JPH1081934A - High temperature parts sliding guide material - Google Patents

High temperature parts sliding guide material

Info

Publication number
JPH1081934A
JPH1081934A JP23567396A JP23567396A JPH1081934A JP H1081934 A JPH1081934 A JP H1081934A JP 23567396 A JP23567396 A JP 23567396A JP 23567396 A JP23567396 A JP 23567396A JP H1081934 A JPH1081934 A JP H1081934A
Authority
JP
Japan
Prior art keywords
weight
valve
guide
guide material
sliding guide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP23567396A
Other languages
Japanese (ja)
Other versions
JP3901253B2 (en
Inventor
Noriaki Katori
法章 香取
Masayoshi Ono
正善 大野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hino Motors Ltd
Kasuya Seiko KK
Original Assignee
Hino Motors Ltd
Kasuya Seiko KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hino Motors Ltd, Kasuya Seiko KK filed Critical Hino Motors Ltd
Priority to JP23567396A priority Critical patent/JP3901253B2/en
Publication of JPH1081934A publication Critical patent/JPH1081934A/en
Application granted granted Critical
Publication of JP3901253B2 publication Critical patent/JP3901253B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Heat Treatment Of Articles (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a high temp. parts sliding guide material capable of withstanding high temp. without deteriorating machinability. SOLUTION: This material has a chemical composition consisting of, by weight, 3.5-4.1% C, 1.8-2.4% Si, 0.6-1.0% Mn, 0.3-0.7% P, <=0.1% S, 0.6-1.2% Cr, 1.0-1.5% Ni, 0.03-0.10% B, 0.3-0.6% Cu, and the balance Fe or consisting of, by weight, 2.8-3.4% C, 1.8-2.4% Si, 0.4-0.8% Mn, 0.2-0.5% P, <=0.1% S, 0.3-0.8% Cr, 1.0-1.5% Ni, 0.03-0.10% B, 0.3-0.6% Cu, and the balance Fe.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、エンジンのシリン
ダヘッドに設けられ、高熱状態で摺動するバルブを支持
するバルブガイドの材料に適する高熱部品摺動ガイド材
に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a high heat component sliding guide member suitable for a valve guide material provided on a cylinder head of an engine and supporting a valve which slides in a high temperature state.

【0002】[0002]

【従来の技術】4サイクルエンジンには通常バルブシス
テムが搭載される。バルブシステムはクランクシャフト
の回転をタイミングベルト、チェーン又はギヤ等により
カムシャフトに連結させ、カムシャフトに設けられた略
卵形のカムがシャフトとともに回転することによりロッ
カアームを介してバルブを開閉させるものである。
2. Description of the Related Art A four-stroke engine is usually equipped with a valve system. The valve system connects the rotation of the crankshaft to the camshaft by a timing belt, chain or gear, etc., and opens and closes the valve via the rocker arm by rotating the substantially oval cam provided on the camshaft with the shaft. is there.

【0003】図9に示すように、バルブ11の形状は一
般的にきのこ状に形成され、コイルスプリング12の力
により閉じるようになっている。このバルブ11がロッ
カアーム13の揺動により押されて開放することによ
り、4サイクルの作動における吸気及び排気を行うこと
ができ、開放されたバルブ11から燃焼室とシリンダ内
のガス交換を行うことができるようになっている。バル
ブ11はシリンダヘッド14に形成された孔に挿入さ
れ、その孔を往復運動することによりシリンダ内のガス
を交換するようになっており、孔にはバルブ11の往復
運動に対する摩耗を防止すべくバルブガイド16が設け
られる。このバルブガイド16によりバルブ11自体の
摩耗を防止し、熱によるバルブ11の焼き付きを防止で
きるようになっている。なお、図中符号17はOHV方
式のバルブシステムにおけるプッシュロッドである。
[0003] As shown in FIG. 9, a valve 11 is generally formed in a mushroom shape and is closed by the force of a coil spring 12. When the valve 11 is pushed and opened by the swing of the rocker arm 13, intake and exhaust can be performed in four cycles of operation, and gas exchange between the combustion chamber and the cylinder can be performed from the opened valve 11. I can do it. The valve 11 is inserted into a hole formed in the cylinder head 14, and exchanges gas in the cylinder by reciprocating through the hole. A valve guide 16 is provided. The valve guide 16 prevents wear of the valve 11 itself and prevents burning of the valve 11 due to heat. Reference numeral 17 in the figure denotes a push rod in an OHV type valve system.

【0004】従来、バルブガイド16は非常に厳しい寸
法精度が要求されるためにバルブ11が挿入される孔は
精密機械加工により形成され、構造材はこのような機械
加工性及び耐熱性を考慮していわゆるネズミ鋳鉄をベー
スにしてボロンを添加した合金鋳鉄を使用している。こ
のような合金鋳鉄を使用することにより耐熱性及び機械
加工性の要求を満足させている。
Conventionally, since the valve guide 16 requires extremely strict dimensional accuracy, the hole into which the valve 11 is inserted is formed by precision machining, and the structural material is made in consideration of such machinability and heat resistance. Therefore, alloy cast iron to which boron is added based on so-called gray cast iron is used. By using such an alloy cast iron, the requirements for heat resistance and machinability are satisfied.

【0005】[0005]

【発明が解決しようとする課題】しかし、近年のエンジ
ンの高回転化及び高出力化によりバルブ自体が高温の排
気ガスに曝される時間が長くなり、これに起因してバル
ブ自体が高温化する傾向を生じた。即ち、従来であれば
バルブ自体が400℃以上になることはなかったのに対
し、近年では400℃を越える場合が生じるようになっ
た。このバルブ自体の温度が上昇することに起因して従
来の合金鋳鉄におけるバルブガイドとバルブとのいわゆ
る焼き付きが生じる問題点が発生した。この点を解消す
るために、バルブガイド及びバルブ自体を強制的に冷却
すること、及びバルブガイド自体を高温に耐えられる非
常に固い材料で製作することが考えられるが、バルブの
強制冷却はエンジンの大幅な改良となるために非常にコ
ストが高く、バルブガイドを固い材料にすることはバル
ブガイドを製作する上での加工性が低下する不具合があ
る。本発明の目的は、高熱部品の摺動面に部分的に固い
物質を析出させることにより、切削加工性を低下させる
ことなく高温に耐え得る高熱部品摺動ガイド材を提供す
ることにある。
However, in recent years, the speed of the engine has been increased and the output has been increased, so that the valve itself has been exposed to high-temperature exhaust gas for a long time, and as a result, the valve itself has been heated to a high temperature. A trend has arisen. That is, in the past, the temperature of the valve itself did not exceed 400 ° C., but in recent years, the temperature sometimes exceeded 400 ° C. This raises the problem that the so-called seizure between the valve guide and the valve in the conventional alloy cast iron occurs due to the rise in the temperature of the valve itself. In order to solve this problem, it is conceivable to forcibly cool the valve guide and the valve itself, and to make the valve guide itself from a very hard material that can withstand high temperatures. The cost is extremely high due to a significant improvement, and the use of a hard material for the valve guide has a problem that the workability in manufacturing the valve guide is reduced. An object of the present invention is to provide a high heat component sliding guide material that can withstand high temperatures without deteriorating the machinability by partially depositing a hard substance on the sliding surface of the high heat component.

