JPH1090136A - Large-size water drop-collecting probe for steam flow in turbine - Google Patents

Large-size water drop-collecting probe for steam flow in turbine

Info

Publication number
JPH1090136A
JPH1090136A JP24797296A JP24797296A JPH1090136A JP H1090136 A JPH1090136 A JP H1090136A JP 24797296 A JP24797296 A JP 24797296A JP 24797296 A JP24797296 A JP 24797296A JP H1090136 A JPH1090136 A JP H1090136A
Authority
JP
Japan
Prior art keywords
slit
cylinder
shutter
outer cylinder
guide tube
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP24797296A
Other languages
Japanese (ja)
Inventor
Kenji Enomoto
健次 榎本
Sumio Uchida
澄生 内田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP24797296A priority Critical patent/JPH1090136A/en
Publication of JPH1090136A publication Critical patent/JPH1090136A/en
Withdrawn legal-status Critical Current

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  • Sampling And Sample Adjustment (AREA)

Abstract

PROBLEM TO BE SOLVED: To properly collect liquid drops by forming a shutter cylinder end part selectively aligning with an axial slit fitted in a freely detachable and rotatable fashion in an outer cylinder, and a liquid drop circulation space from a leading end part of the axial slit to a leading end part of a moisture-absorbing mat member in a positioning metal fitting. SOLUTION: An outer cylinder 51 of a water drop probe 50 is formed by sequentially coupling a guide tube 53, a slit tube 55 and a leading guide tube 57 through meshing or the like manner. The slit tube 55 has a slit hole 55a extending in an axial direction, and the leading guide tube 57 has a slit tube hole 57a expanding up to a center position. A positioning metal fitting 59 is fixed at an internal leading end part of the leading guide tube 57. A shutter cylinder 61 is inserted in the outer cylinder 51 in a freely detachable state, having a slit hole 61a selectively aligning with the slit hole 55a. A mat-mounting stage 71 is fixed inside a slot part 65a at a lower part of a supporting rod 65. A moisture-absorbing mat material 75 facing from inside is secured to the mounting stage 71. Moreover, an axial space is provided at a central part of a base end part 65b of the supporting rod 65.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、湿り蒸気流のよう
な気液二相流体中の液相計測に用いられるプローブに関
し、特に低圧タービン内の蒸気流の中に含まれる水滴を
採取するために使用される粗大水滴採取プローブに関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a probe used for measuring a liquid phase in a gas-liquid two-phase fluid such as a wet steam flow, and more particularly to a method for collecting water droplets contained in a steam flow in a low-pressure turbine. The present invention relates to a coarse water drop sampling probe used in the present invention.

【0002】[0002]

【従来の技術】蒸気タービンを用いて発電機を駆動する
発電プラントにおいて、低圧タービンには飽和蒸気に近
い蒸気が導入されるので、最終段の近くでは、蒸気は湿
り蒸気となって大量の水滴を含有し、動翼のエロージョ
ンの発生原因となったり、翼性能の性能低下を招来する
虞れがある。従って、低圧タービンの性能向上のために
は、蒸気流中の粗大水滴の挙動乃至飛跡パターンを計
測、把握するのが肝要であり、図3に示すような要領で
粗大水滴を採取する。図3において、タービンロータ1
に植設された動翼3、5は、静翼7、9によって案内さ
れた蒸気で駆動される。即ち、蒸気は白抜き矢印に示す
ように流れる。そして、最終段の静翼を通る蒸気流の粗
大水滴の飛跡パターンは、外車室11の外側から挿入さ
れたプローブ20により計測される。図4及び図5はプ
ローブ20の装着状況を若干詳しく示したもので、外車
室11の取付け管13を通してプローブ20を挿入し、
駆動装置15によりプローブ20の水滴取り入れ口を開
閉する。このプローブ20は、水滴取り入れ口を翼のベ
ース側から翼のチップ側まで移動できると共に軸回りに
回転でき、必要な位置で且つ所望の向きに取り入れ口を
固定し、蒸気流中の水滴を採取する。
2. Description of the Related Art In a power plant in which a generator is driven by using a steam turbine, near-saturated steam is introduced into a low-pressure turbine. And may cause erosion of the moving blade, or may cause deterioration of blade performance. Therefore, in order to improve the performance of the low-pressure turbine, it is important to measure and grasp the behavior or track pattern of the coarse water droplets in the steam flow. The coarse water droplets are collected in the manner shown in FIG. In FIG. 3, the turbine rotor 1
The moving blades 3 and 5 implanted in are driven by the steam guided by the stationary blades 7 and 9. That is, the steam flows as shown by the white arrow. Then, the trace pattern of the coarse water droplet of the steam flow passing through the final stage stationary blade is measured by the probe 20 inserted from the outside of the outer casing 11. 4 and 5 show the mounting state of the probe 20 in a little more detail. The probe 20 is inserted through the mounting pipe 13 of the outer casing 11, and FIG.
The drive unit 15 opens and closes the water drop inlet of the probe 20. The probe 20 can move the water drop inlet from the base side of the wing to the tip side of the wing and rotate around the axis, fix the inlet at a required position and in a desired direction, and collect water drops in the steam flow. I do.

