送速度に対して±10%以内に変化させて処
理することを特徴とする請求項1に記載の平版印刷版用
支持体の製造方法。
5. The lithographic printing plate support according to claim 1, wherein the processing is performed by changing the peripheral speed of the pair of rollers within ± 10% of the conveying speed of the aluminum plate. Method.
【請求項6】 請求項1〜5に記載の平版印刷版用支持
体の製造方法を用いて得られた平板印刷版用支持体。
6. A lithographic printing plate support obtained by using the method for producing a lithographic printing plate support according to claim 1.
【請求項7】 請求項6に記載の平版印刷版用支持体に
感光性組成物を塗設した感光性平版印刷版。
7. A photosensitive lithographic printing plate comprising the lithographic printing plate support according to claim 6 coated with a photosensitive composition.
JP28640197A 1997-10-20 1997-10-20 Method for producing lithographic printing plate support, lithographic printing plate support and photosensitive lithographic printing plate Expired - Fee Related JP3804032B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28640197A JP3804032B2 (en) 1997-10-20 1997-10-20 Method for producing lithographic printing plate support, lithographic printing plate support and photosensitive lithographic printing plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28640197A JP3804032B2 (en) 1997-10-20 1997-10-20 Method for producing lithographic printing plate support, lithographic printing plate support and photosensitive lithographic printing plate

Publications (2)

Publication Number Publication Date
JPH11115339A true JPH11115339A (en) 1999-04-27
JP3804032B2 JP3804032B2 (en) 2006-08-02

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Country Link
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010008257A (en) * 2000-11-18 2001-02-05 유장근 Automation surface treatment instrument of aluminium using off-set printing plate
JP2006281567A (en) * 2005-03-31 2006-10-19 Fuji Photo Film Co Ltd Manufacturing method of substrate for lithographic printing plate

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010008257A (en) * 2000-11-18 2001-02-05 유장근 Automation surface treatment instrument of aluminium using off-set printing plate
JP2006281567A (en) * 2005-03-31 2006-10-19 Fuji Photo Film Co Ltd Manufacturing method of substrate for lithographic printing plate
JP4648057B2 (en) * 2005-03-31 2011-03-09 富士フイルム株式会社 Method for producing support for lithographic printing plate

Also Published As

Publication number Publication date
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