【0006】[0006]

【課題を解決するための手段】請求項1に係る発明は、
化学成分として、3.5〜4.1重量%のCと、1.8
〜2.4重量%のSiと、0.6〜1.0重量%のMn
と、0.3〜0.7重量%のPと、0.1重量%以下の
Sと、0.6〜1.2重量%のCrと、1.0〜1.5
重量%のNiと、0.03〜0.10重量%のBと、
0.3〜0.6重量%のCuと、残部にFeを含む高熱
部品摺動ガイド材である。請求項2に係る発明は、化学
成分として、2.8〜3.4重量%のCと、1.8〜
2.4重量%のSiと、0.4〜0.8重量%のMn
と、0.2〜0.5重量%のPと、0.1重量%以下の
Sと、0.3〜0.8重量%のCrと、1.0〜1.5
重量%のNiと、0.03〜0.10重量%のBと、
0.3〜0.6重量%のCuと、残部にFeを含む高熱
部品摺動ガイド材である。この請求項1又は請求項2に
係るガイド材では、従来のいわゆるネズミ鋳鉄における
ガイド材よりクロム、ボロン及びリンの含有量を増加さ
せることにより、ガイド材に炭化ボロン(B3C)、リ
ン化鉄(Fe3P)及び炭化クロム(Cr3C)の固い物
質を部分的に析出させることができ、このガイド材を加
工することにより加工された表面を摺動する高熱部品の
摩耗を低減し、高熱部品との焼き付きを防止する。
The invention according to claim 1 is
3.5 to 4.1% by weight of C and 1.8 as chemical components
-2.4 wt% Si and 0.6-1.0 wt% Mn
0.3-0.7 wt% P, 0.1 wt% or less S, 0.6-1.2 wt% Cr, 1.0-1.5 wt%
Wt% Ni, 0.03-0.10 wt% B,
It is a high heat component sliding guide material containing 0.3 to 0.6% by weight of Cu and the balance of Fe. The invention according to claim 2 is characterized in that 2.8 to 3.4% by weight of C and 1.8 to
2.4 wt% Si and 0.4-0.8 wt% Mn
0.2 to 0.5% by weight of P, 0.1% by weight or less of S, 0.3 to 0.8% by weight of Cr, 1.0 to 1.5% by weight.
Wt% Ni, 0.03-0.10 wt% B,
It is a high heat component sliding guide material containing 0.3 to 0.6% by weight of Cu and the balance of Fe. In the guide material according to claim 1 or 2, the content of chromium, boron and phosphorus is increased compared to the conventional guide material of so-called gray cast iron, so that boron carbide (B 3 C) and phosphide are added to the guide material. Hard substances such as iron (Fe 3 P) and chromium carbide (Cr 3 C) can be partially precipitated, and by processing this guide material, wear of high heat parts sliding on the processed surface can be reduced. To prevent seizure with hot parts.

【0007】請求項3に係る発明は、請求項1又は2記
載の高熱部品摺動ガイド材であって、炭素当量が4.1
〜5.1である高熱部品摺動ガイド材である。この請求
項3に係る高熱部品摺動ガイド材では、炭素当量が上記
範囲を外れると、ガイド材の加工性が低下する。
According to a third aspect of the present invention, there is provided a sliding guide member having a high heat component according to the first or second aspect, wherein the carbon equivalent is 4.1.
摺 動 5.1 is a high heat component sliding guide material. In the high heat component sliding guide according to the third aspect, when the carbon equivalent is out of the above range, the workability of the guide is reduced.

【0008】請求項4に係る発明は、請求項ないし3い
ずれか記載の発明であって、ロックウェル硬さHRB
94〜103であって、析出黒鉛が均一又はバラ状に無
方向に配列しかつその黒鉛片の大きさが100倍の倍率
で長さ6.3〜25.4mmの範囲にあり、炭化ボロ
ン、リン化鉄及び炭化クロムからなる群より選ばれた1
種又は2種以上の析出硬化物が5〜10重量%含有する
高熱部品摺動ガイド材である。この請求項4に係る高熱
部品摺動ガイド材では、耐摩耗性及び焼き付きを有効に
防止するうえでの析出黒鉛の形状、大きさ及び析出量を
得ることができる。
[0008] The invention according to claim 4 is an invention in accordance with claim 3, Rockwell hardness HR B is a 94-103, deposited graphite uniform or rose shape arranged in the non-oriented And the size of the graphite flakes is in the range of 6.3 to 25.4 mm at a magnification of 100 times and selected from the group consisting of boron carbide, iron phosphide and chromium carbide.
A high heat component sliding guide material containing 5 to 10% by weight of one or more kinds of precipitation hardened materials. With the high heat component sliding guide material according to the fourth aspect, it is possible to obtain the shape, size, and amount of precipitated graphite for effectively preventing wear resistance and seizure.

【0009】[0009]

【発明の実施の形態】次に本発明の実施の形態を図面に
基づいて詳しく説明する。本実施の形態における高熱部
品摺動ガイド材はエンジンのバルブを支持するバルブガ
イドに使用されるバルブガイド材である。高熱部品であ
るバルブを支持するバルブガイドは機械加工することに
より作製され、機械加工される高熱部品摺動ガイド材は
化学成分として、従来のガイド材よりクロム、ボロン及
びリンの含有量を増加させ、3.5〜4.1重量%のC
と、1.8〜2.4重量%のSiと、0.6〜1.0重
量%のMnと、0.3〜0.7重量%のPと、0.1重
量%以下のSと、0.6〜1.2重量%のCrと、1.
0〜1.5重量%のNiと、0.03〜0.10重量%
のBと、0.3〜0.6重量%のCuと、残部にFeを
含むか、或いは2.8〜3.4重量%のCと、1.8〜
2.4重量%のSiと、0.4〜0.8重量%のMn
と、0.2〜0.5重量%のPと、0.1重量%以下の
Sと、0.3〜0.8重量%のCrと、1.0〜1.5
重量%のNiと、0.03〜0.10重量%のBと、
0.3〜0.6重量%のCuと、残部にFeを含む。
Embodiments of the present invention will now be described in detail with reference to the drawings. The high heat component sliding guide member in the present embodiment is a valve guide member used for a valve guide supporting an engine valve. The valve guide that supports the valve, which is a high-temperature component, is manufactured by machining, and the high-temperature component sliding guide material that is machined increases the content of chromium, boron, and phosphorus as a chemical component compared to conventional guide materials. 3.5-4.1% by weight of C
1.8 to 2.4% by weight of Si, 0.6 to 1.0% by weight of Mn, 0.3 to 0.7% by weight of P, and 0.1% by weight or less of S , 0.6-1.2% by weight of Cr;
0-1.5% by weight of Ni and 0.03-0.10% by weight
B containing 0.3 to 0.6% by weight of Cu and the balance containing Fe, or 2.8 to 3.4% by weight of C and 1.8 to
2.4 wt% Si and 0.4-0.8 wt% Mn
0.2 to 0.5% by weight of P, 0.1% by weight or less of S, 0.3 to 0.8% by weight of Cr, 1.0 to 1.5% by weight.
Wt% Ni, 0.03-0.10 wt% B,
It contains 0.3 to 0.6% by weight of Cu and the balance Fe.