【0003】図6乃至図8に従来のプローブ20の構造
が示されている。これらの図を参照するに、プローブ2
0の細長い円断面の外筒21は、水滴取り入れ口として
のスリット穴21aを有し、これに内側から臨んで水滴
吸着用マット材23が取付台25に固定されている。取
付台25は更に組立構造の支持棒27に固定され、そし
てマット材23、取付台25及び支持棒27を取り囲む
シャッタ筒29が軸受31、33を介して支持棒27の
両端部を回動自在に支持している。シャッタ筒29は内
部の構造部材と一緒に外筒21に挿脱可能である。そし
てシャッタ筒29は、外筒21のスリット穴21aと選
択的に整列するスリット穴29aを有している。支持棒
27の上部の中心軸穴に挿入されたプランジャ35は、
ピン37を介してシャッタ筒29に固定され、その外端
面に向かってエアホース39の空気孔が開口している。
そして、エアホース37から高圧空気を出すと、軸方向
ばね41及び回転方向ばね43に抗してプランジャ35
を動かす。プランジャ35に連結されたシャッタ筒29
は、支持棒27に対し軸方向に変位しつつ回転し、スリ
ット穴21a,29aが整列し、シャッタが開くことに
なる。図示の状態はこの状態を示し、通常はスリット穴
21a,29aが互いに円周方向にずれて水滴取り入れ
口は閉じている。以上のような構造のプローブ20を図
4及び図5に示すように、低圧タービンの所要位置に位
置決めし、且つ所望の向きに外筒21のスリット穴21
aを向け、シャッタ筒29を動かし、蒸気流中の水滴を
マット材23に吸着させる。このような水滴採取動作を
必要な空間領域内で適宜行うと、粗大水滴の挙動乃至飛
跡パターンが計測され、把握される。
FIGS. 6 to 8 show the structure of a conventional probe 20. FIG. Referring to these figures, probe 2
The outer cylinder 21 having an elongated circular cross section of 0 has a slit hole 21a as a water droplet intake port, and a mat member 23 for water droplet adsorption is fixed to the mounting table 25 from the inside thereof. The mount 25 is further fixed to a support rod 27 of an assembled structure, and a mat member 23, a shutter cylinder 29 surrounding the mount 25 and the support rod 27 are rotatable at both ends of the support rod 27 via bearings 31 and 33. I support it. The shutter cylinder 29 can be inserted into and removed from the outer cylinder 21 together with the internal structural members. The shutter cylinder 29 has a slit hole 29a that is selectively aligned with the slit hole 21a of the outer cylinder 21. The plunger 35 inserted into the central shaft hole at the upper part of the support rod 27
The air hose 39 is fixed to the shutter cylinder 29 via a pin 37, and an air hole of the air hose 39 is opened toward an outer end surface thereof.
When high-pressure air is discharged from the air hose 37, the plunger 35 is opposed to the axial spring 41 and the rotational spring 43.
Move. Shutter cylinder 29 connected to plunger 35
Rotates while being displaced in the axial direction with respect to the support rod 27, the slit holes 21a and 29a are aligned, and the shutter is opened. The state shown in the figure shows this state. Normally, the slit holes 21a and 29a are shifted from each other in the circumferential direction, and the water droplet intake port is closed. As shown in FIGS. 4 and 5, the probe 20 having the above structure is positioned at a required position of the low-pressure turbine, and the slit hole 21 of the outer cylinder 21 is oriented in a desired direction.
A is directed, and the shutter cylinder 29 is moved to adsorb water droplets in the steam flow to the mat member 23. When such a water drop collecting operation is appropriately performed in a necessary space area, the behavior or track pattern of the coarse water drops is measured and grasped.