【0010】上述した化学成分によりガイド材に炭化ボ
ロン(B3C)、リン化鉄(Fe3P)及び炭化クロム
(Cr3C)の固い物質が部分的に析出する。この場合
のガイド材の炭素当量は4.1〜5.1であることが好
ましい。即ち、珪素(Si)とリン(P)を炭素量に換
算して実炭素量に加えた全炭素量が4.1〜5.1の範
囲内にあることが好ましい。また、このような化学成分
の合金のロックウェル硬さHRBが94〜103であっ
て、析出黒鉛が均一又はバラ状に無方向に配列している
ことが好ましい。また、その黒鉛片の大きさは100倍
の倍率で長さ6.3〜25.4mmの範囲にあり、析出
硬化物が5〜10重量%含有することが更に好ましい。
上記黒鉛の形状はASTM規格のA(均一分布・無方向
配列)又はB(バラ状分布・無方向配列)に相当し、そ
の黒鉛片の大きさはASTM規格のNo.4(100倍
の倍率で長さ25.4〜12.7mm)及びNo.5
(100倍の倍率で長さ12.7〜6.3mm)に相当
する。このような化学成分を有する高熱部品摺動ガイド
材を機械加工することによりバルブガイドを作成する
と、作成されたバルブガイドは高熱部品の摺動面である
孔の内面に部分的に固い物質が析出する。
Due to the above-mentioned chemical components, hard substances such as boron carbide (B 3 C), iron phosphide (Fe 3 P) and chromium carbide (Cr 3 C) are partially deposited on the guide material. In this case, the guide member preferably has a carbon equivalent of 4.1 to 5.1. That is, it is preferable that the total carbon amount obtained by converting silicon (Si) and phosphorus (P) into the carbon amount and adding it to the actual carbon amount is within the range of 4.1 to 5.1. Further, a Rockwell hardness HR B alloy of such chemical component 94-103, it is preferred that the precipitated graphite are arranged in the non-oriented homogenous or rose-shaped. Further, the size of the graphite flakes is in the range of 6.3 to 25.4 mm in length at a magnification of 100 times, and it is more preferable that the precipitate hardened material contains 5 to 10% by weight.
The shape of the graphite corresponds to A (uniform distribution / non-directional arrangement) or B (loose distribution / non-directional arrangement) of the ASTM standard. No. 4 (length: 25.4 to 12.7 mm at 100 times magnification) and No. 4 5
(12.7 to 6.3 mm in length at a magnification of 100 times). When a valve guide is created by machining a high-temperature component sliding guide material having such a chemical component, a hard substance is partially deposited on the inner surface of a hole, which is a sliding surface of the high-temperature component, in the created valve guide. I do.

【0011】[0011]

【実施例】次に本発明の実施例を図面に基づいて詳しく
説明する。 <実施例1>ガイド材を機械加工することによりエンジ
ンのバルブを支持するバルブガイドを作製した。図7に
示すように、バルブガイド16は外径17mm、長さ7
0mm及び直径10mmの孔16aを有する管状に作製
した。上記ガイド材の化学成分として、3.7重量%の
Cと、2.19重量%のSiと、0.74重量%のMn
と、0.7重量%のPと、0.03重量%のSと、0.
91重量%のCrと、1.5重量%のNiと、0.05
6重量%のBと、0.3重量%のCuと、残部にFeを
含むものである。
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a block diagram showing an embodiment of the present invention; <Example 1> A valve guide for supporting an engine valve was manufactured by machining a guide material. As shown in FIG. 7, the valve guide 16 has an outer diameter of 17 mm and a length of 7 mm.
It was formed into a tube having a hole 16a having a diameter of 0 mm and a diameter of 10 mm. As the chemical components of the guide material, 3.7% by weight of C, 2.19% by weight of Si, and 0.74% by weight of Mn
, 0.7% by weight of P, 0.03% by weight of S,
91% by weight of Cr, 1.5% by weight of Ni, 0.05%
It contains 6% by weight of B, 0.3% by weight of Cu, and the balance Fe.

【0012】機械加工には旋盤を使用し、バルブの摺動
面である孔16aの内面は表面仕上げを行った。このバ
ルブガイド16のロックウェル硬さHRBは102であ
って、炭素当量は4.66である。このバルブガイド1
6は、図1の100倍に拡大された写真に示すように、
析出黒鉛が均一に無方向に配列され、その黒鉛片の大き
さは長さ5〜40mmの範囲に形成された。なお、本実
施例1のバルブガイド16の結晶粒界を明瞭に露出させ
るために、このバルブガイド16を2%ナイタール腐食
液(2%濃硝酸アルコール溶液)に浸漬してエッチング
した後直ちに取り出した。そのエッチング後の表面を5
50倍に拡大した写真を図2に示す。この写真により析
出硬化物が有効にその表面に出現していることがわか
る。
A lathe was used for machining, and the inner surface of the hole 16a, which is the sliding surface of the valve, was finished. Rockwell hardness HR B of the valve guide 16 is a 102, the carbon equivalent is 4.66. This valve guide 1
6, as shown in the photograph magnified 100 times in FIG.
Precipitated graphite was uniformly arranged in the non-direction, and the size of the graphite flakes was formed in the range of 5 to 40 mm in length. In order to clearly expose the crystal grain boundaries of the valve guide 16 of the first embodiment, the valve guide 16 was immersed in a 2% nital etching solution (2% concentrated nitric acid alcohol solution), etched, and immediately taken out. . The surface after etching is 5
FIG. 2 shows a photograph magnified 50 times. From this photograph, it can be seen that the precipitation hardened material has effectively appeared on the surface.

【0013】<実施例2>ガイド材の化学成分を変更し
て機械加工することにより実施例1と同形同大のバルブ
ガイドを作製した。バルブガイド材の化学成分として、
3.2重量%のCと、2.0重量%のSiと、0.7重
量%のMnと、0.03重量%のPと、0.07重量%
のSと、0.58重量%のCrと、1.45重量%のN
iと、0.03重量%のBと、0.58重量%のCu
と、残部にFeを含むものである。このバルブガイドの
ロックウェル硬さHRBは105であって、炭素当量は
3.88である。このバルブガイドは、図3の100倍
に拡大された写真に示すように、析出黒鉛が均一に無方
向に配列され、その黒鉛片の大きさは長さ5〜40mm
の範囲に形成された。実施例2のバルブガイドを2%ナ
イタール腐食液に浸漬してエッチングした後直ちに取り
出した。そのエッチング後の表面を550倍に拡大した
写真を図4に示す。この写真により析出硬化物が有効に
その表面に出現していることがわかる。
<Example 2> A valve guide having the same shape and the same size as in Example 1 was produced by changing the chemical composition of the guide material and performing machining. As a chemical component of the valve guide material,
3.2% by weight C, 2.0% by weight Si, 0.7% by weight Mn, 0.03% by weight P, 0.07% by weight
Of S, 0.58% by weight of Cr, and 1.45% by weight of N
i, 0.03% by weight of B, and 0.58% by weight of Cu
And the balance contains Fe. The Rockwell hardness HR B of this valve guide is 105 and the carbon equivalent is 3.88. As shown in the photograph enlarged by 100 times in FIG. 3, this valve guide has deposited graphite uniformly arranged in a non-directional manner, and the size of the graphite piece is 5 to 40 mm in length.
Formed in the range. The valve guide of Example 2 was immersed in a 2% nital etching solution and immediately removed after etching. FIG. 4 shows a photograph in which the surface after the etching is magnified 550 times. From this photograph, it can be seen that the precipitation hardened material has effectively appeared on the surface.

【0014】<比較例1>従来のガイド材を機械加工す
ることにより実施例1と同形同大のバルブガイドを作製
した。従来のバルブガイド材の化学成分として、3.3
5重量%のCと、1.85重量%のSiと、0.7重量
%のMnと、0.25重量%のPと、0.03重量%の
Sと、0.05重量%のBと、残部にFeを含むもので
ある。このバルブガイドのロックウェル硬さHRBは1
00であって、炭素当量は4.05である。このバルブ
ガイドは、図5の100倍に拡大された写真に示すよう
に、析出黒鉛は実施例1及び2に比較して少なく、黒鉛
片の大きさも長さ5〜20mmの範囲で短く形成され
た。比較例1のバルブガイドを2%ナイタール腐食液に
浸漬してエッチングした後直ちに取り出した。そのエッ
チング後の表面を550倍に拡大した写真を図6に示
す。この写真により析出硬化物が少ないことがわかる。
Comparative Example 1 A conventional guide member was machined to produce a valve guide of the same shape and size as in Example 1. 3.3 as a chemical component of the conventional valve guide material
5% by weight of C, 1.85% by weight of Si, 0.7% by weight of Mn, 0.25% by weight of P, 0.03% by weight of S and 0.05% by weight of B And the balance contains Fe. Rockwell hardness HR B of this valve guide is 1
00 and the carbon equivalent is 4.05. In this valve guide, as shown in the photograph magnified 100 times in FIG. 5, the amount of precipitated graphite is smaller than that in Examples 1 and 2, and the size of graphite flakes is formed shorter in the range of 5 to 20 mm in length. Was. The valve guide of Comparative Example 1 was immersed in a 2% nital etching solution and immediately removed after etching. FIG. 6 shows a photograph of the etched surface magnified 550 times. This photograph shows that the amount of the precipitation hardened material is small.

【0015】<比較試験と評価>図7に示す摩耗試験装
置20を用いて実施例1、実施例2及び比較例1のバル
ブガイド16を使用した場合のバルブ26の摩耗試験を
行った。この装置20は、机21上の基台22に垂直板
23を立設し、垂直板23にバルブガイド16を水平に
装着する孔24aが形成された装着部材24が設けられ
る。孔24aには被評価物であるバルブガイド16が装
着できるようになっており、バルブガイドの孔16aに
は外側からバルブ26が挿入される。挿入されてバルブ
ガイド16を貫通したバルブの軸部26aには一端が装
着部材24に係止するバルブスプリング27が嵌入さ
れ、軸部16aの先端にはバルブスプリング27の他端
が係止するリテーナ28が固着される。リテーナ28の
背面には偏心カム29の周面が当接し、偏心カム29は
図示しない駆動モータにより回転するように構成され
る。この装置20では、バルブスプリング27がリテー
ナ28の背面を常に偏心カム29の周面に当接するよう
に付勢するので、偏心カム29の実線矢印で示すような
回転により、リテーナ28介してバルブ26がバルブガ
イド16の孔16aを往復動するように構成される。バ
ルブ26には下方から500℃に加熱された空気が図の
矢印Aで示すように吹き付けられ、バルブ26が加熱さ
れるように構成される。
<Comparison Test and Evaluation> Using the wear test apparatus 20 shown in FIG. 7, a wear test was performed on the valve 26 when the valve guides 16 of Examples 1, 2 and Comparative Example 1 were used. In this apparatus 20, a vertical plate 23 is erected on a base 22 on a desk 21, and a mounting member 24 having a hole 24a for horizontally mounting the valve guide 16 is formed on the vertical plate 23. The valve guide 16 to be evaluated can be mounted in the hole 24a, and the valve 26 is inserted from the outside into the hole 16a of the valve guide. A valve spring 27 whose one end is locked to the mounting member 24 is fitted into a shaft 26a of the valve that has been inserted and penetrated through the valve guide 16, and a retainer that locks the other end of the valve spring 27 to the tip of the shaft 16a. 28 is fixed. A peripheral surface of an eccentric cam 29 is in contact with the back surface of the retainer 28, and the eccentric cam 29 is configured to be rotated by a drive motor (not shown). In this device 20, since the valve spring 27 always urges the back surface of the retainer 28 so as to abut the peripheral surface of the eccentric cam 29, the rotation of the eccentric cam 29 as indicated by the solid line arrow causes the valve 26 to pass through the retainer 28. Is configured to reciprocate through a hole 16 a of the valve guide 16. Air heated to 500 ° C. is blown from below onto the valve 26 as shown by an arrow A in the figure, and the valve 26 is heated.