【0004】[0004]

【発明が解決しようとする課題】前述のようなプローブ
20等を使用して測定した低圧タービンのドレーンキャ
ッチャ17取り付け部の水滴の飛跡分布の一例を図9の
(a)図に示す。低圧タービン内に挿入されるプローブ
20のスリット穴21aと水滴の飛跡パターンA,B,
Cとの関係を示すと(b)図のようになり、飛跡パター
ンA及び飛跡パターンBが多いことが判明した。このた
め、前述のようにプローブ20の外筒21の側部のみに
水滴取り込み用スリット穴21aがある従来のもので
は、飛跡パターンA,Bの水滴流に対し正確な水滴量を
計測するのは困難であった。従って、本発明の課題は、
湿り蒸気の様な気液二相流の中で液滴がどのような向
き、パターンで流れても、その液滴を適切且つ正確に採
取できる粗大水滴採取プローブを提供することにある。
FIG. 9 (a) shows an example of the track distribution of water droplets at the mounting portion of the drain catcher 17 of the low-pressure turbine measured using the probe 20 and the like as described above. The slit holes 21a of the probe 20 inserted into the low-pressure turbine and the trace patterns A, B,
The relationship with C is shown in FIG. 7B, and it was found that there were many track patterns A and B. For this reason, as described above, in the conventional device having the slit 21a for taking in water droplets only on the side of the outer cylinder 21 of the probe 20, it is not possible to accurately measure the amount of water droplets for the water droplet flows of the track patterns A and B. It was difficult. Therefore, the object of the present invention is to
It is an object of the present invention to provide a coarse water droplet sampling probe that can appropriately and accurately collect a droplet in any direction and pattern in a gas-liquid two-phase flow such as wet steam.

【0005】[0005]

【課題を解決するための手段】如上の課題を解決するた
め、本発明によれば、タービン内蒸気流用の粗大水滴採
取プローブは、先端部側面及び先端面中央にかけて連続
した軸方向スリットが形成された外筒、この外筒内に挿
脱自在且つ回転自在に装着され前記軸方向スリットに選
択的に整列するシャッタスリットを備えたシャッタ筒、
このシャッタ筒内に前記軸方向スリットに内側から臨ん
で配置された吸湿マット材を支持すると共に前記シャッ
タ筒内に設けられた棒状支持部材、この棒状支持部材の
基端側中空軸部に摺動自在に挿入され前記シャッタ筒に
連絡した操作プランジャ、前記外筒の内部先端に固定し
て設けられた位置決め金具、及び前記シャッタ筒の先端
面を貫いて延びた支持部材先端に取り付けられ前記位置
決め金具に係合する案内管から構成され、シャッタ筒の
先端部及び位置決め金具に軸方向スリットの先端部から
吸湿マット部材の先端部に向かって水滴流通空間を形成
してなることを特徴とする。
According to the present invention, there is provided a coarse water drop sampling probe for a steam flow in a turbine, wherein a continuous axial slit is formed on the side surface of the tip and the center of the tip surface. An outer cylinder, a shutter cylinder having a shutter slit which is removably and rotatably mounted in the outer cylinder and which is selectively aligned with the axial slit.
A rod-shaped support member provided in the shutter cylinder and supporting the moisture-absorbing mat member disposed inside the shutter cylinder from the inside of the axial slit and sliding on the base-side hollow shaft portion of the rod-shaped support member. An operation plunger freely inserted and connected to the shutter barrel, a positioning bracket fixedly provided at an inner tip of the outer barrel, and the positioning bracket attached to a tip of a support member extending through a tip face of the shutter barrel; , And a water drop circulation space is formed in the distal end portion of the shutter cylinder and the positioning fitting from the distal end portion of the axial slit toward the distal end portion of the moisture absorbing mat member.