【0016】試験は供試品である実施例1、実施例2及
び比較例1のバルブガイド16をそれぞれ装着部材24
に装着し、バルブ26をその孔に所定量往復動させた後
のバルブ26の軸部26aの摩耗量を測定することによ
り行う。試験に使用するバルブ26は鉄からなる合金に
より作られ、その軸部の当初の直径は10mmである。
偏心カム29は直径119mmであって、カムが1回転
することによりバルブ26は1往復してその移動距離が
13mmになるように構成される。カム29は1100
回転/分で回転し、バルブ26の移動距離が3、5、1
0×103m摺動した時点でそれぞれの摩耗量を測定し
た。摩耗量は摺動後のバルブの軸部26aの直径と当初
の直径とを比較して、その直径差を摩耗量として示し
た。その結果を図8に示す。
In the test, the valve guides 16 of Examples 1, 2 and Comparative Example 1, which are test samples, were mounted on the mounting members 24, respectively.
And the amount of wear of the shaft portion 26a of the valve 26 after the valve 26 is reciprocated in the hole by a predetermined amount. The valve 26 used for the test is made of an alloy made of iron, and its shaft has an initial diameter of 10 mm.
The eccentric cam 29 has a diameter of 119 mm, and the valve 26 is reciprocated once by one rotation of the cam, so that the moving distance thereof is 13 mm. Cam 29 is 1100
The valve 26 rotates at a rate of rotation / minute, and the moving distance of the valve 26 is 3, 5, 1
The amount of wear was measured at the time of sliding of 0 × 10 3 m. The amount of abrasion was represented by comparing the diameter of the shaft portion 26a of the valve after sliding with the initial diameter, and expressing the difference between the diameters as the amount of abrasion. FIG. 8 shows the result.

【0017】図8から明らかなように、実施例1及び実
施例2のバルブガイド16では従来品である比較例1の
バルブガイドに比較してバルブ26の摩耗量が顕著に少
ないことがわかる。これはガイド材に炭化ボロン(B3
C)、リン化鉄(Fe3P)及び炭化クロム(Cr3C)
の固い物質が部分的に析出したことに起因する高温下に
おける摩擦係数の減少によるものと考えられる。
As is apparent from FIG. 8, the amount of wear of the valve 26 in the valve guides 16 of the first and second embodiments is significantly smaller than that of the valve guide of the comparative example 1 which is a conventional product. This is because boron carbide (B 3
C), iron phosphide (Fe 3 P) and chromium carbide (Cr 3 C)
This is considered to be due to a decrease in the friction coefficient at a high temperature due to the partial precipitation of the hard material.

【0018】[0018]

【発明の効果】以上述べたように、本発明によれば、高
熱部品摺動ガイド材が化学成分として、3.5〜4.1
重量%のCと、1.8〜2.4重量%のSiと、0.6
〜1.0重量%のMnと、0.3〜0.7重量%のP
と、0.1重量%以下のSと、0.6〜1.2重量%の
Crと、1.0〜1.5重量%のNiと、0.03〜
0.10重量%のBと、0.3〜0.6重量%のCu
と、残部にFeを含むか、或いは、合金鋳鉄の化学成分
が、2.8〜3.4重量%のCと、1.8〜2.4重量
%のSiと、0.4〜0.8重量%のMnと、0.2〜
0.5重量%のPと、0.1重量%以下のSと、0.3
〜0.8重量%のCrと、1.0〜1.5重量%のNi
と、0.03〜0.10重量%のBと、0.3〜0.6
重量%のCuと、残部にFeを含むことにより、ガイド
材に炭化ボロン(B3C)、リン化鉄(Fe3P)及び炭
化クロム(Cr3C)の固い物質が部分的に析出させる
ことができる。この結果、高熱部品と高熱部品摺動ガイ
ド材との高温下における摩擦係数の上昇を防止して高温
に耐え得る高熱部品摺動ガイド材を得ることができる。
As described above, according to the present invention, the sliding guide material having a high heat component has a chemical composition of 3.5 to 4.1.
Wt. C, 1.8-2.4 wt.% Si, 0.6 wt.
-1.0 wt% Mn and 0.3-0.7 wt% P
0.1% by weight or less, 0.6% to 1.2% by weight of Cr, 1.0% to 1.5% by weight of Ni, and 0.03% to
0.10 wt% B and 0.3-0.6 wt% Cu
And the balance contains Fe or the chemical composition of the alloy cast iron is 2.8 to 3.4% by weight of C, 1.8 to 2.4% by weight of Si, and 0.4 to 0. 8% by weight of Mn, 0.2 to
0.5% by weight of P, 0.1% by weight or less of S, 0.3% by weight
0.8% by weight of Cr and 1.0% to 1.5% by weight of Ni
And 0.03 to 0.10% by weight of B, and 0.3 to 0.6.
By containing Cu by weight and Fe in the balance, hard materials such as boron carbide (B 3 C), iron phosphide (Fe 3 P) and chromium carbide (Cr 3 C) are partially deposited on the guide material. be able to. As a result, it is possible to obtain a high heat component sliding guide material that can withstand high temperatures by preventing an increase in the coefficient of friction between the high heat component and the high heat component sliding guide material at high temperatures.

【0019】また、炭素当量を4.1〜5.1の範囲に
すれば、ガイド材内部に部分的に固い物質を有効に析出
させることができ、かつ高熱部品摺動ガイド材の切削加
工性を低下させることがない。更に、ロックウェル硬さ
HRBが94〜103であって、析出黒鉛が均一又はバ
ラ状に無方向に配列しかつその黒鉛片の大きさが100
倍の倍率で長さ6.3〜25.4mmの範囲にあり、炭
化ボロン、リン化鉄及び炭化クロムからなる群より選ば
れた1種又は2種以上の析出硬化物が5〜10重量%含
有すれば、耐摩耗性及び焼き付きを有効に防止するうえ
での析出黒鉛の形状、大きさ及び析出量を得ることがで
き、高温に十分耐え得る高熱部品摺動ガイド材を得るこ
とができる。
Further, when the carbon equivalent is in the range of 4.1 to 5.1, a hard substance can be effectively deposited partially in the guide material, and the cutting workability of the sliding guide material for high heat components can be improved. Is not reduced. Further, Rockwell hardness HR B is a 94 to 103, the size of the precipitated graphite arranged in a non-oriented homogenous or rose-like and the graphite piece 100
One or two or more precipitation hardened materials selected from the group consisting of boron carbide, iron phosphide, and chromium carbide are in a range of 6.3 to 25.4 mm in length at a magnification of 2 to 5% by weight. If it is contained, the shape, size, and amount of precipitated graphite for effectively preventing wear resistance and seizure can be obtained, and a high-temperature component sliding guide material that can sufficiently withstand high temperatures can be obtained.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施例1のエッチング前のガイド材の
表面を100倍に拡大した金属組織を示す顕微鏡写真
図。
FIG. 1 is a photomicrograph showing a metallographic structure of a guide material before etching according to Example 1 of the present invention, which is enlarged by 100 times.

【図2】実施例1のエッチング後のガイド材の表面を5
50倍に拡大した金属組織を示す顕微鏡写真図。
FIG. 2 shows the surface of the guide material after etching of Example 1 as 5
The microscope photograph figure which shows the metal structure expanded 50 times.

【図3】実施例2のエッチング前のガイド材の表面を1
00倍に拡大した金属組織を示す顕微鏡写真図。
FIG. 3 shows the surface of the guide member before etching in Example 2 as 1
FIG. 3 is a micrograph showing a metal structure enlarged to a magnification of 00 times.

【図4】実施例2のエッチング後のガイド材の表面を5
50倍に拡大した金属組織を示す顕微鏡写真図。
FIG. 4 shows the surface of the guide material after etching of Example 2 as 5
The microscope photograph figure which shows the metal structure expanded 50 times.

【図5】比較例1のエッチング前のガイド材の表面を1
00倍に拡大した金属組織を示す顕微鏡写真図。
FIG. 5 shows the surface of the guide member before etching in Comparative Example 1 as 1
FIG. 3 is a micrograph showing a metal structure enlarged to a magnification of 00 times.

【図6】比較例1のエッチング後のガイド材の表面を5
50倍に拡大した金属組織を示す顕微鏡写真図。
FIG. 6 shows the surface of the guide material after etching of Comparative Example 1 as 5
The microscope photograph figure which shows the metal structure expanded 50 times.

【図7】バルブ摩耗試験装置の構成図。FIG. 7 is a configuration diagram of a valve wear test device.

【図8】上記試験装置により実施例1及び実施例2のバ
ルブガイドと比較例1のバルブガイドを試験した後のバ
ルブのそれぞれの摩耗量を示す図。
FIG. 8 is a view showing the respective wear amounts of the valves after the valve guides of Example 1 and Example 2 and the valve guide of Comparative Example 1 were tested by the test apparatus.

【図9】バルブガイドが使用されている状態を示す断面
図。
FIG. 9 is a sectional view showing a state where the valve guide is used.

【符号の説明】[Explanation of symbols]

16 バルブガイド 16 Valve guide

─────────────────────────────────────────────────────
────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成8年9月6日[Submission date] September 6, 1996

【手続補正1】[Procedure amendment 1]

【補正対象書類名】図面[Document name to be amended] Drawing

【補正対象項目名】図1[Correction target item name] Fig. 1

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【図1】 FIG.

【手続補正2】[Procedure amendment 2]

【補正対象書類名】図面[Document name to be amended] Drawing

【補正対象項目名】図2[Correction target item name] Figure 2

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【図2】 FIG. 2

【手続補正3】[Procedure amendment 3]

【補正対象書類名】図面[Document name to be amended] Drawing

【補正対象項目名】図3[Correction target item name] Figure 3

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【図3】 FIG. 3

【手続補正4】[Procedure amendment 4]

【補正対象書類名】図面[Document name to be amended] Drawing

【補正対象項目名】図4[Correction target item name] Fig. 4

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【図4】 FIG. 4

【手続補正5】[Procedure amendment 5]

【補正対象書類名】図面[Document name to be amended] Drawing

【補正対象項目名】図5[Correction target item name] Fig. 5

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【図5】 FIG. 5

【手続補正6】[Procedure amendment 6]

【補正対象書類名】図面[Document name to be amended] Drawing

【補正対象項目名】図6[Correction target item name] Fig. 6

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【図6】 ─────────────────────────────────────────────────────
FIG. 6 ────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成8年9月18日[Submission date] September 18, 1996

【手続補正1】[Procedure amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】請求項4[Correction target item name] Claim 4

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【手続補正2】[Procedure amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0008[Correction target item name] 0008

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0008】請求項4に係る発明は、請求項ないし3い
ずれか記載の発明であって、ロックウェル硬さがHRB
94〜103であって、析出黒鉛が均一又はバラ状に無
方向に配列しかつその黒鉛片の大きさが100倍の倍率
で長さ6.3〜25.4mmの範囲にあり、炭化ボロ
ン、リン化鉄及び炭化クロムからなる群より選ばれた1
種又は2種以上の析出硬化物が5〜10重量%析出する
高熱部品摺動ガイド材である。この請求項4に係る高熱
部品摺動ガイド材では、耐摩耗性及び焼き付きを有効に
防止するうえでの析出黒鉛の形状、大きさ及び析出量を
得ることができる。
The invention according to claim 4 is the invention according to any one of claims 3 to 3, wherein the Rockwell hardness is HRB.
94 to 103, in which the precipitated graphite is arranged in a uniform or loose manner in a non-directional manner, and the size of the graphite flakes is in the range of 6.3 to 25.4 mm at a magnification of 100 times, and boron carbide, 1 selected from the group consisting of iron phosphide and chromium carbide
It is a high heat component sliding guide material on which 5 to 10% by weight of a kind or two or more kinds of precipitation hardened substances are precipitated . With the high heat component sliding guide material according to the fourth aspect, it is possible to obtain the shape, size, and amount of precipitated graphite for effectively preventing wear resistance and seizure.

【手続補正3】[Procedure amendment 3]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0010[Correction target item name] 0010