【0006】[0006]

【発明の実施の形態】以下添付の図面を参照して、本発
明の実施形態を説明する。図1及び図2を参照するに、
水滴プローブ50の外筒51は、ガイド管53、スリッ
ト管55及び先端ガイド管57を螺合乃至ピン接合によ
り順次継合して形成されている。スリット管55には軸
方向に延びるスリット穴55aが形成され、先端ガイド
管57には、球状の先端面の中心位置まで延びるスリッ
ト穴57aが形成され、スリット穴55aとスリット穴
57aとは図示のように一列に整列している。そして先
端ガイド管57の内部の先端部には、位置決め金具59
が固定されている。この位置決め金具59は円筒形をし
ていて、更にスリット穴57aに連続するスリット穴5
9aを有している。一方、又その外筒51内には、シャ
ッタ筒61が挿脱自在に挿着され、これはスリット穴5
5aに選択的に整列するスリット穴61aを有し、これ
は更に先端部のスリット穴61bに続いている。位置決
め金具59に係合して向きを決定する案内管63を先端
部に備えた棒状支持部材即ち支持棒65は、シャッタ筒
61の中に軸受67,69により相対回転可能に支持さ
れている。支持棒65の下部のスロット部65aの中に
マット取付台71が取付けボルト73により固定されて
いて、スリット穴55aに内側から臨む吸湿性のマット
材75がマット取付台71に固定されている。更に支持
棒65の基端部65bは中心部に軸方向空間を有し、こ
の中に従来のものと同様の操作プランジャ77が相対変
位自在に挿入されている。プランジャ77は、連結ピン
79によりシャッタ筒61に連結されている。
Embodiments of the present invention will be described below with reference to the accompanying drawings. Referring to FIGS. 1 and 2,
The outer tube 51 of the water drop probe 50 is formed by sequentially joining a guide tube 53, a slit tube 55, and a tip guide tube 57 by screwing or pin joining. A slit hole 55a extending in the axial direction is formed in the slit tube 55, and a slit hole 57a extending to the center position of the spherical distal end surface is formed in the distal end guide tube 57. The slit hole 55a and the slit hole 57a are shown in FIG. And so on. A positioning metal fitting 59 is provided at the distal end inside the distal end guide tube 57.
Has been fixed. The positioning metal fitting 59 has a cylindrical shape, and further has a slit hole 5 continuous with the slit hole 57a.
9a. On the other hand, a shutter cylinder 61 is removably inserted into the outer cylinder 51, which is
5a has a slit hole 61a that is selectively aligned, which further follows the slit hole 61b at the tip. A rod-shaped support member or support rod 65 having a guide tube 63 at the distal end which engages with the positioning metal fitting 59 to determine the direction is supported in the shutter cylinder 61 by bearings 67 and 69 so as to be relatively rotatable. A mat mounting base 71 is fixed in a slot portion 65a below the support rod 65 by mounting bolts 73, and a hygroscopic mat member 75 facing the slit hole 55a from inside is fixed to the mat mounting base 71. Further, the base end portion 65b of the support rod 65 has an axial space at the center portion, into which an operation plunger 77 similar to a conventional one is inserted so as to be relatively displaceable. The plunger 77 is connected to the shutter cylinder 61 by a connecting pin 79.