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0010】上述した化学成分によりガイド材に炭化ボ
ロン(B3C)、リン化鉄(Fe3P)及び炭化クロム
(Cr3C)の固い物質が部分的に析出する。この場合
のガイド材の炭素当量は4.1〜5.1であることが好
ましい。即ち、珪素(Si)とリン(P)を炭素量に換
算して実炭素量に加えた全炭素量が4.1〜5.1の範
囲内にあることが好ましい。また、このような化学成分
の合金のロックウェル硬さがHRB94〜103であっ
て、析出黒鉛が均一又はバラ状に無方向に配列している
ことが好ましい。また、その黒鉛片の大きさは100倍
の倍率で長さ6.3〜25.4mmの範囲にあり、析出
硬化物が5〜10重量%析出することが更に好ましい。
上記黒鉛の形状はASTM規格のA(均一分布・無方向
配列)又はB(バラ状分布・無方向配列)に相当し、そ
の黒鉛片の大きさはASTM規格のNo.4(100倍
の倍率で長さ25.4〜12.7mm)及びNo.5
(100倍の倍率で長さ12.7〜6.3mm)に相当
する。このような化学成分を有する高熱部品摺動ガイド
材を機械加工することによりバルブガイドを作成する
と、作成されたバルブガイドは高熱部品の摺動面である
孔の内面に部分的に固い物質が析出する。
Due to the above-mentioned chemical components, hard substances such as boron carbide (B 3 C), iron phosphide (Fe 3 P) and chromium carbide (Cr 3 C) are partially deposited on the guide material. In this case, the guide member preferably has a carbon equivalent of 4.1 to 5.1. That is, it is preferable that the total carbon amount obtained by converting silicon (Si) and phosphorus (P) into the carbon amount and adding it to the actual carbon amount is within the range of 4.1 to 5.1. Further, it is preferable that the Rockwell hardness of the alloy having such a chemical component is HRB 94 to 103, and the precipitated graphite is uniformly or non-uniformly arranged in a non-directional manner. Further, the size of the graphite flakes is in the range of 6.3 to 25.4 mm in length at a magnification of 100 times, and it is more preferable that the precipitation hardened material precipitates in 5 to 10% by weight.
The shape of the graphite corresponds to A (uniform distribution / non-directional arrangement) or B (loose distribution / non-directional arrangement) of the ASTM standard. No. 4 (length: 25.4 to 12.7 mm at 100 times magnification) and No. 4 5
(12.7 to 6.3 mm in length at a magnification of 100 times). When a valve guide is created by machining a high-temperature component sliding guide material having such a chemical component, a hard substance is partially deposited on the inner surface of a hole, which is a sliding surface of the high-temperature component, in the created valve guide. I do.

【手続補正4】[Procedure amendment 4]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0012[Correction target item name] 0012

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0012】機械加工には旋盤を使用し、バルブの摺動
面である孔16aの内面は表面仕上げを行った。このバ
ルブガイド16のロックウェル硬さはHRB102であ
って、炭素当量は4.66である。このバルブガイド1
6は、図1の100倍に拡大された写真に示すように、
析出黒鉛が均一に無方向に配列され、その黒鉛片の大き
さは長さ5〜40mmの範囲に形成された。なお、本実
施例1のバルブガイド16の結晶粒界を明瞭に露出させ
るために、このバルブガイド16を2%ナイタール腐食
液(2%濃硝酸アルコール溶液)に浸漬してエッチング
した後直ちに取り出した。そのエッチング後の表面を5
50倍に拡大した写真を図2に示す。この写真により析
出硬化物が有効にその表面に出現していることがわか
る。
A lathe was used for machining, and the inner surface of the hole 16a, which is the sliding surface of the valve, was finished. The Rockwell hardness of this valve guide 16 is HRB 102 and the carbon equivalent is 4.66. This valve guide 1
6, as shown in the photograph magnified 100 times in FIG.
Precipitated graphite was uniformly arranged in the non-direction, and the size of the graphite flakes was formed in the range of 5 to 40 mm in length. In order to clearly expose the crystal grain boundaries of the valve guide 16 of the first embodiment, the valve guide 16 was immersed in a 2% nital etching solution (2% concentrated nitric acid alcohol solution), etched, and immediately taken out. . The surface after etching is 5
FIG. 2 shows a photograph magnified 50 times. From this photograph, it can be seen that the precipitation hardened material has effectively appeared on the surface.

【手続補正5】[Procedure amendment 5]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0013[Correction target item name] 0013

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0013】<実施例2>ガイド材の化学成分を変更し
て機械加工することにより実施例1と同形同大のバルブ
ガイドを作製した。バルブガイド材の化学成分として、
3.2重量%のCと、2.0重量%のSiと、0.7重
量%のMnと、0.03重量%のPと、0.07重量%
のSと、0.58重量%のCrと、1.45重量%のN
iと、0.03重量%のBと、0.58重量%のCu
と、残部にFeを含むものである。このバルブガイドの
ロックウェル硬さはHRB105であって、炭素当量は
3.88である。このバルブガイドは、図3の100倍
に拡大された写真に示すように、析出黒鉛が均一に無方
向に配列され、その黒鉛片の大きさは長さ5〜40mm
の範囲に形成された。実施例2のバルブガイドを2%ナ
イタール腐食液に浸漬してエッチングした後直ちに取り
出した。そのエッチング後の表面を550倍に拡大した
写真を図4に示す。この写真により析出硬化物が有効に
その表面に出現していることがわかる。
<Example 2> A valve guide having the same shape and the same size as in Example 1 was produced by changing the chemical composition of the guide material and performing machining. As a chemical component of the valve guide material,
3.2% by weight C, 2.0% by weight Si, 0.7% by weight Mn, 0.03% by weight P, 0.07% by weight
Of S, 0.58% by weight of Cr, and 1.45% by weight of N
i, 0.03% by weight of B, and 0.58% by weight of Cu
And the balance contains Fe. The Rockwell hardness of this valve guide is HRB 105 and the carbon equivalent is 3.88. As shown in the photograph enlarged by 100 times in FIG. 3, this valve guide has deposited graphite uniformly arranged in a non-directional manner, and the size of the graphite piece is 5 to 40 mm in length.
Formed in the range. The valve guide of Example 2 was immersed in a 2% nital etching solution and immediately removed after etching. FIG. 4 shows a photograph in which the surface after the etching is magnified 550 times. From this photograph, it can be seen that the precipitation hardened material has effectively appeared on the surface.

【手続補正6】[Procedure amendment 6]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0014[Correction target item name] 0014

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0014】<比較例1>従来のガイド材を機械加工す
ることにより実施例1と同形同大のバルブガイドを作製
した。従来のバルブガイド材の化学成分として、3.3
5重量%のCと、1.85重量%のSiと、0.7重量
%のMnと、0.25重量%のPと、0.03重量%の
Sと、0.05重量%のBと、残部にFeを含むもので
ある。このバルブガイドのロックウェル硬さはHRB
00であって、炭素当量は4.05である。このバルブ
ガイドは、図5の100倍に拡大された写真に示すよう
に、析出黒鉛は実施例1及び2に比較して少なく、黒鉛
片の大きさも長さ5〜20mmの範囲で短く形成され
た。比較例1のバルブガイドを2%ナイタール腐食液に
浸漬してエッチングした後直ちに取り出した。そのエッ
チング後の表面を550倍に拡大した写真を図6に示
す。この写真により析出硬化物が少ないことがわかる。
Comparative Example 1 A conventional guide member was machined to produce a valve guide of the same shape and size as in Example 1. 3.3 as a chemical component of the conventional valve guide material
5% by weight of C, 1.85% by weight of Si, 0.7% by weight of Mn, 0.25% by weight of P, 0.03% by weight of S and 0.05% by weight of B And the balance contains Fe. Rockwell hardness of this valve guide is HRB 1
00 and the carbon equivalent is 4.05. In this valve guide, as shown in the photograph magnified 100 times in FIG. 5, the amount of precipitated graphite is smaller than that in Examples 1 and 2, and the size of graphite flakes is formed shorter in the range of 5 to 20 mm in length. Was. The valve guide of Comparative Example 1 was immersed in a 2% nital etching solution and immediately removed after etching. FIG. 6 shows a photograph of the etched surface magnified 550 times. This photograph shows that the amount of the precipitation hardened material is small.

【手続補正7】[Procedure amendment 7]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0019[Correction target item name] 0019

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0019】また、炭素当量を4.1〜5.1の範囲に
すれば、ガイド材内部に部分的に固い物質を有効に析出
させることができ、かつ高熱部品摺動ガイド材の切削加
工性を低下させることがない。更に、ロックウェル硬さ
がHRB94〜103であって、析出黒鉛が均一又はバ
ラ状に無方向に配列しかつその黒鉛片の大きさが100
倍の倍率で長さ6.3〜25.4mmの範囲にあり、炭
化ボロン、リン化鉄及び炭化クロムからなる群より選ば
れた1種又は2種以上の析出硬化物が5〜10重量%
すれば、耐摩耗性及び焼き付きを有効に防止するうえ
での析出黒鉛の形状、大きさ及び析出量を得ることがで
き、高温に十分耐え得る高熱部品摺動ガイド材を得るこ
とができる。
Further, when the carbon equivalent is in the range of 4.1 to 5.1, a hard substance can be effectively deposited partially in the guide material, and the cutting workability of the sliding guide material for high heat components can be improved. Is not reduced. In addition, Rockwell hardness
There a HRB ninety-four to one hundred and three, the size of the precipitated graphite arranged in a non-oriented homogenous or rose-like and the graphite piece 100
One or two or more precipitation hardened materials selected from the group consisting of boron carbide, iron phosphide, and chromium carbide are in a range of 6.3 to 25.4 mm in length at a magnification of 2 to 5% by weight. Analysis
If it comes out , it is possible to obtain the shape, size, and amount of precipitated graphite for effectively preventing wear resistance and seizure, and it is possible to obtain a high-temperature component sliding guide material that can sufficiently withstand high temperatures.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 化学成分として、3.5〜4.1重量%
のCと、1.8〜2.4重量%のSiと、0.6〜1.
0重量%のMnと、0.3〜0.7重量%のPと、0.
1重量%以下のSと、0.6〜1.2重量%のCrと、
1.0〜1.5重量%のNiと、0.03〜0.10重
量%のBと、0.3〜0.6重量%のCuと、残部にF
eを含む高熱部品摺動ガイド材。
1. As a chemical component, 3.5 to 4.1% by weight
C, 1.8 to 2.4% by weight of Si, and 0.6 to 1.
0 wt% Mn, 0.3-0.7 wt% P,
1% by weight or less of S, 0.6 to 1.2% by weight of Cr,
1.0 to 1.5% by weight of Ni, 0.03 to 0.10% by weight of B, 0.3 to 0.6% by weight of Cu, and the balance of F
High heat parts sliding guide material containing e.
【請求項2】 化学成分として、2.8〜3.4重量%
のCと、1.8〜2.4重量%のSiと、0.4〜0.
8重量%のMnと、0.2〜0.5重量%のPと、0.
1重量%以下のSと、0.3〜0.8重量%のCrと、
1.0〜1.5重量%のNiと、0.03〜0.10重
量%のBと、0.3〜0.6重量%のCuと、残部にF
eを含む高熱部品摺動ガイド材。
2. 2.8 to 3.4% by weight as a chemical component
C, 1.8 to 2.4% by weight of Si, and 0.4 to 0.4% by weight.
8% by weight of Mn, 0.2-0.5% by weight of P;
1% by weight or less of S, 0.3-0.8% by weight of Cr,
1.0 to 1.5% by weight of Ni, 0.03 to 0.10% by weight of B, 0.3 to 0.6% by weight of Cu, and the balance of F
High heat parts sliding guide material containing e.
【請求項3】 炭素当量が4.1〜5.1である請求項
1又は2記載の高熱部品摺動ガイド材。
3. The sliding guide according to claim 1, wherein the carbon equivalent is 4.1 to 5.1.
【請求項4】 ロックウェル硬さHRBが94〜103
であって、析出黒鉛が均一又はバラ状に無方向に配列し
かつその黒鉛片の大きさが100倍の倍率で長さ6.3
〜25.4mmの範囲にあり、炭化ボロン、リン化鉄及
び炭化クロムからなる群より選ばれた1種又は2種以上
の析出硬化物が5〜10重量%含有する請求項1ないし
3いずれか記載の高熱部品摺動ガイド材。
4. A Rockwell hardness HR B of 94 to 103.
Wherein the precipitated graphite is uniformly or non-uniformly arranged in a non-directional manner, and the size of the graphite piece is 6.3 at a magnification of 100 times and a length of 6.3.
4 to 25.4 mm, and contains 5 to 10% by weight of one or more precipitation hardened materials selected from the group consisting of boron carbide, iron phosphide and chromium carbide. The sliding guide material of the high heat component described.
JP23567396A 1996-09-06 1996-09-06 High heat component sliding guide material Expired - Fee Related JP3901253B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23567396A JP3901253B2 (en) 1996-09-06 1996-09-06 High heat component sliding guide material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23567396A JP3901253B2 (en) 1996-09-06 1996-09-06 High heat component sliding guide material

Publications (2)

Publication Number Publication Date
JPH1081934A true JPH1081934A (en) 1998-03-31
JP3901253B2 JP3901253B2 (en) 2007-04-04

Family

ID=16989514

Family Applications (1)

Application Number Title Priority Date Filing Date
JP23567396A Expired - Fee Related JP3901253B2 (en) 1996-09-06 1996-09-06 High heat component sliding guide material

Country Status (1)

Country Link
JP (1) JP3901253B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007056967A1 (en) * 2005-11-17 2007-05-24 Federal-Mogul Burscheid Gmbh Process for producing sliding rings and/or mating rings of a sliding-ring seal by means of laser hardening
WO2013073821A1 (en) 2011-11-14 2013-05-23 Lg Electronics Inc. Alloy cast iron and manufacturing method of rolling piston using the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007056967A1 (en) * 2005-11-17 2007-05-24 Federal-Mogul Burscheid Gmbh Process for producing sliding rings and/or mating rings of a sliding-ring seal by means of laser hardening
WO2013073821A1 (en) 2011-11-14 2013-05-23 Lg Electronics Inc. Alloy cast iron and manufacturing method of rolling piston using the same
EP2780487A4 (en) * 2011-11-14 2015-08-05 Lg Electronics Inc Alloy cast iron and manufacturing method of rolling piston using the same

Also Published As

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