【0007】以上のような構成の水滴プローブ50の使
用方法を説明すると、従来のものと同様図3乃至図4に
示すような状態で、低圧タービンの中に入れる。そし
て、図示しない空気配管からの高圧空気を操作プランジ
ヤ75の図示しない端部に作用せしめると、操作プラン
ジャ77はばね81に抗して動き、シャッタ筒61を下
方に相対変位させる。回転しない支持棒65との相互関
係により、シャッタ筒61は所定角度回転し、図示のよ
うにマット材75がスリット穴55a,57aを介して
外部に暴露される。水滴プローブ50の周囲を流れる蒸
気中の水滴は、スリット穴55a,57aを通ってマッ
ト材75に衝突し、吸着される。詳言すると、上向きの
蒸気流の水滴は、スリット穴57aを上向きに流れ、更
に位置決め金具59のスリット穴59a及びシャッタ筒
61の先端のスリット穴61bを上向きに流れてマット
材75に到達して吸着される。所定の採取時間が経過し
たら、操作プランジャ77の高圧空気による押し付けを
停止する。こうすれば、シャッタ筒61は上方位置に復
帰し、スリット穴55a,57aはシャッタ筒61によ
り閉じられる。
[0007] The method of using the water droplet probe 50 having the above-described configuration will be described. The water droplet probe 50 is put into a low-pressure turbine in a state as shown in Figs. When high-pressure air from an unillustrated air pipe acts on an unillustrated end of the operation plunger 75, the operation plunger 77 moves against the spring 81 and relatively displaces the shutter cylinder 61 downward. The shutter cylinder 61 rotates by a predetermined angle due to the mutual relationship with the non-rotating support bar 65, and the mat member 75 is exposed to the outside through the slit holes 55a and 57a as shown in the figure. Water droplets in the steam flowing around the water droplet probe 50 collide with the mat member 75 through the slit holes 55a and 57a and are adsorbed. Specifically, the water droplet of the upward steam flow flows upward through the slit hole 57a, further flows upward through the slit hole 59a of the positioning metal fitting 59 and the slit hole 61b at the tip of the shutter cylinder 61, and reaches the mat member 75. Adsorbed. When the predetermined sampling time has elapsed, the pressing of the operation plunger 77 by the high-pressure air is stopped. By doing so, the shutter cylinder 61 returns to the upper position, and the slit holes 55a and 57a are closed by the shutter cylinder 61.

【0008】[0008]

【発明の効果】以上説明したように、本発明によれば、
プローブの水滴取入口である軸方向スリットを外筒の側
面ばかりでなく先端面の中央にまで形成したので、低圧
タービン内において水平方向に流れる蒸気流の水滴ばか
りでなく上向き蒸気流のものまで取り入れるから、蒸気
流の方向による制約がなくなり、広範囲の蒸気流中の水
滴を適切に吸着することができる。
As described above, according to the present invention,
The axial slit, which is the water inlet for the probe, is formed not only on the side surface of the outer cylinder but also on the center of the tip surface, so that not only water droplets of the steam flowing horizontally in the low-pressure turbine but also those of the upward steam flow can be taken in. Therefore, there is no restriction due to the direction of the steam flow, and water droplets in a wide range of the steam flow can be appropriately adsorbed.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施形態の要部を示す一部切欠き部分
断面図である。
FIG. 1 is a partially cutaway partial cross-sectional view showing a main part of an embodiment of the present invention.

【図2】図1の断面図に対応する一部切欠き正面図であ
る。
FIG. 2 is a partially cutaway front view corresponding to the cross-sectional view of FIG.

【図3】本発明に係る装置によって気液二相流体の水滴
が測定される一例を示す概念断面図である。
FIG. 3 is a conceptual sectional view showing an example in which water droplets of a gas-liquid two-phase fluid are measured by the device according to the present invention.

【図4】本発明に係る装置によって気液二相流体の水滴
が測定される状況を示す概念断面図である。
FIG. 4 is a conceptual cross-sectional view showing a situation where water droplets of a gas-liquid two-phase fluid are measured by the device according to the present invention.

【図5】図4に対応する概念図である。FIG. 5 is a conceptual diagram corresponding to FIG.

【図6】従来のプローブの一例を示す部分断面図であ
る。
FIG. 6 is a partial sectional view showing an example of a conventional probe.

【図7】従来のプローブの一例を示す一部切欠き部分正
面図である。
FIG. 7 is a partially cutaway front view showing an example of a conventional probe.

【図8】図6のVIII-VIII線に沿う断面図である。FIG. 8 is a sectional view taken along line VIII-VIII in FIG.

【図9】蒸気タービン内の蒸気流中の水滴の飛跡パター
ンを示す概念図である。
FIG. 9 is a conceptual diagram showing a trace pattern of water droplets in a steam flow in a steam turbine.

【符号の説明】[Explanation of symbols]

50 プローブ 51 外筒 53 ガイド管 55 スリット管 55a スリット穴 57 先端ガイド管 57a スリット穴 59 位置決め金具 59a スリット穴 61 シャッタ筒 61a,61b スリット穴 63 案内管 65 支持棒 67,69 軸受 71 取付台 75 マット材 77 操作プランジャ Reference Signs List 50 probe 51 outer tube 53 guide tube 55 slit tube 55a slit hole 57 tip guide tube 57a slit hole 59 positioning fitting 59a slit hole 61 shutter tube 61a, 61b slit hole 63 guide tube 65 support rod 67, 69 bearing 71 mounting table 75 mat Material 77 Operation plunger

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 先端部側面及び先端面中央にかけて連続
した軸方向スリットが形成された外筒、同外筒内に挿脱
自在且つ回転自在に装着され前記軸方向スリットに選択
的に整列するシャッタスリットを備えたシャッタ筒、同
シャッタ筒内に前記軸方向スリットに内側から臨んで配
置された吸湿マット材を支持すると共に前記シャッタ筒
内に設けられた棒状支持部材、同棒状支持部材の基端側
中空軸部に摺動自在に挿入され前記シャッタ筒に連絡し
た操作プランジャ、前記外筒の内部先端に固定して設け
られた位置決め金具、及び前記シャッタ筒の先端面を貫
いて延びた支持部材先端に取り付けられ前記位置決め金
具に係合する案内管を有し、前記シャッタ筒の先端部及
び前記位置決め金具に前記軸方向スリットの先端部から
前記吸湿マット部材の先端部に向かって水滴流通空間を
形成してなることを特徴とするタービン内蒸気流用の粗
大水滴採取プローブ。
An outer cylinder having a continuous axial slit formed on a side surface of the distal end portion and a center of the distal end surface, and a shutter selectively removably and rotatably mounted in the outer cylinder and inserted in and removed from the outer cylinder. A shutter cylinder provided with a slit, a rod-shaped support member provided in the shutter cylinder for supporting a moisture-absorbing mat member disposed inside the shutter cylinder so as to face the axial slit, and a base end of the rod-shaped support member An operation plunger slidably inserted into the side hollow shaft portion and connected to the shutter cylinder, a positioning bracket fixedly provided at an inner distal end of the outer cylinder, and a support member extending through the distal end surface of the shutter cylinder A guide tube attached to a leading end for engaging with the positioning fitting, wherein the hygroscopic mat member is provided at the leading end of the shutter cylinder and the positioning fitting from the leading end of the axial slit. A water droplet circulation space is formed toward the tip of the turbine, and a coarse water droplet sampling probe for steam flow in a turbine characterized by being formed.
JP24797296A 1996-09-19 1996-09-19 Large-size water drop-collecting probe for steam flow in turbine Withdrawn JPH1090136A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24797296A JPH1090136A (en) 1996-09-19 1996-09-19 Large-size water drop-collecting probe for steam flow in turbine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24797296A JPH1090136A (en) 1996-09-19 1996-09-19 Large-size water drop-collecting probe for steam flow in turbine

Publications (1)

Publication Number Publication Date
JPH1090136A true JPH1090136A (en) 1998-04-10

Family

ID=17171298

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24797296A Withdrawn JPH1090136A (en) 1996-09-19 1996-09-19 Large-size water drop-collecting probe for steam flow in turbine

Country Status (1)

Country Link
JP (1) JPH1090136A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004037753A1 (en) * 2002-10-21 2004-05-06 Exxonmobil Chemical Patents Inc. Method and system for reducing decomposition byproducts in a methanol to olefin reactor system

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004037753A1 (en) * 2002-10-21 2004-05-06 Exxonmobil Chemical Patents Inc. Method and system for reducing decomposition byproducts in a methanol to olefin reactor system

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A300 Withdrawal of application because of no request for examination

Free format text: JAPANESE INTERMEDIATE CODE: A300

Effective date: 20031202